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Silicon (Si) has turned out to be a promising active material for next‐generation lithium‐ion battery anodes. Nevertheless, the issues known from Si as electrode material (pulverization effects, volume change etc.) are impeding the development of Si anodes to reach market maturity. In this study, we are investigating a possible application of Si anodes in low‐power printed electronic applications. Tailored Si inks are produced and the impact of carbon coating on the printability and their electrochemical behavior as printed Si anodes is investigated. The printed Si anodes contain active material loadings that are practical for powering printed electronic devices, like electrolyte gated transistors, and are able to show high capacity retentions. A capacity of 1754 mAh/gSi is achieved for a printed Si anode after 100 cycles. Additionally, the direct applicability of the printed Si anodes is shown by successfully powering an ink‐jet printed transistor.
Fast charging of lithium-ion batteries remains one of the most delicate challenges for the automotive industry, being seriously affected by the formation of lithium metal in the negative electrode. Here we present a physicochemical pseudo-3D model that explicitly includes the plating reaction as side reaction running in parallel to the main intercalation reaction. The thermodynamics of the plating reaction are modeled depending on temperature and ion concentration, which differs from the often-used assumption of a constant plating condition of 0 V anode potential. The reaction kinetics are described with an Arrhenius-type rate law parameterized from an extensive literature research. Re-intercalation of plated lithium was modeled to take place either via reverse plating (solution-mediated) or via an explicit interfacial reaction (surface-mediated). At low temperatures not only the main processes (intercalation and solid-state diffusion) become slow, but also the plating reaction itself becomes slower. Using this model, we are able to predict typical macroscopic experimental observables that are indicative of plating, that is, a voltage plateau during discharge and a voltage drop upon temperature increase. A spatiotemporal analysis of the internal cell states allows a quantitative insight into the competition between intercalation and plating. Finally, we calculate operation maps over a wide range of C-rates and temperatures that allow to assess plating propensity as function of operating condition.
Plant oils may be used as a sustainable, nearly CO2neutral fuel for diesel engines. This work investigates experimentally the particulate and gaseous emissions of diesel engines fuelled with different non-esterified, pure plant oils. The data are collected from three engines: a) Common rail 1.7 liter passenger car engine from Opel AG b) 12.8 liter truck engine from VOLVO c) Truck engine from MAN AG.
The emissions of the MAN engine have been used to perform AMES tests to analyze possible health impacts of plant oil operation. Finally, all emission results with plant oils have been compared to traditional gas oils.
Non-esterified plant oils gain ecological and economical importance, particularly in the EU where it is intended to increase the share of renewable energies. Plant oils do not require any chemical treatment so do not cause secondary pollution. The importance of plant oil will increase in Germany for mobile and stationary applications. The generation co-generation of heat and power is subsidized by the German “Erneuerbares Energiegesetz” and the “Kraft-Wärme-Kopplungsgesetz” when renewable fuels are used such as plant oils..
Plant oils have a much higher viscosity than conventional gas oil. It is mandatory to decrease the oil viscosity by heating prior to injection to assure proper injection and to avoid engine damage due to coke formation in the combustion chamber and at the injection nozzle. The German quality standard of Weihenstephan (RK-Qualitätsstandard 05/2000) for rape seed oil should be followed for use as diesel fuel. The chemical composition of plant oils is appreciably different in comparison to diesel fuels derived from mineral oils suggesting also different emission behavior.
The following contribution deals with the experimental investigation and theoretical evaluation of fatigue crack growth under isothermal and non-isothermal conditions at the nickel alloy 617. The microstructure and mechanical properties of alloy 617 are influenced significantly by the thermal heat treatment and the following thermal exposure in service. Hence, a solution annealed and a long-time service exposed material condition is studied. The crack growth measurement is carried out by using an alternate current potential drop system, which is integrated into a thermomechanical fatigue (TMF) test facility. The measured fatigue crack growth rates results in a function of material condition, temperature and load waveform. Furthermore, the results of the non-isothermal tests depend on the phase between thermal and mechanical load (in-phase, out-of-phase). A fracture mechanic based, time dependent model is upgraded by an approach to consider environmental effects, where almost all model parameters represent directly measureable values. A consistent description of all results and a good correlation with the experimental data can be achieved.
