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Purpose
To summarize the mechanical loading of the spine in different activities of daily living and sports.
Methods
Since the direct measurement is not feasible in sports activities, a mathematical model was applied to quantify spinal loading of more than 600 physical tasks in more than 200 athletes from several sports disciplines. The outcome is compression and torque (normalized to body weight/mass) at L4/L5.
Results
The data demonstrate high compressive forces on the lumbar spine in sport-related activities, which are much higher than forces reported in normal daily activities and work tasks. Especially ballistic jumping and landing skills yield high estimated compression at L4/L5 of more than ten times body weight. Jumping, landing, heavy lifting and weight training in sports demonstrate compression forces significantly higher than guideline recommendations for working tasks.
Conclusion
These results may help to identify acute and long-term risks of low back pain and, thus, may guide the development of preventive interventions for low back pain or injury in athletes.
Footwear plays a critical role in our daily lives, affecting our performance, health and overall well-being. Well-designed footwear can provide protection, comfort and improved foot functionality, while poorly designed footwear can lead to mobility problems and declines in physical activity. The overall goal of footwear research is to provide a scientific basis for professionals in the field to provide an optimal footwear solution for a given person, for a given task, in a given environment, while using sustainable manufacturing processes. This article suggests potential directions for future research with a focus on athletic footwear biomechanics. Directions include the evidence-based individualisation of footwear, the interaction between design and prolonged use, and improving the sustainability of footwear. The authors also provide a speculative outlook on methodological developments that may provide greater insight into these areas. These developments may include: (1) the use of larger scale, real-world and representative data, (2) the use of 3D printing to create experimental footwear, (3) the advancement of in silico research methods, and (4) furthering multidisciplinary collaboration. If successfully applied in the future, footwear research will contribute to active and healthy lifestyles across the lifespan.
Appraising the Methodological Quality of Sports Injury Video Analysis Studies: The QA-SIVAS Scale
(2023)
Background
Video analysis (VA) is commonly used in the assessment of sports injuries and has received considerable research interest. Until now, no tool has been available for the assessment of study quality. Therefore, the objective of this study was to develop and evaluate a valid instrument that reliably assesses the methodological quality of VA studies.
Methods
The Quality Appraisal for Sports Injury Video Analysis Studies (QA-SIVAS) scale was developed using a modified Delphi approach including expert consensus and pilot testing. Reliability was examined through intraclass correlation coefficient (ICC3,1) and free-marginal kappa statistics by three independent raters. Construct validity was investigated by comparing QA-SIVAS with expert ratings by using Kendall’s tau analysis. Rating time was studied by applying the scale to 21 studies and computing the mean time for rating per study article.
Results
The QA-SIVAS scale consists of an 18-item checklist addressing the study design, data source, conduct, report, and discussion of VA studies in sports injury research. Inter- and intra-rater reliability were excellent with ICCs > 0.97. Expert ratings revealed a high construct validity (0.71; p < 0.001). Mean rating time was 10 ± 2 min per article.
Conclusion
QA-SIVAS is a reliable and valid instrument that can be easily applied to sports injury research. Future studies in the field of VA should adhere to standardized methodological criteria and strict quality guidelines.
The increasingly stringent CO2 emissions standards require innovative solutions in the vehicle development process. One possibility to reduce CO2 emissions is the electrification of powertrains. The resulting increased complexity, as well as the increased competition and time pressure make the use of simulation software and test benches indispensable in the early development phases. This publication therefore presents a methodology for test bench coupling to enable early testing of electrified powertrains. For this purpose, an internal combustion engine test bench and an electric motor test bench are virtually interconnected. By applying and extending the Distributed Co-Simulation Protocol Standard for the presented hybrid electric powertrain use case, real-time-capable communication between the two test benches is achieved. Insights into the test bench setups, and the communication between the test benches and the protocol extension, especially with regard to temperature measurements, enable the extension to be applied to other powertrain or test bench configurations. The shown results from coupled test bench operations emphasize the applicability. The discussed experiences from the test bench coupling experiments complete the insights.
Injury prevention is essential in running due to the risk of overuse injury development. Tailoring running shoes to individual needs may be a promising strategy to reduce this risk. Novel manufacturing processes allow the production of individualised running shoes that incorporate features that meet individual biomechanical and experiential needs. However, specific ways to individualise footwear to reduce injury risk are poorly understood. Therefore, this scoping review provides an overview of (1) footwear design features that have the potential for individualisation; and (2) the literature on the differential responses to footwear design features between selected groups of individuals. These purposes focus exclusively on reducing the risk of overuse injuries. We included studies in the English language on adults that analysed: (1) potential interaction effects between footwear design features and subgroups of runners or covariates (e.g., age, sex) for running-related biomechanical risk factors or injury incidences; (2) footwear comfort perception for a systematically modified footwear design feature. Most of the included articles (n = 107) analysed male runners. Female runners may be more susceptible to footwear-induced changes and overuse injury development; future research should target more heterogonous sampling. Several footwear design features (e.g., midsole characteristics, upper, outsole profile) show potential for individualisation. However, the literature addressing individualised footwear solutions and the potential to reduce biomechanical risk factors is limited. Future studies should leverage more extensive data collections considering relevant covariates and subgroups while systematically modifying isolated footwear design features to inform footwear individualisation.
With the function RooTri(), we present a simple and robust calculation method for the approximation of the intersection points of a scalar field given as an unstructured point cloud with a plane oriented arbitrarily in space. The point cloud is approximated to a surface consisting of triangles whose edges are used for computing the intersection points. The function contourc() of Matlab is taken as a reference. Our experiments show that the function contourc() produces outliers that deviate significantly from the defined nominal value, while the quality of the results produced by the function RooTri() increases with finer resolution of the examined grid.
Background
To assess the in-field walking mechanics during downhill hiking of patients with total knee arthroplasty five to 14 months after surgery and an age-matched healthy control group and relate them to the knee flexor and extensor muscle strength.
