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The effective executing innovation projects requires multiple estimation of market success of new product features in the early stages of customer-centered innovation process such as strategy formulation, evaluation of ideas and concepts and also at a stage close to the market launch. The attempts to integrate customers for estimation of the market success often result in time-consuming customer interviews or lengthy field research. For this reason, industrial companies usually try to skip customer surveys even if they risk that their innovations will fail to bring the anticipated economic outcomes. In many practical cases, the customer surveys are simply not feasible or too expensive. As a result, the internal assessments within companies are frequently the only resource available in innovation process in the industrial environment. The paper discusses the possibilities of the fast identification of promising innovation opportunities and new product features based on the internal competences of companies. It compares the results of customer surveys with the estimation of internal company-experts and analyses the accuracy and validity of the expert assessments. The presented case studies demonstrate the accuracy rate between 43% and 77% for prediction of new product features with high market potential by company-internal experts. The paper proposes the evaluation methods to increase the accuracy rate and outlines that one of the essential requirements for reliable forecasting by the experts is their profound understanding of the customer working process, the ability to estimate the importance of customer needs and to assess the level of customer satisfaction with current products on the market.
The communication between objects, i.e. between cars (car-2-car, C2C), between cars and infrastructure (car-2-infrastructure, C2I) and between cars and vulnerable road users (car-2-VRU, C2VRU) is a major stepping stone towards traffic applications to enable efficient and safe traffic flow. However, these applications pose very high requirements to the communication protocols, which go beyond the capabilities of an available standardized solution.
This contribution shows how iterative design processes can help to fulfill these requirements, while re-using a maximum of elements from one level to the next and thus avoiding unrealistic overhead. In especially, the added value of simulation and emulation in this iterative process is elaborated.
The formation of secondary phases in the porous electrodes is a severe mechanism affecting the lifetime of solid oxide fuel cells (SOFC). It can occur via various chemical mechanisms and it has a significant influence on cell performance due to pore clogging and deactivation of active surfaces and triple-phase boundary (TPB). We present a modeling and simulation study of nickel oxide formation (reoxidation) and carbon formation (coking) within the SOFC anode. We use a 2D continuum model based on a multi-phase framework [Neidhardt et al., J. Electrochem. Soc., 159, 9 (2012)] that allows the introduction of arbitrary solid phases (here: Ni, YSZ, NiO, Carbon) plus gas phase. Reactions between the bulk phases are modeled via interface-adsorbed species and are described by an elementary kinetic approach. Published experimental data are used for parameterization and validation. Simulations allow the prediction of cell performance under critical operation conditions, like (i) a non-fuel operation test, where NiO formation is taking place (Figure 1a), or (ii) an open circuit voltage (OCV) stability test under hydrocarbon atmosphere, where solid carbon is formed (Figure 1b). Results are applied for enhanced interpretation of experimental data and for prediction of safe operation conditions.
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things. It can be observed that most of the available solutions are following an open source approach, which significantly leads to a fast development of technologies and of markets. Although the currently available implementations are in a pretty good shape, all of them come with some significant drawbacks. It was therefore decided to start the development of an own implementation, which takes the advantages from the existing solutions, but tries to avoid the drawbacks. This paper discussed the reasoning behind this decision, describes the implementation and its characteristics, as well as the testing results. The given implementation is available as open-source project under [15].
Non-fluoroscopic Imaging with MRT/CT Image Integration - Catheter Positioning with Double Precision
(2014)
Introduction: When antiarrhythmic drug therapy has failed, different approaches of pulmonary vein isolation are considered a reasonable option in the treatment of atrial fibrillation. It will be performed predominantly by radiofrequency catheter ablation. As the individual anatomy of left atrium and the pulmonary veins differs considerably, accurate visualization of these structures is essential during catheter positioning. Using non-fluoroscopic electroanatomic mapping system with image integration, electroanatomic mapping can be combined with highly detailed anatomical MRT or CT information on complex left atrial structures. This may facilitate catheter navigation during ablation for atrial fibrillation.
