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Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties

  • Two closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution patternTwo closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution pattern and by choice of the metal ion.show moreshow less

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Author:Merten Kobalz, Jörg Lincke, Karolin Kobalz, Oliver Erhart, Jens Bergmann, Daniel Lässig, Marcus Lange, Jens MöllmerGND, Roger Gläser, Reiner StaudtGND, Harald Krautscheid
Year of Publication:2016
Date of first Publication:2016/03/07
Language:English
GND Keyword:Leitfähige Polymere; Raumgitter; Schaufelrad
Parent Title (English):Inorganic Chemistry
Volume:55
Issue:6
First Page:3030
Last Page:3039
Document Type:Article (reviewed)
Institutes:Hochschule Offenburg / Bibliografie
Release Date:2018/01/30
Licence (German):License LogoEs gilt das UrhG
DOI:https://doi.org/10.1021/acs.inorgchem.5b02921