Refine
Year of publication
Document Type
- Article (reviewed) (104)
- Conference Proceeding (93)
- Bachelor Thesis (66)
- Part of a Book (27)
- Article (unreviewed) (25)
- Master's Thesis (18)
- Book (9)
- Contribution to a Periodical (7)
- Report (4)
- Other (1)
Conference Type
- Konferenzartikel (78)
- Konferenz-Abstract (6)
- Sonstiges (4)
- Konferenz-Poster (3)
- Konferenzband (2)
Keywords
- Dünnschichtchromatographie (19)
- Adsorption (8)
- Metallorganisches Netzwerk (7)
- Biomechanik (6)
- Haustechnik (6)
- Leichtbau (6)
- Plastizität (6)
- Finite-Elemente-Methode (5)
- Materialermüdung (5)
- Regelungstechnik (5)
Institute
- Fakultät Maschinenbau und Verfahrenstechnik (M+V) (354) (remove)
Open Access
- Closed Access (354) (remove)
In the course of the last few years, our students are becoming increasingly unhappy. Sometimes they stop attending lectures and even seem not to know how to behave correctly. It feels like they are getting on strike. Consequently, drop-out rates are sky-rocketing. The lecturers/professors are not happy either, adopting an “I-don’t-care” attitude.
An interdisciplinary, international team set in to find out: (1) What are the students unhappy about? Why is it becoming so difficult for them to cope? (2) What does the “I-don’t-care” attitude of professors actually mean? What do they care or not care about? (3) How far do the views of the parties correlate? Could some kind of mutual understanding be achieved?
The findings indicate that, at least at our universities, there is rather a long way to go from “Engineering versus Pedagogy” to “Engineering Pedagogy”.
Technologie spielt im Sport schon immer eine große Rolle. Mit steigender Leistungsdichte im Spitzensport wird versucht mithilfe technischer Hilfsmittel dem Sportler die optimalen Umstände zu ermöglichen. Dazu gehört nicht nur Technik im Sportequiptment, sondern auch Sportuntersuchungen wie Leistungsdiagnostiken. Im Laufsport zählen dazu Ausdauer- und Krafttests. Bei Ausdauertests werden physiologische Parameter wie Laktat, Herzfrequenz oder Sauerstoffaufnahme gemessen. Zusätzlich wird die Lauftechnik für einen kurzen Zeitpunkt analysiert. Wie sich diese unter anhaltender Belastung verhält, wird nicht untersucht. Mit neuen Technologien im Bereich Bewegungsanalyse, können immer schneller größere Datensätze ausgewertet werden. Aus diesem Grund wird in dieser Studie die Lauftechnik über mehrere Zeitpunkte aufgezeichnet und nach Ermüdungserscheinungen untersucht.
Dazu wurde am Institut für angewandte Trainingswissenschaften (IAT) während einer komplexen Leistungsdiagnostik im März 2021 bei einem Laufbandstufentest (4x2000m oder 4x3000m) die Lauftechnik von 15 Elite- und Elitenachwuchsläufer:innen (m=8, w=7) mithilfe eines 3D-Bewegungsanalyse Systems nach Veränderungen in Winkelstellung und Bodenreaktionskraft untersucht. Als physiologische Vergleichsparameter wurde Herzfrequenz und Laktat aufgenommen.
Bei der Analyse der Daten wurden diese in der Gruppe betrachtet. Dabei haben sich schwach signifikante Veränderungen (p=0,047) der vertikalen Bodenreaktionskraft links am Ende der Stufe aufgezeigt. Weitere signifikante Unterschiede (p=0,020) sind im maximalen Kniehub links zu einem größerer Hüftwinkel am Ende sichtbar. Da sonst keine signifikanten Unterschiede zu sehen sind, lässt sich, bei dem hier durchgeführten Protokoll, nicht statistisch gesichert feststellen, ob auftretende Ermüdungserscheinungen die Lauftechnik beeinflussen und verändern. Um festzustellen, ob es geschlechts- oder protokollanhängige Effekte hinsichtlich einer ermüdungsbedingte Lauftechnikveränderung gibt, wurde auch dies statistisch untersucht.
Hier zeigten sich jeweils in einzelnen Parametern signifikante Unterschiede (Parameter TO\_knee\_left; p=0,026) in der Geschlechtsspezifik und in der protokollabhängigen Untersuchung (Parameter TSw\_hip\_left; p=0,04)
Für weitere Studien zur Untersuchung von Lauftechnikveränderung sollten umfangreichere physiologische Daten zur genaueren Betrachtung der Ermüdung verwendet werden. Grundsätzlich müsste das Protokoll auf eine maximale Ausbelastung (beispielsweise Dauerstufentest von 10-15km oder Ausbelastungs-/Abbruchtest) ausgelegt sein.
Grundlegend ist festzustellen, dass sich Simi-Shape als 3D-Bewegungsanalyse-Methode eignet, um spezifische Parameter in der Lauftechnik zu diagnostizieren, gerade hinsichtlich der Effizienz im Auswerteprozess.
The aim of this study was to develop a biomechanically validated finite element model to predict the biomechanical behaviour of the human lumbar spine in compression.
For validation of the finite element model, an in vitro study was performed: Twelve human lumbar cadaveric spinal segments (six segments L2/3 and six segments L4/5) were loaded in axial compression using 600 N in the intact state and following surgical treatment using two different internal stabilisation devices. Range of motion was measured and used to calculate stiffness.
A finite element model of a human spinal segment L3/4 was loaded with the same force in intact and surgically altered state, corresponding to the situation of biomechanical in vitro study.
The results of the cadaver biomechanical and finite element analysis were compared. As they were close together, the finite element model was used to predict: (1) load-sharing within human lumbar spine in compression, (2) load-sharing within osteoporotic human lumbar spine in compression and (3) the stabilising potential of the different spinal implants with respect to bone mineral density.
A finite element model as described here may be used to predict the biomechanical behaviour of the spine. Moreover, the influence of different spinal stabilisation systems may be predicted.
