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One of the major challenges impeding the energy transition is the intermittency of solar and wind electricity generation due to their dependency on weather changes. The demand-side energy flexibility contributes considerably to mitigate the energy supply/demand imbalances resulting from external influences such as the weather. As one of the largest electricity consumers, the industrial enterprises present a high demand-side flexibility potential from their production processes and on-site energy assets. In this direction, methods are needed with a focus on enabling the energy flexibility and ensure an active participation of such enterprises in the electricity markets especially with variable prices of electricity. This paper presents a generic model library for an industrial enterprise implemented with optimal control for energy flexibility purposes. The components in the model library represent the typical technical units of an industrial enterprise on material, media, and energy flow levels with their operative constraints. A case study of a plastic manufacturing plant using the generic model library is also presented, in which the results of two simulation with different electricity prices are compared and the behavior of the model can be assessed. The results show that the model provides an optimal scheduling of the manufacturing system according to the variations in the electricity prices, and ensures an optimal control for utilities and energy systems needed for the production.
Solar energy plays a central role in the energy transition. Clouds generate locally large fluctuations in the generation output of photovoltaic systems, which is a major problem for energy systems such as microgrids, among others. For an optimal design of a power system, this work analyzed the variability using a spatially distributed sensor network at Stuttgart Airport. It has been shown that the spatial distribution partially reduces the variability of solar radiation. A tool was also developed to estimate the output power of photovoltaic systems using irradiation time series and assumptions about the photovoltaic sites. For days with high fluctuations of the estimated photovoltaic power, different energy system scenarios were investigated. It was found the approach can be used to have a more realistic representation of aggregated PV power taking spatial smoothing into account and that the resulting PV power generation profiles provide a good basis for energy system design considerations like battery sizing.
In recent years, light-weight cryptography has received a lot of attention. Many primitives suitable for resource-restricted hardware platforms have been proposed. In this paper, we present a cryptanalysis of the new stream cipher A2U2 presented at IEEE RFID 2011 [9] that has a key length of 56 bit. We start by disproving and then repairing an extremely efficient attack presented by Chai et al. [8], showing that A2U2 can be broken in less than a second in the chosen-plaintext case. We then turn our attention to the more challenging known-plaintext case and propose a number of attacks. A guess-and-determine approach combined with algebraic cryptanalysis yields an attack that requires about 249 internal guesses. We also show how to determine the 5-bit counter key and how to reconstruct the 56-bit key in about 238 steps if the attacker can freely choose the IV. Furthermore, we investigate the possibility of exploiting the knowledge of a “noisy keystream” by solving a Max-PoSSo problem. We conclude that the cipher needs to be repaired and point out a number of simple measures that would prevent the above attacks.
With the expansion of IoT devices in many aspects of our life, the security of such systems has become an important challenge. Unlike conventional computer systems, any IoT security solution should consider the constraints of these systems such as computational capability, memory, connectivity, and power consumption limitations. Physical Unclonable Functions (PUFs) with their special characteristics were introduced to satisfy the security needs while respecting the mentioned constraints. They exploit the uncontrollable and reproducible variations of the underlying component for security applications such as identification, authentication, and communication security. Since IoT devices are typically low cost, it is important to reuse existing elements in their hardware (for instance sensors, ADCs, etc.) instead of adding extra costs for the PUF hardware. Micro-electromechanical system (MEMS) devices are widely used in IoT systems as sensors and actuators. In this thesis, a comprehensive study of the potential application of MEMS devices as PUF primitives is provided. MEMS PUF leverages the uncontrollable variations in the parameters of MEMS elements to derive secure keys for cryptographic applications. Experimental and simulation results show that our proposed MEMS PUFs are capable of generating enough entropy for a complex key generation, while their responses show low fluctuations in different environmental conditions.
Keeping in mind that the PUF responses are prone to change in the presence of noise and environmental variations, it is critical to derive reliable keys from the PUF and to use the maximum entropy at the same time. In the second part of this thesis, we elaborate on different key generation schemes and their advantages and drawbacks. We propose the PUF output positioning (POP) and integer linear programming (ILP) methods, which are novel methods for grouping the PUF outputs in order to maximize the extracted entropy. To implement these methods, the key enrollment and key generation algorithms are presented. The proposed methods are then evaluated by applying on the responses of the MEMS PUF, where it can be practically shown that the proposed method outperforms other existing PUF key generation methods.
