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This paper describes the Sweaty II humanoid adult size robot trying to qualify for the RoboCup 2018 adult size humanoid competition. Sweaty came 2nd in RoboCup 2017 adult size league. The main characteristics of Sweaty are described in the Team Description Paper 2017. The improvements that have been made or are planned to be implemented for RoboCup 2018 are described in this paper.
Accelerated transformation of the society and industry through digi-talization, artificial intelligence and other emerging technologies has intensified the need for university graduates that are capable of rapidly finding breakthrough solutions to complex problems, and can successfully implement innovation con-cepts. However, there are only few universities making significant efforts to com-prehensively incorporate creative and systematic tools of TRIZ (theory of in-ventive problem solving) and KBI (knowledge-based innovation) into their de-gree structure. Engineering curricula offer little room for enhancing creativity and inventiveness by means of discipline‐specific subjects. Moreover, many ed-ucators mistakenly believe that students are either inherently creative, or will in-evitably obtain adequate problem-solving skills as a result of their university study. This paper discusses challenges of intelligent integration of TRIZ and KBI into university curricula. It advocates the need for development of standard guidelines and best-practice recommendations in order to facilitate sustainable education of ambitious, talented, and inventive specialists. Reflections of educa-tors that teach TRIZ and KBI to students from mechanical, electrical, process engineering, and business administration are presented.
Process engineering (PE) focuses on the design, operation, control and optimization of chemical, physical and biological processes and has applications in many industries. Process intensification (PI) is the key development approach in the modern process engineering. The theory of inventive problem solving (TRIZ) is today considered as the most comprehensive and systematically organized invention knowledge and creative thinking methodology. This paper analyses the opportunities of TRIZ application in PE and especially in combination with PI. In this context the paper outlines the major challenges for TRIZ application in PE, conceptualizes a possible TRIZ-based approach for process intensification and problem solving in PE, and defines the corresponding research agenda. It also presents the results of the original empirical innovation research in the field of solid handling in the ceramic industry, demonstrates a method for identification and prediction of contradictions and introduces the concept of the probability of contradiction occurrence. Additionally, it describes a technique of process mapping that is based on the function and multi-screen analysis of the processes. This technique is illustrated by a case study dealing with granulation process. The research work presented in this paper is a part of the European project “Intensified by Design® platform for the intensification of processes involving solids handling”.
Im Rahmen der Konstruktionsausbildung an der Hochschule Offenburg wird die Lehre im Fach Technische Dokumentation fortlaufend optimiert. In der vorliegenden Laborstudie wurde das visuelle Wahrnehmen von 34 Maschinenbaustudierenden (2w + 32m) im Alter von 19 bis 29 Jahren mithilfe der Eye-Tracking-Technik und einer Videokamera bei der Analyse einer Baugruppenzeichnung beobachtet.
In the 19th century Alexander von Humboldt explored the nature and was conceived a new vision of nature that still influences the way we understand the new world. Humboldt believed in the importance of accurate measurements and precise description of observations. His vision of nature included not only facts but also emotions.
Nowadays smart solutions will be developed by using computer technology, which will influence our relationship to nature, our handling of the complexity and diversity of nature itself and the technological influences on the society. Could we avoid a new form of “Colonialism”, when a network of super computers will create a smarter world?
Freiwillige Fachtutorien erreichen aus unterschiedlichen Gründen nicht alle Studierenden. Allein der subjektive Eindruck, dass zu wenige Ressourcen seitens der Hochschule (Übungsräume, studentische Tutoren, lückenlose Stundenplanpassung) oder der Studierenden (Zeit, Motivation) zur Verfügung stünden, führt zu Absenzen bei freiwilligen Präsenztutorien. Um die empfundenen und realen Begrenzungen dieser Veranstaltungen zu verringern, wurden für den Studiengang Maschinenbau die Musterlösungen der Übungsaufgaben Physik und Mathematik in Form von Videoclips erstellt und über die Lernplattform Moodle für alle Studierende des Semesters bereitgestellt. Die Clips beziehen sich jeweils auf eine Teilaufgabe und besitzen die Länge eines typischen Youtube-Tutorials. In etwa 5 Minuten bieten sie dem Zuschauer einen Lösungsweg zu den jeweiligen Übungsaufgaben. Die Studierenden können die Clips alternativ oder ergänzend zur Präsenzveranstaltung nutzen. Bei der Erstellung der Clips wurde auf den Einsatz von Spezialeffekten wie Animationen etc. zugunsten einer effizienten Produktion verzichtet, so dass eine einzelne Lehrperson pro Stunde etwa 10 bis 20 Minuten Videoclips aufzeichnen kann. Die Auswertung der Zugriffszahlen auf die Clip-Dateien ermöglicht eine aufgabengenaue Ermittlung der aktiven Nutzer. Im Betrag wird eine vorläufige Auswertung der Teilnehmerzahl und der Korrelation zwischen Klausurergebnis und Nutzungsgrad präsentiert.
