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This paper focuses on the microstructure-dependent inelastic behavior of lamellar gray cast iron. It comprises the reconstruction of three dimensional volume elements by use of the serial sectioning method for the materials GJL-150, GJL-250 and GJL-350. The obtained volume elements are prepared for the numerical analyses by means of finite-element method. In the finite-element analysis, the metallic matrix is modeled with an elastic–plastic deformation law. The graphite inclusions are modeled nonlinear elastic with a decreasing value of Young’s modulus for increasing tensile loading. Thus, the typical tension–compression asymmetry of this material class can be described. The stress–strain curves obtained with the microstructure-based finite-element models agree well with experimental curves of tension and compression tests. Besides the analysis of the whole volume element, the scatter of the stress–strain response in smaller statistical volume elements is investigated. Furthermore, numerical studies are performed to reduce computational costs.
Two closely related series of paddle-wheel-based triazolyl isophthalate MOFs are presented. Thermal and CO2 adsorption studies reveal network flexibility induced by alkyl substituents of the linker. By choice of the substituent, the pore volumes and pore diameters can be adjusted. Fine-tuning of the gate opening pressure and the hysteresis shape is possible by modulating the substitution pattern and by choice of the metal ion.
Mit der Messung des Wärme- und Kälteverbrauchs im Labor gelingt es, sowohl thermisch träge als auch agile Flächentemperiersysteme unter praxisnahen, dynamischen Bedingungen messtechnisch zu bewerten. Werden Nutzwärme- und Nutzkältebedarf berechnet und ins Verhältnis zu den gemessenen Verbräuchen gesetzt, können die Aufwandzahlen für die Nutzenübergabe ece für verschiedene Flächentemperiersysteme und in Kombinationen mit anderen Übergabesystemen unter verschiedenen Nutzungsbedingungen und für unterschiedliche Betriebsführungsstrategien bestimmt werden. Damit stehen Aufwandszahlen auf Basis kalorischer Messungen zur Verfügung, die je nach Aufgabenstellung entweder produkt- oder objektbezogen in der Planung komplexer Energiekonzepte verwendet werden können und die tatsächlichen Aufwandszahlen eh, ce für den Heizfall bzw. ec, ce für den Kühlfall genauer als Literaturwerte bzw. projektbezogen beschreiben
Process engineering focuses on the design, operation, control and optimization of chemical, physical and biological processes and has applications in many industries. Process Intensification is the key development approach in the modern process engineering. The proposed Advanced Innovation Design Approach (AIDA) combines the holistic innovation process with the systematic analytical and problem solving tools of the theory of inventive problem solving TRIZ. The present paper conceptualizes the AIDA application in the field of process engineering and especially in combination with the Process Intensification. It defines the AIDA innovation algorithm for process engineering and describes process mapping, problem ranking, and concept design techniques. The approach has been validated in several industrial case studies. The presented research work is a part of the European project “Intensified by Design® platform for the intensification of processes involving solids handling”.
The collection of selected papers of the TRIZ Future Conference 2017 is in open access and is included to the Innovator, the journal of the European TRIZ Assocation.
The paper is addressing the needs of the universities regarding qualification of students as future R&D specialists in efficient techniques for successfully running innovation process. In comparison with the engineers, the students often demonstrate lower motivation in learning systematic inventive techniques, like for example TRIZ methodology, and prefer random brainstorming for idea generation. The quality of obtained solutions also depends on the level of completeness of the problem analysis, which is more complex and time consuming in the case of interdisciplinary systems. The paper briefly describes one-semester-course of 60 hours in new product development with the Advanced Innovation Design Approach and TRIZ methodology, in which a typical industrial innovation process for one selected interdisciplinary mechatronic product is modelled.
In the course of the last few years, our students are becoming increasingly unhappy. Sometimes they stop attending lectures and even seem not to know how to behave correctly. It feels like they are getting on strike. Consequently, drop-out rates are sky-rocketing. The lecturers/professors are not happy either, adopting an “I-don’t-care” attitude.
An interdisciplinary, international team set in to find out: (1) What are the students unhappy about? Why is it becoming so difficult for them to cope? (2) What does the “I-don’t-care” attitude of professors actually mean? What do they care or not care about? (3) How far do the views of the parties correlate? Could some kind of mutual understanding be achieved?
The findings indicate that, at least at our universities, there is rather a long way to go from “Engineering versus Pedagogy” to “Engineering Pedagogy”.
We present a two-dimensional (2D) planar chromatographic separation method for phytoestrogenic active compounds on RP-18 W (Merck, 1.14296) phase. It could be shown that an ethanolic extract of liquorice (Glycyrrhiza glabra) roots contains four phytoestrogenic active compounds. As solvent, in the first direction, the mix of hexane, ethyl acetate, and acetone (45:15:10, v/v) was used, and, in the second direction, that of acetone and water (15:10, v/v) was used. After separation, a modified yeast estrogen screen (YES) test was applied, using the yeast strain Saccharomyces cerevisiae BJ3505. The test strain (according to McDonnell) contains the estrogen receptor. Its activation by estrogen active compounds is measured by inducing the reporter gene lacZ which encodes the enzyme β-galactosidase. This enzyme activity is determined on plate by using the fluorescent substrate MUG (4-methylumbelliferyl-β-d-galactopyranoside). The enzyme can also hydrolyse X-β-Gal (5-bromo-4-chloro-3-indoxyl-β-d-galactopyranosid) into β-galactose and 5-bromo-4-chloro-3-indoxyl. The indoxyl compound is oxidized by oxygen forming the deep-blue dye 5,5β-dibromo-4,4β-dichloro-indigo which allows to detect phytoestrogenic activity more specific in the presence of native fluorescing compounds.
Viele hochbeanspruchte Bauteile müssen zur Erfüllung ihres konstruktiven Zwecks mit Durchdringungskerben versehen werden. Infolge der gegenseitigen Wechselwirkung gelten für die Kerbwirkung dieser Art von Mehrfachkerben andere Gesetzmäßigkeiten als bei Einzelkerben. Die Weiterentwicklung der Lehre von der Tragfähigkeitsberechnung höchstbeanspruchter Maschinenelemente macht es notwendig, sich mit der Durchdringungskerbwirkung eingehend zu befassen. Thum und Svenson [1] entwickelten im Jahr 1949 ein Näherungsverfahren zur Abschätzung der Formzahl an einem zugbelasteten Stab mit Durchdringungskerben. In vielen Lehrbüchern findet dieses Verfahren Anwendung. Aus heutiger Sicht erscheint die Eignung der aus diesem Ansatz erzielten Ergebnisse als dringend überprüfungswürdig. Das thum’sche Verfahren wird unter die Lupe genommen. Der hier vorliegende Beitrag präsentiert mit Hilfe der Finiten-Elemente-Methode (FEM) neue Untersuchungsergebnisse an zugbeanspruchten Stäben mit Halbkreisnut und überlagerter Querbohrung. Diese ergaben, dass die Berechnung nach [1] Lücken aufweist. Ihr Ansatz stellt für den heutigen Entwicklungsstand eine mit zu großen Abweichungen behaftete Näherungshypothese dar.
