Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties
- Two closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution patternTwo closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution pattern and by choice of the metal ion.…
| Author: | Merten Kobalz, Jörg Lincke, Karolin Kobalz, Oliver Erhart, Jens Bergmann, Daniel Lässig, Marcus Lange, Jens MöllmerGND, Roger Gläser, Reiner StaudtGND, Harald Krautscheid |
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| Year of Publication: | 2016 |
| Date of first Publication: | 2016/03/07 |
| Language: | English |
| GND Keyword: | Leitfähige Polymere; Raumgitter; Schaufelrad |
| Parent Title (English): | Inorganic Chemistry |
| Volume: | 55 |
| Issue: | 6 |
| First Page: | 3030 |
| Last Page: | 3039 |
| Document Type: | Article (reviewed) |
| Institutes: | Bibliografie |
| Release Date: | 2018/01/30 |
| Licence (German): |  Es gilt das UrhG |
| DOI: | https://doi.org/10.1021/acs.inorgchem.5b02921 |