Numerous 2,5-dimethoxy-N-benzylphenethylamines (NBOMe), carrying a variety of lipophilic substituents at the 4-position, are potent agonists at 5-hydroxytryptamine (5HT2A ) receptors and show hallucinogenic effects. The present study investigated the metabolism of 25D-NBOMe, 25E-NBOMe, and 25N-NBOMe using the microsomal model of pooled human liver microsomes (pHLM) and the microbial model of the fungi Cunninghamella elegans (C. elegans). Identification of metabolites was performed using liquid chromatography-high resolution-tandem mass spectrometry (LC-HR-MS/MS) with a quadrupole time-of-flight (QqToF) instrument. In total, 36 25D-NBOMe phase I metabolites, 26 25E-NBOMe phase I metabolites and 24 25N-NBOMe phase I metabolites were detected and identified in pHLM. Furthermore, 14 metabolites of 25D-NBOMe, 11 25E-NBOMe metabolites, and nine 25N-NBOMe metabolites could be found in C. elegans. The main biotransformation steps observed were oxidative deamination, oxidative N-dealkylation also in combination with hydroxylation, oxidative O-demethylation possibly combined with hydroxylation, oxidation of secondary alcohols, mono- and dihydroxylation, oxidation of primary alcohols, and carboxylation of primary alcohols. Additionally, oxidative di-O-demethylation for 25E-NBOMe and reduction of the aromatic nitro group and N-acetylation of the primary aromatic amine for 25N-NBOMe took place. The resulting 25N-NBOMe metabolites were unique for NBOMe compounds. For all NBOMes investigated, the corresponding 2,5-dimethoxyphenethylamine (2C-X) metabolite was detected. This study reports for the first time 25X-NBOMe N-oxide metabolites and hydroxylamine metabolites, which were identified for 25D-NBOMe and 25N-NBOMe and all three investigated NBOMes, respectively. C. elegans was capable of generating all main biotransformation steps observed in pHLM and might therefore be an interesting model for further studies of new psychoactive substances (NPS) metabolism.
Die Untersuchungen der Hochschule Offenburg zeigen, dass es durch organische Korrosionsschutzschichten im Kraftfluss von Schraubenverbindungen nicht zu einem verfrühten Abschalten der streckgrenzengesteuerten Schraubmontage kommt. Die fünf untersuchten Lacksysteme zeigten ein sehr unterschiedliches Reibverhalten, der Anzugsvorgang wurde jedoch zuverlässig bei Erreichen der Schraubenstreckgrenze beendet. Durch den ermittelten Drehmoment/Drehwinkelverlauf lässt sich das streckgrenzengesteuerte Anzugsverfahren als Analystetool einsetzen, wodurch für den jeweiligen Schraubfall auch Rückschlüsse auf anderen Anzugsverfahren getroffen werden können. Des Weiteren zeigte sich, dass Pulverlacksysteme widerstandsfähiger gegen die bei der Montage wirkenden Belastungen sind und eine Montage direkt auf Lack ermöglichen können.
