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Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties

  • Two closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution patternTwo closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution pattern and by choice of the metal ion.show moreshow less

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Metadaten
Document Type:Article (reviewed)
Zitierlink: https://opus.hs-offenburg.de/2370
Bibliografische Angaben
Title (English):Paddle Wheel Based Triazolyl Isophthalate MOFs: Impact of Linker Modification on Crystal Structure and Gas Sorption Properties
Author:Merten Kobalz, Jörg Lincke, Karolin Kobalz, Oliver Erhart, Jens Bergmann, Daniel Lässig, Marcus LangeStaff Member, Jens MöllmerStaff MemberGND, Roger Gläser, Reiner StaudtStaff MemberGND, Harald Krautscheid
Year of Publication:2016
Date of first Publication:2016/03/07
First Page:3030
Last Page:3039
Parent Title (English):Inorganic Chemistry
Volume:55
Issue:6
DOI:https://doi.org/10.1021/acs.inorgchem.5b02921
Language:English
Inhaltliche Informationen
Institutes:Fakultät Maschinenbau und Verfahrenstechnik (M+V)
Institutes:Bibliografie
GND Keyword:Leitfähige Polymere; Raumgitter; Schaufelrad
Formale Angaben
Licence (German):License LogoUrheberrechtlich geschützt