Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties
- Two closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution patternTwo closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution pattern and by choice of the metal ion.…
Document Type: | Article (reviewed) |
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Zitierlink: | https://opus.hs-offenburg.de/2370 | Bibliografische Angaben |
Title (English): | Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties |
Author: | Merten Kobalz, Jörg Lincke, Karolin Kobalz, Oliver Erhart, Jens Bergmann, Daniel Lässig, Marcus Lange, Jens MöllmerGND, Roger Gläser, Reiner StaudtGND, Harald Krautscheid |
Year of Publication: | 2016 |
Date of first Publication: | 2016/03/07 |
First Page: | 3030 |
Last Page: | 3039 |
Parent Title (English): | Inorganic Chemistry |
Volume: | 55 |
Issue: | 6 |
DOI: | https://doi.org/10.1021/acs.inorgchem.5b02921 |
Language: | English | Inhaltliche Informationen |
Institutes: | Fakultät Maschinenbau und Verfahrenstechnik (M+V) |
Institutes: | Bibliografie |
GND Keyword: | Leitfähige Polymere; Raumgitter; Schaufelrad | Formale Angaben |
Licence (German): | Urheberrechtlich geschützt |