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An Isomorphous Series of Cubic, Copper-Based Triazolyl Isophthalate MOFs: Linker Substitution and Adsorption Properties
- An isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compoundsAn isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compounds ∞3[Cu6(μ4-O)(μ3-OH)2(H-Metrz-ia)4][Cu(H2O)6](NO3)2·10H2O (11) and ∞3[Cu2(H-3py-trz-ia)2(H2O)3] (12Cu), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.…
Document Type: | Article (reviewed) |
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Zitierlink: | https://opus.hs-offenburg.de/3547 | Bibliografische Angaben |
Title (English): | An Isomorphous Series of Cubic, Copper-Based Triazolyl Isophthalate MOFs: Linker Substitution and Adsorption Properties |
Author: | Jörg Lincke, Daniel Lässig, Merten Kolbalz, Jens Bergmann, Marcel Handke, Jens MöllmerGND, Marcus Lange, Christian Roth, Andreas Möller, Reiner StaudtGND, Harald Krautscheid |
Date of Publication (online): | 2012/07/02 |
Creating Corporation: | American Chemical Society |
Publisher: | ACS Publications |
First Page: | 7579 |
Last Page: | 7586 |
Parent Title (English): | Inorganic Chemistry |
Volume: | 51 |
Issue: | 14 |
ISSN: | 0020-1669 |
DOI: | https://doi.org/10.1021/ic3003228 |
Language: | English | Inhaltliche Informationen |
Institutes: | Fakultät Maschinenbau und Verfahrenstechnik (M+V) |
Institutes: | Bibliografie |
GND Keyword: | Adsorption; Metallorganisches Netzwerk | Formale Angaben |
Open Access: | Closed Access |
Licence (German): | Urheberrechtlich geschützt |