High temperature components in internal combustion engines and exhaust systems must withstand severe mechanical and thermal cyclic loads throughout their lifetime. The combination of thermal transients and mechanical load cycling results in a complex evolution of damage, leading to thermomechanical fatigue (TMF) of the material. Analytical tools are increasingly employed by designers and engineers for component durability assessment well before any hardware testing. The DTMF model for TMF life prediction, which assumes that micro-crack growth is the dominant damage mechanism, is capable of providing reliable predictions for a wide range of high-temperature components and materials in internal combustion engines. Thus far, the DTMF model has employed a local approach where surface stresses, strains, and temperatures are used to compute damage for estimating the number of cycles for a small initial defect or micro-crack to reach a critical length. In the presence of significant gradients of stresses, strains, and temperatures, the use of surface field values could lead to very conservative estimates of TMF life when compared with reported lives from hardware testing. As an approximation of gradient effects, a non-local approach of the DTMF model is applied. This approach considers through-thickness fields where the micro-crack growth law is integrated through the thickness considering these variable fields. With the help of software tools, this method is automated and applied to components with complex geometries and fields. It is shown, for the TMF life prediction of a turbocharger housing, that the gradient correction using the non-local approach leads to more realistic life predictions and can distinguish between surface cracks that may arrest or propagate through the thickness and lead to component failure.
Quantifying the midsole material characteristics of athletic footwear is a standard task in footwear research and development. Current material testing protocols primarily focus on the determination of cushioning properties of the heel region or the quantification of the midsole properties as one assembly. However, midsoles possess different spatial material properties that have not been quantified from previous methodologies. Therefore, new material testing methods are required to quantify the local material response of athletic footwear. We developed a cyclical force-controlled material testing protocol for the determination of non-homogeneously distributed material stiffness with a high spatial resolution. In five prototype shoes varying in their stiffness distribution, we found that the material properties can be reliably measured across the midsole. Furthermore, we observed a characteristic non-linear material response regardless of the midsole location. We found that the material stiffness increased with an increase of the applied force and that this effect is further intensified by higher testing cycles. Additionally, the obtained midsole stiffness depends on the geometry of the midsole. We explored different approaches to reduce the measurement time of the testing protocol and found that the number of measurements can be reduced by 70% using 2 D-interpolation procedures. Determining the spatial material properties of midsoles needs to be considered to understand foot-shoe interactions. Furthermore, this measurement protocol can be used for quality control within the footwear and can be adapted for considering the effects of different running styles or speeds on ground force application characteristics.
Uptakes of 9.2 mmol g−1 (40.5 wt %) for CO2 at 273 K/0.1 MPa and 15.23 mmol g−1 (3.07 wt %) for H2 at 77 K/0.1 MPa are among the highest reported for metal–organic frameworks (MOFs) and are found for a novel, highly microporous copper‐based MOF (see picture; Cu turquoise, O red, N blue). Thermal analyses show a stability of the flexible framework up to 250 °C.
Metal–organic frameworks (MOFs) as highly porous materials have gained increasing interest because of their distinct adsorption properties.1–3 They exhibit a high potential for applications in gas separation and storage,4 as sensors5 as well as in heterogeneous catalysis.6 In the last few years, the H2 storage capacity of MOFs has been considerably increased. Mesoporous MOFs show high adsorption capacities for CH4, CO2, and H2 at high pressures.2, 3, 7–10 To increase the uptake of H2 and CO2 by physisorption at ambient pressure, adsorbents with small micropores as well as high specific surface areas and micropore volumes are required.11, 12 Such microporous materials seem to be more appropriate for gas‐mixture separation by physisorption than mesoporous materials. For gas separation in MOFs the interactions between the fluid adsorptive and “open metal sites” (coordinatively unsaturated binding sites) or the ligands are regarded as important.13 Industrial processes, such as natural‐gas purification or biogas upgrading, can be improved with those materials during a vapor‐pressure swing adsorption cycle (VPSA cycle) or a temperature swing adsorption cycle (TSA cycle).14 The microporous MOF series CPO‐27‐M (M=Mg, Co, Ni, Zn), for example, shows very high CO2 uptakes at low pressures (<0.1 MPa).15, 16 Concerning H2 adsorption, the microporous MOF PCN‐12 offers with 3.05 wt % the highest uptake at ambient pressure and 77 K reported to date.17
Herein, we present a novel microporous copper‐based MOF equation image[Cu(Me‐4py‐trz‐ia)] (1; Me‐4py‐trz‐ia2−=5‐(3‐methyl‐5‐(pyridin‐4‐yl)‐4H‐1,2,4‐triazol‐4‐yl)isophthalate) with extraordinarily high CO2 and H2 uptakes at ambient pressure, the H2 uptake being similar to that in PCN‐12. The ligand Me‐4py‐trz‐ia2−, which can be obtained from cheap starting materials by a three‐step synthesis in good yield, combines carboxylate, triazole, and pyridine functions and is adopted from a recently presented series of linkers,18 for which up to now only a few coordination polymers are known.
The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
An algorithm is presented that has successfully been utilized in practice for several years. It improves data analysis in chromatography. The program runs in an extremely reliable way and evaluates chromatographic raw data with an acceptable error. The algorithm requires a minimum of preliminaries and integrates even unsmoothed noisy data correctly.
We report improved separation of the highly toxic contact herbicides paraquat, diquat, difenzoquat, mepiquat, and chloromequat by HPTLC. Quantification was based on a new derivatization reaction using sodium tetraphenylborate. Measurements were in the wavelength range from 440 to 480 nm or from 440 to 590 nm. An LED emitting very intense light at 365 nm was used for excitation. The quantification limits of paraquat and diquat in water, using improved solid-phase extraction, was in the low ng L −1 range. The linear range covered more than two orders of magnitude. Recovery was investigated for all the compounds, and was insufficient, ranging from 11 to 92%, but the method is inexpensive, rapid, and works reliably.
Synthesis and crystal structure of a novel copper-based MOF material are presented. The tetragonal crystal structure of [ ∞ 3 ( Cu 4 ( μ 4 -O ) ( μ 2 -OH ) 2 ( Me 2 trz p ba ) 4 ] possesses a calculated solvent-accessible pore volume of 57%. Besides the preparation of single crystals, synthesis routes to microcrystalline materials are reported. While PXRD measurements ensure the phase purity of the as-synthesized material, TD-PXRD measurements and coupled DTA–TG–MS analysis confirm the stability of the network up to 230 °C. The pore volume of the microcrystalline material determined by nitrogen adsorption at 77 K depends on the synthetic conditions applied. After synthesis in DMF/H2O/MeOH the pores are blocked for nitrogen, whereas they are accessible for nitrogen after synthesis in H2O/EtOH and subsequent MeOH Soxhleth extraction. The corresponding experimental pore volume was determined by nitrogen adsorption to be V Pore = 0.58 cm 3 g - 1 . In order to characterize the new material and to show its adsorption potential, comprehensive adsorption studies with different adsorptives such as nitrogen, argon, carbon dioxide, methanol and methane at different temperatures were carried out. Unusual adsorption–desorption isotherms with one or two hysteresis loops are found – a remarkable feature of the new flexible MOF material.
