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A wet-chemical treatment system for electrochemically coating flat substrates with coating material, has having a basin for receiving an electrolyte, a transporting means, by means of which the flat substrates can be transported through the electrolyte horizontally, and at least one contact element which comprises a shaft having an axis of rotation and a cylindrical circumferential surface suitable for rolling on the substrate, wherein the circumferential surface comprises at least one electrically insulated segment and at least one electrically conductive segment which can be connected to a current source in such a way that the polarity can be reversed, wherein the axis of rotation of the contact element is positioned above the surface of the electrolyte, and wherein the contact element is designed as a consumable electrode.
본 발명은 기판들을 금속화하기 위한 디바이스에 관한 것이다. 특별히, 본 발명은 습식-화학물질 연속 (인-라인) 처리 시스템 환경에서 솔라 셀들을 전기도금하기 위해 사용되는 컨택 엘리먼트(contact element)들의 분야에 관한 것이다. 코팅 재료로 평평한 기판들(1)들을 전기화학적으로 코팅하기 위한 본 발명에 따른 습식-화학물질 처리 시스템은 전해질 용액, 이송 수단들 - 이송 수단들을 이용하여 평평한 기판(1)이 전해질 용액을 통과하여 수평으로 이송될 수 있는 - 을 수용하는 용기(basin), 및 회전축(5)을 갖는 샤프트(4) 및 기판(1) 위에서 구르기에 적합한 원통형의 원주 표면을 포함하는 적어도 하나의 컨택 엘리먼트(2)를 가지며, 원주 표면은 극성이 역전될 수 있는 방식으로 전류 소스 (6)에 연결될 수 있는 적어도 하나의 전기적으로 전도성인 세그먼트 (3A) 및 적어도 하나의 전기적으로 절연된 세그먼트 (3B)를 포함하고, 컨택 엘리먼트 (2)의 회전축 (5)은 전해질 용액의 표면 위에 위치되고, 컨택 엘리먼트 (2)는 소모 전극(consumable electrode)으로 디자인된다.
The invention relates to a device for metalising substrates. In particular, the invention relates to the field of contact elements used to electroplate solar cells within the context of a wet-chemical continuous treatment system. A wet-chemical treatment system according to the invention, for electrochemically coating flat substrates (1) with coating material, has a tank for accommodating an electrolyte, transporting means, by means of which the flat substrates (1) can be transported through the electrolyte horizontally, and at least one contact element (2), which comprises a shaft (4) having an axis of rotation (5) and a cylindrical circumferential surface suitable for rolling on the substrate (1), wherein the circumferential surface comprises at least one electrically insulating segment (3B) and at least one electrically conductive segment (3A), which can be connected to a current source (6) in such a way that the polarity can be reversed, wherein the axis of rotation (5) of the contact element (2) is positioned above the surface of the electrolyte, and wherein the contact element (2) is designed as a consumable electrode.
Nasschemische Behandlungsanlage zum elektrochemischen Beschichten von flachen Substraten (1) mit Beschichtungsmaterial, mit einem Becken zur Aufnahme eines Elektrolyten, und mit Transportmitteln, mit welchen die flachen Substrate (1) horizontal durch den Elektrolyten transportierbar sind, sowie mit mindestens einem Kontaktelement (2), welches eine Welle (4) mit Drehachse (5) und eine zum Abrollen auf dem Substrat (1) geeignete zylindrische Umfangsfläche aufweist, wobei die Umfangsfläche mindestens ein elektrisch isoliertes Segment (3B) und mindestens ein elektrisch leitendes Segment (3A) umfasst, das mit einer Stromquelle (6) umpolbar verbindbar ist, wobei die Drehachse (5) des Kontaktelements (2) oberhalb der Oberfläche des Elektrolyten positioniert ist, und wobei das Kontaktelement (2) als Verbrauchselektrode ausgestaltet ist.
Die Erfindung betrifft eine Vorrichtung zum Metallisieren von Substraten. Insbesondere betrifft die Erfindung das Gebiet der zur Galvanisierung von Solarzellen verwendeten Kontaktelemente im Rahmen einer nasschemischen Durchlauf-Behandlungsanlage. Eine erfindungsgemäße nasschemische Behandlungsanlage zum elektrochemischen Beschichten von flachen Substraten (1) mit Beschichtungsmaterial hat ein Becken zur Aufnahme eines Elektrolyten, sowie Transportmittel, mit welchen die flachen Substrate (1) horizontal durch den Elektrolyten transportierbar sind, und mindestens ein Kontaktelement (2), welches eine Welle (4) mit Drehachse (5) und eine zum Abrollen auf dem Substrat (1) geeignete zylindrische Umfangsfläche aufweist, wobei die Umfangsfläche mindestens ein elektrisch isoliertes Segment (3B) und mindestens ein elektrisch leitendes Segment (3A) umfasst, das mit einer Stromquelle (6) umpolbar verbindbar ist, wobei die Drehachse (5) des Kontaktelements (2) oberhalb der Oberfläche des Elektrolyten positioniert ist.
