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Diese Arbeit erläutert die Grundlagen, Abläufe und Formen der Vermarktung von Profifußballern. Das Social Media Marketing wird in diesem Zusammenhang auch für Profifußballer immer wichtiger und ist eines der Kernthemen dieser Arbeit. Social Media Marketing wird dazu in den Gesamtbereich Sportmarketing bzw. Sportlervermarktung eingeordnet und untersucht. Anhand von Beispielen aus dem Profifußball werden Strategien, Tendenzen und Aussichten für das Thema Social Media Marketing für Profifußballer dargestellt und erklärt.
Im Berufsbereich Medien existieren innerhalb einer Berufsuntergruppe die duale Ausbildung zur/zum Mediengestalter/-in Digital und Print sowie die vollzeitschulische Ausbildung zur/zum staatlich-geprüften Grafikdesigner/-in. In der vorliegenden Arbeit werden anhand dieser beiden Ausbildungsberufe die Ausbildungsformen verglichen, deren Stellenwert beleuchtet sowie die Vor- und Nachteile analysiert. Hierfür werden zunächst die theoretischen Hintergründe erarbeitet und die verschiedenen Perspektiven untersucht. Dieser Teil der Arbeit bildet dann die Basis zur Erstellung konkreter Fragen, anhand derer mit einer geeigneten Forschungsmethode empirische Daten erhoben werden sollen. Diese sollen im Anschluss ausgewertet, analysiert und interpretiert werden um möglichst präzise die Forschungsfrage beantworten zu können.
Die vorliegende Arbeit beschäftigt sich mit der Wahrnehmung von Websites im One-Page-Design und der Verbesserung der User Experience mit Hilfe von Blickaufzeichnung und weiteren Methoden.
Für ein Unternehmen ist eine Website mittlerweile ein zentrales Marketinginstrument. Eine gute Umsetzung der Website ist maßgeblich am Unternehmenserfolg beteiligt.
Eine bedeutende Rolle für eine Website spielt das Webdesign. Dies beeinflusst entscheidend, ob das Interesse des Nutzers geweckt wird und er auf der Website verweilt oder diese direkt wieder verlässt. Doch das Webdesign verändert sich laufend. Ein neuer Trend ist die Website im One-Page-Design. Diese bietet neue Möglichkeiten der Gestaltung, stellt Webdesigner jedoch auch bei der Umsetzung vor neue Herausforderungen. Mit der vorliegenden Arbeit sollen deshalb Websites im One-Page-Design hinsichtlich ihrer Wirkung auf den Nutzer analysiert werden. Zu diesem Zweck werden mit ausgewählten Probanden User Experience Tests durchgeführt, die Aufschluss darüber geben sollen, wie die Zielgruppe mit der Website interagiert. Durch die Analyse der gewonnenen Daten und die daraus abgeleiteten Handlungsempfehlungen kann die User Experience von Websites im One-Page-Design gesteigert werden. Neben der Eyetracking-Methode (Blickaufzeichnung) wird die Think Aloud-Methode, der Interview-Leitfragen sowie die Mimikmessung eingesetzt.
Der Begriff Crowdfunding hat im Laufe der vergangenen Jahre an Bedeutung gewonnen und ist heute immer mehr Menschen bekannt. Crowdfunding gibt den Künstlern die Möglichkeit, finanzielle Unterstützung von vielen, vor allem privaten, Geldgebern zu erhalten. Viele Crowdfunding-Projekte scheitern, weil nicht genug Geld gesammelt werden kann. Was aber tatsächlich der Grund für das Scheitern des Projekts war bleibt vielen Künstlern unklar. Diese wissenschaftliche Arbeit soll sich auf der einen Seite mit den Gründen dieses Scheiterns beschäftigen, auf der anderen Seite aber auch aufzeigen, was erfolgreiche Crowdfunding-Projekte ausmacht. Diese Gründe sollen in Form von einzelnen erfolgssteigernden Faktoren, den Erfolgsfaktoren, erklärt und anschließend in Form einer multiplen Fallstudie untersucht werden. Der starke Bezug zur praktischen Anwendung in Crowdfunding-Projekten entsteht unter anderem durch Studien und Experteninterviews aus verschiedenen Quellen, aber auch durch die durchgeführte Fallstudie. Durch die Beachtung der erforschten Faktoren können Finanzierungen über Crowdfunding-Kampagnen eher erfolgreich abgeschlossen werden und die Musiker ihren künstlerischen Zielen wesentlich näher gebracht werden.
Diese Arbeit beschäftigt sich mit den verschiedenen Technologien, welche in verteilten Systemen zur Kommunikation dienen können. Kernpunkt der Arbeit ist es, eine Schnittstelle zu schaffen, in der eine extrem hohe Anzahl einzelner Anwendungen untereinander und mit einer zentralen Simulationsumgebung weitestgehend automatisch - kommunizieren können. Dabei ist auch ein wesentlicher Punkt die Frage wie Daten ausgetauscht werden können. Betrachtet man zunächst das System an sich, so wird es deutlich, dass speziell für die Entwicklung des Gesamtsystems, die Stabilität, Leistungsfähigkeit und Zuverlässigkeit des Interfaces von enormer Wichtigkeit ist.
Instagram-Marketing: Erfolgsfaktoren und Handlungsempfehlungen am Beispiel der Kosmetikindustrie
(2015)
Das Ziel dieser Arbeit lag darin, Faktoren, die den Erfolg eines Instagram-Auftritts von Kosmetik produzierenden oder vertreibenden Unternehmen aus dem deutsch-sprachigen Raum steigern, zu ermitteln und auf Grundlage der Ergebnisse Handlungs-empfehlungen auszusprechen. Im Zuge dessen wurden sieben qualitative Befragungen von Experten durchgeführt und anschließend mit Hilfe der zusammen-fassenden Inhaltsanalyse nach Mayring ausgewertet. Aus der empirischen Studie geht hervor, dass Instagram bereits jetzt eine große Rolle im Social-Media-Mix einnimmt und Unternehmen primär Ziele des Brandings und der Markenrepräsentation auf Instagram verfolgen. Desweiteren konnten mit Hilfe der leitfadengestützten Experteninterviews 15 Faktoren identifiziert werden, die positiven Einfluss auf das Instagram-Marketing ausüben: Persönlichkeit, Qualität, Authentizität, Aktualität, Kanalmix, Hashtags, Videos, die Verknüpfung mit anderen Unternehmensbereichen, Transparenz, Relevanz, Influencer-Relations, Community, Bestätigung und Management. Als am bedeutend-sten haben sich die Punkte Persönlichkeit, Qualität und Relevanz gezeigt: Marken stehen demnach vor der Herausforderung, ästhetische, zielgruppenrelevante Inhalte, die an die Eigenheiten Instagrams als Plattform angepasst sind, zu veröffentlichen und auf Augenhöhe mit den Nutzern zu kommunizieren, ohne sich selbst als Marke zu verlieren. Ferner führte die Expertenbefragung zu der Erkenntnis, dass Instagram sowohl als Community als auch als Marketing-Tool weiterhin an Bedeutung gewinnen wird, vor allem im deutschen Raum und in der Beauty-Branche.