There are additional long-term effects which also change the micro-structure of the polymer network and consequently the effective number of polymer chains in the material. These effects are summarized by ageing processes and will be used in the following to explain the basic assumptions of the model which can be generalized to simulate the viscous behaviour of the material. An implementation of these concepts into FEM codes is straightforward and has been carried out to the solver ABAQUS, Baaser & Ziegler (2006), Baaser et al. (2009).
The formation and analysis of ten microporous triazolyl isophthalate based MOFs, including nine isomorphous and one isostructural compound is presented. The compounds 1 M – 3 M with the general formula [ M ( R 1 - R 2 - trz - ia ) ] ∞ 3 ·x H 2 O (M 2+ = Co 2+ , Cu 2+ , Zn 2+ , Cd 2+ ; R 1 = H, Me; R 2 = 2py, 2pym, prz (2py = 2-pyridinyle; 2pym = 2-pyrimidinyle; prz = pyrazinyle)) crystallize with rtl topology. They are available as single crystals and also easily accessible in a multi-gram scale via refluxing the metal salts and the protonated ligands in a solvent. Their isomorphous structures facilitate the synthesis of heteronuclear MOFs; in case of 2 M , Co 2+ ions could be gradually substituted by Cu 2+ ions. The Co 2+ :Cu 2+ ratios were determined by ICP-OES spectroscopy, the distribution of Co 2+ and Cu 2+ in the crystalline samples are investigated by SEM-EDX analysis leading to the conclusions that Cu 2+ is more favorably incorporated into the framework compared to Co 2+ and, moreover, that the distribution of the two metal ions between the crystals and within the crystals is inhomogeneous if the crystals were grown slowly. The various compositions of the heteronuclear materials lead to different colors and the sorption properties for CO 2 and N 2 are dependent on the integrated metal ions.
A Simple and Reliable HPTLC Method for the Quantification of the Intense Sweetener Sucralose®
(2003)
This paper describes a simple and fast thin layer chromatography (TLC) method for the monitoring of the relatively new intense sweetener Sucralose® in various food matrices. The method requires little or no sample preparation to isolate or concentrate the analyte. The Sucralose® extract is separated on amino‐TLC‐plates, and the analyte is derivatized “reagent‐free” by heating the developed plate for 20 min at 190°C. Spots can be measured either in the absorption or fluorescence mode. The method allows the determination of Sucralose® at the levels of interest regarding foreseen European legislation (>50 mg/kg) with excellent repeatability (RSD = 3.4%) and recovery data (95%).
We present an improved quantification method for urethane found in spirits. The quantification is based on a derivatization reaction using cinnamaldehyde in combination with phosphoric acid. Measurements were carried out in the wavelength range from 445 to 460 nm using a diode-TLC device. An LED was used for illumination purposes. It emits very dense light at 365 nm. The quantification range of urethane is in the lower ng range. By applying 20 µL of sprits, the urethane quantification range is from 320 µg/L to 8.1 mg urethane per litre of spirit. The range of linearity covers nearly two magnitudes. The method is cheap, fast and reliable, and is able to monitor all European legislation limits without time-consuming sample pre-treatments.
Hot work tools are subjected to complex thermal and mechanical loads during hot forming processes. Locally, the stresses can exceed the material’s yield strength in highly loaded areas as e.g. in small radii in die cavities. To sustain the high loads, the hot forming tools are typically made of martensitic hot work steels. While temperatures for annealing of the tool steels usually lie in the range between 400 and 600 °C, the steels may experience even higher temperatures during hot forming, resulting in softening of the material due to coarsening of strengthening particles. In this paper, a temperature dependent cyclic plasticity model for the martensitic hot work tool steel 1.2367 (X38CrMoV5-3) is presented that includes softening due to particle coarsening and that can be applied in finite-element calculations to assess the effect of softening on the thermomechanical fatigue life of hot work tools. To this end, a kinetic model for the evolution of the mean size of secondary carbides based on Ostwald ripening is coupled with a cyclic plasticity model with kinematic hardening. Mechanism-based relations are developed to describe the dependency of the mechanical properties on carbide size and temperature. The material properties of the mechanical and kinetic model are determined on the basis of tempering hardness curves as well as monotonic and cyclic tests.
The DMFC is a promising option for backup power systems and for the power supply of portable devices. However, from the modeling point of view liquid-feed DMFC are challenging systems due to the complex electrochemistry, the inherent two-phase transport and the effect of methanol crossover. In this paper we present a physical 1D cell model to describe the relevant processes for DMFC performance ranging from electrochemistry on the surface of the catalyst up to transport on the cell level. A two-phase flow model is implemented describing the transport in gas diffusion layer and catalyst layer at the anode side. Electrochemistry is described by elementary steps for the reactions occurring at anode and cathode, including adsorbed intermediate species on the platinum and ruthenium surfaces. Furthermore, a detailed membrane model including methanol crossover is employed. The model is validated using polarization curves, methanol crossover measurements and impedance spectra. It permits to analyze both steady-state and transient behavior with a high level of predictive capabilities. Steady-state simulations are used to investigate the open circuit voltage as well as the overpotentials of anode, cathode and electrolyte. Finally, the transient behavior after current interruption is studied in detail.
We present a videodensitometric quantification method for methadone in syrup, separated by thin-layer chromatography (TLC). The quantification is based on a derivation reaction with Dragendorf reagent. Measurements were carried out using a 16-bit flatbed scanner. The range of linearity covers two magnitudes of power using the Kubelka-Munk expression for data transformation. The separation method is inexpensive, fast, and reliable.
There is a growing trend for the use of thermo-active building systems (TABS) for the heating and cooling of buildings, because these systems are known to be very economical and efficient. However, their control is complicated due to the large thermal inertia, and their parameterization is time-consuming. With conventional TABS-control strategies, the required thermal comfort in buildings can often not be maintained, particularly if the internal heat sources are suddenly changed. This paper shows measurement results and evaluations of the operation of a novel adaptive and predictive calculation method, based on a multiple linear regression (AMLR) for the control of TABS. The measurement results are compared with the standard TABS strategy. The results show that the electrical pump energy could be reduced by more than 86%. Including the weather adjustment, it could be demonstrated that thermal energy savings of over 41% could be reached. In addition, the thermal comfort could be improved due to the possibility to specify mean room set-point temperatures. With the AMLR, comfort category I of the comfort norms ISO 7730 and DIN EN 15251 are observed in about 95% of occasions. With the standard TABS strategy, only about 24% are within category I.