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
During pyrolysis, biomass is carbonised in the absence of oxygen to produce biochar with heat and/or electricity as co-products making pyrolysis one of the promising negative emission technologies to reach climate goals worldwide. This paper presents a simplified representation of pyrolysis and analyses the impact of this technology on the energy system. Results show that the use of pyrolysis can allow getting zero emissions with lower costs by making changes in the unit commitment of the power plants, e.g. conventional power plants are used differently, as the emissions will be compensated by biochar. Additionally, the process of pyrolysis can enhance the flexibility of energy systems, as it shows a correlation between the electricity generated by pyrolysis and the hydrogen installation capacity, being hydrogen used less when pyrolysis appears. The results indicate that pyrolysis, which is available on the market, integrates well into the energy system with a promising potential to sequester carbon.
Encapsulant-free N.I.C.E. modules have strong ecological advantages compared to conventional laminated modules but suffer generally from lower electrical performance. Via long-term outdoor monitoring of fullsize industrial modules of both types with identical solar cells, we investigated if the performance difference remains constant over time and which parameters influence its value. After assessing about a full year’s data, two obvious levers for N.I.C.E. optimization are identified: The usage of textured glass and transparent adhesives on the module rear side. Also, the performance loss could be alleviated using tracking systems due to lower AOI values. Our measurements show additionally that N.I.C.E. module surfaces are in average about 2.5°C cooler compared to laminated modules. With these findings, we lay out a roadmap to reduce today’s LIV gap of about 5%rel by different optimizations.
Significant improvements in module performance are possible via implementation of multi-wire electrodes. This is economically sound as long as the mechanical yield of the production is maintained. While flat ribbons have a relatively large contact area to exert forces onto the solar cell, wires with round cross section reduce this contact area considerably – in theory to an infinitively thin line. Therefore, the local stresses induced by the electrodes might increase to a point that mechanical production yields suffer unacceptably.
In this paper, we assess this issue by an analytical mechanical model as well as experiments with an encapsulant-free N.I.C.E. test setup. From these, we can derive estimations for the relationship between lay-up accuracy and expected breakage losses. This paves the way for cost-optimized choices of handling equipment in industrial N.I.C.E.-wire production lines.
Micronization of biochar (BC) may ease its application in agriculture. For example, fine biochar powders can be applied as suspensions via drip-irrigation systems or can be used to produce grnulated fertilizers. However, micronization may effect important physical biochar properties like the water holding capacity (WHC) or the porosity.
The use of biochar is an important tool to improve soil fertility, reduce the negative environmental impacts of agriculture, and build up terrestrial carbon sinks. However, crop yield increases by biochar amendment were not shown consistently for fertile soils under temperate climate. Recent studies show that biochar is more likely to increase crop yields when applied in combination with nutrients to prepare biochar-based fertilizers. Here, we focused on the root-zone amendment of biochar combined with mineral fertilizers in a greenhouse trial with white cabbage (Brassica oleracea convar. Capitata var. Alba) cultivated in a nutrient-rich silt loam soil originating from the temperate climate zone (Bavaria, Germany). Biochar was applied at a low dosage (1.3 t ha−1). The biochar was placed either as a concentrated hotspot below the seedling or it was mixed into the soil in the root zone representing a mixture of biochar and soil in the planting basin. The nitrogen fertilizer (ammonium nitrate or urea) was either applied on the soil surface or loaded onto the biochar representing a nitrogen-enhanced biochar. On average, a 12% yield increase in dry cabbage heads was achieved with biochar plus fertilizer compared to the fertilized control without biochar. Most consistent positive yield responses were observed with a hotspot root-zone application of nitrogen-enhanced biochar, showing a maximum 21% dry cabbage-head yield increase. Belowground biomass and root-architecture suggested a decrease in the fine root content in these treatments compared to treatments without biochar and with soil-mixed biochar. We conclude that the hotspot amendment of a nitrogen-enhanced biochar in the root zone can optimize the growth of white cabbage by providing a nutrient depot in close proximity to the plant, enabling efficient nutrient supply. The amendment of low doses in the root zone of annual crops could become an economically interesting application option for biochar in the temperate climate zone.
As PV enters the terawatt era, reliability, sustainability and low carbon footprint of solar modules are key requirements. The N.I.C.E.TM technology from Apollon Solar is a good candidate for significant improvements in these areas. As the second-generation pilot line is now functional with IEC certification underway, we present a holistic assessment of N.I.C.E.TM technology compared with conventional module technology with encapsulant. This includes electrical performance and cost/consumables, reliability, and degradation mechanisms as well as sustainability aspects. In addition, the new generation of N.I.C.E.-wire modules are presented that use thin round Cu wires instead of flat ribbons for interconnection. This candidate technology for an alternative to the Smart Wire Connection Technology (SWCT) is investigated experimentally as well as via numerical simulations.
The invention relates to the field of transporting flat substrates such as silicon substrates. In particular, the invention relates to particularly protective and continuous transport of such substrates. The method according to the invention is used to transport a vertically aligned flat substrate (1) comprising two flat sides in a transport direction inside a transport channel (2) that is at least partially filled with a liquid medium (F), wherein said liquid medium (F) flows against at least one of the flat sides of the substrate (1) and has a supporting component, which lifts the sum of the weight and buoyancy force of the substrate (1), and an advancing component, which is directed in the transport direction, so that the substrate (1) is supported and transported without mechanical aids. The device according to the invention comprises a transport channel (2) for accommodating a liquid medium (F) and a substrate (1) to be guided in vertical alignment within said medium (F), wherein the transport channel (2) has inflow openings (5) in the walls (3, 4).