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Background: R-wave synchronised atrial pacing is an effective temporary pacing
therapy in infants with postoperative junctional ectopic tachycardia. In the technique
currently used, adverse short or long intervals between atrial pacing and ventricular
sensing (AP–VS) may be observed during routine clinical practice.
Objectives: The aim of the study was to analyse outcomes of R-wave synchronised
atrial pacing and the relationship between maximum tracking rates and AP–VS
intervals.
Methods: Calculated AP–VS intervals were compared with those predicted by experienced
pediatric cardiologist.
Results: A maximum tracking rate (MTR) set 10 bpm higher than the heart rate (HR)
may result in undesirable short AP–VS intervals (minimum 83 ms). A MTR set 20 bpm
above the HR is the hemodynamically better choice (minimum 96 ms). Effects of either
setting on the AP–VS interval could not be predicted by experienced observers. In our
newly proposed technique the AP–VS interval approaches 95 ms for HR > 210 bpm
and 130 ms for HR < 130 bpm. The progression is linear and decreases strictly
(− 0.4 ms/bpm) between the two extreme levels.
Conclusions: Adjusting the AP–VS interval in the currently used technique is complex
and may imply unfavorable pacemaker settings. A new pacemaker design is advisable
to allow direct control of the AP–VS interval.
Printed electronics (PE) circuits have several advantages over silicon counterparts for the applications where mechanical flexibility, extremely low-cost, large area, and custom fabrication are required. The custom (personalized) fabrication is a key feature of this technology, enabling customization per application, even in small quantities due to low-cost printing compared with lithography. However, the personalized and on-demand fabrication, the non-standard circuit design, and the limited number of printing layers with larger geometries compared with traditional silicon chip manufacturing open doors for new and unique reverse engineering (RE) schemes for this technology. In this paper, we present a robust RE methodology based on supervised machine learning, starting from image acquisition all the way to netlist extraction. The results show that the proposed RE methodology can reverse engineer the PE circuits with very limited manual effort and is robust against non-standard circuit design, customized layouts, and high variations resulting from the inherent properties of PE manufacturing processes.
Printed electronics (PE) is a fast-growing field with promising applications in wearables, smart sensors, and smart cards, since it provides mechanical flexibility, and low-cost, on-demand, and customizable fabrication. To secure the operation of these applications, true random number generators (TRNGs) are required to generate unpredictable bits for cryptographic functions and padding. However, since the additive fabrication process of the PE circuits results in high intrinsic variations due to the random dispersion of the printed inks on the substrate, constructing a printed TRNG is challenging. In this article, we exploit the additive customizable fabrication feature of inkjet printing to design a TRNG based on electrolyte-gated field-effect transistors (EGFETs). We also propose a printed resistor tuning flow for the TRNG circuit to mitigate the overall process variation of the TRNG so that the generated bits are mostly based on the random noise in the circuit, providing a true random behavior. The simulation results show that the overall process variation of the TRNGs is mitigated by 110 times, and the generated bitstream of the tuned TRNGs passes the National Institute of Standards and Technology - Statistical Test Suite. For the proof of concept, the proposed TRNG circuit was fabricated and tuned. The characterization results of the tuned TRNGs prove that the TRNGs generate random bitstreams at the supply voltage of down to 0.5 V. Hence, the proposed TRNG design is suitable to secure low-power applications in this domain.
Printed electronics (PE) enables disruptive applications in wearables, smart sensors, and healthcare since it provides mechanical flexibility, low cost, and on-demand fabrication. The progress in PE raises trust issues in the supply chain and vulnerability to reverse engineering (RE) attacks. Recently, RE attacks on PE circuits have been successfully performed, pointing out the need for countermeasures against RE, such as camouflaging. In this article, we propose a printed camouflaged logic cell that can be inserted into PE circuits to thwart RE. The proposed cell is based on three components achieved by changing the fabrication process that exploits the additive manufacturing feature of PE. These components are optically look-alike, while their electrical behaviors are different, functioning as a transistor, short, and open. The properties of the proposed cell and standard PE cells are compared in terms of voltage swing, delay, power consumption, and area. Moreover, the proposed camouflaged cell is fabricated and characterized to prove its functionality. Furthermore, numerous camouflaged components are fabricated, and their (in)distinguishability is assessed to validate their optical similarities based on the recent RE attacks on PE. The results show that the proposed cell is a promising candidate to be utilized in camouflaging PE circuits with negligible overhead.
