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Experimental and theoretical investigations of the time of equalization of the concentration of an impurity in a rectangular flow‐type chamber have been carried out. It has been shown that the process of equalization of the concentration with time is exponential in character. The characteristic equalization time has been computed using the theory of turbulent diffusion. Theoretical results describe experimental regularities with an accuracy of about 10%. The value of the coefficient of turbulent diffusion for different configurations of flows in the chamber has been obtained from a comparison of experimental and calculated results.
The flow field-flow fractionation (FIFFF) technique is a promising method for separating and analysing particles and large size macromolecules from a few nanometers to approximately 50 μm. A new fractionation channel is described featuring well defined flow conditions even for low channel heights with convenient assembling and operations features. The application of the new flow field-flow fractionation channel is proved by the analysis of pigments and other small particles of technical interest in the submicrometer range. The experimental results including multimodal size distributions are presented and discussed.
The importance of obtaining simultaneous particle size and concentration values has grown up with continuing discussion of the health effects, of internal combustion engine generated particulate emissions and in particular of Diesel soot emissions. In the present work an aerosol measurement system is described that delivers information about particle size and concentration directly from the undiluted exhaust gas.
Using three laser diodes of different wavelengths which form one parallel light beam, each spectral attenuation is analysed by a single detector and the particle diameter and concentration is evaluated by the use of the Mie theory and shown on-line at a frequency of 1 Hz. The system includes an optical long-path-cell (White principle) with an adjustable path length from 2.5 to 15 m, which allows the analysis within a broad concentration range.
On-line measurements of the particulate emissions in the hot, undiluted exhaust of Diesel engines are presented under stationary and transient engine’s load conditions. Mean particle diameters well below 100 nm are detected for modern Diesel engines. The measured particle concentration corresponds excellently with the traditional gravimetrical measurements of the diluted exhaust. Additionally, measurements of particle emissions (mostly condensed hydricarbons) from a two-stroke engine are presented and discussed.