Methods
Participants walked on a predetermined hiking trail at a self-selected, comfortable pace wearing an inertial sensor system for recording the whole-body 3D kinematics. Sagittal plane hip, knee, and ankle joint angles were evaluated over the gait cycle at level walking and two different negative slopes. The concentric and eccentric lower extremity muscle strength of the knee flexors and extensors isokinetically at 50 and 120°/s were measured.
Findings
Less knee flexion angles during stance have been measured in patients in the operated limb compared to healthy controls in all conditions (level walking, moderate downhill, steep downhill). The differences increased with steepness. Muscle strength was lower in patients for both muscle groups and all measured conditions. The functional hamstrings to quadriceps ratio at 120°/sec correlated with knee angle during level and downhill walking at the moderate slope in patients, showing higher ratios with lower peak knee flexion angles.
Interpretation
The study shows that even if rehabilitation has been completed successfully and complication-free, five to 14 months after surgery, the muscular condition was still insufficient to display a normal gait pattern during downhill hiking. The muscle balance between quadriceps and hamstring muscles seems related to the persistence of a stiff knee gait pattern after knee arthroplasty. LoE: III.
Maintaining stability while walking on arbitrary surfaces or dealing with external perturbations is of great interest in humanoid robotics research. Increasing the system’s autonomous robustness to a variety of postural threats during locomotion is the key despite the need to evaluate noisy sensor signals. The equations of motion are the foundation of all published approaches. In contrast, we propose a more adequate evaluation of the equations of motion with respect to an arbitrary moving reference point in a non-inertial reference frame. Conceptual advantages are, e.g., getting independent of global position and velocity vectors estimated by sensor fusions or calculating the imaginary zero-moment point walking on different inclined ground surfaces. Further, we improve the calculation results by reducing noise-amplifying methods in our algorithm and using specific characteristics of physical robots. We use simulation results to compare our algorithm with established approaches and test it with experimental robot data.
Featherweight Generic Go (FGG) is a minimal core calculus modeling the essential features of the programming language Go. It includes support for overloaded methods, interface types, structural subtyping, and generics. The most straightforward semantic description of the dynamic behavior of FGG programs is to resolve method calls based on runtime type information of the receiver. This article shows a different approach by defining a type-directed translation from FGG− to an untyped lambda-calculus. FGG− includes all features of FGG but type assertions. The translation of an FGG− program provides evidence for the availability of methods as additional dictionary parameters, similar to the dictionary-passing approach known from Haskell type classes. Then, method calls can be resolved by a simple lookup of the method definition in the dictionary. Every program in the image of the translation has the same dynamic semantics as its source FGG− program. The proof of this result is based on a syntactic, step-indexed logical relation. The step index ensures a well-founded definition of the relation in the presence of recursive interface types and recursive methods. Although being non-deterministic, the translation is coherent.
In 4D printing, an additively manufactured component is given the ability to change its shape or function in an intended and useful manner over time. The technology of 4D printing is still in an early stage of development. Nevertheless, interesting research and initial applications exist in the literature. In this work, a novel methodical approach is presented that helps transfer existing 4D printing research results and knowledge into solving application tasks systematically. Moreover, two different smart materials are analyzed, used, and combined following the presented methodical approach to solving the given task in the form of recovering an object from a poorly accessible space. This is implemented by self-positioning, grabbing, and extracting the target object. The first smart material used to realize these tasks is a shape-memory polymer, while the second is a polymer-based magnetic composite. In addition to the presentation and detailed implementation of the methodical approach, the potentials and behavior of the two smart materials are further examined and narrowed down as a result of the investigation. The results show that the developed methodical approach contributes to moving 4D printing closer toward a viable alternative to existing technologies due to its problem-oriented nature.
Immunosorbent turnip vein clearing virus (TVCV) particles displaying the IgG-binding domains D and E of Staphylococcus aureus protein A (PA) on every coat protein (CP) subunit (TVCVPA) were purified from plants via optimized and new protocols. The latter used polyethylene glycol (PEG) raw precipitates, from which virions were selectively re-solubilized in reverse PEG concentration gradients. This procedure improved the integrity of both TVCVPA and the wild-type subgroup 3 tobamovirus. TVCVPA could be loaded with more than 500 IgGs per virion, which mediated the immunocapture of fluorescent dyes, GFP, and active enzymes. Bi-enzyme ensembles of cooperating glucose oxidase and horseradish peroxidase were tethered together on the TVCVPA carriers via a single antibody type, with one enzyme conjugated chemically to its Fc region, and the other one bound as a target, yielding synthetic multi-enzyme complexes. In microtiter plates, the TVCVPA-displayed sugar-sensing system possessed a considerably increased reusability upon repeated testing, compared to the IgG-bound enzyme pair in the absence of the virus. A high coverage of the viral adapters was also achieved on Ta2O5 sensor chip surfaces coated with a polyelectrolyte interlayer, as a prerequisite for durable TVCVPA-assisted electrochemical biosensing via modularly IgG-assembled sensor enzymes.
In this paper, the performance of different continuous-time and discrete-time models of the electrical subsystem of induction machines and permanent-magnet synchronous machines as well as methods based on them for decoupling the direct and
quadrature axis components of the stator current are investigated and compared. The focus here is on inverter-fed, pulse width modulated drives when operated with a relatively large product of stator frequency and sampling time, where significant
differences between the models and decoupling methods used come to light. Recommendations for a discrete-time model to be used uniformly in the future are made, as well as statements on whether feedforward or feedback decoupling structures are better suited and whether state controllers improve decoupling measures for very steep speed ramps. Simulation studies and measurement results support the statements made above.
Künstliche Intelligenz (KI) durchdringt unser Leben immer stärker. Studierende werden im Alltag und an Hochschulen zunehmend mit KI-Anwendungen konfrontiert. An der Hochschule Offenburg werden deshalb KI-bezogene Lehrangebote curricular verankert, um Studierende im Erwerb von KI-Kompetenz zu unterstützen.