Adaptive predictive control of thermo-active building systems (TABS) based on a multiple regression algorithm: First practical test. Available from: https://www.researchgate.net/publication/305903009_Adaptive_predictive_control_of_thermo-active_building_systems_TABS_based_on_a_multiple_regression_algorithm_First_practical_test [accessed Jul 7, 2017].
Additive manufacturing is a rapidly growing manufacturing process for which many new processes and materials are currently being developed. The biggest advantage is that almost any shape can be produced, while conventional manufacturing methods reach their limits. Furthermore, a lot of material is saved because the part is created in layers and only as much material is used as necessary. In contrast, in the case of machining processes, it is not uncommon for more than half of the material to be removed and disposed of. Recently, new additive manufacturing processes have been on the market that enables the manufacturing of components using the FDM process with fiber reinforcement. This opens up new possibilities for optimizing components in terms of their strength and at the same time increasing sustainability by reducing materials consumption and waste. Within the scope of this work, different types of test specimens are to be designed, manufactured and examined. The test specimens are tensile specimens, which are used both for standardized tensile tests and for examining a practical component from automotive engineering used in student project. This project is a vehicle designed to compete in the Shell Eco-marathon, one of the world’s largest energy efficiency competitions. The aim is to design a vehicle that covers a certain distance with as little fuel as possible. Accordingly, it is desirable to manufacture the components with the lowest possible weight, while still ensuring the required rigidity. To achieve this, the use of fiber-reinforced 3D-printed parts is particularly suitable due to the high rigidity. In particular, the joining technology for connecting conventionally and additively manufactured components is developed. As a result, the economic efficiency was assessed, and guidelines for the design of components and joining elements were created. In addition, it could be shown that the additive manufacturing of the component could be implemented faster and more sustainably than the previous conventional manufacturing.
Adsorption of N2 and CO2 on Activated Carbon, AlO(OH) Nanoparticles, and AlO(OH) Hollow Spheres
(2015)
Adsorption behaviors of nitrogen and CO2 on Norit R1 Extra and AlO(OH) nanoparticles and hollow spheres were measured under different temperature and pressure conditions using a magnetic suspension balance. Independent from the substrate investigated, all isotherms increase at lower pressure, reach a maximum, and then decrease with increasing pressure. In addition, selected experimental data were correlated with different model approaches and compared with reliable literature data. In case of CO2 on AlO(OH), capillary condensation was observed at two defined temperatures. The results suggest that the conversion of the liquid into a supercritical adsorbate phase does not take place suddenly.
Eine neue Prozessidee zur Auftrennung racemischer Wirkstoffe unter Verwendung nanoskaliger AlO(OH)‐Hohlkugeln als Adsorbens und überkritischen Kohlenstoffdioxides (sc‐CO2) als Lösungsmittel wird vorgestellt. Zur Auslegung des Prozesses werden Untersuchungen zur Abscheidung der racemischen Wirkstoffe (RS)‐Flurbiprofen, (RS)‐Ibuprofen, (RS)‐Ketoprofen und den reinen Enantiomeren (R)‐Flurbiprofen, (S)‐Ibuprofen und (S)‐Ketoprofen an AlO(OH)‐Hohlkugeln präsentiert und bewertet. Zudem werden Adsorptionsdaten von gasförmigem CO2 an den Hohlkugeln und kommerziellen AlO(OH)‐Partikeln, die mit einer Magnetschwebewaage ermittelt wurden, verglichen. Abschließend werden erste Ergebnisse von orientierenden Versuchen zur Adsorption von racemischem Flurbiprofen aus sc‐CO2 an den Hohlkugeln vorgestellt.
A systematic toxicological analysis procedure using high-performance thin layer chromatography in combination with fibre optical scanning densitometry for identification of drugs in biological samples is presented. Two examples illustrate the practicability of the technique. First, the identification of a multiple intake of analgesics: codeine, propyphenazone, tramadol, flupirtine and lidocaine, and second, the detection of the sedative diphenhydramine. In both cases, authentic urine specimens were used. The identifications were carried out by an automatic measurement and computer-based comparison of in situ UV spectra with data from a compiled library of reference spectra using the cross-correlation function. The technique allowed a parallel recording of chromatograms and in situ UV spectra in the range of 197–612 nm. Unlike the conventional densitometry, a dependency of UV spectra by concentration of substance in a range of 250–1000 ng/spot was not observed.
Membrane distillation (MD) is a thermal separation process which possesses a hydrophobic, microporous
membrane as vapor space. A high potential application for MD is the concentration of hypersaline brines, such as
e.g. reverse osmosis retentate or other saline effluents to be concentrated to a near saturation level with a Zero
Liquid Discharge process chain. In order to further commercialize MD for these target applications, adapted MD
module designs are required along with strategies for the mitigation of membrane wetting phenomena. This
work presents the experimental results of pilot operation with an adapted Air Gap Membrane Distillation
(AGMD) module for hypersaline brine concentration within a range of 0–240 g NaCl /kg solution. Key performance
indicators such as flux, GOR and thermal efficiency are analyzed. A new strategy for wetting mitigation
by active draining of the air gap channel by low pressure air blowing is tested and analyzed. Only small reductions
in flux and GOR of 1.2% and 4.1% respectively, are caused by air sparging into the air gap channel.
Wetting phenomena are significantly reduced by avoiding stagnant distillate in the air gap making the air blower
a seemingly worth- while additional system component.
An Extraction Method for 17α-Ethinylestradiol from Water using a new kind of monolithic Stir-bar
(2015)
We present a video-densitometric high-performance thin-layer chromatography (HPTLC) quantification method for patulin in apple juice, developed in a vertical chamber from the starting point to a distance of 50 mm, using MTBE, n-pentane (9 + 5, v/v) as mobile phase. After separation the plate is sprayed with methyl-benzothiazolinone hydrazone hydrochloride monohydrate (MBTH) solution (40 mg in 20 mL methanol) and heated at 105 °C for 15 min. Patulin zones are transformed into yellow spots. The quantification is based on direct measurements using an inexpensive 48-bit flatbed scanner for color measurements (in red, green, and blue). Evaluation of the blue channel makes the measurements very specific. Quantification in fluorescence was also done by use of a 16-bit CCD-camera and UV-366 nm illumination as well as using a HPTLC DAD-scanner. For linearization the extended Kubelka–Munk expression for data transformation was used. The range of linearity covers more than two magnitudes and lies between 5 and 800 ng patulin. The extraction of 20 g apple juice and an extract application on plate up to 50 µL allows statistically defined checking the limit of detection (LOD) of 50 ng patulin per track, which is equivalent to 50 µg patulin per kg apple juice.
An isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compounds ∞3[Cu6(μ4-O)(μ3-OH)2(H-Metrz-ia)4][Cu(H2O)6](NO3)2·10H2O (11) and ∞3[Cu2(H-3py-trz-ia)2(H2O)3] (12Cu), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.
Mit der neuen Abgasnorm Euro VI und den steigenden Kraftstoffpreisen müssen Nutzfahrzeugantriebe eine Reduzierung der CO2-Emission und eine höhere Effizienz vorweisen (Umweltbundesamt, 2015). Um diese Anforderungen erfüllen zu können, wird bei vielen Nutzfahrzeugherstellern intensiv an Systemen zur Rückgewinnung von Abgasenergie, den sogenannten Waste-Heat-Recovery-Systemen, geforscht. Eine Kraftstoffersparnis von rund 5 % wird dabei angestrebt.
Das System basiert auf einem ORC-Prozess. Bei diesem thermodynamischen Kreisprozess wird die Abwärme des Abgases über einen Wärmetauscher geführt, der das organische Arbeitsfluid Ethanol in einem geschlossenen Kreislauf erhitzt. Durch den Dampfdruckaufbau wird eine Turbine angetrieben. Zur Transformation der Enthalpie des Ethanoldampfes in mechanische Energie sind Drehzahlen von bis zu 120000 U/min notwendig, um eine hohe Effizienz des Systems vorweisen zu können. Systemdrücke bis 50 bar und Temperaturen des Ethanoldampfes von maximal 300 °C treten im WHR-System auf und führen zu extremen Beanspruchungen. Eine besondere Herausforderung stellen hierbei die Wellendichtungen, vor allem bei nutzfahrzeugtypischen Lebensdauern, dar. Als interessante Alternative zeigt sich die Zentrifugal-Wellendichtung, um die hohen Dichtungsanforderungen über die geforderten Laufzeiten zuverlässig zu erfüllen.
Durch methodisch stufenweise ablauforientiertes Vorgehen wird die Analyse der Zentrifugal-Wellendichtungen durchgeführt. Hierbei wird zuallererst das Wirkprinzip untersucht. Ein besonderes Augenmerk wird dabei auf die Wärmeeinträge aus der Umgebung und Verwendung unterschiedlicher Sperrfluide gelegt.
Für eine Testdrehzahl von 15000 U/min ergibt sich, bei einer beidseitig glatten Scheibe mit einem Scheibenradius von 8,7 mm, eine maximal abdichtbare Druckdifferenz von 0,04 bar. Im Sperrfluid herrschen hierbei Temperaturen von rund 50 °C. Die Versuche zeigen Korrelationen zu den bekannten theoretischen Ansätzen von Ketola und McGrey. Die maximale Druckdifferenz beträgt in diesem Fall 0,043 bar. Nachdem stationäre Betrachtungen ausreichend untersucht werden, widmet sich diese Arbeit dem Anfahr- und Not-Aus-Verhalten. Die Optimierung des Projekts wird durch abschließende Verbesserungsvorschläge, für die Realisierung höherer Sperrdrücke, erzielt.
Ein tiefgreifendes Verständnis des zyklischen Plastizitätsverhaltens metallischer Werkstoffe ist sowohl für die Optimierung der Materialeigenschaften als auch für die industrielle Auslegung und Fertigung von Bauteilen von hoher Relevanz. Insbesondere moderne Legierungen wie Duplex-Stähle zeigen unter Lastumkehr aufgrund des komplexen mehrphasigen Gefüges sowie der Neigung zu verschiedenen Ausscheidungsreaktionen einen ausgeprägten Bauschinger-Effekt, welcher bei technischen Umformvorgängen berücksichtigt werden muss. Der Bauschinger-Effekt begründet sich maßgeblich in der Entstehung von Rückspannungen, welche aus dem unterschiedlichen Plastizitätsverhalten der austenitischen und ferritischen Phase resultieren. Instrumentierte Mikroindenter-Versuche in ausgewählten Ferrit- und Austenitkörnern haben gezeigt, dass austenitische Gefügebestandteile durch einen deutlich früheren Fließbeginn sowie eine stärkere Rückplastifizierung während der Entlastung charakterisiert sind. Zudem wurde nachgewiesen, dass Ausscheidungen im Rahmen einer 475°C-Versprödung diesen Phasenunterschied verstärken und somit in einem höheren Bauschinger-Effekt resultieren.
In dieser Arbeit wird das Verformungsverhalten und die Stabilität des Frontflügels des Formula Student Rennwagens der HS Offenburg untersucht. Die Analyse wird mittels der Finiten-Elemente-Methode durchgeführt (Programm: ANSYS Workbench). In der Simulation wird das Modell mit verschiedenen statischen Kräften belastet, unter anderem die Kräfte aus dem technischen Reglement und die auftretende Abtriebskraft. Neben der Verformung werden auch verschiedene Stabilisierungsmöglichkeiten analysiert. Zusätzlich zu den Simulationsergebnissen selbst werden in dieser Arbeit der Simulationsvorbereitungsprozess sowie die Konstruktion des Frontflügels und Grundlagen der FEM beschrieben. Eine Besonderheit bildet dabei die Verwendung des ANSYS Composite PrePost um die verwendeten Verbundwerkstoffe zu untersuchen.
Das Black Forest Formula Team hat es sich nach der Neugründung im Jahre 2019 zum Ziel gemacht, mit einem eigens konstruierten Elektro-Rennwagen beim Formula Student Germany (folgend FSG genannt) Wettbewerb teilzunehmen.
Zu Beginn der Bachelorarbeit wurde bereits ein Fahrzeugrahmen konstruiert und in der Schweißwerkstatt der Hochschule Offenburg fertig geschweißt. Da bei der Konstruktion der Hauptfokus auf das Fertigstellen eines Rahmens gesetzt wurde, verfolgt diese Bachelorarbeit das Ziel, den Rahmen mittels der Finite Elemente Methode zu analysieren und erste Verbesserungsvorschläge für das Nachfolgerfahrzeug zu erarbeiten. Um sich seinen Möglichkeiten bewusst zu werden, wurde zunächst das Reglement ausgiebig studiert. Nach ausgiebiger Recherche wurde das CAD-Modell des Rahmens für die Simulation vorbereitet, folglich durch verschiedene Lasteinwirkungen simuliert und dessen Auswirkungen analysiert. Um die Simulationsergebnisse zu validieren, wurden die in der Simulation vorkommenden Lasteinwirkungen in der Realität nachgestellt und miteinander verglichen.