Three real-lab trigeneration microgrids are investigated in non-residential environments (educational, office/administrational, companies/production) with a special focus on domain-specific load characteristics. For accurate load forecasting on such a local level, à priori information on scheduled events have been combined with statistical insight from historical load data (capturing information on not explicitly-known consumer behavior). The load forecasts are then used as data input for (predictive) energy management systems that are implemented in the trigeneration microgrids. In real-world applications, these energy management systems must especially be able to carry out a number of safety and maintenance operations on components such as the battery (e.g. gassing) or CHP unit (e.g. regular test runs). Therefore, energy management systems should combine heuristics with advanced predictive optimization methods. Reducing the effort in IT infrastructure the main and safety relevant management process steps are done on site using a Smart & Local Energy Controller (SLEC) assisted by locally measured signals or operator given information as default and external inputs for any advanced optimization. Heuristic aspects for local fine adjustment of energy flows are presented.
A former remote area power supply was converted to a smart cogeneration subnet with combined heat and power to develop and validate a forecast based energy management at the University of Applied Sciences in Offenburg/Germany. Locally processed weather forecasts and forecasted demand profiles are integrated to allow a precise reaction to changes of fluctuating power sources, changes in scheduled demand profiles and to improve the energy efficiency of the supply. The management of the electrical and thermal storages is influenced by the forecasted energy contributions and the forecasted demand. Further approaches should improve the accuracy of forecasting algorithms and integrate parameter models gained of a detailed monitoring to realize predictive controllers.
Polygeneration systems are a key technology for the reduction of primary energy usage and emissions. High costs, lack of flexibility and effort for parameterization hinder the wide usage of modeling tools during their conceptual design. This paper describes how planning tools can be structured for the conceptual design phase where only little information is available to the planner. A library concept was developed using the principles of object-oriented modeling to address the flexibility issue. With respect to cost and expandability, the open-source modeling language Modelica was chosen. Furthermore, easy-to-parameterize component models were developed. In addition to the improved library concept and novel component models, an easy-to-adapt control concept is proposed. The component models were validated and the applicability of the library was demonstrated by means of an example. It was shown that the data usually obtained from spec sheets are sufficient to parameterize the models. In addition to this, the control concept was approved.
Micro gas turbines (MGTs) are regarded as combined heat and power (CHP) units which offer high fuel utilization and low emissions. They are applied in decentralized energy neration.
To facilitate the planning process of energy systems, namely in the context of the increasing application of optimization techniques, there is a need for easy-to-parametrize component models with sufficient accuracy which allow a fast computation. In this paper, a model is proposed where the non-linear part load characteristics of the MGT are linearized by means of physical insight of the working principles of turbomachinery. Further, it is shown that the model can be parametrized by the data usually available in spec sheets. With this model a uniform description of MGTs from several manufacturers
covering an electrical power range from 30kW to 333kW can be obtained. The MGT model was
implemented by means of Modelica/Dymola. The resulting MGT system model, comprising further heat exchangers and hydraulic components, was validated using the experimental data of a 65kW MGT from a trigeneration energy system.
Radiation is an important means of heat transfer inside an electric arc furnace (EAF).
To gain insight into the complex processes of heat transfer inside the EAF vessel, not only radiation from the surfaces but also emission and absorption of the gas phase and the dust cloud need to be considered.
Furthermore, the radiative heat exchange depends on the geometrical configuration which is continuously changing throughout the process.
The present paper introduces a system model of the EAF which takes into account the radiative heat transfer between the surfaces
and the participating medium. This is attained by the development of a simplified geometrical model,
the use of a weighted-sum-of-gray-gases model, and a simplified consideration of dust radiation.
The simulation results were compared with the data of real EAF plants available in literature.
The following contribution deals with the growth of cracks in low-cycle fatigue (LCF) and thermomechanical fatigue (TMF) tested specimens of Inconel 718 measured by using the replica method. The specimens are loaded with different strain rates. The material shows a significantly higher crack growth rate if the strain rate is decreased. Electron backscatter diffraction (EBSD) is adopted to identify the failure mechanism and the misorientation relationship of failed grain boundaries in secondary cracks. The analyzed cracks propagated mainly transgranular but also intergranular failure can be observed in some areas. It is found that grain boundaries with coincidence site lattice (CSL) boundary structure are generally less susceptible for intergranular failure than grain boundaries with random misorientation. For modeling the experimentally identified crack behavior an existing model for fatigue crack growth based on the mechanism of time dependent elastic–plastic crack tip blunting is enhanced to describe environmental effects based on the mechanism of oxygen diffusion at the crack tip. For the diffusion process the temperature dependent parabolic diffusion law is assumed. As a result, the time dependent cyclic crack tip opening displacement (DCTOD) is used as representative value to describe both mechanisms. Thus, most
of the included model parameters characterize the deformation behavior of the material and can be determined by independent material tests. With the determined material properties, the proposed model describes the experimentally measured crack growth curves very well. The model is validated based on predictions of the number of cycles to failure of LCF as well as in-phase and out-of-phase TMF tests in the temperature range between room temperature and 650 °C.
Cast iron materials are used as materials for cylinder heads for heavy duty internal combustion engines. These components must withstand severe cyclic mechanical and thermal loads throughout their service life. While high-cycle fatigue (HCF) is dominant for the material in the water jacket region, the combination of thermal transients with mechanical load cycles results in thermomechanical fatigue (TMF) of the material in the fire deck region, even including superimposed TMF and HCF loads. Increasing the efficiency of the engines directly leads to increasing combustion pressure and temperature and, thus, lower safety margins for the currently used cast iron materials or alternatively the need for superior cast iron materials. In this paper (Part I), the TMF properties of the lamellar graphite cast iron GJL250 and the vermicular graphite cast iron GJV450 are characterized in uniaxial tests and a mechanism-based model for TMF life prediction is developed for both materials. The model can be used to estimate the fatigue life of components by means of finite-element calculations (Part II of the paper) and supports engineers in finding the appropriate material and design. Furthermore, the effect of the elastic, plastic and creep properties of the materials on the fatigue life can be evaluated with the model. However, for a material selection also the thermophysical properties, controlling to a high level the thermal stresses in the component, must be considered. Hence, the need for integral concepts for material characterization and selection from a multitude of existing and soon-to-be developed cast iron materials is discussed.