Vorrichtung (2) zur Analyse von Urin, umfassend: – eine Zuführ- und Abführeinrichtung (7), welche zur Zuführung einer bestimmten Urinmenge in eine wenigstens einen Analysebereich (8) aufweisende Analysekammer (9) eines Urinteststreifens (10) und zur Abführung einer bestimmten Urinmenge aus einer wenigstens einen Analysebereich (8) aufweisenden Analysekammer (9) eines Urinteststreifens (10) eingerichtet ist, wobei die Zuführ- und Abführeinrichtung (7) wenigstens ein bewegbar gelagertes Zuführ- und/oder Abführelement (28, 29) zum Zuführen einer bestimmten Urinmenge in einen Zuführbereich (33) der Analysekammer (9) des Urinteststreifens (10) und/oder zum Abführen einer bestimmten Urinmenge aus einem Abführbereich (34) der Analysekammer (9) des Urinteststreifens (10) aufweist, und – eine Erfassungseinrichtung (11), welche zur Erfassung einer zumindest abschnittsweisen Änderung wenigstens eines optisch erfassbaren Parameters, welcher sich in Abhängigkeit der Zusammensetzung einer diesen kontaktierenden Urinmenge optisch erfassbar verändert, des oder eines entsprechenden Analysebereichs (8) des oder eines entsprechenden Urinteststreifens (10) sowie zur Erzeugung einer Erfassungsinformation, welche wenigstens einen optisch erfassten Parameter des oder eines entsprechenden Analysebereichs (8) oder eine Änderung eines solchen beschreibt, eingerichtet ist.
Hot work tools are subjected to complex thermal and mechanical loads during hot forming processes. Locally, the stresses can exceed the material’s yield strength in highly loaded areas as e.g. in small radii in die cavities. To sustain the high loads, the hot forming tools are typically made of martensitic hot work steels. While temperatures for annealing of the tool steels usually lie in the range between 400 and 600 °C, the steels may experience even higher temperatures during hot forming, resulting in softening of the material due to coarsening of strengthening particles. In this paper, a temperature dependent cyclic plasticity model for the martensitic hot work tool steel 1.2367 (X38CrMoV5-3) is presented that includes softening due to particle coarsening and that can be applied in finite-element calculations to assess the effect of softening on the thermomechanical fatigue life of hot work tools. To this end, a kinetic model for the evolution of the mean size of secondary carbides based on Ostwald ripening is coupled with a cyclic plasticity model with kinematic hardening. Mechanism-based relations are developed to describe the dependency of the mechanical properties on carbide size and temperature. The material properties of the mechanical and kinetic model are determined on the basis of tempering hardness curves as well as monotonic and cyclic tests.
In this paper, the temperature dependent cyclic mechanical properties of the martensitic hot work tool steel 1.2367 after tempering are investigated. To this end, hardness measurements as well as monotonic and cyclic tests at temperatures in the range from room temperature to 650 °C are performed on material tempered for different tempering times and temperatures. To describe the observed time and temperature dependent softening during tempering a kinetic model for the evolution of the mean size of secondary carbides based on Ostwald ripening is developed. Furthermore, mechanism-based as well as phenomenological relations for the cyclic mechanical properties of the Ramberg-Osgood model depending on carbide size and temperature are introduced. A good overall agreement of the measured and the calculated stress-strain hysteresis loops for different temperatures and heat treatments is obtained using the determined material properties of the kinetic and mechanical model.
Modelling detailed chemistry in lithium-ion batteries: Insight into performance, ageing and safety
(2018)
CONTEXT
The paper addresses the needs of medium and small businesses regarding qualification of R&D specialists in the interdisciplinary cross-industry innovation, which promises a considerable reduction of investments and R&D expenditures. The cross-industry innovation is commonly understood as identification of analogies and transfer of technologies, processes, technical solutions, working principles or business models between industrial sectors. However, engineering graduates and specialists frequently lack the advanced skills and knowledge required to run interdisciplinary innovation across the industry boundaries.
PURPOSE
The study compares the efficiency of the cross-industry innovation methods in one semester project-oriented course. It identifies the individual challenges and preferred working techniques of the students with different prior knowledge, sets of experiences, and cultural contexts, which require attention by engineering educators.
APPROACH
Two parallel one-semester courses were offered to the mechanical and process engineering students enrolled in bachelor’s and master’s degree programs at the faculty of mechanical and process engineering. The students from different years of study were working in 12 teams of 3…6 persons each on different innovation projects, spending two hours a week in the classroom and additionally on average two hours weekly on their project research. Students' feedback and self-assessments concerning gained skills, efficiency of learned tools and intermediate findings were documented, analysed, and discussed regularly along the course.
RESULTS
Analysis of numerous student projects allows to compare and to select the tools most appropriate for finding cross-industry solutions, such as thinking in analogies, web monitoring, function-oriented search, databases of technological effects and processes, special creativity techniques and others. The utilization of learned skills in practical innovation work strengthens the motivation of students and enhances their entrepreneurial competences. Suggested learning course and given recommendations help facilitate sustainable education of ambitious specialists.