Advances in printed electronics (PE) enables new applications, particularly in ultra-low-cost domains. However, achieving high-throughput printing processes and manufacturing yield is one of the major challenges in the large-scale integration of PE technology. In this article, we present a programmable printed circuit based on an efficient printed lookup table (pLUT) to address these challenges by combining the advantages of the high-throughput advanced printing and maskless point-of-use final configuration printing. We propose a novel pLUT design which is more efficient in PE realization compared to existing LUT designs. The proposed pLUT design is simulated, fabricated, and programmed as different logic functions with inkjet printed conductive ink to prove that it can realize digital circuit functionality with the use of programmability features. The measurements show that the fabricated LUT design is operable at 1 V.
Energy efficiency and hygrothermal performance of hemp clay walls for Moroccan residential buildings
(2023)
Hemp-based building envelopes have gained significant popularity in developed countries, and now the trend of constructing houses with hemp-clay blocks is spreading to developing countries like Morocco. Investigating the hygrothermal behavior of such structures under actual climate conditions is essential for advancing and promoting this sustainable practice. This paper presents an in-depth experimental characterization of a commercial hemp-clay brick that has been exposed to the outdoor environment for four years, in addition to field measurements on a building scale demonstration prototype. Additionally, the study simulates 17 representative cities to assess the hygrothermal performance and energy-saving potential in each of Morocco's six existing climate zones, using the EnergyPlus engine. The experimental campaign's findings demonstrate excellent indoor air temperature and relative humidity regulation within the hemp-clay wall building, leading to satisfactory levels of thermal comfort within hemp-clay wall buildings. This is attributed to the material's good thermal conductivity and excellent moisture buffering capacity (found to be 0.31 W/mK and 2.25 g/m2%RH), respectively). The energy simulation findings also point to significant energy savings, with cooling and heating energy reductions ranging from 27.7% to 47.5% and 33.7% to 79.8%, respectively, as compared to traditional Moroccan buildings.
Economic growth is usually driven by improvements in productivity, economic efficiency, trade and innovation. Increasing efficiency means to produce larger output using the same amount of factors for production such as raw materials, labour, and capital. However, regardless of the driver, growth is often investment-hungry and it is not rare to find an economy with potential for growth but lacking locally available investment. In this scenario, Foreign Direct Investment (FDI) can fill the gap between investment needed to promote economic growth and locally available investments.
This review provides an overview on the production and analysis techniques of antioxidative peptides from food proteins. Regarding the production of antioxidative peptides, interlinked factors must be considered. Depending on the protein substrate, different peptidases or peptidase systems containing multiple enzymes as well as a specific production process must be chosen. The antioxidative peptides might be produced in a batch process including multiple pre- and post-treatments, besides the hydrolyses with peptidases itself. As an alternative, the potential of continuous production systems is discussed in this review. Furthermore, robust analyses tools are needed to gain control of the process and final product properties. With no standardized methodology available for antioxidative peptide evaluation, pros and cons of various strategies for peptide separation and antioxidative measurement are discussed in this review. Therefore, this review provides a roadmap for antioxidative peptide generation from various sources for research and development as well as for potential industrial use.
Properties of higher-order surface acoustic wave modes in Al(1-x)Sc(x)N / sapphire structures
(2021)
In this work, surface acoustic wave (SAW) modes and their dependence on propagation directions in epitaxial Al0.68Sc0.32N(0001) films on Al2O3(0001) substrates were studied using numerical and experimental methods. In order to find optimal propagation directions for higher-order SAW modes, phase velocity dispersion branches of Al0.68Sc0.32N on Al2O3 with Pt mass loading were computed for the propagation directions <11-20> and <1-100> with respect to the substrate. Experimental investigations of phase velocities and electromechanical coupling were performed for comparison with the numerical results. Simulations carried out with the finite element method (FEM) and with a Green function approach allowed identification of each wave type, including Rayleigh, Sezawa and shear horizontal wave modes. For the propagation direction <1-100>, significantly increased wave guidance of the Sezawa mode compared to other directions was observed, resulting in enhanced electromechanical coupling (k2eff = 1.6 %) and phase velocity (vphase = 6 km/s). We demonstrated, that selecting wave propagation in <1-100> with high mass density electrodes results in increased electromechanical coupling without significant reduction in phase velocities for the Sezawa wave mode. An improved combination of metallization, Sc concentration x, and SAW propagation direction is suggested which exhibits both high electromechanical coupling (k2eff > 6 %) and high velocity (vphase = 5.5 km/s) for the Sezawa mode.