Process engineering industries are now facing growing economic pressure and societies' demands to improve their production technologies and equipment, making them more efficient and environmentally friendly. However unexpected additional technical and ecological drawbacks may appear as negative side effects of the new environmentally-friendly technologies. Thus, in their efforts to intensify upstream and downstream processes, industrial companies require a systematic aid to avoid compromising of ecological impact. The paper conceptualises a comprehensive approach for eco-innovation and eco- design in process engineering. The approach combines the advantages of Process Intensification as Knowledge-Based Engineering (KBE), inventive tools of Knowledge-Based Innovation (KBI), and main principles and best-practices of Eco-Design and Sustainable Manufacturing. It includes a correlation matrix for identification of eco-engineering contradictions and a process mapping technique for problem definition, database of Process Intensification methods and equipment, as well as a set of strongest inventive operators for eco-ideation.
As engineering graduates and specialists frequently lack the advanced skills and knowledge required to run eco-innovation systematically, the paper proposes a new teaching method and appropriate learning materials in the field of eco-innovation and evaluates the learning experience and outcomes. This programme is aimed at strengthening student’s skills and motivation to identify and creatively overcome secondary eco-contradictions in case if additional environmental problems appears as negative side effects of eco-friendly solutions.
Based on a literature analysis and own investigations, authors propose to introduce a manageable number of eco-innovation tools into a standard one-semester design course in process engineering with particular focus on the identification of eco-problems in existing technologies, selection of the appropriate new process intensification technologies (knowledge-based engineering), and systematic ideation and problem solving (knowledge-based innovation and invention).
The proposed educational approach equips students with the advanced knowledge, skills and competences in the field of eco-innovation. Analysis of the student’s work allows one to recommend simple-to-use tools for a fast application in process engineering, such as process mapping, database of eco-friendly process intensification technologies, and up to 20 strongest inventive operators for solving of environmental problems. For the majority of students in the survey, even the small workload has strengthened their self-confidence and skills in eco-innovation
Growing demands for cleaner production and higher eco-efficiency in process engineering require a comprehensive analysis of technical and environmental outcomes of customers and society. Moreover, unexpected additional technical or ecological drawbacks may appear as negative side effects of new environ-mentally friendly technologies. The paper conceptualizes a comprehensive ap-proach for analysis and ranking of engineering and ecological requirements in process engineering in order to anticipate secondary problems in eco-design and to avoid compromising the environmental or technological goals. For this purpose, the paper presents a method based on integration of the Quality Func-tion Deployment approach with the Importance-Satisfaction Analysis for the requirements ranking. The proposed method identifies and classifies compre-hensively the potential engineering and eco-engineering contradictions through analysis of correlations within requirements groups such as stakehold-er requirements (SRs) and technical requirements (TRs), and additionally through cross-relationship between SRs and TRs.
The 40 Altshuller Inventive Principles with numerous sub-principles remain over decades the most frequently applied tool of the Theory of Inventive Problem Solving TRIZ for systematic idea generation. However, their application often requires a concentrated, creative and abstract way of thinking that can be fairly challenging for the newcomers to TRIZ. This paper describes an approach to reduce the abstraction level of inventive sub-principles and presents the results of the idea generation experiment conducted with three groups of undergraduate and graduate students from different years of study in mechanical and process engineering. The students were asked to generate and to record their individual ideas for three design problems using a pre-defined set of classical and modified sub-principles within 10 minutes. The overall outcomes of the experiment support the assumption that the less abstract wording of the modified sub-principles leads to higher number of ideas. The distribution of ideas between the fields of MATCHEM-IBD (Mechanical, Acoustic, Thermal, Chemical, Electrical, Magnetic, Intermolecular, Biological and Data processing) differs significantly between groups using modified and abstract sub-principles.
In this article we outline the model development planned within the joint projectModel-based city planningand application in climate change (MOSAIK). The MOSAIK project is funded by the German FederalMinistry of Education and Research (BMBF) within the frameworkUrban Climate Under Change ([UC]2)since 2016. The aim of MOSAIK is to develop a highly-efficient, modern, and high-resolution urban climatemodel that allows to be applied for building-resolving simulations of large cities such as Berlin (Germany).The new urban climate model will be based on the well-established large-eddy simulation code PALM, whichalready has numerous features related to this goal, such as an option for prescribing Cartesian obstacles. Inthis article we will outline those components that will be added or modified in the framework of MOSAIK.Moreover, we will discuss the everlasting issue of acquisition of suitable geographical information as inputdata and the underlying requirements from the model's perspective.