CONCLUSIONS
The structured cross-industry innovation can be successfully run as a systematic process and learned in one semester course. The choice of the preferred working teqniques made by the students is affected by their prior knowledge in science, practical experience, and cultural contexts. Major outcomes of the students’ innovation projects such as feasibility, novelty and customer value of the concepts are primarily influenced by students’ engineering design skills, prior knowledge of the technologies, and industrial or business experience.
The comprehensive assessment method includes 80 innovation performance parameters and 10 key indicators of innovation capability, such as innovation process performance, innovating system performance, market and customer orientation, technology orientation, creativity, leadership, communication and knowledge management, risk and cost management, innovative climate, and innovation competences. The cross-industry study identifies parameters critical for innovation success and reveals different innovation performance patterns in companies.
The modern TRIZ is today considered as the most organized and comprehensive methodology for knowledge-driven invention and innovation. When applying TRIZ for inventive problem solving, the quality of obtained solutions strongly depends on the level of completeness of the problem analysis and the abilities of designers to identify the main technical and physical contradictions in the inventive situation. These tasks are more complex and hence more time consuming in the case of interdisciplinary systems. Considering a mechatronic product as a system resulting from the integration of different technologies, the problem definition reveals two kinds of contradictions: 1) the mono-disciplinary contradictions within a homogenous sub-system, e.g., only mechanical or only electrical; 2) the interdisciplinary contradictions resulting from the interaction of the mechatronic sub-systems (mechanics, electrics, control and software). This paper presents a TRIZ-based approach for a fast and systematic problem definition and contradiction identification, which could be useful both for engineers and students facing mechatronic problems. It also proposes some useful problem formulation tech-niques such as the System Circle Diagram, the enhancement of System Operator with the Evolution Patterns, the extension of MATChEM-IB operator with Infor-mation field and Human Interactions, as well as the Cause-Effect-Matrix.
The research work analyses the relationship of 155 Process Intensification (PI) technologies to the components of the Theory of Inventive Problem Solving (TRIZ). It outlines TRIZ inventive principles frequently used in PI, and identifies opportunities for enhancing systematic innovation in process engineering by applying complementary TRIZ and PI. The study also proposes 70 additional inventive TRIZ sub-principles for the problems frequently encountered in process engineering, resulting in the advanced set of 160 inventive operators, assigned to the 40 TRIZ inventive principles. Finally, we analyse and discuss inventive principles used in 150 patent documents published in the last decade in the field of solid handling in the ceramic and pharmaceutical industries.
Economic growth and ecological problems have pushed industries to switch to eco-friendly technologies. However, environmental impact is still often neglected since production efficiency remains the main concern. Patent analysis in the field of process engineering shows that, on the one hand, some eco-issues appear as secondary problems of the new technologies, and on the other hand, eco-friendly solutions often show lower efficiency or performance capability. The study categorizes typical environmental problems and eco-contradictions in the field of process engineering involving solids handling and identifies underlying inventive principles that have a higher value for environmental innovation. Finally, 42 eco-innovation methods adapting TRIZ are chronologically presented and discussed.
In recent years, the application of TRIZ methodology in the process engineering has been found promising to develop comprehensive inventive solution concepts for process intensification (PI). However, the effectiveness of TRIZ for PI is not measured or estimated. The paper describes an approach to evaluate the efficiency of TRIZ application in process intensification by comparing six case studies in the field of chemical, pharmaceutical, ceramic, and mineral industries. In each case study, TRIZ workshops with the teams of researchers and engineers has been performed to analyze initial complex problem situation, to identify problems, to generate new ideas, and to create solution concepts. The analysis of the workshop outcomes estimates fulfilment of the PI-goals, impact of secondary problems, variety and efficiency of ideas and solution concepts. In addition to the observed positive effect of TRIZ application, the most effective inventive principles for process engineering have been identified.
Identification of Secondary Problems of New Technologies in Process Engineering by Patent Analysis
(2018)
The implementation of new technologies in production plants often causes negative side effects and drawbacks. In this context, the prediction of the secondary problems and risks can be used advantageously for selecting best solutions for intensification of the processes. The proposed method puts primary emphasis on systematic and fast anticipation of secondary problems using patent documents, and on extraction and prediction of possible engineering contradictions within novel technical systems. The approach comprises three ways to find secondary problems: (a) direct knowledge-based identification of secondary problems in new technologies or equipment; (b) identification of secondary problems of prototypes mentioned in patent citation trees; and (c) prediction of negative side effects using the correlation matrix for invention goals and secondary problems in a specific engineering domain.