Der Beitrag stellt ein Konzept für die Entwicklung von Lehrveranstaltungen nach der Idee des pädagogischen Makings zur Förderung von KI-Kompetenz in der Hochschullehre vor. Konkretisiert wird das Konzept anhand eines Moduls zum Thema Chatbots, dessen Lehrinhalte interdisziplinär aus verschiedenen Perspektiven ausgearbeitet werden.
This paper presents a framework for numerical building validation enhancement based on detailed building specifications from in-situ measurements and evidence-based validation assessment undertaken on a detached sustainable lightweight building in a semi-arid climate. The validation process has been undergone in a set of controlled experiments – a free-float period, and steady-state internal temperatures. The validation was conducted for a complete year with a 1-min time step for the hourly indoor temperature and the variable refrigerant flow (VRF) energy consumption. The initial baseline model was improved by three series of validation steps per three different field measurements including thermal transmittance, glazing thermal and optical properties, and airtightness. Then, the accurate and validated model was used for building energy efficiency assessment in 12 regions of Morocco. This study aims to assess the effect of accurate building characteristics values on the numerical model enhancement. The initial CV(RMSE) and NMBE have improved respectively from 14.58 % and −11.23 %–7.85 % and 1.86 % for the indoor temperature. Besides, from 31.17 % to 14.37 %–20.57 % and 9.77 % for energy consumption. The findings demonstrate that the lightweight construction with the use of a variable refrigerant flow system could be energy efficient in the southern regions of Morocco.
Energy efficiency and hygrothermal performance of hemp clay walls for Moroccan residential buildings
(2023)
Hemp-based building envelopes have gained significant popularity in developed countries, and now the trend of constructing houses with hemp-clay blocks is spreading to developing countries like Morocco. Investigating the hygrothermal behavior of such structures under actual climate conditions is essential for advancing and promoting this sustainable practice. This paper presents an in-depth experimental characterization of a commercial hemp-clay brick that has been exposed to the outdoor environment for four years, in addition to field measurements on a building scale demonstration prototype. Additionally, the study simulates 17 representative cities to assess the hygrothermal performance and energy-saving potential in each of Morocco's six existing climate zones, using the EnergyPlus engine. The experimental campaign's findings demonstrate excellent indoor air temperature and relative humidity regulation within the hemp-clay wall building, leading to satisfactory levels of thermal comfort within hemp-clay wall buildings. This is attributed to the material's good thermal conductivity and excellent moisture buffering capacity (found to be 0.31 W/mK and 2.25 g/m2%RH), respectively). The energy simulation findings also point to significant energy savings, with cooling and heating energy reductions ranging from 27.7% to 47.5% and 33.7% to 79.8%, respectively, as compared to traditional Moroccan buildings.
Given the looming threats of climate change and the rapid worldwide urbanization, it is a necessity to prioritize the transition towards a carbon-free built environment. This research study provides a holistic digital methodology for parametric design of urban residential buildings with regard to the Mediterranean semi-arid climate zone of Morocco in the early design phase. The morphological parameters of the urban residential buildings, namely the buildings’ typology, the distance between buildings, the urban grid’s orientation, and the window-towall ratio, are evaluated in order to identify the key combinations of passive and active solar design strategies that determine the high energy performing configurations, based on the introduced Energy Performance Index (EPI), which is the ratio between solar BIPV production to maximum available installed BIPV capacity and the normalized thermal energy needs. Through an automated processing of 2187 iterations via Grasshopper, we simulate daylight autonomy, indoor thermal comfort and solar rooftop photovoltaic and building integrated photovoltaic (BIPV) energy potential. Then, we analyze the conflicting objectives of energy efficiency measures, active solar design strategies, and indoor visual comfort in the decision-making process that supports our goal of getting closer to net zero urban residential buildings. The digital workflow showed interesting trends in reaching a balanced equilibrium between performance metrics influenced by the contrasting impact of solar exposure on indoor daylight autonomy and thermal energy demand. Furthermore, the study’s findings indicate that it is possible to achieve an annual load match exceeding 66,56 % while simultaneously ensuring an acceptable visual indoor comfort (sDA higher than 0.4). The findings also highlight the important role of the BIPV system in shifting towards the net zero energy goal, by contributing up to 30 % of the overall solar energy output and covering up to 20 % of the yearly self-consumption. Moreover, the energy balance evaluation on an hourly basis indicates that BIPV system notably enhances the daily load cover factor by up to 5.5 %, particularly in the case of slab SN typology, throughout the different seasons. Graphical representations of the yearly, monthly and hourly load matches and the hourly energy balance of the best performing configurations provide a thorough understanding of the potential evolution of the urban energy system over time as a result of the gradual integration of active solar electricity production.
Entrepreneurial Leadership
(2023)
Die Medienbranche ist seit Jahren von disruptiven Veränderungen betroffen, sodass die Unternehmen und zentralen Akteure in einem dauerhaften Veränderungsmodus sind. Gestiegene Anforderungen an Führungskräfte, Kostendruck und geringe Zeitbudgets für Weiterbildung reduzieren die Möglichkeiten für umfassende Ausbildungsmöglichkeiten. Dieser Beitrag beschreibt einen Lösungsansatz, wie trotz begrenzter Budget- und Zeitressourcen eine individuelle Begleitung von Führungskräften möglich wird. Mit einer Kombination von stärkenorientierter Selbstreflexion und gezielten Impulsen werden Führungskräfte in ihrer Entwicklung als selbstverantwortliche, unternehmerisch denkende Führungskraft gestärkt.
The aim of this paper is to identify indicators at country level that could prove useful in improving the effectiveness of fraud detection in European Structural and Investment Funds. We analyse data for 454 funds, belonging to the period 2014-2020, from the 28 countries that were members of the European Union in 2014. Explanatory results suggest the convenience of tracking funds, especially in countries with higher GDP and higher transparency levels, and the lesser relevance of the number of irregularities for countries with higher GDP and those receiving larger funds. Fraud and fraud detection rates in individual funds vary significantly across states. Federal states, such as the Federal Republic of Germany, are comparatively successful in detecting fraud in EU funds.