Methods: The CARTO XP electroanatomic system was used in a project during biomedical engineering study to practice image integration of anonymized real patients that underwent pulmonary vein isolation by CARTO XP and a MRT/CT procedure. Using the image integration software, MRT or CT images were imported into the CARTO XP system. The next process was segmentation of the acquired images. It involves dividing the images into different regions in order to select the structures of interest. In clinical routine, this segmentation has to be performed before catheter ablation. Then, the segmented images were aligned with the reconstructed electroanatomic maps. This consists of several steps, including selection of the left atrium, scaling of the reconstructed geometry, fusion of the structures using landmarks, and optimization of the integration by adjusting the reconstructed geometry of the left atrium.
Results: In the 3 months lasting period of the project, image integration was trained in 13 patients undergoing catheter ablation for atrial fibrillation. Within this period, time consumption for the process decreased from about 90 minutes at the beginning to about 35 minutes at the end for one patient.
Conclusion: Image integration into non-fluoroscopic electroanatomic map is a sophisticated tool in cardiac radiofrequency catheter ablation. Intensive training is necessary to control the procedure.
Using patent information for identification of new product features with high market potential
(2014)
Recently a P-matrix and COM formalism was presented, which predicts third order intermodulation (IMD3) and triple beat with good accuracy and needs only a single nonlinearity constant. This formalism describes frequency dependence correctly. In this work the dependence of this nonlinearity constant on metalization ratio is investigated for aluminum metalization on LiTaO 3 (YXl)/42°. By comparison to test devices the nonlinearity constant is shown to be largely independent of metalization ratio. The nonlinear effect, however, strongly depends on metalization ratio, which is well described by the model. The linearity of a duplexer is optimized by reduction of metalization ratio and redesign of Tx branch topology.
Pure component sorption isotherms of n-butane, isobutane, 1-butene and isobutene on the metal–organic framework (MOF) 3∞[Cu4(μ4-O)(μ2-OH)2(Me2trz-pba)4] at various temperatures between 283 K and 343 K and pressures up to 300 kPa are presented. The isotherms show a stepwise pore filling which is typical for structurally flexible materials with broad adsorption–desorption hysteresis loops. Gate opening pressures in their endemic characteristic depend on the used hydrocarbon gases. From all investigated gases only the isotherms of 1-butene present a second step at a relative pressure above p/p0 = 0.55. As a consequence, only 1-butene can fully open the framework resulting in a pore volume of 0.54 cm3 g−1. This result is in good agreement with the value of 0.59 cm3 g−1 calculated based on single crystal structure data. The isosteric heat of adsorption was calculated from the experimental isotherms for all C4-isomers. At low loadings the isosteric heat is in a narrow region between 41 and 49 kJ mol−1. Moreover, in situ XRD measurements at different relative hydrocarbon pressures were performed at 298 K for the C4-isomers. The differences in the pressure-depending powder diffraction patterns indicate phase transitions as a result of adsorption. Similar diffraction patterns were observed for all C4-hydrocarbons, except 1-butene, where the second step at higher relative pressure (p/p0 > 0.55) is accompanied by an additional phase transition. This powder pattern resembles that of the as-synthesized MOF material containing solvent molecules in the pore system. The resulting structural changes of the material during guest and pressure induced external stimuli are evidenced by the new coupled XRD adsorption equipment.
A series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. Single crystal X-ray structure determination was successfully performed for all compounds after the phase transition. In the zinc-based coordination polymer, various amounts of a second type of metal ions such as Co(2+) or Fe(2+) could be incorporated. Furthermore, the catalytic behavior of the homo- and heteronuclear 3D coordination polymers in an oxidation model reaction was investigated.
Automatic Meter Reading (AMR) is a major enabler for the upcoming smart grid. Potentially, it will be one of the first really large-scale M2M-communication solutions for sensor applications.