Die Einbindung von Mini- und Mikro-BHKW in ein virtuelles Kleinkraftwerk (VKK) bietet vielfältige wirtschaftliche, Smart-Grids- und Klimaschutzpotentiale zur Unterstützung der "Wärmewende". Eine Einbindung solcher Anlagen ist bisher jedoch mit zumeist hohen Kosten verbunden, weshalb i.d.R. nur Anlagen in höheren Leistungsklassen (> 500 kWel) umgesetzt werden. Im Rahmen des Projekts mikroVKK wurde deshalb das Ziel verfolgt zu demonstriert und nachzuweisen, dass auch BHKW-Anlagen unter 100 kWel in ein virtuelles Kleinkraftwerk (VKK) wirtschaftlich einzubinden sind.
GridSystronic Energy (GSE) hat hierfür ein spezielles VKK-System (gs.system) entwickelt, welches im Rahmen des Projekts unter realen Bedingungen erprobt, weiterentwickelt und möglichst zur Marktreife gebracht wurde. Durch die Konfiguration des Systems - d.h. einfache Steuerboxen (gs.box) werden als Gateway für die Kommunikation vor Ort zur Anlagen- und Zähleranbindung verbaut, wohingegen die Berechnungen, Simulationen und Optimierung der Steuersignale auf dem zentralen gs.server erfolgt - lässt sich eine kostengünstige und skalierbare Lösung darstellen.
Zusammen mit zehn Stadtwerken als Praxispartner wurden unterschiedliche BHKW- Standorte identifiziert und auf deren technische Eignung und die Umsetzbarkeit neuer Geschäftsmodelle auf Basis einer intelligenten Steuerung analysiert. Für ausgewählte Objekte, wie z.B. Schulen, Wärmenetze, Mehrfamiliengebäude, wurde durch GSE eine Anbindung der für die Regelung notwendigen Geräte und Zähler realisiert. Regelwerke, wie z.B. "Lastprofil folgen", als Basis für neue Geschäftsmodelle wurden mit den Praxispartnern abgestimmt und entwickelt. Anhand der Erkenntnisse zu den Effekten der intelligenten Steuerung (z.B. Nutzung von möglichen Flexibilitäten, Stabilität des Systems, Verschiebung der Betriebszeiten, Änderung der Lieferquoten etc.) wurden neue Geschäftsmodelle detailliert analysiert und mit den Praxispartnern prototypisch umgesetzt. Die Evaluation zu den Smart-Grids-Potenzialen (Flexibilität, netzdienliche Einspeisung etc.) sowie die Potenziale zur Unterstützung des Klimaschutzes (CO2-Minderung) erfolgte anhand von gemessenen und simulierten Werten.
Während der Projektlaufzeit konnte die technische Anbindbarkeit von BHKW-Anlagen mit einer elektrischen Leistung bis 100 kWel demonstriert werden. Die Vorarbeiten für die Erarbeitung einer standardisierten und kostengünstigen Anbindungslösung war jedoch sehr viel zeitintensiver als ursprünglich geplant, weshalb die Anlagen verspätet oder z.T. gar nicht angebunden werden konnten. Wegen der geringen Datenbasis konnten die grundsätzlichen wirtschaftlichen Potenziale einer VKK Steuerung deshalb nur auf theoretischer Basis nachgewiesen werden. Die Anbindungs- und Integrationskosten hängen stark von den örtlichen Gegebenheiten ab, weshalb es hierfür keine pauschale Aussage getroffen werden kann. Durch die gewonnenen Erfahrungen und Lernprozesse konnte jedoch im Laufe des Projektes bereits eine erhebliche Kostenreduktion erzielt werden. Auch bei Neuanlagen, bei denen die Anbindung bereits vorab eingeplant werden kann, können die Kosten der Anbindung stark reduziert werden. Die Smart-Grid-Potenziale und die Klimaschutzpotenziale eines VKK-Einsatzes wurden von der Hochschule Offenburg ebenfalls auf einer theoretischen Basis ermittelt. In einem nächsten Schritt wäre es deshalb notwendig zu analysieren, ob sich die ermittelten Effekte auch unter realen Bedingungen einstellen.