Gamification is increasingly successful in the field of education and health. However, beyond call-centers and applications in human resources, its utilization within companies remains limited. In this paper, we examine the acceptance of gamification in a large company (with over 17,000 employees) across three generations, namely X, Y, and Z. Furthermore, we investigate which gamification elements are suited for business contexts, such as the dissemination of company principles and facts, or the organization of work tasks. To this end, we conducted focus group discussions, developed the prototype of a gamified company app, and performed a large-scale evaluation with 367 company employees. The results reveal statistically significant intergenerational disparities in the acceptance of gamification: younger employees, especially those belonging to Generation Z, enjoy gamification more than older employees and are most likely to engage with a gamified app in the workplace. The results further show a nuanced range of preferences regarding gamification elements: avatars are popular among all generations, badges are predominantly appreciated by Generations Z and Y, while leaderboards are solely liked by Generation Z. Drawing upon these insights, we provide recommendations for future gamification projects within business contexts. We hope that the results of our study regarding the preferences of the gamification elements and understanding generational differences in acceptance and usage of gamification will help to create more engaging and effective apps, especially within the corporate landscape.
Unterschiedliche Stimulationszeitpunkte bei bimodaler Versorgung mit Hörgerät und Cochleaimplantat
(2023)
Die bimodale Versorgung von Patienten mit Hörgerät (HG) ipsilateral und Cochleaimplantat (CI) kontralateral bei asymmetrischem Hörverlust ist aufgrund vieler inhärenter Variablen die komplizierteste Versorgungsart im Kontext der Versorgung mit CI. Im vorliegenden Übersichtsartikel werden alle systematischen interauralen Unterschiede zwischen elektrischer und akustischer Stimulation dargestellt, die bei dieser Versorgungsart auftreten können. Darüber hinaus werden Methoden zur Quantifizierung des interauralen Latenzoffsets, also des Zeitunterschieds zwischen der akustischen und elektrischen Stimulation des Hörnervs, mittels Registrierung auditorisch evozierter Potenziale – erzeugt durch akustische bzw. elektrische Stimulation – und Messungen an den Sprachprozessoren und Hörgeräten vorgestellt. Die technische Kompensation des interauralen Latenzoffsets und ihre positive Auswirkung auf die Schalllokalisationsfähigkeit bimodal mit CI und HG versorgter Patienten wird ebenfalls beschrieben. Zuletzt werden neueste Erkenntnisse diskutiert, die Gründe dafür aufzeigen, warum die Kompensation des interauralen Latenzoffsets das Sprachverstehen im Störgeräusch bei bimodal versorgten CI-/HG-Trägern nicht verbessert.
Decentralized applications (dApp) have proliferated in recent years, but their long-term viability is a topic of debate. However, for dApps to be sustainable, and suitable for integration into a larger service networks, they need to attract users and promise reliable availability. Therefore, assessing their longevity is crucial. Analyzing the utilization trajectory of a service is, however, challenging due to several factors, such as demand spikes, noise, autocorrelation, and non-stationarity. In this study, we employ robust statistical techniques to identify trends in currently popular dApps. Our findings demonstrate that a significant proportion of dApps, across a range of categories, exhibit statistically significant positive overall trends, indicating that success in decentralized computing can be sustainable and transcends specific fields. However, there is also a substantial number of dApps showing negative trends, with a disproportionately high number from the decentralized finance (DeFi) category. Furthermore, a more detailed inspection of time series segments shows a clearly diminishing proportion of positive trends from mid-2021 to the present. In summary, we conclude that the dApp economy might have lost some momentum, and that there is a strong element of uncertainty regarding its future significance.
International trade requires sufficient, reliable, and affordable sources of financing. Export credit agencies (ECAs) fill trade finance gaps by offering financing, insurance and guarantees to provide liquidity or mitigate risks. They help to create or secure jobs in the domestic economy. However, comprehensive government support is required to create significant impact. This includes ‘full faith and credit’ of the state. In the context of public foreign trade promotion, full faith and credit is defined as an explicit, direct or indirect, irrevocable, legal commitment to accept all liabilities of an ECA as unconditional obligations of the respective government. Our policy recommendations for countries with relatively young ECAs, for example in Ukraine, Armenia, and Malawi, are to establish a full guarantee in addition to an efficient legal set-up, sufficient capital, and sound risk management of the respective agency. Without full faith and credit, policy goals of fostering economic growth through foreign trade fall short.
Lithium-ion battery cells exhibit a complex and nonlinear coupling of thermal, electrochemical,and mechanical behavior. In order to increase insight into these processes, we report the development of a pseudo-three-dimensional (P3D) thermo-electro-mechanical model of a commercial lithium-ion pouch cell with graphite negative electrode and lithium nickel cobalt aluminum oxide/lithium cobalt oxide blend positive electrode. Nonlinear molar volumes of the active materials as function of lithium stoichiometry are taken from literature and implemented into the open-source software Cantera for convenient coupling to battery simulation codes. The model is parameterized and validated using electrical, thermal and thickness measurements over a wide range of C-rates from 0.05 C to 10 C. The combined experimental and simulated analyses show that thickness change during cycling is dominated by intercalation-induced swelling of graphite, while swelling of the two blend components partially cancel each other. At C-rates above 2 C, electrochemistry-induced temperature increase significantly contributes to cell swelling due to thermal expansion. The thickness changes are nonlinearly distributed over the thickness of the electrode pair due to gradients in the local lithiation, which may accelerate local degradation. Remaining discrepancies between simulation and experiment at high C-rates might be attributed to lithium plating, which is not considered in the model at present.
Public export credits and trade insurance require a global framework of institutions, rules and regulations to avoid subsidies and a race to the bottom. The extensive modernisation of the Arrangement on Officially Supported Export Credits (Arrangement) of the Organisation for Economic Co-operation and Development intends to re-level the playing field. This Practitioner Commentary describes the demand for adequate government interventions, considers the need for the reform and discusses key aspects of the new Arrangement. We argue that there is a breakthrough in several important areas such as tenors, repayment terms and green finance. However, we also find that the modernisation falls short in areas such as the interplay between different rulebooks, pre-shipment instruments' regulations and climate action.