Diese Thesis befasst sich mit einer Erweiterung für die bestehende SoftwareSIDEXIS 4 der Firma Sirona GmbH. Die Funktion der Erweiterung besteht darin, Röntgenbilder eines Patienten zum Herunterladen bereit zu stellen. Dabeiwerden die Bilddateien verschlüsselt auf eine Online-Plattform hochgeladen undein Quick-Response-Code (QR-Code) zu der Internet-Adresse der Ressource generiert. Der Patient hat die Möglichkeit, durch Abfotografieren des QR-Codes,seine Röntgenbilder einzusehen und diese zu speichern. Fragen in Bezug auf dieDatensicherheit im Bereich von Patientendaten, werden ebenfalls ausführlich beschrieben und behandelt.
Die Motivation zur Entwicklung dieser Erweiterung ist eine flexible, modernePatientenkommunikation. Dadurch kann der Patient seine Bilder digital mit sichführen und gegebenenfalls weiter verwalten.
Rechtliche Dimension des Journalismus: Redaktionelle Verantwortung und User Generated Content
(2015)
Journalismus wandelt sich durch die Einbeziehung von User Generated Content. Dies hat nicht nur publizistische Folgen, sondern führt auch zu Problemen im Bereich der medienrechtlichen Verantwortung für die so publizierten Inhalte. Vor allem urheber- und persönlichkeitsrechtlichen Fragen sind für neue digitale Produkte zu prüfen. Insgesamt zeigt sich auch aus rechtlicher Sicht, dass eine Kombination unter Einbeziehung klassischer journalistischer Strukturen hilfreich ist, während rein von anonymen Nutzern gestaltete Produkte erhebliche Risiken bergen.
Covert and Side-Channels have been known for a long time due to their versatile forms of appearance. For nearly every technical improvement or change in technology, such channels have been (re-)created or known methods have been adapted. For example the introduction of hyperthreading technology has introduced new possibilities for covert communication between malicious processes because they can now share the arithmetic logical unit (ALU) as well as the L1 and L2 cache which enables establishing multiple covert channels. Even virtualization which is known for its isolation of multiple machines is prone to covert and side-channel attacks due to the sharing of resources. Therefore itis not surprising that cloud computing is not immune to this kind of attacks. Even more, cloud computing with multiple, possibly competing users or customers using the same shared resources may elevate the risk of unwanted communication. In such a setting the ”air gap” between physical servers and networks disappears and only the means of isolation and virtual separation serve as a barrier between adversary and victim. In the work at hand we will provide a survey on weak spots an adversary trying to exfiltrate private data from target virtual machines could exploit in a cloud environment. We will evaluate the feasibility of example attacks and point out possible mitigation solutions if they exist.
Bluetooth Low Energy extends the Bluetooth standard in version 4.0 for ultra-low energy applications through the extensive usage of low-power sleeping periods, which inherently difficult in frequency hopping technologies. This paper gives an introduction into the specifics of the Bluetooth Low Energy protocol, shows a sample implementation, where an embedded device is controlled by an Android smart phone, and shows the results of timing and current consumption measurements.
Massiv gescheitert
(2015)
EuGH "Videoüberwachung"
(2015)
We propose secure multi-party computation techniques for the distributed computation of the average using a privacy-preserving extension of gossip algorithms. While recently there has been mainly research on the side of gossip algorithms (GA) for data aggregation itself, to the best of our knowledge, the aforementioned research line does not take into consideration the privacy of the entities involved. More concretely, it is our objective to not reveal a node's private input value to any other node in the network, while still computing the average in a fully-decentralized fashion. Not revealing in our setting means that an attacker gains only minor advantage when guessing a node's private input value. We precisely quantify an attacker's advantage when guessing - as a mean for the level of data privacy leakage of a node's contribution. Our results show that by perturbing the input values of each participating node with pseudo-random noise with appropriate statistical properties (i) only a minor and configurable leakage of private information is revealed, by at the same time (ii) providing a good average approximation at each node. Our approach can be applied to a decentralized prosumer market, in which participants act as energy consumers or producers or both, referred to as prosumers.
Eine Mitte November veröffentlichte EU-Richtlinie sieht vor, dass ab 2017 Unternehmen mit durchschnittlich mehr als 500 Mitarbeitern bestimmte Nachhaltigkeitsangaben im Lagebericht veröffentlichen müssen. Auf den ersten Blick scheint hier weiterer administrativer Ballast für die wenigen betroffenen Genossenschaftsbanken zu entstehen. Doch daraus ergeben sich für die Institute auch Chancen. Es lohnt sich zu prüfen, ob ein aktives Nachhaltigkeitsmanagement sinnvoll erscheint.
Wir brauchen mehr Klarheit
(2015)
In online analytical processing (OLAP), filtering elements of a given dimensional attribute according to the value of a measure attribute is an essential operation, for example in top-k evaluation. Such filters can involve extremely large amounts of data to be processed, in particular when the filter condition includes “quantification” such as ANY or ALL, where large slices of an OLAP cube have to be computed and inspected. Due to the sparsity of OLAP cubes, the slices serving as input to the filter are usually sparse as well, presenting a challenge for GPU approaches which need to work with a limited amount of memory for holding intermediate results. Our CUDA solution involves a hashing scheme specifically designed for frequent and parallel updates, including several optimizations exploiting architectural features of Nvidia’s Fermi and Kepler GPUs.
Cardiac resynchronization therapy (CRT) is an established class I level A biventricular pacing therapy in chronic heart failure patients with left bundle branch block and reduced left ventricular ejection fraction, but not all patients improved clinically. Purpose of the study was to evaluate electrical interatrial conduction delay (IACD) to interventricular conduction delay (IVCD) ratio with focused transesophageal left atrial and left ventricular electrocardiography.
