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Ziel des Projekts STABIL war die Vorhersage der Alterung und Verbesserung der Lebensdauer von mobilen und stationären Lithium-Ionen-Batterien. Batterien sind zentrale Komponenten der Elektromobilität und der stationären Speicherung von regenerativem Strom. Die im Stand der Technik unzureichende Lebensdauer der Batterie ist heute wesentlicher Kostentreiber. Im Projekt wurde daher in einem skalenübergreifenden und interdisziplinären Ansatz das Verhalten von einzelnen Batteriezellen und ganzen Batteriesystemen unter zwei unterschiedlichen systemischen Randbedingungen untersucht.
Ziel des LiBaLu-Teilprojekts Modellierung und Simulation war die Unterstützung der Elektroden- und Zellentwicklung mit Hilfe umfangreicher Computersimulationen im Sinne des computergestützten Engineering (CAE). Zwei verschiedene Schwerpunkte standen im Mittelpunkt der Untersuchungen. Zum einen wurde das mechanistische Verständnis der komplexen Elektrochemie in Lithium-Luftbatterien durch mikrokinetische Modelle aufgeklärt. Auf Basis von postulierten Mehrschrittmechanismen wurden makroskopische Eigenschaften (Entlade-/Ladekennlinien, Zyklovoltammogramme) vorhergesagt und mit experimentellen Daten der Projektpartner verglichen. Zum anderen wurde das Design der Prototypzelle mit Hilfe numerischer Simulationen untersucht und optimiert. So konnten z. B. optimale Schichtdicken oder die Rolle von Gastransportlimitierungen identifiziert werden.
Auswahl von elektrischen Antriebskomponenten zur Elektrifizierung des Antriebes eines „Tuk-Tuks“
(2019)
Die vorliegende Abschlussarbeit handelt von einem Tuk-Tuk. Im Ausgangszustand ist dieses mit einem 1-Zylinder Ottomotor versehen.
Im Rahmen eines Hochschulprojektes wird dieser Motor durch einen Elektromotor ersetzt. Ziel dieser Thesis ist es, einen passenden Motor zu finden. Dabei soll eine Auslegung erarbeitet werden, die es ermöglicht, sämtliche Widerstandskräfte zu berechnen und daraus auf die notwendigen Antriebsleistungen bzw. Drehmomente zu schließen. Im Anschluss daran kann eine Aussage getroffen werden, ob der Elektromotor die gewünschten Anforderungen erfüllt.
This article presents the development, parameterization, and experimental validation of a pseudo-three-dimensional (P3D) multiphysics model of a 350 mAh high-power lithium-ion pouch cell with graphite anode and lithium cobalt oxide/lithium nickel cobalt aluminum oxide (LCO/NCA) blend cathode. The model describes transport processes on three different scales: Heat transport on the macroscopic scale (cell), mass and charge transport on the mesoscopic scale (electrode pair), and mass transport on the microscopic scale (active material particles). A generalized description of electrochemistry in blend electrodes is developed, using the open-source software Cantera for calculating species source terms. Very good agreement of model predictions with galvanostatic charge/discharge measurements, electrochemical impedance spectroscopy, and surface temperature measurements is observed over a wide range of operating conditions (0.05C to 10C charge and discharge, 5°C to 35°C). The behavior of internal states (concentrations, potentials, temperatures) is discussed. The blend materials show a complex behavior with both intra-particle and inter-particle non-equilibria during cycling.
As part of the design education at Offenburg University, the teaching in technical documentation is continuously optimised. In this study, numerous mechanical engineering students, ages 19 to 29, are observed using the eye tracking technology and a video camera while performing various design exercises. The aim of the study is to enhance the students’ ability to read, understand and analyse complex engineering drawings. In one experiment, the students are asked to perform the “cube perspective test” after Stumpf and Fay to assess their ability for mental rotation as part of spatial visualization ability. Furthermore, the students are asked to prepare and give micro presentations on a topic related to their studies. Students have a maximum of 100 s time for these presentations. Thus, they can practise presenting important information in a short amount of time, show their rhetorical skills and demonstrate their acquisition of basic knowledge. During the presentation, the eye movement of a few selected students is recorded to analyse their information acquisition. In a further test, the students’ eye movements are analysed while reading an engineering drawing that consists of multiple views. All the spatial connections have to be included based on the different component views. Including these and their acquired knowledge, the students are asked to identify the correct representation of a component view. Furthermore the subjects are describing the function of an assembly, a parallel gripper and then they are to mentally disassemble the assembly to replace a damaged cylindrical pin. Simultaneously, they are filmed using a video camera to see which terms the students use for the individual technical terms. The evaluation of the eye movements shows that the increasing digitalisation of society and the use of electronic devices in everyday life lead to fast and only selective perceptual behaviour and that students feel insecure when dealing with technical drawings. The analysis of the videos shows a mostly non-technical and inaccurate manner of expression and a poor use of technical terms. The transferability of the achieved results to other technical tasks is part of further investigations.