A balcony photovoltaic (PV) system, also known as a micro-PV system, is a small PV system consisting of one or two solar modules with an output of 100–600 Wp and a corresponding inverter that uses standard plugs to feed the renewable energy into the house grid. In the present study we demonstrate the integration of a commercial lithium-ion battery into a commercial micro-PV system. We firstly show simulations over one year with one second time resolution which we use to assess the influence of battery and PV size on self-consumption, self-sufficiency and the annual cost savings. We then develop and operate experimental setups using two different architectures for integrating the battery into the micro-PV system. In the passive hybrid architecture, the battery is in parallel electrical connection to the PV module. In the active hybrid architecture, an additional DC-DC converter is used. Both architectures include measures to avoid maximum power point tracking of the battery by the module inverter. Resulting PV/battery/inverter systems with 300 Wp PV and 555 Wh battery were tested in continuous operation over three days under real solar irradiance conditions. Both architectures were able to maintain stable operation and demonstrate the shift of PV energy from the day into the night. System efficiencies were observed comparable to a reference system without battery. This study therefore demonstrates the feasibility of both active and passive coupling architectures.
Electrochemical pressure impedance spectroscopy (EPIS) is an emerging tool for the diagnosis of polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of the cell voltage with respect to an excitation of the gas-phase pressure. Several experimental studies in the past decade have shown the complexity of EPIS signals, and so far there is no agreement on the interpretation of EPIS features. The present study contributes to shed light into the physicochemical origin of EPIS features, by using a combination of pseudo-two-dimensional modeling and analytical interpretation. Using static simulations, the contributions of cathode equilibrium potential, cathode overpotential, and membrane resistance on the quasi-static EPIS response are quantified. Using model reduction, the EPIS responses of individual dynamic processes are predicted and compared to the response of the full model. We show that the EPIS signal of the PEMFC studied here is dominated by the humidifier. The signal is further analyzed by using transfer functions between various internal cell states and the outlet pressure excitation. We show that the EPIS response of the humidifier is caused by an oscillating oxygen molar fraction due to an oscillating mass flow rate.
Eine Regelung zur optimalen Kraftschlußausnutzung von Lokomotiven setzt das Erreichen folgender Ziele voraus: Frühzeitiges Erkennen der Schleudergrenze zur Vermeidung von Gleitvorgängen; Fahren eines optimalen Kraftschlusses vom Fahr- und Bremsbetrieb ohne Überschreitung des Kraftschlußmaximums und schnelle Anpassung an wechselnde Arbeitspunkte, zum Beispiel an wechselnde Schienenzustände. Die vorgestellte optimale Regelung der Kraftschlußausnutzung erfaßt Schleuder- und Gleitzustände, die mit bisher eingesetzten Verfahren nicht erkannt werden können und ist Basis für ein Konzept, das ein quasi permanentes Fahren in der Nähe des Kraftschlußmaximums ermöglicht.
In this paper, the J-integral is derived for temperature-dependent elastic–plastic materials described by incremental plasticity. It is implemented using the equivalent domain integral method for assessment of three-dimensional cracks based on results of finite-element calculations. The J-integral considers contributions from inhomogeneous temperature fields and temperature-dependent elastic and plastic material properties as well as from gradients in the plastic strains and the hardening variables. Different energy densities are considered, the Helmholtz free energy and the stress-working density, providing a physical meaning of the J-integral as a fracture criteria for crack growth. Results obtained for a plate with two different crack configurations each loaded by a cool-down thermal shock show domain-independence of the incremental J-integral for different energy densities even for high temperature gradients and significant temperature-dependence of the yield stress and the hardening exponent in the presence of large scale yielding. Hence, the derived J-integral is an appropriate parameter for the assessment of cracks in thermomechanically loaded components.
Subjects utilizing a cochlear implant (CI) in one ear and a hearing aid (HA) on the contralateral ear suffer from mismatches in stimulation timing due to different processing latencies of both devices. This device delay mismatch leads to a temporal mismatch in auditory nerve stimulation. Compensating for this auditory nerve stimulation mismatch by compensating for the device delay mismatch can significantly improve sound source localization accuracy. One CI manufacturer has already implemented the possibility of mismatch compensation in its current fitting software. This study investigated if this fitting parameter can be readily used in clinical settings and determined the effects of familiarization to a compensated device delay mismatch over a period of 3–4 weeks. Sound localization accuracy and speech understanding in noise were measured in eleven bimodal CI/HA users, with and without a compensation of the device delay mismatch. The results showed that sound localization bias improved to 0°, implying that the localization bias towards the CI was eliminated when the device delay mismatch was compensated. The RMS error was improved by 18% with this improvement not reaching statistical significance. The effects were acute and did not further improve after 3 weeks of familiarization. For the speech tests, spatial release from masking did not improve with a compensated mismatch. The results show that this fitting parameter can be readily used by clinicians to improve sound localization ability in bimodal users. Further, our findings suggest that subjects with poor sound localization ability benefit the most from the device delay mismatch compensation.
High performance thin layer chromatography (HPTLC) is a frequently used separation technique which works well for quantification of caffeine and quinine in beverages. Competing separation techniques, e.g. high-performance liquid chromatography (HPLC) or gas chromatography (GC), are not suitable for sugar-containing samples, because these methods need special pretreatment by the analyst. In HPTLC, however, it is possible to separate ‘dirty’ samples without time-consuming pretreatment, because disposable HPTLC plates are used. A convenient method for quantification of caffeine and quinine in beverages, without sample pretreatment, is presented below. The basic theory of in-situ quantification in HPTLC by use of remitted light is introduced and discussed. Several linearization models are discussed.