To date, the definition of the standardized communication stacks for Local Metrological Network (LMN) in AMR is still ongoing. This holds true both for ZigBee Smart Energy Profile and for Wireless M-Bus according to EN 13757. During this process, there is the necessity for flexible, albeit optimized solutions, which support the different existing and upcoming versions of the communication protocols. In the case of Wireless M-Bus, the major contender for European and possibly Asian installations, this is valid not only for the different operation modes (C-, N-, P-, Q-, R-, S-, and T-modes), which work in different frequencies (i.e. 868 MHz, 433 MHz, and 169 MHz) but also for the application layer, where additional bodies, like EN137575, Open Metering System (OMS) Group, or national bodies follow their approaches.
This contribution describes requirements, design techniques and experiences from the development of highly efficient Wireless M-Bus protocol stacks with support of good flexibility and portability between microcontroller platforms and RF-transceivers. The presented approach is not limited to the use of modern software engineering design processes, as such, but also includes essential additional features like testing or simulation, as well as tools for commissioning and monitoring.
Ranging errors are inevitable in all local positioning systems, including those based on Time-of-Flight (ToF) technique. Results of experiments show that the major cause for these errors is a signal degradation from multipath propagation. This effect is especially critical in case of Non-Light-of-Sight (NLOS) conditions. This paper describes causes that affects ranging errors for nanoLOC™-TOF-technology and presents estimations for the probability density functions of such errors under different NLOS conditions. The provided estimations allow the improvement of the accuracy of the localization through the subsequent mitigation of the ranging errors from the measurements. Additionally, it is proposed to increase the number of cases of NLOS-conditions for the improvement of the accuracy.
Efficient, low-cost, secure and reliable communication solutions are a major stepping stone for smart metering and smart grid applications. This especially holds true for the so called primary communication or local metrological network (LMN) between a local meter or actuator and a data collector or gateway, where the highest requirements with regard to cost, bandwidth, and energy efficiency have to be taken into consideration. Multiple developments and field tests are going on in this field, however, energy autarkic devices are hardly found, yet.
The communication technologies for automatic me-ter reading (smart metering) and for energy production and distribution networks (smart grid) have the potential to be one of the first really highly scaled machine-to-machine-(M2M)-applications. During the last years two very promising devel-opments around the wireless part of smart grid communication were initialized, which possibly have an impact on the markets far beyond Europe and far beyond energy automation. Besides the specifications of the Open Metering System (OMS) Group, the German Federal Office for Information Security (Bundesamt für Sicherheit in der Informationstechnik, BSI) has designed a protection profile (PP) and a technical directive (TR) for the communication unit of an intelligent measurement sys-tem (smart meter gateway), which were released in March 2013. This design uses state-of-the-art technologies and prescribes their implementation in real-life systems. At first sight the expenditures for the prescribed solutions seem to be significant. But in the long run, this path is inevitable and comes with strategic advantages.
Efficient, low-cost, secure and reliable communication solutions are a major stepping stone for smart metering and smart grid applications. This especially holds true for the so called primary communication or local metrological network (LMN) between a local meter or actuator and a data collector or gateway, where the highest requirements with regard to cost, bandwidth, and energy efficiency have to be taken into consideration. Multiple developments and field tests are going on in this field, however, energy autarkic devices are hardly found, yet. This contribution describes the development of an automatic water meter reading (AWMR) technology based on Wireless M-Bus to provide water utility companies with an automatic remote water meter reading solution. It addresses the special needs of home utilities by providing a remote metering solution independent from the electricity infrastructure, both in terms of data communication and in terms of power supply. For this project, a cost efficient integrated energy harvesting system powered by the available water flow was developed, to enable operation independently of the mains grid, and eliminate the need for battery replacement for near-zero maintenance costs.
