TY  - JOUR
U1  - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed)
A1  - Kettner, Florian
A1  - Worch, Christian
A1  - Möllmer, Jens
A1  - Gläser, Roger
A1  - Staudt, Reiner
A1  - Krautscheid, Harald
T1  - Synthesis, Crystal Structure and Catalytic Behavior of Homo- and Heteronuclear Coordination Polymers [M(tdc)(bpy)] (M2+ = Fe2+, Co2+, Zn2+, Cd2+; tdc2– = 2,5-thiophenedicarboxylate)
JF  - Inorganic Chemistry
N2  - A series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. Single crystal X-ray structure determination was successfully performed for all compounds after the phase transition. In the zinc-based coordination polymer, various amounts of a second type of metal ions such as Co(2+) or Fe(2+) could be incorporated. Furthermore, the catalytic behavior of the homo- and heteronuclear 3D coordination polymers in an oxidation model reaction was investigated.
KW  - Polymere
KW  - Synthese
KW  - Kristallstruktur
KW  - Katalyse
Y1  - 2013
SN  - 0020-1669
SS  - 0020-1669
U6  - https://doi.org/10.1021/ic400857s
DO  - https://doi.org/10.1021/ic400857s
PM  - 23865443
VL  - 52
IS  - 15
SP  - 8738
EP  - 8742
ER  -