A home-made diode-array scanner has been used for quantification; this, for the first time, enables simultaneous measurements at different wavelengths. The new scanner also enables fluorescence evaluation without further equipment. Simultaneous recording at different wavelengths improves the accuracy and reliability of HPTLC analysis. These aspects result in substantial improvement of in-situ quantitative densitometric analysis and enable quantification of compounds in beverages.
A new diode-array scanner in combination with a computer-controlled application system meets all the demands of modern HPTLC measurement. Automatic application, simultaneous measurements at different wavelengths, and different linearization models enable appropriate evaluation of all analytical questions. The theory of error propagation recommends quantification at reflectance values smaller than 0.8; this can be verified only by use of diode-array scanning. The same theory also recommends quantification by use of peak height data, because the theory predicts best precision only for peak height evaluation. Diode-array scanning with reflectance monitoring enables appropriate validation in TLC and HPTLC analysis. All these aspects result in substantial improvement of in-situ quantitative densitometric analysis, and simultaneous recording at different wavelengths opens the way for chemometric evaluation, e.g. peak purity monitoring, which improves the accuracy and reliability of HPTLC analysis.
Fluorescence Enhancement of Pyrene Measured by Thin-Layer Chromatography with Diode-Array Detection
(2003)
In-situ densitometry for qualitative or quantitative purposes is a key step in thin-layer chromatography. It offers a simple way of quantifying by measuring the optical density of the separated spots directly on the plate. A new TLC scanner has been developed which is able to measure TLC plates or HPTLC plates, at different wavelengths simultaneously, without destroying the plate surface. The system enables absorbance and fluorescence measurements in one run. Fluorescence measurements are possible without filters or other adjustments.
The measurement of fluorescence from a TLC plate is a versatile means of making TLC analysis more sensitive. Fluorescence measurements with the new scanner are possible without filters or special lamps. Improvement of the signal-to-noise ratio is achieved by wavelength bundling. During plate scanning the scattered light and the fluorescence are both emitted from the surface of the TLC plate and this emitted light provides the desired spectral information from substances on the TLC plate. The measurement of fluorescence spectra and absorbance spectra directly from a TLC plate is based on differential measurement of light emerging from sample-free and sample-containing zones.
The literature recommends dipping TLC plates in viscous liquids to enhance fluorescence. Measurement of the fluorescence and absorbance spectra of pyrene spots reveals the mechanism of enhancement of plate dipping in viscous liquids—blocked contact of the fluorescent molecules with the stationary phase or other sample molecules is responsible for the enhanced fluorescence at lower concentrations.
In conclusion, dipping in TLC analysis is no miracle. It is based on similar mechanisms observable in liquids. The measured TLC spectra are also very similar to liquid spectra and this makes TLC spec-troscopy an important tool in separation analysis.
A new formula is presented for transforming fluorescence measurements in accordance with Kubelka-Munk theory. The fluorescence signals, the absorption signals, and data from a selected reference are combined in one expression. Only diode-array techniques can measure all the required data simultaneously to linearize fluorescence data correctly. To prove the new theory HPTLC quantification of the analgesic flupirtine was performed over the mass range 300 to 5000 ng per spot. The fluorescence calibration curve was linear over the whole range. The transformation of fluorescence measurements into linear mass-dependent data extends the technique of in-situ fluorescence analysis to the high concentration range. It also extends Kubelka-Munk theory from absorption to fluorescence analysis. The results presented also emphasize the importance of Kubelka-Munk theory for in-situ measurements in scattering media, especially in planar chromatography.
Material flow simulation is a core technology of Industry 4.0. It can analyze and improve large-scale production systems through experimentation with digital simulation models. However, modeling in discrete event simulation is considered as an effortful and time-consuming activity and challenges especially small and medium-sized enterprises. Systematic experiments and what-if-analysis require a large number of models. Modeling and simulation becomes a repetitive activity and the ability to model and simulate instantly becomes crucial for industry, 4.0. However, model generation typically uses specific methods to build models with individual properties for specific physical systems. A general literature review cannot sufficiently describe the current state of model generation. This study aims to provide an analysis of model generation based on the modeling strategy, modeling view, and production system type, as well as model properties and limitations.
Gamification wird in vielen Bereichen, die auch den Bildungssektor einschließen, zur Motivations- und Leistungssteigerung eingesetzt. Dieser Beitrag beschreibt das Design, die Umsetzung und Evaluierung eines Gamification-Konzeptes für die Vorlesung „Software Engineering" an der Hochschule Offenburg. Gamification soll nach Intention der Lehrenden eine kontinuierliche und tiefergehende Auseinandersetzung mit den Themen der Vorlesung forcieren sowie einen positiven Einfluss auf die Motivation der Studierenden haben, um den Lernprozess zu unterstützen. Zentral für das Gamification-Design sind dabei eine freiwillige Teilnahme, die Wahrnehmung der Bedeutung der Lerninhalte und ein zielorientierter Einsatz von Gamification-Elementen. Das entwickelte Konzept wurde in der Lernplattform Moodle realisiert, über drei Semester eingesetzt und parallel evaluiert. Die Ergebnisse dieser Evaluierungen zeigen, dass die Studierenden den gamifizierten Kurs intensiv und oft über das gesamte Semester nutzten und aus eigenem Antrieb eine Vielzahl von Übungen absolvierten.
Building energy management systems (BEMSs), dedicated to sustainable buildings, may have additional duties, such as hosting efficient energy management systems (EMSs) algorithms. This duty can become crucial when operating renewable energy sources (RES) and eventual electric energy storage systems (ESSs). Sophisticated EMS approaches that aim to manage RES and ESSs in real time may need high computing capabilities that BEMSs typically cannot provide. This article addresses and validates a fuzzy logic-based EMS for the optimal management of photovoltaic (PV) systems with lead-acid ESSs using an edge computing technology. The proposed method is tested on a real smart grid prototype in comparison with a classical rule-based EMS for different weather conditions. The goal is to investigate the efficacy of islanding the building local network as a control command, along with ESS power control. The results show the implementation feasibility and performance of the fuzzy algorithm in the optimal management of ESSs in both operation modes: grid-connected and islanded modes.