The final part of this thesis is dedicated to the application of the MEMS PUF as a security solution for IoT systems. We select the mutual authentication of IoT devices and their backend system, and propose two lightweight authentication protocols based on MEMS PUFs. The presented protocols undergo a comprehensive security analysis to show their eligibility to be used in IoT systems. As the result, the output of this thesis is a lightweight security solution based on MEMS PUFs, which introduces a very low overhead on the cost of the hardware.
The number of use cases for autonomous vehicles is increasing day by day especially in commercial applications. One important application of autonomous vehicles can be found within the parcel delivery section. Here, autonomous cars can massively help to reduce delivery efforts and time by supporting the courier actively. One important component of course is the autonomous vehicle itself. Nevertheless, beside the autonomous vehicle, a flexible and secure communication architecture also is a crucial key component impacting the overall performance of such system since it is required to allow continuous interactions between the vehicle and the other components of the system. The communication system must provide a reliable and secure architecture that is still flexible enough to remain practical and to address several use cases. In this paper, a robust communication architecture for such autonomous fleet-based systems is proposed. The architecture provides a reliable communication between different system entities while keeping those communications secure. The architecture uses different technologies such as Bluetooth Low Energy (BLE), cellular networks and Low Power Wide Area Network (LPWAN) to achieve its goals.
The desire to connect more and more devices and to make them more intelligent and more reliable, is driving the needs for the Internet of Things more than ever. Such IoT edge systems require sound security measures against cyber-attacks, since they are interconnected, spatially distributed, and operational for an extended period of time. One of the most important requirements for the security in many industrial IoT applications is the authentication of the devices. In this paper, we present a mutual authentication protocol based on Physical Unclonable Functions, where challenge-response pairs are used for both device and server authentication. Moreover, a session key can be derived by the protocol in order to secure the communication channel. We show that our protocol is secure against machine learning, replay, man-in-the-middle, cloning, and physical attacks. Moreover, it is shown that the protocol benefits from a smaller computational, communication, storage, and hardware overhead, compared to similar works.
In recent years, Physical Unclonable Functions (PUFs) have gained significant attraction in the Internet of Things (IoT) for security applications such as cryptographic key generation and entity authentication. PUFs extract the uncontrollable production characteristics of physical devices to generate unique fingerprints for security applications. One common approach for designing PUFs is exploiting the intrinsic features of sensors and actuators such as MEMS elements, which typically exist in IoT devices. This work presents the Cantilever-PUF, a PUF based on a specific MEMS device – Aluminum Nitride (AlN) piezoelectric cantilever. We show the variations of electrical parameters of AlN cantilevers such as resonance frequency, electrical conductivity, and quality factor, as a result of uncontrollable manufacturing process variations. These variations, along with high thermal and chemical stability, and compatibility with silicon technology, makes AlN cantilever a decent candidate for PUF design. We present a cantilever design, which magnifies the effect of manufacturing process variations on electrical parameters. In order to verify our findings, the simulation results of the Monte Carlo method are provided. The results verify the eligibility of AlN cantilever to be used as a basic PUF device for security applications. We present an architecture, in which the designed Cantilever-PUF is used as a security anchor for PUF-enabled device authentication as well as communication encryption.
In recent years, physically unclonable functions (PUFs) have gained significant attraction in IoT security applications, such as cryptographic key generation and entity authentication. PUFs extract the uncontrollable production characteristics of different devices to generate unique fingerprints for security applications. When generating PUF-based secret keys, the reliability and entropy of the keys are vital factors. This study proposes a novel method for generating PUF-based keys from a set of measurements. Firstly, it formulates the group-based key generation problem as an optimization problem and solves it using integer linear programming (ILP), which guarantees finding the optimum solution. Then, a novel scheme for the extraction of keys from groups is proposed, which we call positioning syndrome coding (PSC). The use of ILP as well as the introduction of PSC facilitates the generation of high-entropy keys with low error correction costs. These new methods have been tested by applying them on the output of a capacitor network PUF. The results confirm the application of ILP and PSC in generating high-quality keys.