A complete thermomechanical fatigue (TMF) life prediction methodology is developed for predicting the TMF life of cast iron cylinder heads for efficient heavy duty internal combustion engines. The methodology uses transient temperature fields as thermal loads for the non-linear structural finite-element analysis (FEA). To obtain reliable stress and strain histories in the FEA for cast iron materials, a time and temperature dependent plasticity model which accounts for viscous effects, non-linear kinematic hardening and tensioncompression asymmetry is required. For this purpose a unified elasto-viscoplastic Chaboche model coupled with damage is developed and implemented as a user material model (USERMAT) in the general purpose FEA program ANSYS. In addition, the mechanismbased DTMF model for TMF life prediction developed in Part I of the paper is extended to three-dimensional stress states under transient non-proportional loading conditions. The material properties of the plasticity model are determined for lamellar graphite cast iron GJL250 and vermicular graphite cast iron GJV450 from isothermal and non-isothermal uniaxial tests. The methodology is applied to obtain a TMF life prediction on two cast iron cylinder heads for heavy duty diesel engine applications made from both cast iron materials. It is shown that the life predictions using the developed methodology correlate very well with observed lives from two bench tests in terms of location as well as number of cycles to failure.
Warmumformwerkzeuge unterliegen während des Betriebes komplexen thermischen und mechanischen Beanspruchungen. In kritischen Bereichen können dadurch lokal Spannungen entstehen, die die Fließgrenze überschreiten. Bei der Serienproduktion führt dies zu zyklischen plastischen Verformungen und zur thermomechanischen Ermüdung, welche die Lebensdauer der Warmumformwerkzeuge maßgeblich bestimmen kann. Zur Bewertung der thermomechanischen Ermüdung der Warmumformwerkzeuge gibt es jedoch heute keine etablierten Konzepte, da dieser Aspekt erst durch die Notwendigkeit einer höheren Ressourcen- und Energieeffizienz und optimierter Produktionsprozesse (beispielsweise im Rahmen von Industrie 4.0) eine höhere Aufmerksamkeit erreicht. In dieser Arbeit wird zum einen die aktuell industriell angewandte Vorgehensweise zur Auslegung von Warmumformwerkzeugen hinsichtlich der Lebensdauer erläutert. Des Weiteren wird ein Überblick über existierende Plastizitätsmodelle und Lebensdauermodelle gegeben. Dabei wird zwischen rein phänomenologischen und mechanismenbasierten Modellen unterschieden. Aus der betriebenen Recherche wird ersichtlich, dass weiterer Forschungsbedarf auf diesem Gebiet notwendig ist.
For the RoboCup Soccer AdultSize League the humanoid robot Sweaty uses a single fully convolutional neural network to detect and localize the ball, opponents and other features on the field of play. This neural network can be trained from scratch in a few hours and is able to perform in real-time within the constraints of computational resources available on the robot. The time it takes to precess an image is approximately 11 ms. Balls and goal posts are recalled in 99 % of all cases (94.5 % for all objects) accompanied by a false detection rate of 1.2 % (5.2 % for all). The object detection and localization helped Sweaty to become finalist for the RoboCup 2017 in Nagoya.
One of the challenges in humanoid robotics is motion control. Interacting with humans requires impedance control algorithms, as well as tackling the problem of the closed kinematic chains which occur when both feet touch the ground. However, pure impedance control for totally autonomous robots is difficult to realize, as this algorithm needs very precise sensors for force and speed of the actuated parts, as well as very high sampling rates for the controller input signals. Both requirements lead to a complex and heavy weight design, which makes up for heavy machines unusable in RoboCup Soccer competitions.
A lightweight motor controller was developed that can be used for admittance and impedance control as well as for model predictive control algorithms to further improve the gait of the robot.
Simulation-based degradation assessment of lithium-ion batteries in a hybrid electric vehicle
(2017)
The insufficient lifetime of lithium-ion batteries is one of the major cost driver for mobile applications. The battery pack in vehicles is one of the most expensive single components that practically must be excluded from premature replacement (i.e., before the life span of the other components end). Battery degradation is a complex physicochemical process that strongly depends on operating condition and environment. We present a simulation-based analysis of lithium-ion battery degradation during operation with a standard PHEV test cycle. We use detailed multiphysics (extended Newman-type) cell models that allow the assessment of local electrochemical potential, species and temperature distributions as driving forces for degradation, including solid electrolyte interphase (SEI) formation [1]. Fig. 1 shows an exemplary test cycle and the predicted resulting spatially-averaged SEI formation rate. We apply a time-upscaling approach to extrapolate the degradation analysis over long time scales, keeping physical accuracy while allowing end-of-life assessment [2]. Results are presented for lithium-ion battery cells with graphite/LFP chemistry. The behavior of these cells in terms of degradation propensity, performance, state of charge and other internal states is predicted during long-term cycling. State of health (SOH) is quantified as capacity fade and internal resistance increase as function of operation time.
Practical bottlenecks associated with commercialization of Lithium-air cells include capacity limitation and low cycling efficiency. The origin of such losses can be traced to complex electrochemical side reactions and reactant mass transport losses[1]. The efforts to minimize such losses include exploration of various electrolytes with additives[2], and cell component geometry and material design. Given the wide range of options for such materials, it is almost impractical to experimentally setup and characterize all those cells. Consequently, modeling and simulation studies are efficient alternatives to analyze spatially and temporally resolved cell behavior for various combinations of materials[3]. In this study, with the help of a two-dimensional multi physics model, we have focused on the effect of electrode and electrolyte interaction (electrochemistry), choice of electrolyte (species transport), and electrode geometry (electrode design) on the performance of a lithium-air button cell. Figure1a shows the schematics of the 2D axisymmetric computational domain. A comparative analysis of five different electrolytes was performed while focusing on the 2D distribution of local current density and the concentration of electro-chemically active species in the cell, that is, O2and Li+. Using two different cathode configurations, namely, flooded electrode and gas diffusion electrode (GDE)[4] at different cathode thickness, the effect of cell geometry and electrolyte saturation on cell performance was explored. Further, a detailed discussion on electrode volume utilization (cf. Figure1b) is presented via changes in the active volume of cathode that produces 90% of the total current with the cell current density for different combinations of electrolyte saturations and cathode thickness.
Simulation-based degradation assessment of lithium-ion batteries in a hybrid electric vehicle
(2017)
Muli-scale thermos-electrochemical modelling of aging mechanisms in an LFP/graphite lithium-ion cell
(2017)
Passive hybridization of battery cell and photovoltaic cell: modeling and experimental validation
(2017)
Electrochemical impedance spectroscopy (EIS) is a widely-used diagnostic technique to characterize electrochemical processes. It is based on the dynamic analysis of two electrical observables, that is, current and voltage. Electrochemical cells with gaseous reactants or products (e.g., fuel cells, metal/air cells, electrolyzers) offer an additional observable, that is, the gas pressure. The dynamic coupling of current and/or voltage with gas pressure gives rise to a number of additional impedance definitions, for which we have introduced the term electrochemical pressure impedance spectroscopy (EPIS) [1,2]. EPIS shows a particular sensitivity towards transport processes of gas-phase or dissolved species, in particular, diffusion coefficients and transport pathway lengths. It is as such complementary to standard EIS, which is mainly sensitive towards electrochemical processes. This sensitivity can be exploited for model parameterization and validation. A general analysis of EPIS is presented, which shows the necessity of model-based interpretation of the complex EPIS shapes in the Nyquist plot (cf. Figure). We then present EPIS simulations for two different electrochemical cells: (1) a sodium/oxygen battery cell and (2) a hydrogen/air fuel cell. We use 1D or 2D electrochemical and transport models to simulate current excitation/pressure detection or pressure excitation/voltage detection. The results are compared to first EPIS experimental data available in literature [2,3].