Methods: Thirty eight chronic heart failure patients (age 63.4±10.2 years; 3 females, 35 males) with New York Heart Association (NYHA) functional class 3.0±0.2 and 171.71±36.17ms QRS duration were analysed using posterior left atrial and left ventricular transesophageal electrocardiography with hemispherical electrodes before CRT. Electrical IACD was measured between onset of P-wave in the surface ECG and onset of left atrial signal. Electrical IVCD was measured between onset of QRS complex in the surface ECG and onset of left ventricular signal.
Results: Electrical IACD and IVCD could be evaluated by transesophageal left atrial and left ventricular electrocardiography in all heart failure patients with correlation to 1.18±0.92 IACD-IVCD-ratio (r=-0.57, P<0.001; r=0.66, P<0.001). There were 32 CRT responder with reduction of NYHA class from 3.0±0.22 to 1.97±0.31 (P<0.001) during 16.5±18.9 month CRT with 75.19±33.49ms IACD, 78.91±24.73ms IVCD, 1.04±0.66 IACD-IVCD-ratio and correlation between IACD and IACDIVCD- ratio (r=0.84, P<0.001). There were 6 CRT nonresponder with no reduction of NYHA class from 3.0±0.3 to 2.9±0.5 during 14.3±13.7 month biventricular pacing, 50.0±28.26ms IVCD (P=0.014), 1.92±1.65 IACD-IVCD-ratio (P=0,029) and correlation between 67.0±24.9ms IACD and IACD-IVCD-ratio (r=0.85, P=0.031).
Conclusions: Focused transesophageal left atrial and left ventricular electrocardiography can be utilized to analyse electrical IACD and IVCD in heart failure patients. IACDIVDC- ratio may be a useful parameter to evaluate electrical left cardiac desynchronization in heart failure patients.
Cardiac resynchronization therapy (CRT) is an established biventricular pacing therapy in heart failure patients with left bundle branch block and reduced left ventricular ejection fraction, but not all patients improved clinically as CRT responder. Purpose of the study was to evaluate electrical left atrial conduction delay (LACD) with focused transesophageal electrocardiography in CRT responder and CRT non-responder.
Methods: Twenty heart failure patients (age 66.6±8.2 years; 2 females, 18 males) with New York Heart Association functional class 3.0±0.3 and 174.2±40.2ms QRS duration were analysed using posterior left atrial transesophageal electrocardiography with hemispherical electrodes. Electrical LACD was measured between onset and offset of transesophageal left atrial signal before implantation of CRT devices.
Results: Electrical LACD could be evaluated by bipolar transesophageal left atrial electrocardiography using TO Osypka electrode in all heart failure patients with negative correlation between 54.7±18.1ms LACD and 24.9±6.4% left ventricular ejection fraction (r=-0.65, P=0.002). There were 16 CRT responders with reduction of New York Heart Association functional class from 3.0±0.29 to 2.1±0.2 (r=0.522, P=0.038) during 9.41±10.96 month biventricular pacing and negative correlation between 49.6±14.2ms LACD and 26.0±6.2% left ventricular ejection fraction (r=-0.533, P=0.034). There were 4 CRT non-responders with no reduction of New York Heart Association functional class from 3.0±0.4 to 2.8±0.5 (r=0.816, P=0.184) during with 13.88±16.39 month biventricular pacing and no correlation between 75.25±19.17ms LACD and 20.75±6.4% left ventricular ejection fraction (r=-0.831, P=0.169).
Conclusions: Focused transesophageal left atrial electrocardiography can be utilized to analyse electrical LACD in heart failure patients. LACD correlated negative with left ventricular ejection fraction in CRT responders. LACD may be a useful parameter to evaluate electrical left atrial desynchronization in heart failure patients.
Was ist eine Theorie?
(2015)
Die traditionellen Geschäftsmodelle der Zeitungsverlage beruhen auf der Werbevermarktung von Anzeigen und Beilagen und dem direkten Erlösmodell für journalistische Inhalte durch Abonnement, bzw. Einzelverkaufserlöse. Diese Geschäftsmodelle verändern sich zugunsten neuer nicht-journalistischer digitaler Geschäftsmodelle, deren Zukunftsfähigkeit jedoch in vielen Fällen noch nicht bewiesen ist.
Dieses Kapitel beschreibt den technologischen, politischen und wirtschaftlichen Hintergrund, vor dem die derzeitigen Veränderungen der deutschen Zeitungslandschaft zu bewerten sind. Das Phänomen der Konvergenz, d. h. unterschiedliche Entwicklungslinien bewegen sich aufeinander zu, können wir in ganz unterschiedlichen gesellschaftlichen Bereichen immer wieder feststellen. Positionen politischer Parteien konvergieren, Hochschulgattungen nähern sich einander an und ebenso die Mediengattungen in Form der „Medienkonvergenz“.
Soccer simulation league is one of the founding leagues of RoboCup. In this paper we discuss the past, present and planned future achievements and changes. Also we summarize the connections and inter-league achievements of this league and provide an overview of the community contributions that made this league successful.
Im Projekt bwLehrpool wurde ein verteiltes System für die flexible Nutzung von Rechnerpools durch Desktop-Virtualisierung entwickelt. Auf Basis eines zentral gebooteten Linux- Grundsystems können beliebige virtualisierbare Betriebssysteme für Lehrund Prüfungszwecke zentral bereitgestellt und lokal auf den Maschinen aus-gewählt werden. Die verschiedenen Ar- beitsumgebungen müssen nicht mehr auf den PCs installiert werden und erlauben so eine multifunktionale Nutzung von PCs und Räumen für vielfältige Lehrund Lernszenarien sowie für elektronische Prüfungen. bwLehrpool abstrahiert von der PC-Hardware vor Ort und ermöglicht den Dozenten die eigene Gestaltung und Verwaltung ihrer Softwareumgebungen als Self-Service. Darüber hinaus fördert bwLehrpool den hochschulübergreifenden Austausch von Kursumgebungen.
Die Vermittlung von Handlungs-und Prozesswissen in der industriellen Produktion erfordert neue Ansätze, insbesondere eine Flexibilisierung und Integration von Lernprozessen in reale Arbeitssituationen. Der vorliegende Beitrag beschreibt das Zwischenergebnis eines größeren Forschungsvorhabens im Bereich Mobile Learning mit kontextbezogenen mobilen Diensten im betrieblichen Umfeld. Er stellt Anforderungen, Lösungsansätze und einen Prototypen zur Realisie-rung von kontextbezogenen mobilen Diensten im Bereichder Unfallverhütung und Sicherheits-einweisungen in Fertigungsprozessen vor. Die zu unterstützenden kontextbezogenen Prozesse eines Industriepartners werden analysiert und unter Verwendung eines Domänenmodells, generi-scher Prozessmodelle und kontextbezogenen mobilen Anwendungen realisiert. Im Beitrag werden außerdem Lösungsansätze für plattformunabhängige mobile Applikationen, sowie die Integration von Persistenzmechanismen und Gerätefunktionen mittels hybrider Ansätze vorgestellt. Ergebnis der Arbeit ist ein erster Prototyp einer hybriden mobilen Applikation der im realen Betrieb syste-matisch getestet und weiterentwickelt wird.