Seit den ersten Projekten der 90er Jahre arbeiten Hochschulen daran, geeignete Servicestrukturen für E-Learning zu etablieren, die die erforderliche technische, didaktische und organisatorische Unterstützung hochschulweit zur Verfügung stellen. Ging es zunächst darum, Services überhaupt dauerhaft zu sichern, steht heute die Frage des „wie“ im Vordergrund. Dabei wird am Bereich E-Learning ein eigentlich viel allgemeineres Problem deutlich: Die bisher überwiegende Organisation der Hochschule nach funktionellen Einheiten stößt an ihre Grenzen. Wir schlagen eine stärker prozessorientierte Sichtweise vor, analog zu Entwicklungen bei der Organisation von Unternehmen.
Bud type carbon nanohorns (CNHs) are composed of carbon and have a closed conical tip at one end protruding from an aggregate structure. By employing a simple oxidation process in CO2 atmosphere, it is possible to open the CNH tips which increases their specific surface area by four fold. These tip opened CNHs combine the microporous nature of activated carbons and the crystalline mesoporous character of carbon nanotubes. The results for the high pressure CO2 gas adsorption of tip opened CNHs are reported herein for the first time and are found to be superior to traditional CO2 adsorbents like zeolites. The modified CNHs are also found to be promising materials for lithium ion batteries and the performance is found to be on a par with carbon nanotubes and carbon nanofibers.
Der Beitrag behandelt ausgewählte Themenkomplexe im Zusammenhang mit der Vorspannung von Schraubenverbindungen im Stahlbau. Es werden verschiedene Anwendungen und damit verbundene Aspekte beleuchtet und diskutiert, zum Beispiel die Schraubensicherung durch Vorspannung oder die Steifigkeit der Verbindung. Dem vorangestellt ist eine kurze Einführung in die mechanische Wirkung der Vorspannung in der Verbindung sowie eine Vorstellung der Vorspannverfahren.
In this study the dynamics and stability of thin and electrically conductive aqueous films under the influence of a time-periodic electric field are explored. With the help of analytical linear stability analysis for long wavelength disturbances, the stability threshold of the system as a function of various electrochemical parameters and transport coefficients is presented. The contributions of parameters like surface tension, disjoining pressure, electric double layer (Debye length and interfacial zeta potential), and unsteady Maxwell and viscous stresses are highlighted with the help of appropriate dimensionless groups. The physical mechanisms affecting the stability of thin films are detailed with the above-mentioned forces and parametric dependence of stability trends is discussed.
Authentic corporate social responsibility: antecedents and effects on consumer purchase intention
(2023)
Purpose
The aim of the research is to identify the factors that create an authentic company's corporate social responsibility (CSR) engagement and to investigate whether an authentic CSR engagement influences the purchase intention. In addition, the study attempts to provide insights into the mediation role of attitude toward the company and frequency of purchase on purchase intention.
Design/methodology/approach
In this study, a theoretical framework is developed in which major antecedents of authentic CSR are identified. A specific example of a brand and its corporate social responsibility activities was used for the study. An online questionnaire was used to collect the data. To verify the hypothesis, structural equation modeling with the partial least squares method was used. A total of 240 people participated in the study.
Findings
The results of the study confirmed that CSR authenticity positively influences consumer purchase intention. Furthermore, the hypothesized impact of CSR authenticity on attitudes toward the company and frequency of purchase could be verified.
Originality/value
Although there is research on the antecedents influencing the consumer's perceived authenticity of CSR, it has not addressed differences in impact and has not presented a full picture of influencing antecedents. In addition, CSR proof as a new antecedent is investigated in the study. Moreover, research on outcomes of perceived CSR authenticity still lacks depth. The study therefore addresses this research gap by providing an extensive research framework including antecedents influencing CSR authenticity and outcomes of CSR authenticity.
In diesem Beitrag werden die Bereitstellungskosten flexibler Systemkomponenten im deutschen Stromsystem analysiert, zu deren Quantifizierung eine einheitliche Methodik entwickelt wird. Dabei ist das Ziel des Beitrags, zeitlich differenzierte Kostenpotenzialkurven für die Jahre 2015 und 2030 zu erarbeiten, anhand derer die energiespezifischen Kosten der markt- und systemdienlichen Flexibilitätsbereitstellung verglichen und die einzelnen Flexibilitätsoptionen in einen Gesamtkontext eingeordnet werden können.
Der Einsatz flexibler Systemkomponenten wird hierzu in die drei Hauptphasen (1) Vorhaltung, (2) Abruf und (3) Einsatzfolgen unterteilt, woraus sich drei kongruente Kostengruppen ableiten lassen, nach denen die einzelnen Kostenbestandteile identifiziert und als Ergebnis die Bereitstellungskosten quantifiziert werden. Neben fossil-thermischen Kraftwerken werden dabei bspw. die Kraft-Wärme-Kopplung, Biogasanlagen, Pumpspeicher- und Laufwasserkraftwerke sowie steuerbare Lasten untersucht.
Zur anschließenden Abbildung der teils negativen Bereitstellungskosten wird die herkömmliche Darstellungsform der Merit Order entlang der Ordinate um die Abbildung negative Werte erweitert und die Abszisse für die Abbildung negativer Flexibilität in umgekehrter Reihenfolge angeordnet. Das Ergebnis sind zwei zusammenhängende Graphen, mittels derer sich die Bereitstellungskosten verschiedener Flexibilitätsoptionen gegenüberstellen und anschaulich vergleichen lassen.
