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Batteries typically consist of multiple individual cells connected in series. Here we demonstrate single-cell state of charge (SOC) and state of health (SOH) diagnosis in a 24 V class lithium-ion battery. To this goal, we introduce and apply a novel, highly efficient algorithm based on a voltage-controlled model (VCM). The battery, consisting of eight single cells, is cycled over a duration of five months under a simple cycling protocol between 20 % and 100 % SOC. The cell-to-cell standard deviations obtained with the novel algorithm were 1.25 SOC-% and 1.07 SOH-% at beginning of cycling. A cell-averaged capacity loss of 9.9 % after five months cycling was observed. While the accuracy of single-cell SOC estimation was limited (probably owed to the flat voltage characteristics of the lithium iron phosphate, LFP, chemistry investigated here), single-cell SOH estimation showed a high accuracy (2.09 SOH-% mean absolute error compared to laboratory reference tests). Because the algorithm does not require observers, filters, or neural networks, it is computationally very efficient (three seconds analysis time for the complete data set consisting of eight cells with approx. 780.000 measurement points per cell).
Weg- und Winkelsensoren
(2014)
Weg- und Winkelaufnehmer werden überall dort benötigt wo veränderliche Positionen, (Abstände, Längen oder Winkel) erfasst werden müssen, um entweder als reiner Messwert ausgegeben zu werden oder in einem Regelkreis zumeist die Regelgröße als Messwert zur Verfügung zu stellen. Grundsätzlich unterscheidet man zwischen berührenden (tastenden) und berührungslosen Aufnehmern. Zu den berührenden Sensoren zählen dabei alle Aufnehmer, die ein spezielles Messobjekt als Weg- oder Winkelvermittler benötigen, das während der Messung fest mit dem eigentlichen Messobjekt verbunden ist. Diese Bezeichnung gilt auch dann, wenn die eigentliche Messung gegen das vermittelnde Objekt im Endeffekt berührungslos erfolgt. Berührungslose Weg- und Winkelaufnehmer können ohne einen solchen Vermittler direkt gegen das zu vermessende Objekt messen.
Previous studies of the hyphenation of gas chromatographic separation and spectrophotometric detection in the ultraviolet wavelength range between 168 and 330 nm showed a high potential for applications where the analysis of complex samples is required. Within this paper the development of a state-of-the-art detection system for compounds in the vapour phase is described, offering an improved behaviour compared to previous systems: Dependent on the requirements of established detection systems hyphenated with gas chromatography, the main components of the system have to be designed for optimum performance and reliability of the spectrophotometric detector: A deuterium lamp as a broadband light source has been selected for improved stability in the measurements. A new-type absorption cell based on fiber-optics has been developed considering the dynamic necessary to compete with existing techniques. In addition, the influence of the volume of the cell on the chromatogram needs to be analyzed. Tests for determining the performance of the absorption cell in terms of chemical and thermal influences have been carried out. A new spectrophotometer with adequate spectral resolution in the wavelength range, offering improved stability and dynamic for an efficient use in this application was developed. Furthermore, the influence of each component on the performance, reliability and stability of the sensor system will be discussed. An overview and outlook over the potential applications in the environmental, scientific and medical field will be given.
In thin-layer chromatography, fiber-bundle arrays have been introduced for spectral absorption measurements in the UV-region. Using all-silica fiber bundles, the exciting light will be detected after re-emission on the plate with a fiberoptic spectrometer. In addition, fluorescence light can be detected which will be masked by the re-emitted light. Therefore, it is helpful to separate the absorption and fluorescence on the TLC-plate. A modified three-array assembly has been developed: using one array for detection, the two others are used for excitation with broadband band deuterium-light and with UV-LEDs adjusted to the substances under test. As an example, the quantification of glucosamine in nutritional supplements or spinach leaf extract will be described. Using simply heating of the amino-plate for derivation, the reaction product of Glucosamine can be detected sensitively either by light absorption or by fluorescence, using the new fiber-optic assembly. In addition, the properties of the new 3-row fiber-optic array and the commercially available UV-LEDs will be shown, in the interesting wavelength region for excitation of fluorescence, from 260 nm to 360 nm. The squint angle having an influence on coupling efficiency and spatial resolution will be measured with the inverse farfield method. Some properties of UV-LEDs for analytical applications will be described and discussed, too.
A wet-chemical treatment system for electrochemically coating flat substrates with coating material, has having a basin for receiving an electrolyte, a transporting means, by means of which the flat substrates can be transported through the electrolyte horizontally, and at least one contact element which comprises a shaft having an axis of rotation and a cylindrical circumferential surface suitable for rolling on the substrate, wherein the circumferential surface comprises at least one electrically insulated segment and at least one electrically conductive segment which can be connected to a current source in such a way that the polarity can be reversed, wherein the axis of rotation of the contact element is positioned above the surface of the electrolyte, and wherein the contact element is designed as a consumable electrode.