Der hier vorliegende Beitrag beschreibt erste Untersuchungsergebnisse mit der Finite-Elemente-Methode (FEM) zur Entlastung der Kerbspannungen an Getriebewellen mit Durchdringungskerben. Es handelt sich bei den Kerben um eine Umlaufnut mit überlagerter Querbohrung und um einen Wellenabsatz mit überlagerter Querbohrung. Die neu entwickelte Entlastungskerbe erweitert die üblichen Möglichkeiten zur Entlastung von Durchdringungskerben und ermöglicht bedeutende Spannungsreduktionen bis etwa 48% bei Biegung oder Zug/Druck. Die Entlastung bei Torsionsbelastung beträgt maximal etwa 18%. Es wurden Spannungsdiagramme der variierten Entlastungsnutparameter erstellt und Formeln zur näherungsweisen Berechnung der zu erwartenden Spannungen in der Durchdringungskerbe und in der Entlastungsnut ermittelt, zudem werden Empfehlungen zur Gestaltung der Entlastungskerbe gegeben. Dieser Beitrag bietet eine Grundlage zur weiteren Untersuchung zum Thema „räumliche Durchdringungskerben“ und deren Entlastung.
Eye-Tracking-Analyse des Betrachtungsverhaltens bei Micro-Präsentationen in der CAE-Ausbildung
(2015)
Die Zielsetzung des vorliegenden Beitrags ergibt sich aus der persönlichen Motivation der Autoren, das visuelle Verhalten und das Handeln vom jungen Ingenieur beim Micro-Präsentieren technischer Inhalte und Lösungsergebnisse in bildlicher und begrifflicher Form besser zu verstehen und somit effizienter unterstützen zu können. Dabei wurden mehrere Einzelpersonen aus dem Studiengang des Maschinenbaus der Hochschule Offenburg mit Hilfe der Eye-Tracking-Technick beobachtet. Die Probanden befinden sich im 6. Semester, sind im Alter von 21 bis 24 Jahren und zeichnen sich durch einen einheitlichen Ausbildungsstand aus. Die Versuchszeit für die Präsentation der Aufgabe betrug 100 Sekunden. Die Analyse der gewonnenen Daten dieser empirischen Laboruntersuchung erlaubt erste Einblicke in die visuelle Wahrnehmung technischer Objekte beim Vortragen.
Who is Who? Joseph Fourier
(2015)
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things (IoT). Whereas the lower layers (IEEE802.15.4 and 6LoWPAN) are already well defined and consolidated with regard to frame formats, header compression, routing protocols and commissioning procedures, there is still an abundant choice of possibilities on the application layer. Currently, various groups are working towards standardization of the application layer, i.e. the ETSI Technical Committee on M2M, the IP for Smart Objects (IPSO) Alliance, Lightweight M2M (LWM2M) protocol of the Open Mobile Alliance (OMA), and OneM2M. This multitude of approaches leaves the system developer with the agony of choice. This paper selects, presents and explains one of the promising solutions, discusses its strengths and weaknesses, and demonstrates its implementation.
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things. It can be observed that most of the available solutions are following an open source approach, which significantly leads to a fast development of technologies and of markets. Although the currently available implementations are in a pretty good shape, all of them come with some significant drawbacks. It was therefore decided to start the development of an own implementation, which takes the advantages from the existing solutions, but tries to avoid the drawbacks. This paper discussed the reasoning behind this decision, describes the implementation and its characteristics, as well as the testing results. The given implementation is available as open-source project under [15].
The application of leaky feeder (radiating) cables is a common solution for the implementation of reliable radio communication in huge industrial buildings, tunnels and mining environment. This paper explores the possibilities of leaky feeders for 1D and 2D localization in wireless systems based on time of flight chirp spread spectrum technologies. The main focus of this paper is to present and analyse the results of time of flight and received signal strength measurements with leaky feeders in indoor and outdoor conditions. The authors carried out experiments to compare ranging accuracy and radio coverage area for a point-like monopole antenna and for a leaky feeder acting as a distributed antenna. In all experiments RealTrac equipment based on nanoLOC radio standard was used. The estimation of the most probable path of a chirp signal going through a leaky feeder was calculated using the ray tracing approach. The typical non-line-of-sight errors profiles are presented. The results show the possibility to use radiating cables in real time location technologies based on time-of-flight method.
The demand of wireless solutions in industrial applications increases since the early nineties. This trend is not only ongoing, it is further pushed by developments in the area of software stacks like the latest Bluetooth Low Energy Stack. It is also pushed by new chip-designs and powerful and highly integrated electronic hardware. The acceptance of wireless technologies as a possible solution for industrial applications, has overcome the entry barrier [1]. The first step to see wireless as standard for many industrial applications is almost accomplished. Nevertheless there is nearly none acceptance of wireless technology for Safety applications. One highly challenging and demanding requirement is still unsolved: The aspect safety and robustness. Those topics have been addressed in many cases but always in a similar manner. WirelessHART as an example addresses this topic with redundant so called multiple propagation paths and frequency hopping to handle with interferences and loss of network participants. So far the pure peer to peer link is rarely investigated and there are less safety solutions available. One product called LoRa™ can be seen as one possible solution to address this lack of safety within wireless links. This paper focuses on the safety performance evaluation of a modem-chip-design. The use of diverse and redundant wireless technologies like LoRa can lead to an increase acceptance of wireless in safety applications. Many measurements in real industrial application have been carried out to be able to benchmark the new chip in terms of the safety aspects. The content of this research results can help to raise the level of confidence in wireless. In this paper, the term “safety” is used for data transmission reliability.
In this paper an RFID/NFC (ISO 15693 standard) based inductively powered passive SoC (system on chip) for biomedical applications is presented. A brief overview of the system design, layout techniques and verification method is dis-cussed here. The SoC includes an integrated 32 bit microcontroller, sensor interface circuit, analog to digital converter, integrated RAM, ROM and some other peripherals required for the complete passive operation. The entire chip is realized in CMOS 0.18 μm technology with a chip area of 1.52mm x 3.24 mm.