Für zukünftig folgende Fahrzeugrahmen werden Verbesserungs- bzw. Optimierungsmethoden erarbeitet, um vor allem das Fahrzeuggewicht zu zu reduzieren und die Steifigkeit möglichst hoch zu halten.
Global energy demand is still on an increase during the last decade, with a lot of impact on the climate change due to the intensive use of conventional fossil-based fuels power plants to cover this demand. Most recently, leaders of the globe met in 2015 to come out with the Paris Agreement, stating that the countries will start to take a more responsible and effective behaviour toward the global warming and climate change issues. Many studies have discussed how the future energy system will look like with respecting the countries’ targets and limits of greenhouse gases and their CO2 emissions. However, these studies rarely discussed the industry sector in detail even though it is one of the major role players in the energy sector. Moreover, many studies have simulated and modelled the energy system with huge jumps of intervals in terms of years and environmental goals. In the first part of this study, a model will be developed for the German electrical grid with high spatial and temporal resolutions and different scenarios of it will be analysed meticulously on shorter periods (annual optimization), with different flexibilities and used technologies and degrees of innovations within each scenario. Moreover, the challenge in this research is to adequately map the diverse and different characteristics of the medium-sized industrial sector. In order to be able to take a first step in assessing the relevance of the industrial sector in Germany for climate protection goals, the industrial sector will be mapped in PyPSA-Eur (an open-source model data set of the European energy system at the level of the transmission network) by detailing the demand for different types of industry and assigning flexibilities to the industrial types. Synthetically generated load profiles of various industrial types are available. Flexibilities in the industrial sector are described by the project partner Fraunhofer IPA in the GaIN project and can be used. Using a scenario analysis, the development of the industrial sector and the use of flexibilities are then to be assessed quantitatively.
One of the main problematics of the seals tests is the time and money consuming they are. Up to now, there are few tries to do a digitalisation of a test where the seals behaviour can be known.
This work aims to digitally reproduce a seal test to extract their behaviour when working under different operation conditions to see their impact on the pimp’s efficiency. In this thesis, due to the Lomaking effect, the leakage and the forces applied on the stator will be the base of analysis.
First of all, among all the literature available for very different kind of seals and inner patterns, it has been chosen the most appropriate and precise data. The data chosen is “Test results for liquid Damper Seals using a Round-Hole Roughness Pattern for the Stator” from Fayolle, P. and “Static and Rotordynamic Characteristics of Liquid Annular Seals with Circumferentially/Grooved Stator and Smooth Rotor using three levels of circumferential Inlet-Fluid” from Torres J.M.
From the literature, dimensions of the test rig and the seals will be extracted to model them into a 3D CAD software. With the 3D CAD digitalisation, the fluid volumes for a rotor-centred position, meaning without eccentricity, will be extracted, and used. The following components have been modelled:
- Smooth Annular Liquid Seal (Grooved Rotor)
- Grooved Annular Liquid Seal (Smooth Rotor)
- Round-Hole Pattern Annular Liquid Seal (𝐻𝑑=2 𝑚𝑚) (Smooth Rotor)
- Straight Honeycomb Annular Liquid Seal (Smooth Rotor)
- Convergent Honeycomb Annular Liquid Seal (Smooth Rotor)
- Smooth Rotor / Smooth Annular Liquid Seal (Smooth Rotor)
As there is just one test rig, all the components have been adapted to the different dimensions of the seals by referencing some measures. This allows to test any seal with the same test rig.
Afterwards a CFD simulation that will be used to obtain leakage and stator forces. The parameters that will be changed are the rotational velocity of the fluid (2000 rpm, 4000 rpm, and 6000 rpm) and the pressure drop (2,068 bar, 4,137 bar, 6,205 bar, and 8,274 bar).
Those results will be compared to the literature ones, and they will determine if digitalisation can be validated or not. Even though the relative error is higher than 5% but the tendency is the same and it is thought that by changing some parameters the test results can be even closer to the literature ones.
To date, many experiments have been performed to study how the internal geometrical shapes of the annular liquid seal can reduce internal leakage and increase pump efficiency. These can be time-consuming and expensive as all rotordynamic coefficients must be determined in each case.
Nowadays, accurate simulation methods to calculate rotordynamic coefficients of annular seals are still rare. Therefore, new numerical methods must be designed and validated for annular seals.
The present study aims to contribute to this labour by providing a summary of the available test rig and seals dimensions and experimental results obtained in the following experiments:
− Kaneko, S et al., Experimental Study on Static and Dynamic Characteristics of Liquid Annular Convergent-Tapered Seals with Honeycomb Roughness Pattern (2003) [1] − J. Alex Moreland, Influence of pre-swirl and eccentricity in smooth stator/grooved rotor liquid annular seals, static and rotordynamic characteristics (2016) [2]
A 3D CAD simulation with Siemens NX Software of the test rig used in J. Alex Moreland’s experiment has been made. The following annular liquid seals have also been 3D modelled, as well as their fluid volume:
− Smooth Annular Liquid Seal (SS/GR) (J. Alex Moreland experiment)
− Grooved Annular Liquid Seal (GS/SR)
− Round-Hole Pattern Annular Liquid Seal (𝐻𝑑=2 mm) (GS/SR)
− Straight Honeycomb Annular Liquid Seal (GS/SR)
− Convergent Honeycomb Annular Liquid Seal (No. 3) (GS/SR)
− Smooth Annular Liquid Seal (SS/SR) (S. Kaneko experiment)
In the case of the seals used in S. Kaneko’s experiments, the test rig has been adapted to each seal, defining interpart expressions which can be easily modified.
Afterwards, it has been done a CFD simulation of the Smooth Annular Liquid Seal using Ansys CFX Software. To do so, the fluid volume geometry has been simplified to do a first approximation. Results have been compared for an eccentricity 𝜀0=0.00 for the following ranges of rotor speeds and differential of pressure:
− Δ𝑃= 2.07, 4.14, 6.21, and 8.27 bar,
− 𝜔= 2, 4, 6 and 8 krpm.
Even results obtained have the same trend as the one proportionated by the literature, they cannot be validated as the error is above 5%. It is also observed that as the pressure drop increases, the relative error decreases considerably.
The Lattice Boltzmann Method is a useful tool to calculate fluid flow and acoustic effects at the same time. Although the acoustic perturbation is much smaller than normal pressure differences in fluid flow, this direct calculation is a great advantage of the Lattice Boltzmann Method (LBM). But each border used in calculation produces a multitude of reflections with the acoustic waves, which lead to an unusable result. Therefore, it is worked on different absorbing techniques.