본 발명은 기판들을 금속화하기 위한 디바이스에 관한 것이다. 특별히, 본 발명은 습식-화학물질 연속 (인-라인) 처리 시스템 환경에서 솔라 셀들을 전기도금하기 위해 사용되는 컨택 엘리먼트(contact element)들의 분야에 관한 것이다. 코팅 재료로 평평한 기판들(1)들을 전기화학적으로 코팅하기 위한 본 발명에 따른 습식-화학물질 처리 시스템은 전해질 용액, 이송 수단들 - 이송 수단들을 이용하여 평평한 기판(1)이 전해질 용액을 통과하여 수평으로 이송될 수 있는 - 을 수용하는 용기(basin), 및 회전축(5)을 갖는 샤프트(4) 및 기판(1) 위에서 구르기에 적합한 원통형의 원주 표면을 포함하는 적어도 하나의 컨택 엘리먼트(2)를 가지며, 원주 표면은 극성이 역전될 수 있는 방식으로 전류 소스 (6)에 연결될 수 있는 적어도 하나의 전기적으로 전도성인 세그먼트 (3A) 및 적어도 하나의 전기적으로 절연된 세그먼트 (3B)를 포함하고, 컨택 엘리먼트 (2)의 회전축 (5)은 전해질 용액의 표면 위에 위치되고, 컨택 엘리먼트 (2)는 소모 전극(consumable electrode)으로 디자인된다.
The invention relates to a device for metalising substrates. In particular, the invention relates to the field of contact elements used to electroplate solar cells within the context of a wet-chemical continuous treatment system. A wet-chemical treatment system according to the invention, for electrochemically coating flat substrates (1) with coating material, has a tank for accommodating an electrolyte, transporting means, by means of which the flat substrates (1) can be transported through the electrolyte horizontally, and at least one contact element (2), which comprises a shaft (4) having an axis of rotation (5) and a cylindrical circumferential surface suitable for rolling on the substrate (1), wherein the circumferential surface comprises at least one electrically insulating segment (3B) and at least one electrically conductive segment (3A), which can be connected to a current source (6) in such a way that the polarity can be reversed, wherein the axis of rotation (5) of the contact element (2) is positioned above the surface of the electrolyte, and wherein the contact element (2) is designed as a consumable electrode.
Nasschemische Behandlungsanlage zum elektrochemischen Beschichten von flachen Substraten (1) mit Beschichtungsmaterial, mit einem Becken zur Aufnahme eines Elektrolyten, und mit Transportmitteln, mit welchen die flachen Substrate (1) horizontal durch den Elektrolyten transportierbar sind, sowie mit mindestens einem Kontaktelement (2), welches eine Welle (4) mit Drehachse (5) und eine zum Abrollen auf dem Substrat (1) geeignete zylindrische Umfangsfläche aufweist, wobei die Umfangsfläche mindestens ein elektrisch isoliertes Segment (3B) und mindestens ein elektrisch leitendes Segment (3A) umfasst, das mit einer Stromquelle (6) umpolbar verbindbar ist, wobei die Drehachse (5) des Kontaktelements (2) oberhalb der Oberfläche des Elektrolyten positioniert ist, und wobei das Kontaktelement (2) als Verbrauchselektrode ausgestaltet ist.
Die Erfindung betrifft eine Vorrichtung zum Metallisieren von Substraten. Insbesondere betrifft die Erfindung das Gebiet der zur Galvanisierung von Solarzellen verwendeten Kontaktelemente im Rahmen einer nasschemischen Durchlauf-Behandlungsanlage. Eine erfindungsgemäße nasschemische Behandlungsanlage zum elektrochemischen Beschichten von flachen Substraten (1) mit Beschichtungsmaterial hat ein Becken zur Aufnahme eines Elektrolyten, sowie Transportmittel, mit welchen die flachen Substrate (1) horizontal durch den Elektrolyten transportierbar sind, und mindestens ein Kontaktelement (2), welches eine Welle (4) mit Drehachse (5) und eine zum Abrollen auf dem Substrat (1) geeignete zylindrische Umfangsfläche aufweist, wobei die Umfangsfläche mindestens ein elektrisch isoliertes Segment (3B) und mindestens ein elektrisch leitendes Segment (3A) umfasst, das mit einer Stromquelle (6) umpolbar verbindbar ist, wobei die Drehachse (5) des Kontaktelements (2) oberhalb der Oberfläche des Elektrolyten positioniert ist.