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An Agglomerate Model of Lithium-Ion Battery Cathodes

  • n this work a mathematical model for describing the performance of lithium-ion battery electrodes consisting of porous active material particles is presented. The model represents an extension of the Newman-type model, accounting for the agglomerate structure of the active material particles, here Li(Ni1/3Co1/3Mn1/3)O2 (NCM) and Li(Ni1/3Co1/3Al1/3)O2 (NCA). To this goal, an additional pore spacen this work a mathematical model for describing the performance of lithium-ion battery electrodes consisting of porous active material particles is presented. The model represents an extension of the Newman-type model, accounting for the agglomerate structure of the active material particles, here Li(Ni1/3Co1/3Mn1/3)O2 (NCM) and Li(Ni1/3Co1/3Al1/3)O2 (NCA). To this goal, an additional pore space is introduced on the active material level. The space is filled with electrolyte and a charge-transfer reaction takes place at the liquid-solid interface within the porous active material particles. Volume-averaging techniques are used to derive the model equations. A local Thiele modulus is defined and provides an insight into the potentially limiting factors on the active material level. The introduction of a liquid-phase ion transport within the active material reduces the overall transport losses, while the additional active surface area within the agglomerate lowers the charge-transfer resistance. As a consequence, calculated discharge capacities are higher for particles modeled as agglomerates. This finding is more pronounced in the case of high C-ratesshow moreshow less

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Metadaten
Document Type:Article (reviewed)
Zitierlink: https://opus.hs-offenburg.de/2371
Bibliografische Angaben
Title (English):An Agglomerate Model of Lithium-Ion Battery Cathodes
Author:Sabine Lueth, Ulrich S. Sauter, Wolfgang G. BesslerStaff MemberORCiDGND
Year of Publication:2016
First Page:A210
Last Page:A222
Parent Title (English):Journal of Electrochemical Society
Volume:163
Issue:2
DOI:https://doi.org/10.1149/2.0291602jes
Language:English
Inhaltliche Informationen
Institutes:Forschung / INES - Institut für nachhaltige Energiesysteme
Fakultät Elektrotechnik und Informationstechnik (E+I) (bis 03/2019)
Institutes:Bibliografie
GND Keyword:Agglomerat; Lithiumbatterie
Formale Angaben
Licence (German):License LogoUrheberrechtlich geschützt