Physical unclonable functions (PUFs) are increasingly generating attention in the field of hardware-based security for the Internet of Things (IoT). A PUF, as its name implies, is a physical element with a special and unique inherent characteristic and can act as the security anchor for authentication and cryptographic applications. Keeping in mind that the PUF outputs are prone to change in the presence of noise and environmental variations, it is critical to derive reliable keys from the PUF and to use the maximum entropy at the same time. In this work, the PUF output positioning (POP) method is proposed, which is a novel method for grouping the PUF outputs in order to maximize the extracted entropy. To achieve this, an offset data is introduced as helper data, which is used to relax the constraints considered for the grouping of PUF outputs, and deriving more entropy, while reducing the secret key error bits. To implement the method, the key enrollment and key generation algorithms are presented. Based on a theoretical analysis of the achieved entropy, it is proven that POP can maximize the achieved entropy, while respecting the constraints induced to guarantee the reliability of the secret key. Moreover, a detailed security analysis is presented, which shows the resilience of the method against cyber-security attacks. The findings of this work are evaluated by applying the method on a hybrid printed PUF, where it can be practically shown that the proposed method outperforms other existing group-based PUF key generation methods.
Steroid hormones (SHs) are a rising concern due to their high bioactivity, ubiquitous nature, and prolonged existence as a micropollutants in water, they pose a potential risk to both human health and the environment, even at low concentrations. Estrogens, progesterone, and testosterone are the three important types of steroids essential for human development and maintaining multiorgan balance, are focus to this concern. These steroid hormones originate
from various sources, including human and livestock excretions, veterinary medications, agricultural runoff, and pharmaceuticals, contributing to their presence in the environment. According to the recommendation of WHO, the guidance value for estradiol (E2) is 1 ng/L. There are several methods been attempted to remove the SH micropollutant by conventional water and wastewater technologies which are still under research. Among the various methods, electrochemical membrane reactor (EMR) is one of the emerging technologies that can address the challenge of insufficient SHs removal from the aquatic environment by conventional treatment. The degradation of SHs can be significantly influenced by various factors when treated with EMR.
In this project, the removal of SH and the important mechanism for the removal using carbon nanotube CNT-EMR is studied and the efficiency of CNT-EMR in treating the SH micropollutant is identified. By varying different parameters this experiment is carried out with the (PES-CNTs) ultrafiltration membrane. The study is carried out depending upon the SH removal based on the limiting factor such as cell voltage, flux, temperature, concentration, and type of the SH.
This thesis focuses on the development and implementation of a Datagram Transport Layer Security (DTLS) communication framework within the ns-3 network simulator, specifically targeting the LoRaWAN model network. The primary aim is to analyse the behaviour and performance of DTLS protocols across different network conditions within a LoRaWAN context. The key aspects of this work include the following.
Utilization of ns-3: This thesis leverages ns-3’s capabilities as a powerful discrete event network simulator. This platform enables the emulation of diverse network environments, characterized by varying levels of latency, packet loss, and bandwidth constraints.
Emulation of Network Challenges: The framework specifically addresses unique challenges posed by certain network configurations, such as duty cycle limitations. These constraints, which limit the time allocated for data transmission by each device, are crucial in understanding the real-world performance of DTLS protocols.
Testing in Multi-client-server Scenarios: A significant feature of this framework is its ability to test DTLS performance in complex scenarios involving multiple clients and servers. This is vital for assessing the behaviour of a protocol under realistic network conditions.
Realistic Environment Simulation: By simulating challenging network conditions, such as congestion, limited bandwidth, and resource constraints, the framework provides a realistic environment for thorough evaluation. This allows for a comprehensive analysis of DTLS in terms of security, performance, and scalability.
Overall, this thesis contributes to a deeper understanding of DTLS protocols by providing a robust tool for their evaluation under various and challenging network conditions.
Global energy demand is still on an increase during the last decade, with a lot of impact on the climate change due to the intensive use of conventional fossil-based fuels power plants to cover this demand. Most recently, leaders of the globe met in 2015 to come out with the Paris Agreement, stating that the countries will start to take a more responsible and effective behaviour toward the global warming and climate change issues. Many studies have discussed how the future energy system will look like with respecting the countries’ targets and limits of greenhouse gases and their CO2 emissions. However, these studies rarely discussed the industry sector in detail even though it is one of the major role players in the energy sector. Moreover, many studies have simulated and modelled the energy system with huge jumps of intervals in terms of years and environmental goals. In the first part of this study, a model will be developed for the German electrical grid with high spatial and temporal resolutions and different scenarios of it will be analysed meticulously on shorter periods (annual optimization), with different flexibilities and used technologies and degrees of innovations within each scenario. Moreover, the challenge in this research is to adequately map the diverse and different characteristics of the medium-sized industrial sector. In order to be able to take a first step in assessing the relevance of the industrial sector in Germany for climate protection goals, the industrial sector will be mapped in PyPSA-Eur (an open-source model data set of the European energy system at the level of the transmission network) by detailing the demand for different types of industry and assigning flexibilities to the industrial types. Synthetically generated load profiles of various industrial types are available. Flexibilities in the industrial sector are described by the project partner Fraunhofer IPA in the GaIN project and can be used. Using a scenario analysis, the development of the industrial sector and the use of flexibilities are then to be assessed quantitatively.