Cellular phone antennas are generally designed to have radiation patterns that are as omnidirectional as possible. Omnidirectional antennas allow a phone’s radio to work well for many orientations of the phone with respect to the cellular base station. Recent studies, however, are generating uncertainty about the health effects of prolonged exposure to electromagnetic (EM) radiation from cellular phones. In this paper, an antenna array is designed primarily to minimize users’ exposure to EM radiation. The antenna comprises a beamforming 4 by 3 array of microstrip patch antennas that is controlled by an accelerometer-only inertial navigation system. The proposed design reduces radiated power directed toward the user to below 10% of the total in the worst case.
Printed electronics can benefit from the deployment of electrolytesas gate insulators,which enables a high gate capacitance per unit area (1–10 μFcm−2) due to the formation of electrical double layers (EDLs). Consequently, electrolyte-gated field-effect transistors (EGFETs) attain high-charge carrier densities already in the subvoltage regime, allowing for low-voltage operation of circuits and systems. This article presents a systematic study of lumped terminal capacitances of printed electrolyte-gated transistors under various dc bias conditions. We perform voltage-dependent impedancemeasurements and separate extrinsic components from the lumped terminal capacitance.
The proposed Meyer-like capacitance model, which also accounts for the nonquasi-static (NQS) effect, agrees well with experimental data. Finally, to verify the model, we implement it in Verilog-A and simulate the transient response of an inverter and a ring oscillator circuit. Simulation results are in good agreement with the measurement data of fabricated devices.
Electrolyte-gated, printed field-effect transistors exhibit high charge carrier densities in the channel and thus high on-currents at low operating voltages, allowing for the low-power operation of such devices. This behavior is due to the high area-specific capacitance of the device, in which the electrolyte takes the role of the dielectric layer of classical architectures. In this paper, we investigate intrinsic double-layer capacitances of ink-jet printed electrolyte-gated inorganic field-effect transistors in both in-plane and top-gate architectures by means of voltage-dependent impedance spectroscopy. By comparison with deembedding structures, we separate the intrinsic properties of the double-layer capacitance at the transistor channel from parasitic effects and deduce accurate estimates for the double-layer capacitance based on an equivalent circuit fitting. Based on these results, we have performed simulations of the electrolyte cutoff frequency as a function of electrolyte and gate resistances, showing that the top-gate architecture has the potential to reach the kilohertz regime with proper optimization of materials and printing process. Our findings additionally enable accurate modeling of the frequency-dependent capacitance of electrolyte/ion gel-gated devices as required in the small-signal analysis in the circuit simulation.
Rectifiersare vital electronic circuits for signal and power conversion in various smart sensor applications. The ability to process low input voltage levels, for example, from vibrational energy harvesters is a major challenge with existing passive rectifiers in printed electronics, stemming mainly from the built-in potential of the diode's p-njunction. To address this problem, in this work, we design, fabricate, and characterize an inkjet-printed full-wave rectifier using diode-connected electrolyte-gated thin-film transistors (EGTs). Using both experimental and simulation approaches, we investigate how the rectifier can benefit from the near-zero threshold voltage of transistors, which can be enabled by proper channel geometry setting in EGT technology. The presented circuit can be operated at 1-V input voltage, featuring a remarkably small voltage loss of 140 mV and a cutoff frequency of ~300 Hz. Below the cutoff frequency, more than 2.6-μW dc power is obtained over the load resistances ranging from 5 to 20 kQ. Furthermore, experiments show that the circuit can work with an input amplitude down to 500 mV. This feature makes the presented design highly suitable for a variety of energy-harvesting applications.