Bauteilaktivierung
(2015)
Phenolic compounds, such as flavonoids and phenolic acids, are very important substances that occur in various medicinal plants. They show different pharmacological activities which might be useful in the therapy of many diseases. Phenolic compounds have achieved an increasing interest over the last years because these compounds are easily oxidized and, thus, act as strong antioxidants. We present the chemiluminescence of different phenolic compounds measured directly on high-performance thin-layer chromatography LiChrospher® plates using the oxalic acid derivative bis(2,4,6-trichlorophenyl) oxalate (TCPO) in conjunction with H2O2. Our results indicate that chemiluminescence intensity increases with an ascending number of phenolic groups in the molecule. The method can be used to detect phenolic compounds in beverages like coffee, tea, and wine.
We present a videodensitometric quantification method for methadone in syrup, separated by thin-layer chromatography (TLC). The quantification is based on a derivation reaction with Dragendorf reagent. Measurements were carried out using a 16-bit flatbed scanner. The range of linearity covers two magnitudes of power using the Kubelka-Munk expression for data transformation. The separation method is inexpensive, fast, and reliable.
Battery degradation is a complex physicochemical process that strongly depends on operating conditions. We present a model-based analysis of lithium-ion battery degradation in a stationary photovoltaic battery system. We use a multi-scale multi-physics model of a graphite/lithium iron phosphate (LiFePO4, LFP) cell including solid electrolyte interphase (SEI) formation. The cell-level model is dynamically coupled to a system-level model consisting of photovoltaics (PV), inverter, load, grid interaction, and energy management system, fed with historic weather data. Simulations are carried out for two load scenarios, a single-family house and an office tract, over annual operation cycles with one-minute time resolution. As key result, we show that the charging process causes a peak in degradation rate due to electrochemical charge overpotentials. The main drivers for cell ageing are therefore not only a high state of charge (SOC), but the charging process leading towards high SOC. We also show that the load situation not only influences system parameters like self-sufficiency and self-consumption, but also has a significant impact on battery ageing. We assess reduced charge cut-off voltage as ageing mitigation strategy.
One of the practical bottlenecks associated with commercialization of lithium-air cells is the choice of an appropriate electrolyte that provides the required combination of cell performance, cyclability and safety. With the help of a two-dimensional multiphysics model, we attempt to narrow down the electrolyte choice by providing insights into the effect of the transport properties of electrolyte, electrode saturation (flooded versus gas diffusion), and electrode thickness on a single discharge performance of a lithium-air button cell cathode for five different electrolytes including water, ionic liquid, carbonate, ether, and sulfoxide. The 2D distribution of local current density and concentrations of electrochemically active species (O2 and Li+) in the cathode is also discussed w.r.t electrode saturation. Furthermore, the efficacy of species transport in the cathode is quantified by introducing two parameters, firstly, a transport efficiency that gives local insight into the distribution of mass transfer losses, and secondly, an active electrode volume that gives global insight into the cathode volume utilization at different current densities. A detailed discussion is presented toward understanding the design-induced performance limitations in a Li-air button cell prototype.
The DMFC is a promising option for backup power systems and for the power supply of portable devices. However, from the modeling point of view liquid-feed DMFC are challenging systems due to the complex electrochemistry, the inherent two-phase transport and the effect of methanol crossover. In this paper we present a physical 1D cell model to describe the relevant processes for DMFC performance ranging from electrochemistry on the surface of the catalyst up to transport on the cell level. A two-phase flow model is implemented describing the transport in gas diffusion layer and catalyst layer at the anode side. Electrochemistry is described by elementary steps for the reactions occurring at anode and cathode, including adsorbed intermediate species on the platinum and ruthenium surfaces. Furthermore, a detailed membrane model including methanol crossover is employed. The model is validated using polarization curves, methanol crossover measurements and impedance spectra. It permits to analyze both steady-state and transient behavior with a high level of predictive capabilities. Steady-state simulations are used to investigate the open circuit voltage as well as the overpotentials of anode, cathode and electrolyte. Finally, the transient behavior after current interruption is studied in detail.
Lithium-ion batteries show a complex thermo-electrochemical performance and aging behavior. This paper presents a modeling and simulation framework that is able to describe both multi-scale heat and mass transport and complex electrochemical reaction mechanisms. The transport model is based on a 1D + 1D + 1D (pseudo-3D or P3D) multi-scale approach for intra-particle lithium diffusion, electrode-pair mass and charge transport, and cell-level heat transport, coupled via boundary conditions and homogenization approaches. The electrochemistry model is based on the use of the open-source chemical kinetics code CANTERA, allowing flexible multi-phase electrochemistry to describe both main and side reactions such as SEI formation. A model of gas-phase pressure buildup inside the cell upon aging is added. We parameterize the model to reflect the performance and aging behavior of a lithium iron phosphate (LiFePO4, LFP)/graphite (LiC6) 26650 battery cell. Performance (0.1–10 C discharge/charge at 25, 40 and 60°C) and calendaric aging experimental data (500 days at 30°C and 45°C and different SOC) from literature can be successfully reproduced. The predicted internal cell states (concentrations, potential, temperature, pressure, internal resistances) are shown and discussed. The model is able to capture the nonlinear feedback between performance, aging, and temperature.
There is a growing trend for the use of thermo-active building systems (TABS) for the heating and cooling of buildings, because these systems are known to be very economical and efficient. However, their control is complicated due to the large thermal inertia, and their parameterization is time-consuming. With conventional TABS-control strategies, the required thermal comfort in buildings can often not be maintained, particularly if the internal heat sources are suddenly changed. This paper shows measurement results and evaluations of the operation of a novel adaptive and predictive calculation method, based on a multiple linear regression (AMLR) for the control of TABS. The measurement results are compared with the standard TABS strategy. The results show that the electrical pump energy could be reduced by more than 86%. Including the weather adjustment, it could be demonstrated that thermal energy savings of over 41% could be reached. In addition, the thermal comfort could be improved due to the possibility to specify mean room set-point temperatures. With the AMLR, comfort category I of the comfort norms ISO 7730 and DIN EN 15251 are observed in about 95% of occasions. With the standard TABS strategy, only about 24% are within category I.
Adaptive predictive control of thermo-active building systems (TABS) based on a multiple regression algorithm: First practical test. Available from: https://www.researchgate.net/publication/305903009_Adaptive_predictive_control_of_thermo-active_building_systems_TABS_based_on_a_multiple_regression_algorithm_First_practical_test [accessed Jul 7, 2017].
