@article{KettnerWorchMoellmeretal.2013, author = {Florian Kettner and Christian Worch and Jens M{\"o}llmer and Roger Gl{\"a}ser and Reiner Staudt and Harald Krautscheid}, title = {Synthesis, Crystal Structure and Catalytic Behavior of Homo- and Heteronuclear Coordination Polymers [M(tdc)(bpy)] (M2+ = Fe2+, Co2+, Zn2+, Cd2+; tdc2– = 2,5-thiophenedicarboxylate)}, series = {Inorganic Chemistry}, volume = {52}, number = {15}, organization = {American Chemical Society}, issn = {0020-1669}, doi = {10.1021/ic400857s}, pages = {8738 -- 8742}, year = {2013}, abstract = {A series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. Single crystal X-ray structure determination was successfully performed for all compounds after the phase transition. In the zinc-based coordination polymer, various amounts of a second type of metal ions such as Co(2+) or Fe(2+) could be incorporated. Furthermore, the catalytic behavior of the homo- and heteronuclear 3D coordination polymers in an oxidation model reaction was investigated.}, language = {en} }