An analytical and numerical study of the wobbling dynamics of friction disks is presented. Of particular interest is the excitation mechanism taking into account two contrarian effects both originating in dry friction: the circulatory terms describing the energy input due to the sliding contacts and the friction induced damping which stabilizes the system. Balance of these terms determines the instability domain in the parameter space. It is shown that there is a slip threshold so that, if the slip is under this limit, the system remains stable. If the slip is larger than this limit, then the criterion of stability is determined by the relation between the friction coefficient and the internal damping. The limit cycle appearing in the unstable domain is also investigated. It is shown that the limit cycle can be described as a kind of a regular reverse precession of the wobbling disc. Its amplitude is limited by the geometric nonlinearity and partial contact loss. Analytic results are compared with numeric simulations.
In the present paper, the influence of locally varying microstructures in case of an AlSi12 cast aluminium alloy is investigated by means of extracting the test pieces from different removal positions and low cycle fatigue tests. The temperature-dependent damage mechanisms, the material specific defect types, sizes and their influence on the fatigue properties of two AlSi7 and AlSi12 cast aluminium alloys are studied. An extreme value statistics methodology is applied to predict maximum defect sizes expected in a critical surface volume from two-dimensional metallographic micrographs. A damage map for the AlSi12 cast aluminium alloy is presented explaining the influence of the temperature- and load-dependent damage mechanisms on the observed isothermal and thermomechanical lifetime behavior.
Detailed material investigations of the fatigue behavior of two cast aluminium alloys used in combustion engines are presented. The network of intermetallic phases of both aluminium alloys is characterized by means of detailed energy dispersive X-ray spectroscopy. In order to investigate the temperature-dependent fatigue behavior of the materials, tensile, low cycle and thermomechanical fatigue tests are performed over a wide temperature and loading range. The influence of the temperature dependence on the experimental results is discussed.
In this work, the influence of superimposed high cycle fatigue on the LCF/HCF and TMF/HCF lifetime is investigated for two cast aluminium alloys of the types AlSi7 and AlSi12. The replica technique is used to examine the short crack growth behavior under pure LCF and LCF/HCF loading. The observed short crack growth evolution explains the observed lifetime reduction with increasing HCF amplitudes.
In this paper fatigue crack closure under in-phase and out-of-phase thermomechanical fatigue (TMF) loading is studied using a temperature dependent strip yield model. It is shown that fatigue crack closure is strongly influenced by the phase relation between mechanical loading and temperature, if the temperature difference goes along with a temperature dependence of the yield stress. In order to demonstrate the effect of the temperature dependent yield stress, the influence of in-phase and out-of-phase TMF loading is studied for a polycrystalline nickel-base superalloy. By using a mechanism based lifetime model, implications for fatigue lives are demonstrated.
A crack opening stress equation for in-phase and out-of-phase thermomechanical fatigue loading
(2016)
In this paper, a crack opening stress equation for in-phase and out-of-phase thermomechanical fatigue (TMF) loading is proposed. The equation is derived from systematic calculations of the crack opening stress with a temperature dependent strip yield model for both plane stress and plane strain, different load ratios and different ratios of the temperature dependent yield stress in compression and tension. Using a load ratio scaled by the ratio of the yield stress in compression and tension, the equation accounts for the effect of the temperature dependent yield stress and the constraint on the crack opening stress. Based on the scaling relation established in this paper, Newman's crack opening stress equation for isothermal loading is enabled to predict the crack opening stress under TMF loading.
This paper treats the interaction between acoustic modes and light (Brillouin scattering) in a single mode optical fibre. Different observed spectra of the Brillouin backscattering in several fibres have been already reported. In order to have a clear idea of the process, we made a simulation to be able to `draw' the theoretical Brillouin spectrum of an optical fibre and to identify the origin of the observed backscattered lines.
First, the model and the computation method used in our simulation are described. Second, the experimentally observed spectra of two real fibres are compared with their computed spectra. Real spectra and simulated spectra are in good agreement.
Our work provides an interesting tool to investigate the changes in the Brillouin spectrum when the input parameters (characteristics of an optical fibre) vary. This should give useful indications to people working on systems which use Brillouin backscattering.