The communication technologies for automatic meter reading (smart metering) and for energy production and distribution networks (smart grid) have the potential to be one of the first really highly scaled machine-to-machine-M2M-applications. During the last years, two very promising developments around the wireless part of the smart grid communication were initialized, which possibly could have an impact on the network architectures and the markets far beyond Germany and far beyond energy automation. Besides the specification of the OMS Group of a security extension to the Wireless M-Bus protocol (EN13757-4), the German Federal Office for Information Security (Bundesamt für Sicherheit in der Informationstechnik, BSI) has designed a Protection Profile (PP) and a Technical Directive (TR) for the communication unit of an intelligent measurement system (Smart Meter Gateway), which were released in March 2013. This design uses state of the art technologies and prescribes their implementation in real-life systems. At first, the proposed paper will present the most important characteristics of this architecture. It will then give an insight into the implementation of the OMS security protocols, which imply the usage of a mutually authenticated SSL protocol also in the Local Metrological Network. This is achieved with the help of an additional Authentication and Fragmentation Layer (AFL). This secure communication will be terminated in a BSI conformant secure smart meter gateway, which is developed in a different project and described in the second step. Finally, the contribution will discuss the integration of such a metering network into an overall telecommunication network and PKI infrastructure.
A Localization System Using Inertial Measurement Units from Wireless Commercial Handheld Devices
(2013)
This paper describes a newly developed technology for the calculation of trajectories of mobile objects, which is based on commercially available sensors being integrated into modern mobile phones and other gadgets. First, a step counting technique was implemented. Second, a novel step length estimator is proposed. These two algorithms utilize the data from accelerometer sensor only. Third, the heading information was obtained using a gyroscope with complementary filter in quaternion form. The combined algorithm was implemented on a low-power ARM processor to provide the trajectory points relative to an initial point. The proposed technique was tested by 10 subjects, in different shoes with different paces. The dependence of the performance of the technology on the attaching point of the mobile device is weak. The proposed algorithms have better balance and estimation accuracy and depend in less degree on the variety in physical parameters of people in comparison with the existing techniques. In experiments inertial measurement units were mounted in different places, i.e. in the hand, in trousers or in T-shirt pockets. The return position error did not exceed 5% of the total travelled distance for all performed tests.
A highly scalable IEEE802.11p communication and localization subsystem for autonomous urban driving
(2013)
The IEEE802.11p standard describes a protocol for car-to-X and mainly for car-to-car-communication. It has found its place in hardware and firmware implementations and is currently tested in various field tests. In the research project Ko-TAG, which is part of the research initiative Ko-FAS, cooperative sensor technology is developed for the support of highly autonomous driving. A secondary radar principle based on communication signals enables localization of objects with simultaneous data transmission. It mainly concentrates on the detection of pedestrians and other vulnerable road users (VRU), but also supports pre crash safety applications. Thus it is mainly targeted for the support of traffic safety applications in intra-urban scenarios. This contribution describes the Ko-TAG part of the overall initiative, which develops a subsystem to improve the real-time characteristics of IEEE802.11p needed for precise time of flight real-time localization. In doing this, it still fits into the regulatory schemes. It discusses the approach for definition and verification of the protocol design, while maintaining the close coexistence with existing IEEE802.11p subsystems. System simulations were performed and hardware was implemented. Test results are shown in the last part of the paper.
Multi-agent systems are a subject of continuously increasing interest in applied technical sciences. Smart grids are one evolving field of application. Numerous smart grid projects with various interpretations of multi-agent systems as new control concept arose in the last decade. Although several theoretical definitions of the term ‘agent’ exist, there is a lack of practical understanding that might be improved by clearly distinguishing the agent technologies from other state-of-the-art control technologies. In this paper we clarify the differences between controllers, optimizers, learning systems, and agents. Further, we review most recent smart grid projects, and contrast their interpretations with our understanding of agents and multi-agent systems. We point out that multi-agent systems applied in the smart grid can add value when they are understood as fully distributed networks of control entities embedded in dynamic grid environments; able to operate in a cooperative manner and to automatically (re-)configure themselves.
