Volltext-Downloads (blau) und Frontdoor-Views (grau)
The search result changed since you submitted your search request. Documents might be displayed in a different sort order.
  • search hit 4 of 11
Back to Result List

A novel Zn4O-based triazolyl benzoate MOF: synthesis, crystal structure, adsorption properties and solid state 13C NMR investigations

  • The newly synthesized Zn4O-based MOF 3∞[Zn4(μ4-O){(Metrz-pba)2mPh}3]·8 DMF (1·8 DMF) of rare tungsten carbide (acs) topology exhibits a porosity of 43% and remarkably high thermal stability up to 430 °C. Single crystal X-ray structure analyses could be performed using as-synthesized as well as desolvated crystals. Besides the solvothermal synthesis of single crystals a scalable synthesis ofThe newly synthesized Zn4O-based MOF 3∞[Zn4(μ4-O){(Metrz-pba)2mPh}3]·8 DMF (1·8 DMF) of rare tungsten carbide (acs) topology exhibits a porosity of 43% and remarkably high thermal stability up to 430 °C. Single crystal X-ray structure analyses could be performed using as-synthesized as well as desolvated crystals. Besides the solvothermal synthesis of single crystals a scalable synthesis of microcrystalline material of the MOF is reported. Combined TG-MS and solid state NMR measurements reveal the presence of mobile DMF molecules in the pore system of the framework. Adsorption measurements confirm that the pore structure is fully accessible for nitrogen molecules at 77 K. The adsorptive pore volume of 0.41 cm3 g−1 correlates well with the pore volume of 0.43 cm3 g−1 estimated from the single crystal structure.show moreshow less

Export metadata

Additional Services

Search Google Scholar

Statistics

frontdoor_oas
Metadaten
Document Type:Article (reviewed)
Zitierlink: https://opus.hs-offenburg.de/3548
Bibliografische Angaben
Title (English):A novel Zn4O-based triazolyl benzoate MOF: synthesis, crystal structure, adsorption properties and solid state 13C NMR investigations
Author:Jörg Lincke, Daniel Lässig, Karolin Stein, Jens MöllmerStaff MemberGND, Anusree Viswanath Kuttatheyil, Christian Reichenbach, Andreas Möller, Reiner StaudtStaff MemberGND, Grit Kalies, Marko Bertmer, Harald Krautscheid
Date of Publication (online):2011/11/10
Creating Corporation:Royal Society of Chemistry
Place of publication:Cambridge
First Page:817
Last Page:824
Parent Title (English):Dalton Transactions
Volume:41
Issue:3
ISSN:1477-9226
DOI:https://doi.org/10.1039/C1DT11431J
URL:https://www.researchgate.net/publication/51791768
Language:English
Inhaltliche Informationen
Institutes:Fakultät Maschinenbau und Verfahrenstechnik (M+V)
Institutes:Bibliografie
GND Keyword:Adsorption; Metallorganisches Netzwerk
Formale Angaben
Open Access: Open Access 
Licence (German):License LogoUrheberrechtlich geschützt