In den hier vorliegenden Fallstudien wurden mehrere Studierende des Studiengangs Maschinenbau an der Hochschule Offenburg im Alter von 18 bis 28 Jahren bei der Lösungsfindung für Konstruktionsaufgaben mit der Eye-Tracking-Technologie und einer Videokamera beobachtet. Ziel der empirischen Untersuchung war es, die praktische Fähigkeit von Studierenden beim Lesen, Verstehen und Analysieren von technischen Darstellungen zu fördern. Die Auswertung der Augenbewegungen zeigt, dass die zunehmende Digitalisierung der Gesellschaft und der Umgang mit elektronischen Kleinstgeräten im Alltag zu einem punktuellen und flüchtigen Wahrnehmungsverhalten führen und dass sich die Studierenden im Umgang mit technischen Zeichnungen unsicher fühlen. Die Analyse der Videos zeigt eine meist nicht-technische und ungenaue Ausdrucksweise und eine schlechte Verwendung von Fachbegriffen.
The Humboldt Portal has been designed and implemented as part of an ongoing research project to develop an information system on the Internet to share the documents and rare books of Alexander von Humboldt, a 19th century German scientist and explorer, who viewed the natural world holistically and described the harmony of nature among the diversity of the physical world. Even after more than two centuries he is admired for his ability to see the natural world and human nature in the context of a complex network of relationships. The design and implementation of the Humboldt Portal are also oriented to support further research on Humboldt’s intellectual perspective.
Although all of Humboldt's works can be found on the internet as digitized documents, the complexity and internal inter-connectivity of his vision of nature cannot be adequately represented only by digitized papers or scanned documents in digital libraries.
As a consequence a specific portal of the Humboldt's documents was developed, which extends the standards of digital libraries and offers a technical approach for the adequate presentation of highly interconnected data.
Due to the continuous scientific and literary research, new insights and requirements for the digital presentation of Humboldt documents are constantly emerging, so that this article only provides a summary of the concepts realized at now. Consequently, the design and implementation of the Humboldt Portal is both: a consequence of a continuing research project and oriented to support more research on Humboldt´s intellectual holistic perspective, which was an anticipation to the System Approach of the last Century.
More than 200 years ago, the scientist Alexander von Humboldt noted in his travel diaries that "everything is interconnectedness", when he was fascinated by nature and the phenomena observed. The view of nature has become much more detailed through the knowledge of phenomena and natural processes, which led to a more precise view of nature shaped by Humboldt. Technological progress and the artificial intelligence of highly developed computer systems are upsetting this view and changing the established world view through a new, unprecedented interaction between man and machinery. Thus we need digital axioms and comprehensive rules and laws for such autonomous acting systems that determine human interaction between cybernetic systems and biological individuals. This digital humanism should encompass our relationship to nature, our handling of the complexity and diversity of nature and the technological influences on society in order to avoid technical colonialism through supercomputers.
Sweaty has already participated four times in RoboCup soccer competitions (Adult Size) and came second three times. While 2016 Sweaty needed a lot of luck to be finalist, 2017 Sweaty was a serious adversary in the preliminary rounds. In 2018 Sweaty showed up in the final with some lack of experience and room for improvements, but not without any chance. This paper describes the intended improvements of the humanoid adult size robot Sweaty in order to qualify for the RoboCup 2019 adult size competition.
We present a planar chromatographic separation method for the compounds caffeine, artemisinin, and equol, separated on high-performance thin-layer chromatography (HPTLC) silica gel plates. As solvents for separation, methyl t-butyl ether and cyclohexane (1:1, V/V) have been used for equol, cyclohexane and ethyl acetate (7:3, V/V) for artemisinin, and ethyl acetate and acetone (7:3, V/V) for caffeine. After separation, the plate was scanned with a very specific time of flight-direct analysis in real time-mass spectrometry (TOF-DART-MS) system using the (M + 1)+ signals of equol, artemisinin, and caffeine. The (M + 1) peak of artemisinin at 283.13 m/z is clearly detectable, which is the proof that DART-MS is applicable for the quantitative determination of rather instable molecules. The planar set-up of DART source, HPTLC plate and detector inlet in a line showed higher sensitivities compared to desorption at an angle. The optimal detector voltage increases with the molar mass of the analyte, thus an individual determination of optimal detector voltage setting for the different analyte is recommended to achieve the best possible measurement conditions. In conclusion, DART-MS detection in combination with an HPTLC separation allows very specific quantification of all three compounds.