Digitalisierung ist heute allgegenwärtig. Wo im Privaten bereitwillig neue digitale Tools, Apps und Funktionen genutzt werden, tun sich Unternehmen in der Umsetzung von Digitalisierungsprojekten oft schwer. Dieser Beitrag beleuchtet die Motive für Digitalisierungsvorhaben, ihre Hürden sowie die Auswirkung auf die Arbeitsbelastung von Mitarbeitenden und versucht in der Verknüpfung mit den Grundprinzipien des Kontinuierlichen Verbesserungsprozesses, Handlungsempfehlungen für eine erfolgreiche Umsetzung dieser abzuleiten.
In this work the nonlinear behavior of layered surface acoustic wave (SAW) resonators is studied with the help of finite element (FE) computations. The full calculations depend strongly on the availability of accurate tensor data. While there are accurate material data for linear computations, the complete sets of higher-order material constants, needed for nonlinear simulations, are still not available for relevant materials. To overcome this problem, scaling factors were used for each available nonlinear tensor. The approach here considers piezoelectricity, dielectricity, electrostriction, and elasticity constants up to the fourth order. These factors act as a phenomenological estimate for incomplete tensor data. Since no set of fourth-order material constants for LiTaO3 is available, an isotropic approximation for the fourth-order elastic constants was applied. As a result, it was found that the fourth-order elastic tensor is dominated by one-fourth order Lamé constant. With the help of the FE model, derived in two different, but equivalent ways, we investigate the nonlinear behavior of a SAW resonator with a layered material stack. The focus was set to third-order nonlinearity. Accordingly, the modeling approach is validated using measurements of third-order effects in test resonators. In addition, the acoustic field distribution is analyzed.
Bislang gibt es keine Güterstraßenbahnsysteme, die im urbanen Warentransport im Realbetrieb eingesetzt werden. Bestehende Konzepte sind auf einzelne Branchen, ausgewählte Transportgüter oder einzelne Verlader ausgerichtet. Untersuchungen zu Güterstraßenbahnprojekten konzentrieren sich auf individuelle Kunden (zum Beispiel "CarGo Tram" Dresden). Für die Realisierung einer Güterstraßenbahn im urbanen Raum wäre zu klären, welche Anforderungen potenzielle Nutzer haben und wie diese Anforderungen in ein logistisches Konzept integriert werden können. In einer multiplen Fallstudie werden drei Unternehmen aus verschiedenen Branchen analysiert. Aufgrund heterogener Anforderungen wird ein modulares Logistikkonzept vorgeschlagen. Der Beitrag entstand im Rahmen des Projektes "LogIKTram: Logistikkonzept und IKT-Plattform für stadtbahnbasierten Gütertransport".
The instability of ultra-thin films of an electrolyte bordering a dielectric gas in an external tangential electric field is scrutinized. The solid wall is assumed to be either a conducting or charged dielectric surface. The problem has a steady one-dimensional solution. The theoretical results for a plug-like velocity profile are successfully compared with available experimental data. The linear stability of the steady-state flow is investigated analytically and numerically. Asymptotic long-wave expansion has a triple-zero singularity for a dielectric wall and a quadruple-zero singularity for a conducting wall, and four (for a conducting wall) or three (for a charged dielectric wall) different eigenfunctions. For infinitely small wave numbers, these eigenfunctions have a clear physical meaning: perturbations of the film thickness, of the surface charge, of the bulk conductivity, and of the bulk charge. The numerical analysis provides an important result: the appearance of a strong short-wave instability. At increasing Debye numbers, the short-wave instability region becomes isolated and eventually disappears. For infinitely large Weber numbers, the long-wave instability disappears, while the short-wave instability persists. The linear stability analysis is complemented by a nonlinear direct numerical simulation. The perturbations evolve into coherent structures; for a relatively small external electric field, these are large-amplitude surface solitary pulses, while for a sufficiently strong electric field, these are short-wave inner coherent structures, which do not disturb the surface.