This paper will introduce the open-source model MyPyPSA-Ger, a myopic optimization model developed to represent the German energy system with a detailed mapping of the electricity sector, on a highly disaggregated level, spatially and temporally, with regional differences and investment limitations. Furthermore, this paper will give new outlooks on the German federal government 2050 emissions goals of the electricity sector to become greenhouse gas neutral by proposing new CO2 allowance strategies. Moreover, the regional differences in Germany will be discussed, their role and impact on the energy transition, and which regions and states will drive the renewable energy utilization forward.
Following a scenario-based analysis, the results point out the major keystones of the energy transition path from 2020 to 2050. Solar, onshore wind, and gas-fired power plants will play a fundamental role in the future electricity systems. Biomass, run of river, and offshore wind technologies will be utilized in the system as base-load generation technologies. Solar and onshore wind will be installed almost everywhere in Germany. However, due to the nature of Germany’s weather and geographical features, the southern and northern regions will play a more important role in the energy transition.
Higher CO2 allowance costs will help achieve the 1.5-degree-target of the electricity system and will allow for a rapid transition. Moreover, the more expensive, and the earlier the CO2 tax is applied to the system, the less it will cost for the energy transition, and the more emissions will be saved throughout the transition period. An earlier phase-out of coal power plants is not necessary with high CO2 taxes, due to the change in power plant’s unit commitment, as they prioritize gas before coal power plants. Having moderate to low CO2 allowance cost or no clear transition policy will be more expensive and the CO2 budget will be exceeded. Nonetheless, even with no policy, renewables still dominate the energy mix of the future.
However, maintaining the maximum historical installation rates of both national and regional levels, with the current emissions reduction strategy, will not be enough to reach the level of climate-neutral electricity system. Therefore, national and regional installation requirements to achieve the federal government emission reduction goals are determined. Energy strategies and decision makers will have to resolve great challenges in order to stay in line with the 1.5-degree-target.
Most recently, the federal government in Germany published new climate goals in order reach climate neutrality by 2045. This paper demonstrates a path to a cost optimal energy supply system for the German power grid until the year 2050. With special regard to regionality, the system is based on yearly myopic optimization with the required energy system transformation measures and the associated system costs. The results point out, that energy storage systems (ESS) are fundamental for renewables integration in order to have a feasible energy transition. Moreover, the investment in storage technologies increased the usage of the solar and wind technologies. Solar energy investments were highly accompanied with the installation of short-term battery storage. Longer-term storage technologies, such as H2, were accompanied with high installations of wind technologies. The results pointed out that hydrogen investments are expected to overrule short-term batteries if their cost continues to decrease sharply. Moreover, with a strong presence of ESS in the energy system, biomass energy is expected to be completely ruled out from the energy mix. With the current emission reduction strategy and without a strong presence of large scale ESS into the system, it is unlikely that the Paris agreement 2° C target by 2050 will be achieved, let alone the 1.5° C.
With recent developments in the Ukrainian-Russian conflict, many are discussing about Germany’s dependency on fossil fuel imports in its energy system, and how can the country proceed with reducing that dependency. With its wide-ranging consumption sectors, the electricity sector comes as the perfect choice to start with. Recent reports showed that the German federal government is already intending to have a fully renewable electricity by 2035 while exploiting all possible clean power options. This was published in the federal government’s climate emergency program (Easter Package) in early 2022. The aim of this package is to initiate a rapid transition and decarbonization of the electricity sector. The Easter Package expects an enormous growth of renewable energies to a completely new level, with already at least 80% renewable gross energy consumption, with extensive and broad deployment of different generation technologies on various scales. This paper will discuss this ambitious plan and outline some insights into this huge and rapidly increasing step, and show how much will Germany need in order to achieve this huge milestone towards a fully green supply of the electricity sector. Different scenarios and shares of renewables will be investigated in order to elaborate on preponed climate-neutral goal of the electricity sector by 2035. The results pointed out some promising aspects in achieving a 100% renewable power, with massive investments in both generation and storage technologies.
