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Lithium‐ion battery cells are multiscale and multiphysics systems. Design and material parameters influence the macroscopically observable cell performance in a complex and nonlinear way. Herein, the development and application of three methodologies for model‐based interpretation and visualization of these influences are presented: 1) deconvolution of overpotential contributions, including ohmic, concentration, and activation overpotentials of the various cell components; 2) partial electrochemical impedance spectroscopy, allowing a direct visualization of the origin of different impedance features; and 3) sensitivity analyses, allowing a systematic assessment of the influence of cell parameters on capacity, internal resistance, and impedance. The methods are applied to a previously developed and validated pseudo‐3D model of a high‐power lithium‐ion pouch cell. The cell features a blend cathode. The two blend components show strong coupling, which can be observed and interpreted using the results of overpotential deconvolution, partial impedance spectroscopy, and sensitivity analysis. The presented methods are useful tools for model‐supported lithium‐ion cell research and development.
This article presents a comparative experimental study of the electrical, structural and chemical properties of large‐format, 180 Ah prismatic lithium iron phosphate (LFP)/graphite lithium‐ion battery cells from two different manufacturers. These cells are particularly used in the field of stationary energy storage such as home‐storage systems. The investigations include (1) cell‐to‐cell performance assessment, for which a total of 28 cells was tested from each manufacturer, (2) electrical charge/discharge characteristics at different currents and ambient temperatures, (3) internal cell geometries, components, and weight analysis after cell opening, (4) microstructural analysis of the electrodes via light microscopy and scanning electron microscopy, (5) chemical analysis of the electrode materials using energy‐dispersive X‐ray spectroscopy, and (6) mathematical analysis of the electrode balances. The combined results give a detailed and comparative insight into the cell characteristics, providing essential information needed for system integration. The study also provides complete and self‐consistent parameter sets for the use in cells models needed for performance prediction or state diagnosis.
Power systems are increasingly built from distributed generation units and smart consumers that are able to react to grid conditions. Managing this large number of decentralized electricity sources and flexible loads represent a very huge optimization problem. Both from the regulatory and the computational perspective, no one central coordinator can optimize this overall system. Decentralized control mechanisms can, however, distribute the optimization task through price signals or market-based mechanisms. This chapter presents the concepts that enable a decentralized control of demand and supply while enhancing overall efficiency of the electricity system. It highlights both technological and business challenges that result from the realization of these concepts, and presents the state-of-the-art in the respective domains.
The PHOTOPUR project aims to develop a photocatalytic process as a type of AOPs (Advanced Oxidation Processes) for the elimination of plant protection products (PPP) of the cleaning water used to wash sprayers. At INES a PV based energy supply for the photocatalytic cleaning system was developed within the framework of two bachelor theses and assembled as a demonstration unit. Then the system was step by step extended with further process automation features and pushed to a remote operating device. The final system is now available as a mobile unit mounted on a lab table. The latest step was the photocatalytic reactor module which completed the first PHOTOPUR prototype. The system is actually undergoing an intensive testing phase with performance checks at the consortium partners. First results give an overview about the successful operation.
Optimisation based economic despatch of real-world complex energy systems demands reduced order and continuously differentiable component models that can represent their part-load behaviour and dynamic responses. A literature study of existing modelling methods and the necessary characteristics the models should meet for their successful application in model predictive control of a polygeneration system are presented. Deriving from that, a rational modelling procedure using engineering principles and assumptions to develop simplified component models is applied. The models are quantitatively and qualitatively evaluated against experimental data and their efficacy for application in a building automation and control architecture is established.
Cooling towers or recoolers are one of the major consumers of electricity in a HVAC plant. The implementation and analysis of advanced control methods in a practical application and its comparison with conventional controllers is necessary to establish a framework for their feasibility especially in the field of decentralised energy systems. A standard industrial controller, a PID and a model based controller were developed and tested in an experimental set-up using market-ready components. The characteristics of these controllers such as settling time, control difference, and frequency of control actions are compared based on the monitoring data. Modern controllers demonstrated clear advantages in terms of energy savings and higher accuracy and a model based controller was easier to set-up than a PID.
Passive hybridization refers to a parallel connection of photovoltaic and battery cells on the direct current level without any active controllers or inverters. We present the first study of a lithium-ion battery cell connected in parallel to a string of four or five serially-connected photovoltaic cells. Experimental investigations were performed using a modified commercial photovoltaic module and a lithium titanate battery pouch cell, representing an overall 41.7 W-peak (photovoltaic)/36.8 W-hour (battery) passive hybrid system. Systematic and detailed monitoring of this system over periods of several days with different load scenarios was carried out. A scaled dynamic synthetic load representing a typical profile of a single-family house was successfully supplied with 100 % self-sufficiency over a period of two days. The system shows dynamic, fully passive self-regulation without maximum power point tracking and without battery management system. The feasibility of a photovoltaic/lithium-ion battery passive hybrid system could therefore be demonstrated.
Mass transfer phenomena in membrane fuel cells are complex and diversified because of the presence of complex transport pathways including porous media of very different pore sizes and possible formation of liquid water. Electrochemical impedance spectroscopy, although allowing valuable information on ohmic phenomena, charge transfer and mass transfer phenomena, may nevertheless appear insufficient below 1 Hz. Use of another variable, that is, back pressure, as an excitation variable for electrochemical pressure impedance spectroscopy is shown here a promising tool for investigations and diagnosis of fuel cells.
Silicon (Si) has turned out to be a promising active material for next‐generation lithium‐ion battery anodes. Nevertheless, the issues known from Si as electrode material (pulverization effects, volume change etc.) are impeding the development of Si anodes to reach market maturity. In this study, we are investigating a possible application of Si anodes in low‐power printed electronic applications. Tailored Si inks are produced and the impact of carbon coating on the printability and their electrochemical behavior as printed Si anodes is investigated. The printed Si anodes contain active material loadings that are practical for powering printed electronic devices, like electrolyte gated transistors, and are able to show high capacity retentions. A capacity of 1754 mAh/gSi is achieved for a printed Si anode after 100 cycles. Additionally, the direct applicability of the printed Si anodes is shown by successfully powering an ink‐jet printed transistor.