This paper presents a practice and science orientated education approach for freshman students of interdisciplinary bachelor engineering degree programs. This approach is meant to enhance the motivation and success of freshman students during their whole study. The education approach is called Fit4PracSis (Fit for Practice and Sciences) It was started to develop, set up and establish an education approach, which is building a relationship to students' future profession and to scientific working during the introductory study phase. The freshman students will be trained early in important skills, which are necessary for achieving the final degree successfully and handling of future business and research activities.
In this work we describe the implementation details of a protocol suite for a secure and reliable over-the-air reprogramming of wireless restricted devices. Although, recently forward error correction codes aiming at a robust transmission over a noisy wireless medium have extensively been discussed and evaluated, we believe that the clear value of the contribution at hand is to share our experience when it comes to a meaningful combination and implementation of various multihop (broadcast) transmission protocols and custom-fit security building blocks: For a robust and reliable data transmission we make use of fountain codes a.k.a. rateless erasure codes and show how to combine such schemes with an underlying medium access control protocol, namely a distributed low duty cycle medium access control (DLDC-MAC). To handle the well known problem of packet pollution of forward-error-correction approaches where an attacker bogusly modifies or infiltrates some minor number of encoded packets and thus pollutes the whole data stream at the receiver side, we apply homomorphic message authentication codes (HomMAC). We discuss implementation details and the pros and cons of the two currently available HomMAC candidates for our setting. Both require as the core cryptographic primitive a symmetric block cipher for which, as we will argue later, we have opted for the PRESENT, PRIDE and PRINCE (exchangeable) ciphers in our implementation.
The aim of this research work was to develop a boiler model with few parameters required for energy planning. The showcase considered for this work was the boiler system of the energy center at Offenburg University of Applied Sciences. A grey box model of the boiler was developed systematically starting from model abstraction, simplification, model break-down and to the use of empirical correlations wherever necessary to describe the intermediate effects along with the use of information from manufacturer’s specification in order to reduce parameters. This strategy had resulted in a boiler model with only 6 parameters, namely, nominal burner capacity, water gallery capacity, air ratio, heat capacity of wall, thermal conductance on flue gas and hot water side. Most of these parameters can be obtained through the information available in the spec sheets and thus an energy planner will be able to parameterize the model with low effort. The model was validated with the monitored data of the showcase. It was tested for the start-up, shut-down behavior and the effect of storage.
Environmental Monitoring is an attractive application field for Wireless Sensor Network (WSN). Water Level Monitoring helps to increase the efficiency of water distribution and management. In Pakistan, the world’s largest irrigation system covers 90.000 km of channels which needs to be monitored and managed on different levels. Especially the sensor systems for the small distribution channels need to be low energy and low cost. The distribution presents a technical solution for a communication system which is developed in a research project being co-funded by German Academic Exchange Service (DAAD). The communication module is based on IEEE-802.15.4 transceivers which are enhanced through Wake-On-Radio (WOR) to combine low-energy and real-time behavior. On higher layers, IPv6 (6LoWPAN) and corresponding routing protocols like Routing Protocol for Low power and Lossy Networks (RPL) can extend range of the network. The data are stored in a database and can be viewed online via a web interface. Of course, also automatic data analysis can be performed.
We report the use of the Raman spectral information of the chemical compound toluene C7H8 as a reference on the analysis of laboratory-prepared and commercially acquired gasoline-ethanol blends. The rate behavior of the characteristic Raman lines of toluene and gasoline has enabled the approximated quantification of this additive in commercial gasoline-ethanol mixtures. This rate behavior has been obtained from the Raman spectra of gasoline-ethanol blends with different proportions of toluene.
All these Raman spectra have been collected by using a self-designed, frequency precise and low-cost Fourier-transform Raman spectrometer (FT-Raman spectrometer) prototype. This FT-Raman prototype has helped to accurately confirm the frequency position of the main characteristic Raman lines of toluene present on the different gasoline-ethanol samples analyzed at smaller proportions than those commonly found in commercial gasoline-ethanol blends. The frequency accuracy validation has been performed by analyzing the same set of toluene samples with two additional state-of-the-art commercial FT-Raman devices. Additionally, the spectral information has been contrasted, with highly-correlated coefficients as a result, with the values of the standard Raman spectrum of toluene.
La industria del bacanora en Sonora, México, enfrenta la influencia de una compleja red de factores culturales, tecnológicos, económicos y legales que inhiben su desarrollo. Ello ocurre pese al esfuerzo institucional por radicar un marco normativo que elimine la práctica de los métodos informales de elaboración que derivan en calidades heterogéneas de licor. El conseguirlo se complica ante la dificultad que enfrentan los actores de esta industria para implementar prácticas efectivas de verificación de las normas vigentes en los confines de la geografía de la Denominación de Origen. En este documento se describe el uso de un prototipo de espectrómetro Raman por transformada de Fourier para analizar cualitativamente muestras desconocidas de bacanora. Este dispositivo se construyó con el uso de un interferómetro Michelson convencional, un contador de fotones de diseño propio y un foto-detector de referencia. Los resultados del trabajo confirman que dada su naturaleza de diseño y construcción, este instrumento de medición y su efectiva técnica de operación a bajo costo, constituye una alternativa viable, adaptable fácilmente a las necesidades de los actores productivos e institucionales, para asistirlos en la elaboración de bacanora y a la verificación de su calidad conforme a los criterios de la normatividad.
The Raman spectra from the chemical compounds toluene and cyclohexane obtained using a Fourier Transform (FT)-Raman spectrometer prototype have been contrasted with the Raman spectra of these same materials collected with two different commercial FT-Raman devices. The FT-Raman spectrometer consist of a Michelson interferometer, a self-designed photon counter and a reference photo-detector. The evaluation methodology of the spectral information, contrary to the commercial devices that commonly use the zero-crossing method, is carried out by re-sampling the Raman scattering and by accurately extracting the optical path information of the Michelson interferometer. The FTRaman arrangement has been built using conventional parts without disregarding the spectral frequency precision that usually such a FTRaman instruments deliver. No additional complex hardware components or costly software modules have been included in this FT-Raman device. The main Raman lines from the spectra obtained with the three FT-Raman devices have been compared with the Raman lines from the standard Raman spectra of these two materials. The values obtained using the FT-Raman spectrometer prototype have shown a frequency accuracy comparable to that obtained with the commercial devices without facing the need for a large investment. Although the proposed FT-Raman prototype cannot be directly compared to the last generation of FT-Raman spectrometers from the commercial manufacturers, such a device could give an opportunity to users that require high frequency precision in their spectral analysis and are provided with rather scarce resources.