The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
Components of rocket engines as actively cooled combustion chambers must withstand high pressure as well as severe and complex thermal transients. While the thermal transients result in temperature gradients and, thus, in constraint thermal strains, the pressure load induces mean stresses. To assess the mechanical behaviour of such components during design via finite-element calculations, constitutive models are necessary that describe the time- and temperature-dependent plasticity of the material appropriately.
Advanced models account for viscoplastic deformations including isotropic and kinematic hardening, recovery and ratcheting. However, the models contain a relatively large number of temperature-dependent material properties that must be determined on the basis of data of material tests. The determination of the properties is a non-trivial task because it is not clear which loading history must be applied in the tests for a certain material to obtain stable and robust (i.e. objective) material properties. Consequently, the determined properties are depending on the underlying loading history in the tests as well as on the experience and valuation of the person that determined the properties. This results in uncertainties during the assessment of the components that must be faced with conservative designs leading to negative consequences in terms of mass and costs.
It is the aim of this work funded by the European Space Agency ESA to derive a procedure to determine stable and robust material properties of an advanced viscoplastic constitutive model for aerospace materials. To this end, a special loading history is applied in isothermal material tests conducted with copper at different temperatures in the temperature range from 300 to 700 K. To determine the material properties and to assess stability and robustness methods for numerical optimization as well as analytical and statistical methods are used. The determined material properties are validated on the basis of results of thermomechanical material tests also conducted in the temperature range from 300 to 700 K.
Lithium–sulfur (Li/S) cells are promising candidates for a next generation of safe and cost-effective high energy density batteries for mobile and stationary applications. At present, most Li/S cells still suffer from relatively poor cyclability, capacity loss under moderate current densities and self-discharge. Furthermore, the underlying chemical mechanisms of the general discharge/charge behavior as well as Li/S-specific phenomena like the polysulfide shuttle are not yet fully understood. Here we present a thermodynamically consistent, fully reversible continuum model of a Li/S cell with simplified four-step electrochemistry, including a simple description of the polysulfide shuttle effect. The model is parameterized using experimental discharge curves obtained from literature and reproduces behavior at various current densities with fairly high accuracy. While being instructively simple, the presented model can still reproduce distinct macroscopic Li/S-cell features caused by the shuttle effect, e.g., seemingly infinite charging at low charge current densities, and suboptimal coulombic efficiency. The irreversible transport of active material from the cathode to the anode results in a voltage drop and capacity loss during cycling, which can also be observed experimentally.
The characteristic features and applications of linear and nonlinear guided elastic waves propagating along surfaces (2D) and wedges (1D) are discussed. Laser-based excitation, detection, or contact-free analysis of these guided waves with pump–probe methods are reviewed. Determination of material parameters by broadband surface acoustic waves (SAWs) and other applications in nondestructive evaluation (NDE) are considered. The realization of nonlinear SAWs in the form of solitary waves and as shock waves, used for the determination of the fracture strength, is described. The unique properties of dispersion-free wedge waves (WWs) propagating along homogeneous wedges and of dispersive wedge waves observed in the presence of wedge modifications such as tip truncation or coatings are outlined. Theoretical and experimental results on nonlinear wedge waves in isotropic and anisotropic solids are presented.
Cardiac resynchronization therapy is an established therapy for heart failure patients with sinus rhythm, reduced left ventricular ejection fraction and prolongation of QRS duration. The aim of the study was to evaluate ventricular desynchronization with electrical interventricular delay (IVD) to left ventricular delay (LVD) ratio in atrial fibrillation heart failure patients. IVD and LVD were measured by transesophageal posterior left ventricular ECG recording. In atrial fibrillation heart failure patients with prolonged QRS duration, the mean IVD-to-LVD-ratio was 0.84 +/- 0.42 with a range from 0.17 to 2.2 IVD-to-LVD-ratio. IVD-to-LVD-ratio correlated with QRS duration. IVD-to-LVD-ratio may be a useful parameter to evaluate electrical ventricular desynchronization in atrial fibrillation heart failure patients.
