@article{LinckeLaessigKolbalzetal.2012,
  author    = {J{\"o}rg Lincke and Daniel L{\"a}ssig and Merten Kolbalz and Jens Bergmann and Marcel Handke and Jens M{\"o}llmer and Marcus Lange and Christian Roth and Andreas M{\"o}ller and Reiner Staudt and Harald Krautscheid},
  title     = {An Isomorphous Series of Cubic, Copper-Based Triazolyl Isophthalate MOFs: Linker Substitution and Adsorption Properties},
  series   = {Inorganic Chemistry},
  volume    = {51},
  number    = {14},
  publisher = {ACS Publications},
  organization    = {American Chemical Society},
  issn      = {0020-1669},
  doi       = {10.1021/ic3003228},
  pages     = {7579 -- 7586},
  year      = {2012},
  abstract  = {An isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compounds ∞3[Cu6(μ4-O)(μ3-OH)2(H-Metrz-ia)4][Cu(H2O)6](NO3)2·10H2O (11) and ∞3[Cu2(H-3py-trz-ia)2(H2O)3] (12Cu), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66\%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.},
  language  = {en}
}