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The state-of-the-art electrochemical impedance spectroscopy (EIS) calculations have not yet started from fully multi-dimensional modeling. For a polymer electrolyte membrane fuel cell (PEMFC) with long flow channel, the impedance plot shows a multi-arc characteristic and some impedance arcs could merge. By using a step excitation/Fourier transform algorithm, an EIS simulation is implemented for the first time based on the full 2D PEMFC model presented in the first part of this work. All the dominant transient behaviors are able to be captured. A novel methodology called ‘configuration of system dynamics’, which is suitable for any electrochemical system, is then developed to resolve the physical meaning of the impedance spectra. In addition to the high-frequency arc due to charge transfer, the Nyquist plots contain additional medium/low-frequency arcs due to mass transfer in the diffusion layers and along the channel, as well as a low-frequency arc resulting from water transport in the membrane. In some case, the impedance spectra appear partly inductive due to water transport, which demonstrates the complexity of the water management of PEMFCs and the necessity of physics-based calculations.
Eine Mitte November veröffentlichte EU-Richtlinie sieht vor, dass ab 2017 Unternehmen mit durchschnittlich mehr als 500 Mitarbeitern bestimmte Nachhaltigkeitsangaben im Lagebericht veröffentlichen müssen. Auf den ersten Blick scheint hier weiterer administrativer Ballast für die wenigen betroffenen Genossenschaftsbanken zu entstehen. Doch daraus ergeben sich für die Institute auch Chancen. Es lohnt sich zu prüfen, ob ein aktives Nachhaltigkeitsmanagement sinnvoll erscheint.
It is the purpose of this paper to address ethical issues concerning the development and application of Assistive Technology at Workplaces (ATW). We shall give a concrete technical concept how such technology might be constructed and propose eight technical functions it should adopt in order to serve its purpose. Then, we discuss the normative questions why one should use ATW, and by what means. We argue that ATW is good to the extent that it ensures social inclusion and consider four normative domains in which its worth might consists in. In addition, we insist that ATW must satisfy two requirements of good workplaces, which we specify as (a) an exploitation restraint and (b) a duty of care.
The formation and analysis of ten microporous triazolyl isophthalate based MOFs, including nine isomorphous and one isostructural compound is presented. The compounds 1 M – 3 M with the general formula [ M ( R 1 - R 2 - trz - ia ) ] ∞ 3 ·x H 2 O (M 2+ = Co 2+ , Cu 2+ , Zn 2+ , Cd 2+ ; R 1 = H, Me; R 2 = 2py, 2pym, prz (2py = 2-pyridinyle; 2pym = 2-pyrimidinyle; prz = pyrazinyle)) crystallize with rtl topology. They are available as single crystals and also easily accessible in a multi-gram scale via refluxing the metal salts and the protonated ligands in a solvent. Their isomorphous structures facilitate the synthesis of heteronuclear MOFs; in case of 2 M , Co 2+ ions could be gradually substituted by Cu 2+ ions. The Co 2+ :Cu 2+ ratios were determined by ICP-OES spectroscopy, the distribution of Co 2+ and Cu 2+ in the crystalline samples are investigated by SEM-EDX analysis leading to the conclusions that Cu 2+ is more favorably incorporated into the framework compared to Co 2+ and, moreover, that the distribution of the two metal ions between the crystals and within the crystals is inhomogeneous if the crystals were grown slowly. The various compositions of the heteronuclear materials lead to different colors and the sorption properties for CO 2 and N 2 are dependent on the integrated metal ions.
Covert and Side-Channels have been known for a long time due to their versatile forms of appearance. For nearly every technical improvement or change in technology, such channels have been (re-)created or known methods have been adapted. For example the introduction of hyperthreading technology has introduced new possibilities for covert communication between malicious processes because they can now share the arithmetic logical unit (ALU) as well as the L1 and L2 cache which enables establishing multiple covert channels. Even virtualization which is known for its isolation of multiple machines is prone to covert and side-channel attacks due to the sharing of resources. Therefore itis not surprising that cloud computing is not immune to this kind of attacks. Even more, cloud computing with multiple, possibly competing users or customers using the same shared resources may elevate the risk of unwanted communication. In such a setting the ”air gap” between physical servers and networks disappears and only the means of isolation and virtual separation serve as a barrier between adversary and victim. In the work at hand we will provide a survey on weak spots an adversary trying to exfiltrate private data from target virtual machines could exploit in a cloud environment. We will evaluate the feasibility of example attacks and point out possible mitigation solutions if they exist.
In this paper an RFID/NFC (ISO 15693 standard) based inductively powered passive SoC (system on chip) for biomedical applications is presented. A brief overview of the system design, layout techniques and verification method is dis-cussed here. The SoC includes an integrated 32 bit microcontroller, sensor interface circuit, analog to digital converter, integrated RAM, ROM and some other peripherals required for the complete passive operation. The entire chip is realized in CMOS 0.18 μm technology with a chip area of 1.52mm x 3.24 mm.