Cardiac resynchronization therapy with atrioventricular and interventricular pacing delay optimized biventricular pacing is an established therapy for heart failure patients with sinus rhythm and reduced left ventricular ejection fraction. The aim of the study was to evaluate atrioventricular and interventricular pacing delay optimization in cardiac resynchroniza-tion therapy by transthoracic impedance cardiography in biventricular pacing with different left ventricular electrode po-sition. In biventricular pacing heart failure patients with lateral, posterolateral and anterolateral left ventricular electrode position, the mean optimal atrioventricular sening delay was 108.6 ± 20.3 ms and the mean optimal interventricular pac-ing delay -12.3 ± 25.9 ms. Transthoracic impedance cardiography may be a useful technique to optimize atrioventricular and interventricular pacing delay in biventricular pacing with different left ventricular electrode position.
Phosphate-based inorganic–organic hybrid nanoparticles (IOH-NPs) with the general composition [M]2+[Rfunction(O)PO3]2– (M = ZrO, Mg2O; R = functional organic group) show multipurpose and multifunctional properties. If [Rfunction(O)PO3]2– is a fluorescent dye anion ([RdyeOPO3]2–), the IOH-NPs show blue, green, red, and near-infrared fluorescence. This is shown for [ZrO]2+[PUP]2–, [ZrO]2+[MFP]2–, [ZrO]2+[RRP]2–, and [ZrO]2+[DUT]2– (PUP = phenylumbelliferon phosphate, MFP = methylfluorescein phosphate, RRP = resorufin phosphate, DUT = Dyomics-647 uridine triphosphate). With pharmaceutical agents as functional anions ([RdrugOPO3]2–), drug transport and release of anti-inflammatory ([ZrO]2+[BMP]2–) and antitumor agents ([ZrO]2+[FdUMP]2–) with an up to 80% load of active drug is possible (BMP = betamethason phosphate, FdUMP = 5′-fluoro-2′-deoxyuridine 5′-monophosphate). A combination of fluorescent dye and drug anions is possible as well and shown for [ZrO]2+[BMP]2–0.996[DUT]2–0.004. Merging of functional anions, in general, results in [ZrO]2+([RdrugOPO3]1–x[RdyeOPO3]x)2– nanoparticles and is highly relevant for theranostics. Amine-based functional anions in [MgO]2+[RaminePO3]2– IOH-NPs, finally, show CO2 sorption (up to 180 mg g–1) and can be used for CO2/N2 separation (selectivity up to α = 23). This includes aminomethyl phosphonate [AMP]2–, 1-aminoethyl phosphonate [1AEP]2–, 2-aminoethyl phosphonate [2AEP]2–, aminopropyl phosphonate [APP]2–, and aminobutyl phosphonate [ABP]2–. All [M]2+[Rfunction(O)PO3]2– IOH-NPs are prepared via noncomplex synthesis in water, which facilitates practical handling and which is optimal for biomedical application. In sum, all IOH-NPs have very similar chemical compositions but can address a variety of different functions, including fluorescence, drug delivery, and CO2 sorption.
Cardiac resynchronization therapy with atrioventricular and interventricular delay optimized biventricular pacing is an established therapy for symptomatic heart failure patients with prolongation of QRS duration, left bundle branch block and reduced left ventricular ejection fraction. The aim of the investigation was to evaluate right atrial, right ventricular and left ventricular electrical signals of implantable electronic cardiac devices with and without signal averaging technique with novel LabVIEW software. Electrical interatrial conduction delay and inter-ventricular conduction delay may be useful parameters to evaluate electrical atrial and ventricular desynchronization in heart failure patients.
Decrease of non-responder rate is the main chal-lenge in cardiac resynchronization therapy. The problem could be solved, partly, in the follow-up by consequent indi-vidualization of hemodynamic pacing parameters. The eso-phageal electrogram feature of the Biotronik ICS 3000 programmer was used in the follow-up of 20 heart failure patients carrying implants for cardiac resynchronization therapy. Adverse hemodynamic programming of the sensed and paced AV delay could be easily observed and replaced by the individual optimal duration in 3 patients (15%) VDD and DDD operation.This result proves the value of esophageal electrogram recording CRT follow-up.