Within this work, the benefits of using predictive control methods for the operation of Adsorption Cooling Machines (ACMs) are shown on a simulation study. Since the internal control decisions of series-manufactured ACMs often cannot be influenced, the work focuses on optimized scheduling of an ACM considering its internal functioning as well as forecasts for load and driving energy occurrence. For illustration, an assumed solar thermal climate system is introduced and a system model suitable for use within gradient-based optimization methods is developed. The results of a system simulation using a conventional scheme for ACM scheduling are compared to the results of a predictive, optimization-based scheduling approach for the same exemplary scenario of load and driving energy occurrence. The benefits of the latter approach are shown and future actions for application of these methods for system control are addressed.
Wie man die Vorlesung "Technische Mechanik 1 - Statik" für alle Beteiligten dynamisch gestaltet
(2017)
Lehrende nehmen vielfältige Veränderungen, insbesondere bei Studienanfängern wahr: Vorkenntnisse, Aufnahme- und Konzentrationsfähigkeit werden zunehmend heterogener. In der Vorlesung „Technische Mechanik 1“ wurde darauf konstruktiv reagiert, indem der Ablauf und die Struktur verändert wurden. Aufgaben und ihre Lösungen stehen im Mittelpunkt des Unterrichts. Neben der Lehrenden als aktiv Handelnde wird jeder Studierende im Lauf des Semesters in den Ablauf integriert und muss individuelle Lösungen der verteilten Aufgaben präsentieren. Im Vergleich entwickeln die Studierenden durch „Lernen am Modell“ dadurch ihre methodischen und fachlichen Fähigkeiten weiter. Um den Studierenden die Relevanz der behandelten Themenbereiche zu verdeutlichen wurden spezielle Aufgaben mit einem lebensweltlichem Bezug entwickelt. Befragungen zeigen, dass die Studierenden von den vielfältigen interaktiven Lernangeboten profitieren und die entwickelten Kompetenzen auch auf andere Lernsituationen übertragen.
We present a two-dimensional (2D) planar chromatographic separation of estrogenic active compounds on RP-18 W (Merck, 1.14296) phase. A mixture of 8 substances was separated using a solvent mix consisting of hexane, ethyl acetate, acetone (55:15:10, v/v) in the first direction and of acetone and water (15:10, v/v) in the second direction. Separation was performed on an RP-18 W plate over a distance of 70 mm. This 2D-separation method can be used to quantify 17α-ethinylestradiol (EE2) in an effect-directed analysis, using the yeast strain Saccharomyces cerevisiae BJ3505. The test strain (according to McDonnell) contains the estrogen receptor. Its activation by estrogen active compounds is measured by inducing the reporter gene lacZ which encodes the enzyme β-galactosidase. This enzyme activity is determined on plate by using the fluorescent substrate MUG (4-methylumbelliferyl-β-d-galactopyranoside).
Modelling and Simulation of Microscale Trigeneration Systems Based on Real- Life Experimental Data
(2017)
For the shift of the energy grid towards a smarter decentralised system flexible microscale trigeneration systems will play an important role due to their ability to support the demand side management in buildings. However to harness their potential modern control methods like model predictive control must be implemented for their optimal scheduling and control. To implement such supervisory control methods, first, simple analytical models representing the behaviour of the components need to be developed. At the Institute of Energy System Technologies in Offenburg we have built a real-life microscale trigeneration plant and present in this paper the models based on experimental data. These models are qualitatively validated and their application in the future for the optimal scheduling problem is briefly motivated.
The transformation of the building energy sector to a highly efficient, clean, decentralised and intelligent system requires innovative technologies like microscale trigeneration and thermally activated building structures (TABS) to pave the way ahead. The combination of such technologies however presents a scientific and engineering challenge. Scientific challenge in terms of developing optimal thermo-electric load management strategies based on overall energy system analysis and an engineering challenge in terms of implementing these strategies through process planning and control. Initial literature research has pointed out the need for a multiperspective analysis in a real life laboratory environment. To this effect an investigation is proposed wherein an analytical model of a microscale trigeneration system integrated with TABS will be developed and compared with a real life test-rig corresponding to building management systems. Data from the experimental analysis will be used to develop control algorithms using model predictive control for achieving the thermal comfort of occupants in the most energy efficient and grid reactive manner. The scope of this work encompasses adsorption cooling based microscale trigeneration systems and their deployment in residential and light commercial buildings.
Microscale trigeneration systems are highly flexible in their operation and thus offer the technical possibility for peak load shifting in building demand side management. However to harness their potential modern control methods such as model predictive control must be implemented for their optimal scheduling. In literature the need for experimental investigation of microscale trigeneration systems to identify typical characteristics of the components and their interactions has been identified. On a real-life setup control specific information of the components is collected and lessons learnt during commissioning of the equipment is shared. The data is analysed to draw the vital characteristics of the system and it will be used for creating models of the components that can be utilised for optimal control.
The energy system of the future will transform from the current centralised fossil based to a decentralised, clean, highly efficient, and intelligent network. This transformation will require innovative technologies and ideas like trigeneration and the crowd energy concept to pave the way ahead. Even though trigeneration systems are extremely energy efficient and can play a vital role in the energy system, turning around their deployment is hindered by various barriers. These barriers are theoretically analysed in a multiperspective approach and the role decentralised trigeneration systems can play in the crowd energy concept is highlighted. It is derived from an initial literature research that a multiperspective (technological, energy-economic, and user) analysis is necessary for realising the potential of trigeneration systems in a decentralised grid. And to experimentally quantify these issues we are setting up a microscale trigeneration lab at our institute and the motivation for this lab is also briefly introduced.
Biological in situ methanation: Gassing concept and feeding strategy for enhanced performance
(2017)
The expansion of fluctuating renewable electricity production from wind and solar energy requires huge storage capacities. Power-to-gas (PtG) can contribute to tackle that issue via a two-step process, the electrolytic production of hydrogen and a subsequent methanation step (with additional CO2). The resulting fully grid compatible methane, also known as synthetic natural gas (SNG), can be both stored and transported in the vast existing natural gas infrastructure.
To overcome current major drawbacks of PtG, the relatively low efficiency and the high costs, we developed an improved method for the methanation step. In our approach we use a further development of the biological in situ methanation of hydrogen in biogas plants. Because this strategy uses directly internal residual CO2 from the biogas process in the biogas plant, you neither need additional external CO2 nor special reactors. Thus, PtG is combined with the production of an upgraded highly methane rich raw biogas.
However, the low solubility of hydrogen in aqueous solutions and the exploitation of the maximum biological production rates are still an engineering challenge for high performance biological in situ methanation.
In our experiments a setup with membrane gassing turned out to be most promising to ensure a sufficient gas liquid mass transfer of the hydrogen. The monitoring of hydrogenotrophic and aceticlastic archaea showed some adaption of these microbial subgroups to the hydrogen feed.