In this paper the yield surface of a recently presented microstructure-based volume element of the gray cast iron material GJL-250 is assessed after different plastic loading histories. The evolution of the yield surface is investigated for different volumetric, deviatoric and uniaxial loadings. The micromechanical material properties of the metallic matrix and the graphite inclusions are validated by means experimental stress-strain hysteresis loops. The metallic matrix is modeled as elastic-plastic with a non-linear kinematic hardening law. The graphite inclusions are described by means of a volumetric strain state dependent Young’s modulus. The results show that the shape of the yield surface does not change significantly in comparison to the initial yield surface after pure deviatoric loadings. After volumetric loadings, the dependence of the material on the Lode angle is significantly reduced. Uniaxial tensile preloadings result in a deformed yield surface, whereby the magnitude of the deformation depends on the applied load. Uniaxial preloadings to compression do not change the shape of the initial yield surface.
Quantification of astaxanthin in salmons by chemiluminescence and absorption after TLC separation
(2018)
Astaxanthin is a keto-carotenoid, belongs to the chemical class of terpenes and is a yellow lipid soluble compound. The compound is present in marine animals like salmons and crustacean. Its colour is due to conjugated double bonds and these double bonds are responsible for its antioxidant effect. Its antioxidant activity is ten times stronger than other carotenoids and nearly 500 fold stronger than vitamin-E. We present a new thin layer chromatography (TLC) method to measure astaxanthin on TLC-plates (Merck, 1.05554) in the visible absorption range as well as by using chemiluminescence. For separation a solvent mixture of cyclohexane and acetone (10 + 2.4, v/v) was used. The RF-value of astaxanthin is 0.14.The limit of detection in vis-absorption is 64 ng / band and the limit of quantification is 92 ng/band. In chemiluminescence the values are 90 ng / band and 115 ng/band. The method offers two independently working measurement modes on a single plate which increase the accuracy of the quantification.
A Validated Quantification of Sudan Red Dyes in Spicery using TLC and a 16-bit Flatbed Scanner
(2018)
We present a video-densitometric quantification method for Sudan red dyes in spices and spice mixtures, separated by TLC. Application was done band-wise in small dots using a 5 μL glass pipette. For separation, the RP-18 plates (20 × 20 cm with fluorescent dye; Merck, Germany, 1.05559) were developed in a vertical developing chamber without vapor saturation from the starting point to a distance of 70 mm by using acetonitrile, methanol, and aqueous ammonia solution (25%; 8 + 1.8 + 0.2, v/v) as mobile phase. The quantification is based on direct measurements using an inexpensive 16-bit flatbed scanner for color measurements (in red, green, and blue). Evaluation of only the green channel makes the measurements very specific. For linearization, an extended Kubelka-Munk expression for data transformation was used. The range of linearity covers more than two magnitudes and lies between 20 and 500 ng. The extraction from a 2 g sample with acetonitrile, evaporation, and reconstitution to 200 μL with methanol and the band-wise application (7 mm) of a 10 μL sample allows a statistically defined LOD of less than 500 ppb of Sudan red dyes. To perform the analysis, a separation chamber, RP-18 plates, 5 μL glass pipettes, and a 16-bit flatbed scanner for 105 € are needed; therefore, the separation method is inexpensive, fast, and reliable.
We present a planar chromatographic separation method for the phytoestrogenic active compound equol, separated on RP-18 W (Merck, 1.14296) phase. It could be shown that an ethanolic cattle manure extract contains this phytoestrogenic active compound to a larger amount. As solvents for the mobile phase, hexane, ethyl acetate, and acetone (45:15:10, v/v); acetone and water (15:10, v/v); and n-hexane, CH2Cl2, ethyl acetate, methanol, and formic acid (40:40:20:5:1, v/v) have been used. After separation, a modified yeast estrogen screen (YES) test was applied, using the yeast strain Saccharomyces cerevisiae BJ3505 containing an estrogen receptor. Its activation by equol induces the reporter gene lacZ which encodes the enzyme β-galactosidase. The enzyme activity is measured directly on the TLC plate by using the substrate MUG (4-methylumbelliferyl-β-d-galactopyranoside) or the substrate X-β-Gal (5-bromo-4-chloro-3-indoxyl-β-d-galactopyranoside). β-Galactosidase cleaves MUG into a fluorescing compound. X-β- Gal is also hydrolyzed and then oxidized by oxygen forming the deep-blue dye 5,5′-dibromo-4,4′-dichloro-indigo. Both reactions in combination with a thin-layer chromatography (TLC) separation allow very specific detecting of equol in cattle manure, although that is a very challenging matrix. Preliminary results show that the average content of equol in liquid manure is roughly 60 μg g−1. The value for urine is 50 μg mL−1.