An import ban of Russian energy sources to Germany is currently being increasingly discussed. We want to support the discussion by showing a way how the electricity system in Germany can manage low energy imports in the short term and which measures are necessary to still meet the climate protection targets. In this paper, we examine the impact of a complete stop of Russian fossil fuel imports on the electricity sector in Germany, and how this will affect the climate coals of an earlier coal phase-out and climate neutrality by 2045.
Following a scenario-based analysis, the results gave a point of view on how much would be needed to completely rely on the scarce non-renewable energy resources in Germany. Huge amounts of investments would be needed in order to ensure a secure supply of electricity, in both generation energy sources (RES) and energy storage systems (ESS). The key findings are that a rapid expansion of renewables and storage technologies will significantly reduce the dependence of the German electricity system on energy imports. The huge integration of renewable energy does not entail any significant imports of the energy sources natural gas, hard coal, and mineral oil, even in the long term. The results showed that a ban on fossil fuel imports from Russia outlines huge opportunities to go beyond the German government's climate targets, where the 1.5-degree-target is achieved in the electricity system.
Method and system for extractin metal and oxygen from powdered metal oxides (EP000004170066A2)
(2023)
A method for extracting metal and oxygen from powdered metal oxides in electrolytic cell is proposed, the electrolytic cell comprising a container, a cathode, an anode and an oxygen-ion-conducting membrane, the method comprising providing a solid oxygen ion conducting electrolyte powder into a container, providing a feedstock comprising at least one metal oxide in powdered form into the container, applying an electric potential across the cathode and the anode, the cathode being in communication with the electrolyte powder and the anode being in communication with the membrane in communication with the electrolyte powder, such that at least one respective metallic species of the at least one metal oxide is reduced at the cathode and oxygen is oxidized at the anode to form molecular oxygen, wherein the potential across the cathode and the anode is greater than the dissociation potential of the at least one metal oxide and less than the dissociation potential of the solid electrolyte powder and the membrane.
To deal with frequent power outages in developing countries, people turn to solutions like uninterruptible power supply (UPS), which stores electric energy during normal operating hours and use it to meet energy needs during rolling blackout intervals. Locally produced UPSs of poorer power quality are widely accessible in the marketplaces, and they have a negative impact on power quality. The charging and discharging of the batteries in these UPSs generate significant amount of power losses in weak grid environments. The Smart-UPS is our proposed smart energy metering (SEM) solution for low voltage consumers that is provided by the distribution company. It does not require batteries, therefore there is no power loss or harmonic distortion due to corresponding charging and discharging. Through load flow and harmonic analysis of both traditional UPS and Smart-UPS systems on ETAP, this paper examines their impact on the harmonics and stability of the distribution grid. The simulation results demonstrate that Smart-UPS can assist fixing power quality issues in a developing country like Pakistan by providing cleaner energy than the battery-operated traditional UPSs.
Due to its potential in improving the efficiency of energy supply, smart energy metering (SEM) has become an area of interest with the surge in Internet of Things (IoT). SEM entails remote monitoring and control of the sensors and actuators associated with the energy supply system. This provides a flexible platform to conceive and implement new data driven Demand Side Management (DSM) mechanisms. The IoT enablement allows the data to be gathered and analyzed at requisite granularity. In addition to efficient use of energy resources and provisioning of power, developing countries face an additional challenge of temporal mismatch in generation capacity and load factors. This leads to widespread deployment of inefficient and expensive Uninterruptible Power Supply (UPS) solutions for limited power provisioning during resulting blackouts. Our proposed “Soft-UPS” allows dynamic matching of load and generation through a combination of managed curtailment. This eliminates inefficiencies in the energy and power value chain and allows a data-driven approach to solving a widespread problem in developing countries, simultaneously reducing both upfront and running costs of conventional UPS and storage. A scalable and modular platform is proposed and implemented in this paper. The architecture employs “WiMODino” using LoRaWAN with a “Lite Gateway” and SQLite repository for data storage. Role based access to the system through an android application has also been demonstrated for monitoring and control.