TY  - JOUR
U1  - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed)
A1  - Lincke, Jörg
A1  - Lässig, Daniel
A1  - Stein, Karolin
A1  - Möllmer, Jens
A1  - Kuttatheyil, Anusree Viswanath
A1  - Reichenbach, Christian
A1  - Möller, Andreas
A1  - Staudt, Reiner
A1  - Kalies, Grit
A1  - Bertmer, Marko
A1  - Krautscheid, Harald
T1  - A novel Zn4O-based triazolyl benzoate MOF: synthesis, crystal structure, adsorption properties and solid state 13C NMR investigations
JF  - Dalton Transactions
N2  - The newly synthesized Zn4O-based MOF 3∞[Zn4(μ4-O){(Metrz-pba)2mPh}3]·8 DMF (1·8 DMF) of rare tungsten carbide (acs) topology exhibits a porosity of 43% and remarkably high thermal stability up to 430 °C. Single crystal X-ray structure analyses could be performed using as-synthesized as well as desolvated crystals. Besides the solvothermal synthesis of single crystals a scalable synthesis of microcrystalline material of the MOF is reported. Combined TG-MS and solid state NMR measurements reveal the presence of mobile DMF molecules in the pore system of the framework. Adsorption measurements confirm that the pore structure is fully accessible for nitrogen molecules at 77 K. The adsorptive pore volume of 0.41 cm3 g−1 correlates well with the pore volume of 0.43 cm3 g−1 estimated from the single crystal structure.
KW  - Adsorption
KW  - Metallorganisches Netzwerk
Y1  - 2012
UR  - https://www.researchgate.net/publication/51791768
SN  - 1477-9226
SS  - 1477-9226
U6  - https://doi.org/10.1039/C1DT11431J
DO  - https://doi.org/10.1039/C1DT11431J
PM  - 22075969
VL  - 41
IS  - 3
SP  - 817
EP  - 824
CY  - Cambridge
ER  -