In order to achieve high methane concentrations of more than 90 % in the raw biogas a CO2-controlled hydrogen feed flow rate is suggested. For methane concentrations lower than 90 % simple current controlled hydrogen supply can be applied.
Für den Einsatz im Maschinen- und Fahrzeugbau soll eine neuartige Metall-Kohlenstoff-Verbundbeschichtung entwickelt werden, in der die positiven Eigenschaften der Komponenten Molybdän, Wolfram und Kohlenstoff hinsichtlich von Verschleiß- und Temperaturbeständigkeit kombiniert werden sollen. Das Schichtsystem Mo-W-C wird im Verfahren des reaktiven Magnetron-Sputterns hergestellt. In insgesamt 28 Chargen werden systematisch die Prozessparameter Sputtergasfluss (Argon), Prozessgasfluss (C2H2), Kathodenleistungsverteilung (insgesamt konstant, variierte Aufteilung auf die zwei Metalltargets aus Mo und W), Bias-Spannung und Bias-Strom variiert. Anhand der Untersuchungen zu Zusammensetzung, Verschleißeigenschaften, Härte, E-Modul, Struktur und Haftung der Beschichtung mittels mechanischer, optischer und chemischer Prüfverfahren sollen die Einflüsse der Prozessparameter ermittelt werden. Durch vergleichendes Gegenüberstellen wird gezeigt, dass besonders gute Resultate hinsichtlich Härte, E-Modul und Haftung bei den niedrigsten eingestellten Werten für Bias-Spannung (100 V), Bias-Strom (2 A) und C2H2-Gasfluss (30 sccm) sowie dem höchsten eingestellten Argon-Gasfluss (55 sccm) erzielt werden. Gute Verschleißraten werden grundsätzlich bei einer Bias-Spannung von 200 V, einem Bias-Strom von 3 A und einem Argon-Gasfluss von 55 sccm erzielt. Die im Rahmen dieser Arbeit ermittelten Daten stellen die Grundlage für weitere Untersuchungen dar, die das Ziel verfolgen, eine ideale Parameterauswahl für das Schichtsystem Mo-W-C im reaktiven Magnetron-Sputterprozess zu entwickeln.
Die vorliegende Erfindung betrifft ein Verfahren zum Pulverlackieren eines Kunststoff- oder Glasgegenstandes, umfassend die Schritte des Ausbildens einer polaren Beschichtung auf dem Kunststoff- oder Glasgegenstand, umfassend den Teilschritt des Aufbringens einer Beschichtungszusammensetzung auf den Kunststoff- oder Glasgegenstand, wobei die Beschichtungszusammensetzung ein Organosiloxan, das mindestens zwei Si-O-Bindungen aufweist, Wasser, ein organisches Lösemittel und ein pH-regulierendes Mittel, ausgewählt aus einer Brönsted-Säure, in einer katalytischen Menge enthält, mit der Maßgabe, dass die Beschichtungszusammensetzung keinen elektrisch leitfähigen Zusatz, ausgewählt aus ionischen Verbindungen, Metallen, Metall(misch)oxiden, intermetallischen Verbindungen und leitfähigem Kohlenstoff, enthält, sowie die Schritte des Aufbringens eines Pulverlacks auf den derartig beschichteten Kunststoff- oder Glasgegenstand und des Erwärmens des Pulverlacks.
Es wird ein Verfahren zur Herstellung eines nicht geschäumten porösen monolithischen oder faserförmigen Produkts aus anorganischem Polymer beschrieben, bei dem Wasserglas mit einem Carbonat und/oder Amid in bestimmten Mengen in Gegenwart von Wasser gehärtet wird. Außerdem werden monolithische Chromatographiesäulen und -platten, geträgerte Metall-Katalysatoren und Vliese beschrieben.
Die vorliegende Erfindung betrifft ein Verfahren zum Pulverlackieren eines Kunststoffgegenstandes, umfassend die Schritte des Ausbildens einer polaren Beschichtung auf dem Kunststoffgegenstand, umfassend den Teilschritt des Aufbringens einer Beschichtungszusammensetzung auf den Kunststoffgegenstand, wobei die Beschichtungszusammensetzung ein Organosiloxan, das mindestens zwei Si-O-Bindungen aufweist, Wasser, ein organisches Lösemittel und ein pH-regulierendes Mittel enthält, mit der Maßgabe, dass die Beschichtungszusammensetzung keinen elektrisch leitfähigen Zusatz enthält, sowie die Schritte des Aufbringens eines Pulverlacks auf den derartig beschichteten Kunststoffgegenstand und des Erwärmens des Pulverlacks.
Poröse Massen oder Formkörper aus anorganischen polymeren und deren Herstellung (EP000002958875A1)
(2015)
The invention relates to the field of transporting flat substrates such as silicon substrates. In particular, the invention relates to particularly protective and continuous transport of such substrates. The method according to the invention is used to transport a vertically aligned flat substrate (1) comprising two flat sides in a transport direction inside a transport channel (2) that is at least partially filled with a liquid medium (F), wherein said liquid medium (F) flows against at least one of the flat sides of the substrate (1) and has a supporting component, which lifts the sum of the weight and buoyancy force of the substrate (1), and an advancing component, which is directed in the transport direction, so that the substrate (1) is supported and transported without mechanical aids. The device according to the invention comprises a transport channel (2) for accommodating a liquid medium (F) and a substrate (1) to be guided in vertical alignment within said medium (F), wherein the transport channel (2) has inflow openings (5) in the walls (3, 4).
Die vorliegende Erfindung betrifft ein Verfahren zum Pulverlackieren eines Glasgegenstandes, umfassend die Schritte des Ausbildens einer polaren Beschichtung auf dem Glasgegenstand, umfassend den Teilschritt des Aufbringens einer Beschichtungszusammensetzung auf den Glasgegenstand, wobei die Beschichtungszusammensetzung ein Organosiloxan, das mindestens zwei Si-O-Bindungen aufweist, Wasser, ein organisches Lösemittel und ein pH-regulierendes Mittel enthält, mit der Maßgabe, dass die Beschichtungszusammensetzung keinen elektrisch leitfähigen Zusatz enthält, sowie die Schritte des Aufbringens eines Pulverlacks auf den derartig beschichteten Glasgegenstand und des Erwärmens des Pulverlacks.
A crack opening stress equation for in-phase and out-of-phase thermomechanical fatigue loading
(2016)
In this paper, a crack opening stress equation for in-phase and out-of-phase thermomechanical fatigue (TMF) loading is proposed. The equation is derived from systematic calculations of the crack opening stress with a temperature dependent strip yield model for both plane stress and plane strain, different load ratios and different ratios of the temperature dependent yield stress in compression and tension. Using a load ratio scaled by the ratio of the yield stress in compression and tension, the equation accounts for the effect of the temperature dependent yield stress and the constraint on the crack opening stress. Based on the scaling relation established in this paper, Newman's crack opening stress equation for isothermal loading is enabled to predict the crack opening stress under TMF loading.