Distribution of esophageal interventricular conduction delays in CRT patients and healthy subjects
(2015)
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things (IoT). Whereas the lower layers (IEEE802.15.4 and 6LoWPAN) are already well defined and consolidated with regard to frame formats, header compression, routing protocols and commissioning procedures, there is still an abundant choice of possibilities on the application layer. Currently, various groups are working towards standardization of the application layer, i.e. the ETSI Technical Committee on M2M, the IP for Smart Objects (IPSO) Alliance, Lightweight M2M (LWM2M) protocol of the Open Mobile Alliance (OMA), and OneM2M. This multitude of approaches leaves the system developer with the agony of choice. This paper selects, presents and explains one of the promising solutions, discusses its strengths and weaknesses, and demonstrates its implementation.
This paper presents a practice and science orientated education approach for freshman students of interdisciplinary bachelor engineering degree programs. This approach is meant to enhance the motivation and success of freshman students during their whole study. The education approach is called Fit4PracSis (Fit for Practice and Sciences) It was started to develop, set up and establish an education approach, which is building a relationship to students' future profession and to scientific working during the introductory study phase. The freshman students will be trained early in important skills, which are necessary for achieving the final degree successfully and handling of future business and research activities.
In this paper we present a model of the discharge of a lithium–oxygen battery with aqueous electrolyte. Lithium–oxygen batteries (Li–O2) have recently received great attention due to their large theoretical specific energy. Advantages of the aqueous design include the stability of the electrolyte, the long experience with gas diffusion electrodes (GDEs), and the solubility of the reaction product lithium hydroxide. However, competitive specific energies can only be obtained if the product is allowed to precipitate. Here we present a dynamic one-dimensional model of a Li–O2 battery including a GDE and precipitation of lithium hydroxide. The model is parameterized using experimental data from the literature. We demonstrate that GDEs remove power limitations due to slow oxygen transport in solutions and that lithium hydroxide tends to precipitate on the anode side. We discuss the system architecture to engineer where nucleation and growth predominantly occurs and to optimize for discharge capacity.
Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter, we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium–oxygen batteries with organic electrolytes, based on a theory of electrochemical nonequilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.
In the dual membrane fuel cell (DM-Cell), protons formed at the anode and oxygen ions formed at the cathode migrate through their respective dense electrolytes to react and form water in a porous composite layer called dual membrane (DM). The DM-Cell concept was experimentally proven (as detailed in Part I of this paper). To describe the electrochemical processes occurring in this novel fuel cell, a mathematical model has been developed which focuses on the DM as the characteristic feature of the DM-Cell. In the model, the porous composite DM is treated as a continuum medium characterized by effective macro-homogeneous properties. To simulate the polarization behavior of the DM-Cell, the potential distribution in the DM is related to the flux of protons and oxygen ions in the conducting phases by introducing kinetic and transport equations into charge balances. Since water pressure may affect the overall formation rate, water mass balances across the DM and transport equations are also considered. The satisfactory comparison with available experimental results suggests that the model provides sound indications on the effects of key design parameters and operating conditions on cell behavior and performance.
Adsorption of N2 and CO2 on Activated Carbon, AlO(OH) Nanoparticles, and AlO(OH) Hollow Spheres
(2015)
Adsorption behaviors of nitrogen and CO2 on Norit R1 Extra and AlO(OH) nanoparticles and hollow spheres were measured under different temperature and pressure conditions using a magnetic suspension balance. Independent from the substrate investigated, all isotherms increase at lower pressure, reach a maximum, and then decrease with increasing pressure. In addition, selected experimental data were correlated with different model approaches and compared with reliable literature data. In case of CO2 on AlO(OH), capillary condensation was observed at two defined temperatures. The results suggest that the conversion of the liquid into a supercritical adsorbate phase does not take place suddenly.