Durch die Festlegung eines Rahmenszenarios zur Entwicklung des deutschen Stromsystems bis zum Jahr 2030 wird anschließend auch die zukünftige Perspektive der Flexibilitätsbereitstellung in Deutschland analysiert. Aus den Ergebnissen lässt sich ableiten, dass der deutsche Kraftwerkspark mit einem fortschreitenden Rückbau der Kohlekraftwerke nur dann zunehmend flexibler wird und auf höhere Schwankungen im Stromnetz reagieren kann, wenn von einem gleichzeitigen Zubau moderner erdgasbetriebener Kraftwerke ausgegangen wird. In diesem Fall steigen die Bereitstellungskosten positiver Flexibilität, was sich beispielsweise durch zukünftig steigende Brennstoffpreise bergründen lässt. Jedoch kann bspw. durch die Transformation der Kraft-Wärme-Kopplung hin zu einer grundsätzlich stromgeführten Fahrweise zukünftig eine vergleichsweise kostengünstige Flexibilitätsbereitstellung erschlossen und somit auch ein gleichbleibendes oder oftmals sogar höheres Flexibilitätsniveau am Markt erreicht werden.
The growing demand for active medical implantable devices requires data and or power links between the implant and the outside world. Every implant has to be encapsulated from the body by a specific housing and one of the most common materials used is titanium or titanium alloy. Titanium thas the necessary properties in terms of mechanical and chemical stability and biocompatibility. However, its electrical conductivity presents a challenge for the electromagnetic transmission of data and power. The proposed paper presents a fast and practical method to determine the necessary transmission parameters for titanium encapsulated implants. Therefore, the basic transformer-transmission-model is used with measured or calculated key values for the inductances. Those are then expanded with correction factors to determine the behavior with the encapsulation. The correction factors are extracted from finite element method simulations. These also enable the analysis of the magnetic field distribution inside of the housing. The simulated transmission properties are very close to the measured values. Additionally, based on lumped elements and magnetic field distribution, the influential parameters are discussed in the paper. The parameter discussion describes how to enhance the transmitted power, data-rate or distance, or to reduce the size of the necessary coils. Finally, an example application demonstrates the usage of the methods.
Electrolyte-gated transistors (EGTs) represent an interesting alternative to conventional dielectric-gating to reduce the required high supply voltage for printed electronic applications. Here, a type of ink-jet printable ion-gel is introduced and optimized to fabricate a chemically crosslinked ion-gel by self-assembled gelation, without additional crosslinking processes, e.g., UV-curing. For the self-assembled gelation, poly(vinyl alcohol) and poly(ethylene-alt-maleic anhydride) are used as the polymer backbone and chemical crosslinker, respectively, and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]) is utilized as an ionic species to ensure ionic conductivity. The as-synthesized ion-gel exhibits an ionic conductivity of ≈5 mS cm−1 and an effective capacitance of 5.4 µF cm−2 at 1 Hz. The ion-gel is successfully employed in EGTs with an indium oxide (In2O3) channel, which shows on/off-ratios of up to 1.3 × 106 and a subthreshold swing of 80.62 mV dec−1.
In den letzten Jahren sind verstärkt große Batteriespeichersysteme in der Mittel- und Hochspannungsebene in Deutschland installiert worden. Neben dem Einsatz für lokale Anwendungszwecke wie Eigenverbrauchsmaximierung oder Lastspitzenkappung sind seit 2016 etwa 250 MW aus Batteriespeichern für die Teilnahme am Markt für Primärregelleistung (PRL) präqualifiziert worden. Damit können bereits 40 % des aktuellen Bedarfs der deutschen Übertragungsnetzbetreiber (ÜNB) gedeckt werden. Für einen zuverlässigen Betrieb von Batteriespeichern sind intelligente Betriebsstrategien erforderlich, die im Rahmen dieser Analyse vorgestellt werden.
The Humboldt Portal has been designed and implemented as part of an ongoing research project to develop an information system on the Internet to share the documents and rare books of Alexander von Humboldt, a 19th century German scientist and explorer, who viewed the natural world holistically and described the harmony of nature among the diversity of the physical world. Even after more than two centuries he is admired for his ability to see the natural world and human nature in the context of a complex network of relationships. The design and implementation of the Humboldt Portal are also oriented to support further research on Humboldt’s intellectual perspective.
Although all of Humboldt's works can be found on the internet as digitized documents, the complexity and internal inter-connectivity of his vision of nature cannot be adequately represented only by digitized papers or scanned documents in digital libraries.
As a consequence a specific portal of the Humboldt's documents was developed, which extends the standards of digital libraries and offers a technical approach for the adequate presentation of highly interconnected data.
Due to the continuous scientific and literary research, new insights and requirements for the digital presentation of Humboldt documents are constantly emerging, so that this article only provides a summary of the concepts realized at now. Consequently, the design and implementation of the Humboldt Portal is both: a consequence of a continuing research project and oriented to support more research on Humboldt´s intellectual holistic perspective, which was an anticipation to the System Approach of the last Century.
Automatic Identification of Travel Locations in Rare Books - Object Oriented Information Management
(2017)
The digital content of the Internet is growing exponentially and mass digitization of printed media opens access to literature, in particular the genre of travel literature from the 18th and 19th century, which consists of diaries or travel books describing routes, observations or inspirations. The identification of described locations in the digital text is a long-standing challenge which requires information technology to supply dynamic links to sources by new forms of interaction and synthesis between humanistic texts and scientific observations.
Using object oriented information technology, a prototype of a software tool is developed which makes it possible to automatically identify geographic locations and travel routes mentioned in rare books. The information objects contain properties such as names and classification codes for populated places, streams, mountains and regions. Together, with the latitudes and longitudes of every single location, it is possible to geo-reference this information in order that all processed and filtered datasets can be displayed by a map application. This method has already been used in the Humboldt Digital Library to present Alexander von Humboldt’s maps and was tested in a case study to prove the correctness and reliability of the automatic identification of locations based on the work of Alexander von Humboldt and Johann Wolfgang von Goethe.
The results reveal numerous errors due to misspellings, change of location names, equality of terms and location names. But on the other hand it becomes very clear that results of the automatic object detection and recognition can be improved by error-free and comprehensive sources. As a result an increase in quality and usability of the service can be expected, accompanied by more options to detect unknown locations in the descriptions of rare books.