Theoretical details about optics and photonics are not common knowledge nowadays. Physicists are keen to scientifically explain ‘light,’ which has a huge impact on our lives. It is necessary to examine it from multiple perspectives and to make the knowledge accessible to the public in an interdisciplinary, scientifically well-grounded and appealing medial way. To allow an information exchange on a global scale, our project “Invisible Light” establishes a worldwide accessible platform. Its contents will not be created by a single instance, but user-generated, with the help of the global community. The article describes the infotainment portal “Invisible Light,” which stores scientific articles about light and photonics and makes them accessible worldwide. All articles are tagged with geo-coordinates, so they can be clearly identified and localized. A smartphone application is used for visualization, transmitting the information to users in real time by means of an augmented reality application. Scientific information is made accessible for a broad audience and in an attractive manner.
In many scientific studies lens experiments are part of the curriculum. The conducted experiments are meant to give the students a basic understanding for the laws of optics and its applications. Most of the experiments need special hardware like e.g. an optical bench, light sources, apertures and different lens types. Therefore it is not possible for the students to conduct any of the experiments outside of the university’s laboratory. Simple optical software simulators enabling the students to virtually perform lens experiments already exist, but are mostly desktop or web browser based.
Augmented Reality (AR) is a special case of mediated and mixed reality concepts, where computers are used to add, subtract or modify one’s perception of reality. As a result of the success and widespread availability of handheld mobile devices, like e.g. tablet computers and smartphones, mobile augmented reality applications are easy to use. Augmented reality can be easily used to visualize a simulated optical bench. The students can interactively modify properties like e.g. lens type, lens curvature, lens diameter, lens refractive index and the positions of the instruments in space. Light rays can be visualized and promote an additional understanding of the laws of optics. An AR application like this is ideally suited to prepare the actual laboratory sessions and/or recap the teaching content.
The authors will present their experience with handheld augmented reality applications and their possibilities for light and optic experiments without the needs for specialized optical hardware.
Monitors are in the center of media productions and hold an important function as the main visual interface. Tablets and smartphones are becoming more and more important work tools in the media industry. As an extension to our lecture contents an intensive discussion of different display technologies and its applications is taking place now. The established LCD (Liquid Crystal Display) technology and the promising OLED (Organic Light Emitting Diode) technology are in the focus.
The classic LCD is currently the most important display technology. The paper will present how the students should develop sense for display technologies besides the theoretical scientific basics. The workshop focuses increasingly on the technical aspects of the display technology and has the goal of deepening the students understanding of the functionality by building simple Liquid Crystal Displays by themselves.
The authors will present their experience in the field of display technologies. A mixture of theoretical and practical lectures has the goal of a deeper understanding in the field of digital color representation and display technologies. The design and development of a suitable learning environment with the required infrastructure is crucial. The main focus of this paper is on the hands-on optics workshop “Liquid Crystal Display in the do-it-yourself”.
Sicher funken mit 2,45 GHz
(2015)
Crowdinvesting als alternative Unternehmensfinanzierung - Grundlagen und Marktdaten in Deutschland
(2015)
Skills, abilities and capability of our freshmen are increasingly heterogeneous, regarding age, attained levels of education and motivational aspects. Additionally, students tend to recoil from subjects dealing with mathematical backgrounds. As a result high, drop-out numbers are a huge problem in technical degree programs.
Since mechanics is based on physics and mathematics our students face enormous difficulties. To deal with them, a form of teaching and learning has been developed that is composed of the following arrangements:
1. Problems and tasks of different levels are solved during lessons. The access to theoretical issues is being developed by or rather as a result of solving these problems. By doing so, especially students with yet insufficient skills are enabled to develop their methodological skills.
2. Challenging students to independently transfer these skills on other problems is helpful. At the end of each lecture two students are selected randomly. Each of them is faced with an exercise they have to solve and present at the beginning of the next lecture. Because of small student numbers, chances are high that every student participates at least once by the end of semester. Surveys show that particularly weaker students benefit from that kind of model learning.
3. We are surrounded by mechanical issues. Given that, students are presented with “every-day-life” problems which students can apply their theoretical knowledge on. The problems are analyzed by groups of students, which leads to an enhanced and reflective perception of each and every one. Some examples are: “A broomstick in equilibrium”, “Sensitive cups”, “Transforming a roman basilica into a gothic cathedral”.
4. All lectures have been filmed by the staff of the Information Center of the Offenburg University during the previous term. Additionally to the notes taken by the students individually during the lectures, these recordings are helpful in the process of preparation and post-processing of the material. The recordings are accessible via the university’s learning management system “Moodle”.
Surveys show that students benefit from the great variety of the provided, interactive learning arrangements. It is interesting to discover that students not only take positive advantages in the lecture “mechanics 1/statics” but tend to transfer these positive experiences on other subjects.
Additive Manufacturing and Reverse Engineering have increasingly been gaining in importance over the past years. This paper investigates the current status of the implementation of these new technologies in design education and also identifies current shortcomings. Then it develops two new approaches for the teaching of the necessary expertise for the design of 3D-printed components and illustrates these with case studies. First, a workshop is presented in which students gain a broad understanding for the functionalities of additive manufacturing and the creative possibilities and limits of this process, through the assembly and installation of a 3D-printer. A second new approach is the combination of reverse engineering and 3D-printing. Thereby, students learn how to deal with this complex process chain. The result of these new approaches can e.g. be seen in the design guidelines for Additive Manufacturing, which were developed by the students themselves. At the same time, the students are able to estimate opportunities and limits of both technologies. Finally, the success of the new course contents and form is reviewed by an evaluation by the students.
This paper presents a new approach for the teaching of competence in additive manufacturing to engineering students in product development. Particularly new to this approach is the combination of the students' autonomous assembly and commissioning of a 3D-printer, and the independent development of guidelines for this new technology regarding the design of components. This way the students will be able to gain first practical experiences with the data preparation, the additive manufacturing process itself and also the required post-treatment of the 3D-printed parts. To allow the students a significantly deeper insight into the functioning of 3D-printing, the workshop Rapid Prototyping developed a new approach in the course of which the students first assemble a construction kit for a 3D-printer themselves and then commission the printer. This enables the students to gain a better understanding of the functionality and configuration of additive manufacturing. In a next step, the students used the 3D-printers they constructed themselves to produce components which they take from a database. Finally, the experiences of the students in the course of the workshop will be evaluated to review the effectiveness of the new approach.