Optimal microgrid scheduling with peak load reduction involving an electrolyzer and flexible loads
(2016)
This work consists of a multi-objective mixed-integer linear programming model for defining optimized schedules of components in a grid-connected microgrid. The microgrid includes a hydrogen energy system consisting of an alkaline electrolyzer, hydrogen cylinder bundles and a fuel cell for energy storage. Local generation is provided from photovoltaic panels, and the load is given by a fixed load profile combined with a flexible electrical load, which is a battery electric vehicle. The electrolyzer has ramp-up constraints which are modeled explicitly. The objective function includes, besides operational costs and an environmental indicator, a representation of peak power costs, thus leading to an overall peak load reduction under optimized operation. The model is used both for controlling a microgrid in a field trial set-up deployed in South-West Germany and for simulating the microgrid operation for defined period, thus allowing for economic system evaluation. Results from defined sample runs show that the energy storage is primarily used for trimming the peak of electricity drawn from the public grid and is not solely operated with excess power. The flexible demand operation also helps keeping the peak at its possible minimum.
Planung und Inbetriebnahme der raumlufttechnischen Anlage für einen Reinraum in der Pharmazie
(2016)
Eine zentrale Frage der Arbeit ist, wie sich die Änderungen der Probengeometrien, in Abhängigkeit der Versuchs- und Regelparameter, auf die Messergebnisse auswirken. Ziel ist es, Referenzlösungen für eine optimale und reproduzierbare Versuchsdurchführung zu erstellen. Gegebenenfalls muss dabei von der Norm ISO 37 abgewichen werden. Des Weiteren wird die optische Dehnungsmessung untersucht und auf die Versuche angepasst.
Die von der Bundesregierung beschlossene Energiewende stellt Politik und Gesellschaft, Wirtschaft und Wissenschaft vor große Herausforderungen. Entscheidend für den Erfolg der Energiewende wird es sein, die Wettbewerbsfähigkeit des Industriestandortes Deutschland zu erhalten. Dafür muss weiterhin eine hohe Stromversorgungsqualität bei zugleich international wettbewerbsfähigen Strompreisen sichergestellt sein. Der BDI stellt fünf Prinzipien auf dem Weg zu einem neuen Strommarktdesign auf und zeigt, dass eine informations- und kommunikationstechnische Vernetzung relevanter Komponenten des Energiesystems für das künftige System essenziell ist.
Die Weltwirtschaftskrise 2008 hat mit ihrer zeitweisen Verknappung von Acetonitril eindringlich gezeigt, dass man nicht nur auf eine einzige chromatographische Methode setzten sollte. Genau dies wird aber im Augenblick getan, denn Industrie und Forschung setzen mehrheitlich auf die High Performance Liquid Chromatography (HPLC) als die Trennmethode ihrer Wahl. Für viele Anwendungen in der Pharmazie, in der Umweltanalytik, der Lebensmittelanalytik, aber auch in der Inprozesskontrolle gibt es mit der Dünnschichtchromatografie eine Alternative.
Vorrichtung (2) zur Analyse von Urin, umfassend: – eine Zuführ- und Abführeinrichtung (7), welche zur Zuführung einer bestimmten Urinmenge in eine wenigstens einen Analysebereich (8) aufweisende Analysekammer (9) eines Urinteststreifens (10) und zur Abführung einer bestimmten Urinmenge aus einer wenigstens einen Analysebereich (8) aufweisenden Analysekammer (9) eines Urinteststreifens (10) eingerichtet ist, wobei die Zuführ- und Abführeinrichtung (7) wenigstens ein bewegbar gelagertes Zuführ- und/oder Abführelement (28, 29) zum Zuführen einer bestimmten Urinmenge in einen Zuführbereich (33) der Analysekammer (9) des Urinteststreifens (10) und/oder zum Abführen einer bestimmten Urinmenge aus einem Abführbereich (34) der Analysekammer (9) des Urinteststreifens (10) aufweist, und – eine Erfassungseinrichtung (11), welche zur Erfassung einer zumindest abschnittsweisen Änderung wenigstens eines optisch erfassbaren Parameters, welcher sich in Abhängigkeit der Zusammensetzung einer diesen kontaktierenden Urinmenge optisch erfassbar verändert, des oder eines entsprechenden Analysebereichs (8) des oder eines entsprechenden Urinteststreifens (10) sowie zur Erzeugung einer Erfassungsinformation, welche wenigstens einen optisch erfassten Parameter des oder eines entsprechenden Analysebereichs (8) oder eine Änderung eines solchen beschreibt, eingerichtet ist.
In this paper fatigue crack closure under in-phase and out-of-phase thermomechanical fatigue (TMF) loading is studied using a temperature dependent strip yield model. It is shown that fatigue crack closure is strongly influenced by the phase relation between mechanical loading and temperature, if the temperature difference goes along with a temperature dependence of the yield stress. In order to demonstrate the effect of the temperature dependent yield stress, the influence of in-phase and out-of-phase TMF loading is studied for a polycrystalline nickel-base superalloy. By using a mechanism based lifetime model, implications for fatigue lives are demonstrated.
To do justice to the legacy of Alexander von Humboldt, a 19th century German scientist and explorer an information and knowledge management system is required to preserve the author’s original intent and promote an awareness of all his relevant works. Although all of Humboldt's works can be found on the internet as digitized papers, the complexity and internal interconnectivity of the writings is not very transparent. Humboldt's concepts of interaction cannot be adequately represented only by digitized papers or scanned documents.
The Humboldt Portal is an attempt to create a new generation of digital libraries, providing a new form of interaction and synthesis between humanistic texts and scientific observation. The digital version of his documents supplies dynamic links to sources, maps, images, graphs and relevant texts in accordance with his visions, because “everything is interconnectedness”.
Aqueous lithium–oxygen batteries are promising candidates for electric energy storage. In this paper we present and discuss a multiphase continuum model of an aqueous lithium–oxygen single cell including reactions and transport in a porous gas diffusion electrode (GDE). The model is parameterized using in-house half-cell experiments and available literature data on aqueous electrolytes. We validate our transport model with cyclic voltammetry and electrochemical impedance spectroscopy measurements over a wide range of temperatures (25, 40, 55 °C) and electrolyte concentrations (0.1–2 M). We observe very good agreement between simulations and measurements during oxygen reduction conditions. A sensitivity analysis of the validated model demonstrates the influence of the porous structure on GDE performance and gives directions for the future development of electrodes.
