TY  - JOUR
U1  - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed)
A1  - Lincke, Jörg
A1  - Lässig, Daniel
A1  - Kolbalz, Merten
A1  - Bergmann, Jens
A1  - Handke, Marcel
A1  - Möllmer, Jens
A1  - Lange, Marcus
A1  - Roth, Christian
A1  - Möller, Andreas
A1  - Staudt, Reiner
A1  - Krautscheid, Harald
T1  - An Isomorphous Series of Cubic, Copper-Based Triazolyl Isophthalate MOFs: Linker Substitution and Adsorption Properties
JF  - Inorganic Chemistry
N2  - An isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compounds ∞3[Cu6(μ4-O)(μ3-OH)2(H-Metrz-ia)4][Cu(H2O)6](NO3)2·10H2O (11) and ∞3[Cu2(H-3py-trz-ia)2(H2O)3] (12Cu), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.
KW  - Adsorption
KW  - Metallorganisches Netzwerk
Y1  - 2012
SN  - 0020-1669
SS  - 0020-1669
U6  - https://doi.org/10.1021/ic3003228
DO  - https://doi.org/10.1021/ic3003228
PM  - 22747641
VL  - 51
IS  - 14
SP  - 7579
EP  - 7586
PB  - ACS Publications
ER  -