Unternehmen müssen aufgrund hohen Wettbewerbsdrucks ihre Produktivität stetig steigern. Ein Bereich, welcher sich deren permanenter Steigerung annimmt, ist das Industrial Engineering (IE). Gerade im Zuge der Digitalisierung und Vernetzung der Unternehmensprozesse beleuchtet der folgende Beitrag, wie sich Industrie 4.0 auf das IE auswirkt. Der Ansatz ist ein Industrial Engineering 4.0 zu gestalten, das die Fortschritte von Industrie 4.0 und der Digitalen Fabrik miteinander vereint.
Wireless sensor networks have recently found their way into a wide range of applications among which environmental monitoring system has attracted increasing interests of researchers. Such monitoring applications, in general, don way into a wide range of applications among which environmental monitoring system has attracted increasing interests of researc latency requirements regarding to the energy efficiency. Also a challenge of this application is the network topology as the application should be able to be deployed in very large scale. Nevertheless low power consumption of the devices making up the network must be on focus in order to maximize the lifetime of the whole system. These devices are usually battery-powered and spend most of their energy budget on radio transceiver module. A so-called Wake-On-Radio (WoR) technology can be used to achieve a reasonable balance among power consumption, range, complexity and response time. In this paper, some designs for integration of WOR into IEEE 802.1.5.4 are to be discussed, providing an overview of trade-offs in energy consumption while deploying the WoR schemes in a monitoring system.
Extended Performance Measurements of Scalable 6LoWPAN Networks in an Automated Physical Testbed
(2015)
IPv6 over Low power Wireless Personal Area Networks, also known as 6LoWPAN, is becoming more and more a de facto standard for such communications for the Internet of Things, be it in the field of home and building automation, of industrial and process automation, or of smart metering and environmental monitoring. For all of these applications, scalability is a major precondition, as the complexity of the networks continuously increase. To maintain this growing amount of connected nodes a various 6LoWPAN implementations are available. One of the mentioned was developed by the authors' team and was tested on an Automated Physical Testbed for Wireless Systems at the Laboratory Embedded Systems and Communication Electronics of Offenburg University of Applied Sciences, which allows the flexible setup and full control of arbitrary topologies. It also supports time-varying topologies and thus helps to measure performance of the RPL implementation. The results of the measurements prove an excellent stability and a very good short and long-term performance also under dynamic conditions. In all measurements, there is an advantage of minimum 10% with regard to the average times, like global repair time; but the advantage with reagr to average values can reach up to 30%. Moreover, it can be proven that the performance predictions from other papers are consistent with the executed real-life implementations.
Der Studienbeginn wird an der Hochschule Offenburg durch Vorbereitungskurse, sogenannte Brückenkurse, unterstützt. Wir stellen vorläufige Ergebnisse beim Einsatz von Smartphones und Tablets im Rahmen des Physik-Brückenkurses vor, bei dem die Studenten Hilfen zum selbständigen Üben durch eine App erhalten. Durch die Überarbeitung des Kurses und den Einsatz der App konnte der Teilnehmerschwund verringert werden. Die Evaluationsergebnisse bestätigen eine hohe Akzeptanz der Neuerungen seitens der Studierenden. Erste Auswertungen von Ein- und Ausgangstests deuten darauf hin, dass durch den Brückenkurs eine Angleichung der Vorkenntnisse der Studienanfänger erreicht wird, da Teilnehmer mit geringeren Vorkenntnissen tendenziell einen größeren Lernfortschritt erreichen. Durch unterschiedliche Schwierigkeitsstufen und selbstregulierte Übungsphasen in individuellem Tempo können aber auch die Erfordernisse der stärkeren Teilnehmer angemessen berücksichtigt werden.
Adsorption of N2 and CO2 on Activated Carbon, AlO(OH) Nanoparticles, and AlO(OH) Hollow Spheres
(2015)
Adsorption behaviors of nitrogen and CO2 on Norit R1 Extra and AlO(OH) nanoparticles and hollow spheres were measured under different temperature and pressure conditions using a magnetic suspension balance. Independent from the substrate investigated, all isotherms increase at lower pressure, reach a maximum, and then decrease with increasing pressure. In addition, selected experimental data were correlated with different model approaches and compared with reliable literature data. In case of CO2 on AlO(OH), capillary condensation was observed at two defined temperatures. The results suggest that the conversion of the liquid into a supercritical adsorbate phase does not take place suddenly.
Phosphate-based inorganic–organic hybrid nanoparticles (IOH-NPs) with the general composition [M]2+[Rfunction(O)PO3]2– (M = ZrO, Mg2O; R = functional organic group) show multipurpose and multifunctional properties. If [Rfunction(O)PO3]2– is a fluorescent dye anion ([RdyeOPO3]2–), the IOH-NPs show blue, green, red, and near-infrared fluorescence. This is shown for [ZrO]2+[PUP]2–, [ZrO]2+[MFP]2–, [ZrO]2+[RRP]2–, and [ZrO]2+[DUT]2– (PUP = phenylumbelliferon phosphate, MFP = methylfluorescein phosphate, RRP = resorufin phosphate, DUT = Dyomics-647 uridine triphosphate). With pharmaceutical agents as functional anions ([RdrugOPO3]2–), drug transport and release of anti-inflammatory ([ZrO]2+[BMP]2–) and antitumor agents ([ZrO]2+[FdUMP]2–) with an up to 80% load of active drug is possible (BMP = betamethason phosphate, FdUMP = 5′-fluoro-2′-deoxyuridine 5′-monophosphate). A combination of fluorescent dye and drug anions is possible as well and shown for [ZrO]2+[BMP]2–0.996[DUT]2–0.004. Merging of functional anions, in general, results in [ZrO]2+([RdrugOPO3]1–x[RdyeOPO3]x)2– nanoparticles and is highly relevant for theranostics. Amine-based functional anions in [MgO]2+[RaminePO3]2– IOH-NPs, finally, show CO2 sorption (up to 180 mg g–1) and can be used for CO2/N2 separation (selectivity up to α = 23). This includes aminomethyl phosphonate [AMP]2–, 1-aminoethyl phosphonate [1AEP]2–, 2-aminoethyl phosphonate [2AEP]2–, aminopropyl phosphonate [APP]2–, and aminobutyl phosphonate [ABP]2–. All [M]2+[Rfunction(O)PO3]2– IOH-NPs are prepared via noncomplex synthesis in water, which facilitates practical handling and which is optimal for biomedical application. In sum, all IOH-NPs have very similar chemical compositions but can address a variety of different functions, including fluorescence, drug delivery, and CO2 sorption.