Empirische Untersuchungen zum visuellen Wahrnehmen beim Lesen und Verstehen technischer Zeichnungen
(2016)
Es wurden 49 Einzelpersonen aus dem Studiengang „Maschinenbau“ der Hochschule Offenburg bei der Lösungssuche für eine zeichnerische Aufgabe mit Hilfe der Eyetracking-Technik beobachtet. Aus den Experimenten ergeben sich Aufschlüsse über das tatsächliche Vorgehen von Studierenden beim Lesen technischer Zeichnungen. Die Analyse der empirischen Untersuchungen legt die Vermutung nahe, dass die zunehmende Digitalisierung der Gesellschaft und der zunehmende Umgang mit elektronischen Kleinstgeräten verstärkt zu einem punktuellen und schnellen Wahrnehmungsverhalten führen. Ruhe und Gelassenheit im Umgang mit Informationen gehen verloren, ebenso das Denken im Kontext. Somit muss es Aufgabe der Lehre sein, wieder verstärkt ein ruhiges, strukturiertes und auf Zusammenhänge ausgerichtetes Vorgehen zu vermitteln und zu üben.
Der hier vorliegende Beitrag beschreibt die mit der Finite-Elemente-Methode (FEM) gewonnenen Untersuchungsergebnisse zur Bestimmung von Stützziffern und Kerbwirkungszahlen bei Getriebewellen. Es handelt sich dabei zum einen um die Kerbüberlagerung einer umlaufenden Halbkreisnut in Kombination mit überlagerter Querbohrung. Da zur Bestimmung der Stützwirkungszahlen die Berechnung der bezogenen Spannungsgradienten in Tiefenrichtung benötigt wird, wurden die Parameter der Kerbgeometrie (der Umlaufnutradius sowie der Querbohrungsdurchmesser) variiert. Als Ergebnis dieser Arbeit wurde festgehalten, dass sich die Formzahl infolge der Durchdringungskerbe im Vergleich zur Formzahl einer Einzelkerbe (z. B. Umlaufnut oder Querbohrung) erhöht und dementsprechend erhöht sich die Kerbwirkungszahl deutlich im Vergleich zu einer Einzelkerbe. Die numerisch erfassten Kerbwirkungszahlen
an den erforschten Durchdringungskerben wurden mit analytischen Ansätzen aus der Fachliteratur verglichen. Entsprechende Diagramme und Zahlenwerte werden zur Abschätzung der Kerbwirkungs- und Stützzahlen je nach Belastungsart Torsion, Biegung und Zug/Druck angegeben.
In diesem Beitrag wird die Anwendbarkeit von bereits in der Literatur beschriebenen und in der Praxis bewährten Entlastungsgeometrien für Wellenabsätze auf Zahnwellen mit freiem Auslauf mit der Methode der Finiten Elemente FEM untersucht. Dabei zeigte sich, dass eine direkte Verwendung der bestehenden Vorschläge nicht immer möglich war. Deshalb wurden diese Entlastungsnuten und -übergänge für eine beanspruchungsgerechte Anwendung im Bereich der Zahnwellen modifiziert und optimiert. Basierend auf den dabei erzielten Ergebnissen wurden neue konstruktive Möglichkeiten zur günstigsten Ausprägung der freien Auslaufgestaltung entwickelt und erforscht. Der beobachtete merkliche Abfall der Kerbspannung infolge von Entlastungsmöglichkeiten soll dem Konstrukteur einen Anlass geben, diese häufiger anzuwenden. Die Industrie, insbesondere kleinere Betriebe, können mithilfe der in diesem Aufsatz vorliegenden Erkenntnisse durch optimierte Dimensionierung der Profiwellen Kosten und Bauteilgewicht sparen.
Um Rückschlüsse auf das Vorgehen von Studierenden beim Lesen technischer Darstellungen ziehen zu können, wurden 49 Probanden aus dem Studiengang „Maschinenbau“ der Hochschule Offenburg bei ihrer Lösungssuche für eine zeichnerische Aufgabe mit Hilfe der Eyetracking-Technik beobachtet. Die Analyse der empirischen Untersuchungen legt die Vermutung nahe, dass die zunehmende Digitalisierung der Gesellschaft verstärkt zu einem punktuellen und flüchtigen Wahrnehmungsverhalten führen. Ruhe und Gelassenheit im Umgang mit Informationen gehen verloren, ebenso das Denken im Kontext. Nach Ansicht der Autoren sollte in der Ausbildung deshalb eine stärkere Konzentration auf die Grundbausteine und die grundlegenden Zusammenhänge des jeweiligen Fachgebietes, Entschleunigung, Förderung von Versteh-, Abstraktions- und Denkfähigkeit und auf der Motivation zur studentischen Eigenleistung liegen.
Der vorliegende Beitrag beschreibt erste Untersuchungsergebnisse an Wellenabsätzen mit im Kerbgrund überlagerter Schrägbohrung, mit Hilfe der Finite-Elemente-Methode (FEM). Als Beispiel hierfür können Walzen mit Heizkanälen in Walzwerken, Turbinen- und Kurbelwellen genannt werden. Es ist nicht bekannt, welche Spannungserhöhung die Schrägbohrung im Wellenabsatz hervorruft. In den Normen oder Richtlinien sind keine Angaben über Formzahlen für diese Kerbkombination vorhanden. Deshalb werden die Formzahlen für unterschiedliche schräggebohrte Wellenabsätze je Belastungsart ermittelt, ausgewertet und entsprechende Formzahldiagramme und Gestaltungshinweise angegeben.
Seven cell design concepts for aqueous (alkaline) lithium–oxygen batteries are investigated using a multi-physics continuum model for predicting cell behavior and performance in terms of the specific energy and specific power. Two different silver-based cathode designs (a gas diffusion electrode and a flooded cathode) and three different separator designs (a porous separator, a stirred separator chamber, and a redox-flow separator) are compared. Cathode and separator thicknesses are varied over a wide range (50 μm–20 mm) in order to identify optimum configurations. All designs show a considerable capacity-rate effect due to spatiotemporally inhomogeneous precipitation of solid discharge product LiOH·H2O. In addition, a cell design with flooded cathode and redox-flow separator including oxygen uptake within the external tank is suggested. For this design, the model predicts specific power up to 33 W/kg and specific energy up to 570 Wh/kg (gravimetric values of discharged cell including all cell components and catholyte except housing and piping).
We present a two dimensional (2D) planar chromatographic separation of estrogenic active compounds on RP-18 (Merck, 1.05559) and silica gel (Merck, 1.05721) phase. A mixture of 13 substances was separated using a solvent mix consisting of methanol–acetonitrile–water (2 + 2 + 1, v/v/v) on RP-18 phase in the first direction and cyclohexane–butylacetate–methanol (8 + 6 + 1, v/v/v) in the second direction on silica gel plate. Both developments were carried out over a distance of 70 mm. We used the grafted method to combine both plates in a 2D-separation. This 2D-separation method can be used to quantify 17α-ethinylestradiol (EE2) in an effect-directed analysis using the yeast strain Saccharomyces cerevisiae BJ3505. The test strain (according to McDonnell) contains the estrogen receptor. Its activation by estrogen active compounds is measured by inducting the reporter gene lacZ that encodes the enzyme ß-galactosidase. This enzyme activity is determined on plate by using the fluorescent substrate MUG (4-methylumbelliferyl ß-D-galactopyranoside).