In this thesis three absorbing layer techniques are described, explained and reviewed with different simulations. The absorbing layers are implemented in a basic LBM code in C++, and with this umpteen simulations within a box were performed to compare the different absorbing layers. The Doppler effect and a cylinder flow are also examined to compare the damping efficiencies.
The three studied absorbing techniques are the sponge layer, the perfectly matched layer and a force based Term II absorbing layer. The sponge layer is easy to implement but gives worse results than a calculation without any absorbing layer. The perfectly matched layer and a force based absorbing term provide very good results but the perfectly matched layer has problems with instability. The force based absorbing layer represents the best compromise between the additional computation time due the absorbing layer and the achieved damping efficiency.
Soot particles emitted from a light duty (LD) Volkswagen diesel engine running at different operating points (speed and torque levels) are analyzed for mean size determination using a laser‐based three Wavelength Extinction Method (3‐WEM). For this reason, collected soot samples are suspended using an appropriate sample preparation technique with optimized conditions of sonication as it revealed its effect on the soot mean particle size measured by 3‐WEM.
An online Scanning Mobility Particle Analyzer (SMPS) is also used to measure soot emission at identical engine operating points. Size values obtained from SMPS are lower than those of suspended soot samples obtained from 3‐WEM. The size discrepancies are mainly related to the required sample preparation procedure employed for 3‐WEM measurements. The engine operating points affect, differently, the size measurements obtained from SMPS and 3‐WEM.
Sedimentation Field‐Flow Fractionation (SdFFF) is used for density determination of soot samples based on size measurements of fractions collected at peak maxima of fractograms using the off‐line hyphenation with 3‐WEM. It is assumed that a size dependent separation of soot particles occurred with a uniform particle density over the whole size distribution. An average density value is used for the conversion of soot fractograms to size distributions. Discrepancies are also found with size distribution profiles obtained from SMPS for the same engine operating points, due to the sample preparation procedure employed for SdFFF measurements.
In der Planungs- und Betriebspraxis herrscht im Bereich der Betriebsführung von thermisch aktivierten Bauteilsystemen und insbesondere der thermisch trägen Bauteilaktivierung noch große Unsicherheit. Trotz einer weiten Verbreitung dieser Systeme im Neubau von Nichtwohngebäuden hat sich bis heute keine einheitliche Betriebsführungsstrategie durchgesetzt. Vielmehr kritisieren Bauherren und Nutzer regelmäßig zu hohe bzw. niedrige Raumtemperaturen in den Übergangsjahreszeiten und bei Wetterwechsel sowie generell eine mangelhafte Regelbarkeit. Demgegenüber weisen Monitoringprojekte immer wieder einen hohen thermischen Komfort in diesen Gebäuden nach. Offensichtlich unterscheiden sich hier subjektiv empfundene Behaglichkeit und objektiv gemessener Komfort. Gleichzeitig sind Heiz- und Kühlkonzepte mit Flächentemperierung dann besonders energieeffizient, wenn das Regelkonzept auf deren thermische Trägheit angepasst ist. Eine gute Regelung gewährleistet also einen hohen thermischen Komfort und sorgt für einen möglichst niedrigen Energieeinsatz. Das Rechenverfahren mit Anlagenaufwandszahlen (in Anlehnung an DIN V 18599) bietet eine gute Möglichkeit, Anlagenkonzepte inklusive deren Betriebsführungsstrategie zu bewerten. Damit ist es möglich, eine auf das Gebäude angepasste Betriebsführungsstrategie für die Bauteilaktivierung zu finden und einheitlich zu bewerten.
In the present study, in vitro toxicity as well as biopersistence and photopersistence of four artificial sweeteners (acesulfame, cyclamate, saccharine, and sucralose) and five antibiotics (levofloxacin, lincomycin, linezolid, marbofloxacin, and sarafloxacin) and of their phototransformation products (PTPs) were investigated. Furthermore, antibiotic activity was evaluated after UV irradiation and after exposure to inocula of a sewage treatment plant. The study reveals that most of the tested compounds and their PTPs were neither readily nor inherently biodegradable in the Organisation for Economic Co-operation and Development (OECD)-biodegradability tests. The study further demonstrates that PTPs are formed upon irradiation with an Hg lamp (UV light) and, to a lesser extent, upon irradiation with a Xe lamp (mimics sunlight). Comparing the nonirradiated with the corresponding irradiated solutions, a higher chronic toxicity against bacteria was found for the irradiated solutions of linezolid. Neither cytotoxicity nor genotoxicity was found in human cervical (HeLa) and liver (Hep-G2) cells for any of the investigated compounds or their PTPs. Antimicrobial activity of the tested fluoroquinolones was reduced after UV treatment, but it was not reduced after a 28-day exposure to inocula of a sewage treatment plant. This comparative study shows that PTPs can be formed as a result of UV treatment. The study further demonstrated that UV irradiation can be effective in reducing the antimicrobial activity of antibiotics, and consequently may help to reduce antimicrobial resistance in wastewaters. Nevertheless, the study also highlights that some PTPs may exhibit a higher ecotoxicity than the respective parent compounds. Consequently, UV treatment does not transform all micropollutants into harmless compounds and may not be a large-scale effluent treatment option.
In this paper fatigue crack closure under in-phase and out-of-phase thermomechanical fatigue (TMF) loading is studied using a temperature dependent strip yield model. It is shown that fatigue crack closure is strongly influenced by the phase relation between mechanical loading and temperature, if the temperature difference goes along with a temperature dependence of the yield stress. In order to demonstrate the effect of the temperature dependent yield stress, the influence of in-phase and out-of-phase TMF loading is studied for a polycrystalline nickel-base superalloy. By using a mechanism based lifetime model, implications for fatigue lives are demonstrated.
As a basis for the evaluation of hydrogen storage by physisorption, adsorption isotherms of H2 were experimentally determined for several porous materials at 77 K and 298 K at pressures up to 15 MPa. Activated carbons and MOFs were studied as the most promising materials for this purpose. A noble focus was given on how to determine whether a material is feasible for hydrogen storage or not, dealing with an assessment method and the pitfalls and problems of determining the viability. For a quantitative evaluation of the feasibility of sorptive hydrogen storage in a general analysis, it is suggested to compare the stored amount in a theoretical tank filled with adsorbents to the amount of hydrogen stored in the same tank without adsorbents. According to our results, an “ideal” sorbent for hydrogen storage at 77 K is calculated to exhibit a specific surface area of >2580 m2 g−1 and a micropore volume of >1.58 cm3 g−1.