Lithium-oxygen cells with organic electrolyte suffer high overpotentials during charge, indicating asymmetric charge/discharge reaction mechanisms. We present a multi-physics dynamic modeling and simulation study of the Li/O2 cell cycling behavior. We present three different multi-step mechanisms of the 2 Li + O2 ⇄ Li2O2 cell reaction, (A) a reversible 5-step mechanism, (B) a partially irreversible 6-step mechanism, and (C) a partially irreversible 8-step mechanism that includes reactions of a redox mediator. Model predictions are compared to experimental galvanostatic cycling data of Swagelok cells without and with 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) as redox mediator. All mechanisms are able to predict the discharge behavior in good agreement to the experimental results. The experimentally observed high charge overpotentials as well as their reduction by using a redox mediator can be qualitatively reproduced with the irreversible reaction mechanisms. However, the particular shape of the experimental charge curve with continuously increasing charge overpotential cannot be reproduced with the present mechanisms.
The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
Seven cell design concepts for aqueous (alkaline) lithium–oxygen batteries are investigated using a multi-physics continuum model for predicting cell behavior and performance in terms of the specific energy and specific power. Two different silver-based cathode designs (a gas diffusion electrode and a flooded cathode) and three different separator designs (a porous separator, a stirred separator chamber, and a redox-flow separator) are compared. Cathode and separator thicknesses are varied over a wide range (50 μm–20 mm) in order to identify optimum configurations. All designs show a considerable capacity-rate effect due to spatiotemporally inhomogeneous precipitation of solid discharge product LiOH·H2O. In addition, a cell design with flooded cathode and redox-flow separator including oxygen uptake within the external tank is suggested. For this design, the model predicts specific power up to 33 W/kg and specific energy up to 570 Wh/kg (gravimetric values of discharged cell including all cell components and catholyte except housing and piping).
Combined heat and power production (CHP) based on solid oxide fuel cells (SOFC) is a very promising technology to achieve high electrical efficiency to cover power demand by decentralized production. This paper presents a dynamic quasi 2D model of an SOFC system which consists of stack and balance of plant and includes thermal coupling between the single components. The model is implemented in Modelica® and validated with experimental data for the stack UI-characteristic and the thermal behavior. The good agreement between experimental and simulation results demonstrates the validity of the model. Different operating conditions and system configurations are tested, increasing the net electrical efficiency to 57% by implementing an anode offgas recycle rate of 65%. A sensitivity analysis of characteristic values of the system like fuel utilization, oxygen-to-carbon ratio and electrical efficiency for different natural gas compositions is carried out. The result shows that a control strategy adapted to variable natural gas composition and its energy content should be developed in order to optimize the operation of the system.
We provide a privacy-friendly cloud-based smart metering storage architecture which provides few-instance storage on encrypted measurements by at the same time allowing SQL queries on them. Our approach is most flexible with respect to two axes: on the one hand it allows to apply filtering rules on encrypted data with respect to various upcoming business cases; on the other hand it provides means for a storage-efficient handling of encrypted measurements by applying server-side deduplication techniques over all incoming smart meter measurements. Although the work at hand is purely dedicated to a smart metering architecture we believe our approach to have value for a broader class of IoT cloud storage solutions. Moreover, it is an example for Privacy-by-design supporting the positive-sum paradigm.
The energy system of the future will transform from the current centralised fossil based to a decentralised, clean, highly efficient, and intelligent network. This transformation will require innovative technologies and ideas like trigeneration and the crowd energy concept to pave the way ahead. Even though trigeneration systems are extremely energy efficient and can play a vital role in the energy system, turning around their deployment is hindered by various barriers. These barriers are theoretically analysed in a multiperspective approach and the role decentralised trigeneration systems can play in the crowd energy concept is highlighted. It is derived from an initial literature research that a multiperspective (technological, energy-economic, and user) analysis is necessary for realising the potential of trigeneration systems in a decentralised grid. And to experimentally quantify these issues we are setting up a microscale trigeneration lab at our institute and the motivation for this lab is also briefly introduced.
Chronic insomnia is defined by difficulties in falling asleep, maintaining sleep, and early morning awakening, and is coupled with daytime consequences such as fatigue, attention deficits, and mood instability. These symptoms persist over a period of at least 3 months (Diagnostic and Statistical Manual 5 criteria). Chronic insomnia can be a symptom of many medical, neurological, and mental disorders. As a disorder, it incurs substantial health-care and occupational costs, and poses substantial risks for the development of cardiovascular and mental disorders, including cognitive deficits. Family and twin studies confirm that chronic insomnia can have a genetic component (heritability coefficients between 42% and 57%), whereas the investigation of autonomous and central nervous system parameters has identified hyperarousal as a final common pathway of the pathophysiology, implicating an imbalance of sleep–wake regulation consisting of either overactivity of the arousal systems, hypoactivity of the sleep-inducing systems, or both. Insomnia treatments include benzodiazepines, benzodiazepine-receptor agonists, and cognitive behavioural therapy. Treatments currently under investigation include transcranial magnetic or electrical brain stimulation, and novel methods to deliver psychological interventions.
In the present study, in vitro toxicity as well as biopersistence and photopersistence of four artificial sweeteners (acesulfame, cyclamate, saccharine, and sucralose) and five antibiotics (levofloxacin, lincomycin, linezolid, marbofloxacin, and sarafloxacin) and of their phototransformation products (PTPs) were investigated. Furthermore, antibiotic activity was evaluated after UV irradiation and after exposure to inocula of a sewage treatment plant. The study reveals that most of the tested compounds and their PTPs were neither readily nor inherently biodegradable in the Organisation for Economic Co-operation and Development (OECD)-biodegradability tests. The study further demonstrates that PTPs are formed upon irradiation with an Hg lamp (UV light) and, to a lesser extent, upon irradiation with a Xe lamp (mimics sunlight). Comparing the nonirradiated with the corresponding irradiated solutions, a higher chronic toxicity against bacteria was found for the irradiated solutions of linezolid. Neither cytotoxicity nor genotoxicity was found in human cervical (HeLa) and liver (Hep-G2) cells for any of the investigated compounds or their PTPs. Antimicrobial activity of the tested fluoroquinolones was reduced after UV treatment, but it was not reduced after a 28-day exposure to inocula of a sewage treatment plant. This comparative study shows that PTPs can be formed as a result of UV treatment. The study further demonstrated that UV irradiation can be effective in reducing the antimicrobial activity of antibiotics, and consequently may help to reduce antimicrobial resistance in wastewaters. Nevertheless, the study also highlights that some PTPs may exhibit a higher ecotoxicity than the respective parent compounds. Consequently, UV treatment does not transform all micropollutants into harmless compounds and may not be a large-scale effluent treatment option.