Dieser technische Bericht stellt die Verwendung der Zuwendung und der erzielten Ergebnisse im Einzelnen dar. Die Gegenüberstellung mit den vorgegebenen Zielen erfolgt anhand der Beschreibung des Arbeitspakete. Die Verwendung der Zuwendung und Gegenüberstellung mit den vorgegebenen Zielen wird anhand der Arbeitspakete beschrieben, um den Abgleich zwischen Planung und durchgeführten Arbeiten unmittelbar darstellen zu können.
With the need for automatic control based supervisory controllers for complex energy systems, comes the need for reduced order system models representing not only the non-linear behaviour of the components but also certain unknown process dynamics like their internal control logic. At the Institute of Energy Systems Technology in Offenburg we have built a real-life microscale trigeneration plant and present in this paper a rational modelling procedure that satisfies the necessary characteristics for models to be applied in model predictive control for grid-reactive optimal scheduling of this complex energy system. These models are validated against experimental data and the efficacy of the methodology is discussed. Their application in the future for the optimal scheduling problem is also briefly motivated.
Membrane distillation (MD) is a thermal separation process which possesses a hydrophobic, microporous
membrane as vapor space. A high potential application for MD is the concentration of hypersaline brines, such as
e.g. reverse osmosis retentate or other saline effluents to be concentrated to a near saturation level with a Zero
Liquid Discharge process chain. In order to further commercialize MD for these target applications, adapted MD
module designs are required along with strategies for the mitigation of membrane wetting phenomena. This
work presents the experimental results of pilot operation with an adapted Air Gap Membrane Distillation
(AGMD) module for hypersaline brine concentration within a range of 0–240 g NaCl /kg solution. Key performance
indicators such as flux, GOR and thermal efficiency are analyzed. A new strategy for wetting mitigation
by active draining of the air gap channel by low pressure air blowing is tested and analyzed. Only small reductions
in flux and GOR of 1.2% and 4.1% respectively, are caused by air sparging into the air gap channel.
Wetting phenomena are significantly reduced by avoiding stagnant distillate in the air gap making the air blower
a seemingly worth- while additional system component.
The production of potable water in dry areas nowadays is mainly done by the desalination of seawater. State of the art desalination plants usually are built with high production capacities and consume a lot of electrical energy or energy from primary resources such as oil. This causes difficulties in rural areas, where no infrastructure is available neither for the plants’ energy supply nor the distribution of the produced potable water. To address this need, small, self-sustaining and locally operated desalination plants came into the focus of research. In this work, a novel flash evaporator design is proposed which can be driven either by solar power or by low temperature waste heat. It offers low operation costs as well as easy maintenance. The results of an experimental setup operated with water at a feed flow rate of up to 1,600 l/h are presented. It is shown that the proof of concept regarding efficient evaporation as well as efficient gas-liquid separation is provided successfully. The experimental evaporation yield counts for 98 % of the vapor content that is expected from the vapor pressure curve of water. Neither measurements of the electrical conductivity of the gained condensate, nor the analysis of the vapor flow by optical methods show significant droplet entrainment, so there are no concerns regarding the purity of the produced condensate for the use as drinking water.
Colored glass products with various printing technologies are becoming more important in industry. The aim is to achieve individual solution in a very short delivery time. Conventional thermal treatment of burning glasses in oven for tempered color printing has predominant issues with high time consumption, energy consumption and manufacturing cost. It requires alternative process development.
This paper proposes laser process to overcome issues in conventional treatment with the latest results of tempering colored glass. Samples have been analyzed with the scanning electron microscope (SEM). Two different laser systems have been applied and the glass has been printed with black paste.
Grundzüge der Strömungslehre
(2018)
Dieses ausgereifte Lehrbuch bringt in prägnant kurzer und mathematisch verständlicher Darstellung die strömungstechnischen Grundlagen. In der aktuellen Auflage wurde ein Abschnitt zu Dissipation und Viskosen Potentialströmungen ergänzt. Aufgaben mit Lösungen helfen den Lernstoff richtig anzuwenden und fördern das Verständnis.