Der aktuell verbaute Hatz-Dieselmotors des Schluckspecht V soll durch einen leichten und effizienten Ottomotor ersetzt werden. Dieser Ottomotor wird zukünftig mit dem Alkohol Ethanol betrieben. Hierfür müssen, auch hinsichtlich des Wettbewerb-Einsatzes beim Shell Eco-marathon, einige Optimierungen durchgeführt werden.
Die hier vorliegende Master-Thesis behandelt den Aufbau und die Optimierung des Ver-suchsprüfstands, welcher für Testzwecke für den neuen Ottomotor entwickelt wurde. Im speziellen wird auf das Thema Kraftstoffsystem, welches für den Betrieb mit Ethanol aus-gelegt wird, eingegangen. Des Weiteren erfolgt die Konstruktion einer optimierten Ansaugstrecke, welche auf den Verbrennungsmotor appliziert werden soll. Hierfür werden mehrere Varianten strömungstechnisch untersucht und am Objekt getestet. Zudem soll die Verdichtung des Verbrennungsmotors durch einen optimierten Kolben erhöht und die Ventilsteuerzeiten durch eine optimierte Nockenkontur perfektioniert werden. Hierbei besteht die Aufgabe darin diese Bauteile zu besorgen und die Fertigung zu koordinieren. Eine weitere Tätigkeit ist die Aufnahme und Beseitigung von Fehlern des Versuchsprüfstands, welche einen reibungslosen Versuchsalltag verhindern bzw. erschweren. Die letzte Tätigkeit umfasst das Durchführen von experimentellen Untersuchungen des Verbrennungsmotors und das Anlegen von Kennfeldern, welche einen effizienten Motorlauf gewährleisten.
Auslegung eines Baukastensystems für einen Detektor zur optischen Fehlerprüfung von Mantelflächen
(2016)
Im Projekt der Abschlussarbeit wird an der Konstruktion eines sich automatisch zusammenbauenden Baukastensystems für einen Detektor in Anlagen zur optischen Teileprüfung gearbeitet. Der behandelte Detektoraufbau, bestehend aus Bildsensor, Objektiv und Beleuchtung, detektiert dabei Innen- und Außenmantelflächenfehler bei Serienteilen mit Außendurchmessern von 5 mm bis 80 mm und Höhen von 1 mm bis 60 mm. Der Detektor, auch allgemeiner als Sensor bezeichnet, weist im Konstruktionsprozess eine Problematik auf, welche durch die Erzeugung eines Baukastens gelöst werden soll.
Bifaziale Photovoltaikmodule werden durch ihre höhere Leistung, bezogen auf den Flächenbedarf immer attraktiver. Die meisten der bislang hergestellten Photovoltaik Module sind Monofazial ausgeführtund schöpfen damit nicht ihr vollständiges Potential aus. Weiterhin bestehen die konventionell hergestelltenPhotovoltaik(PV) Module aus einem Verbund aus Glas und Kunststoff sowie verschiedenen Metallen, was die Entsorgung oder ein Recycling kostenaufwendig und kompliziert gestaltet. Die Firma Apollon greift diese Punkte auf und versucht, beides in dem NICE-Modul(Siehe Anhang 12.1)zu vereinen,nämlich ein bifaziales Modul, bei dem die PV-Zellen zwischen zwei Glasplatten, anstelle von zwei Kunststoffen eingespannt werden. Die Hochschule Offenburg ist F&E-Partner der Firma Apollon und betreibt ein kleines Labor zur Herstellung von NICE-Modulen. Zu Testzwecken werden diese der Witterung ausgesetzt und so der Energieertrag,sowie deren Lebensdauer unter geltenden Witterungsbedingungen ermittelt. In der Masterarbeit von Benjamin Smith[1]stellte sich heraus, dass sich bei den Modulen nach weniger als zwei Wochen im Freien die Klebefläche zwischen den Glasplatten löste. Somit fielen die Module beim Witterungstest unter realen Bedingungen durch.Im Anschluss an die Arbeit von Benjamin Smith besteht diese Arbeit darin,einen Außenteststand zu konzipieren und aufzubauen, um das in Zwischenzeit neu entworfene Klebe-konzept, welches einem TC 50 Test standhielt, auf die Lebensdauer im Freien und das PV Modul selbst auf den elektrischen Ertrag zu untersuchen. Für den elektrischen Ertrag werden Strom-und Spannungsverlauf aufgezeichnet. Außerdem musste für eine Charakterisierung der Module die Bestrahlungsstärke,der Temperaturverlauf, sowie die Inho-mogenität der Bestrahlungsstärke auf der Rückseite und die Windgeschwindigkeit ermittelt werden. Um eine Alterung des Modulwechselrichters auszuschließen, werden speziell dafür die Wechselspannung und Leistung auf der Ausgangsseite des Modulwechselrichters aufgezeichnet. Sämtliche modulrelevanten Messwerte werden im 3-5 s Intervall abgespeichert und sind auf einem Webserver sowie für eine spätere Datenanalyse als .csv Datei abrufbar. Somit eignet sich die Messeinrichtung lediglich für eine Bilanzierung,nicht aber für eine Leistungsmessung.
Für den Außenteststand musste eine Unterkonstruktion, geeignet für bifaziale Module entworfen und aufgebaut werden. Die Konstruktion ist vollständig aufgebaut. Das Messsystem wurde auf deren Funktion erfolgreich geprüft und steht bis auf die Strahlungsinhomogenitätsmessung im Technikum am Campus Nord der Hochschule Offenburg bereit zur Inbetriebnahme.
Auswahl von elektrischen Antriebskomponenten zur Elektrifizierung des Antriebes eines „Tuk-Tuks“
(2019)
Die vorliegende Abschlussarbeit handelt von einem Tuk-Tuk. Im Ausgangszustand ist dieses mit einem 1-Zylinder Ottomotor versehen.
Im Rahmen eines Hochschulprojektes wird dieser Motor durch einen Elektromotor ersetzt. Ziel dieser Thesis ist es, einen passenden Motor zu finden. Dabei soll eine Auslegung erarbeitet werden, die es ermöglicht, sämtliche Widerstandskräfte zu berechnen und daraus auf die notwendigen Antriebsleistungen bzw. Drehmomente zu schließen. Im Anschluss daran kann eine Aussage getroffen werden, ob der Elektromotor die gewünschten Anforderungen erfüllt.