Diese Arbeit beschäftigt sich mit der Biomechanik der Halswirbelsäule (HWS) beim Umgang mit dem Smartphone. Die Kräfte, die auf Wirbelkörper, Wirbelgelenke, Bandscheiben, Muskeln und Bänder wirken, werden mit steigendem Flexionswinkel der HWS größer. Die Beschwerden hingegen, welche der Smartphone-Nacken hervorruft, sind meist akut und mit regelmäßiger Bewegung und der Stärkung der Nackenmuskulatur gut zu behandeln. Eine Therapie ist somit auch zur Vorbeugung geeignet. Doch die Langzeitauswirkungen sind nicht außer Acht zu lassen, denn durch die steigenden Nutzungsmöglichkeiten der Smartphones steigt auch der durchschnittliche tägliche Gebrauch stärker an. So wird vor allem die tägliche Bildschirmzeit bei Jugendlichen immer länger. Das aktuell noch akute Krankheitsbild des Smartphone-Nackens, das nur selten einen chronischen Verlauf nimmt und Langzeitschäden verursacht, könnte sich durch fehlende oder zu späte Maßnahmen zu einem größeren chronischen Krankheitsbild entwickeln.
Oxide semiconductors are highly promising candidates for the most awaited, next-generation electronics, namely, printed electronics. As a fabrication route for the solution-processed/printed oxide semiconductors, photonic curing is becoming increasingly popular, as compared to the conventional thermal curing method; the former offers numerous advantages over the latter, such as low process temperatures and short exposure time and thereby, high throughput compatibility. Here, using dissimilar photonic curing concepts (UV–visible light and UV-laser), we demonstrate facile fabrication of high performance In2O3 field-effect transistors (FETs). Beside the processing related issues (temperature, time etc.), the other known limitation of oxide electronics is the lack of high performance p-type semiconductors, which can be bypassed using unipolar logics from high mobility n-type semiconductors alone. Interestingly, here we have found that our chosen distinct photonic curing methods can offer a large variation in threshold voltage, when they are fabricated from the same precursor ink. Consequently, both depletion and enhancement-mode devices have been achieved which can be used as the pull-up and pull-down transistors in unipolar inverters. The present device fabrication recipe demonstrates fast processing of low operation voltage, high performance FETs with large threshold voltage tunability.
Surface treatment intensity monitoring is still an open and challenging nondestructive testing problem. For the estimation of residual stress with ultrasonic measurements, local linear and nonlinear elastic constants are needed as input. In this paper, nonlinear elastic-wave interactions (also called wave mixing or scattering) — namely, the generation of secondary ultrasonic waves in a nonlinear medium — are considered as a prospective means for near-surface nonlinear elastic parameter evaluation. The allowed interactions between bulk and surface waves, as well as the dependence of the scattering efficiency on the frequency and angle between source waves, were investigated through an analytical model, then compared with FEM simulations and experimental results. Finally, possible future steps for the development of the applied methods for the determination of near-surface higher-order elastic constants are discussed. In addition, several problem-relevant data processing procedures are presented.
This work compares the performance of Bluetooth Mesh implementations on real chipsets against the ideal implementation of the specification. Measurements are taken in experimental settings and reveal non-idealities in the underlying Bluetooth Low Energy specification in real chipsets and in the implementation of Mesh, which introduces an unruly transmission as well as reception behavior. These effects lead to an impact on transmission rate, reception rate, latency, as well as a more significant impact on the average power consumption.
We revisit the quantitative analysis of the ultrafast magnetoacoustic experiment in a freestanding nickel thin film by Kim and Bigot [J.-W. Kim and J.-Y. Bigot, Phys. Rev. B 95, 144422 (2017)] by applying our recently proposed approach of magnetic and acoustic eigenmode decomposition. We show that the application of our modeling to the analysis of time-resolved reflectivity measurements allows for the determination of amplitudes and lifetimes of standing perpendicular acoustic phonon resonances with unprecedented accuracy. The acoustic damping is found to scale as ∝ω2 for frequencies up to 80 GHz, and the peak amplitudes reach 10−3. The experimentally measured magnetization dynamics for different orientations of an external magnetic field agrees well with numerical solutions of magnetoelastically driven magnon harmonic oscillators. Symmetry-based selection rules for magnon-phonon interactions predicted by our modeling approach allow for the unambiguous discrimination between spatially uniform and nonuniform modes, as confirmed by comparing the resonantly enhanced magnetoelastic dynamics simultaneously measured on opposite sides of the film. Moreover, the separation of timescales for (early) rising and (late) decreasing precession amplitudes provide access to magnetic (Gilbert) and acoustic damping parameters in a single measurement.
Micro gas turbines (MGTs) are regarded as combined heat and power (CHP) units which offer high fuel utilization and low emissions. They are applied in decentralized energy neration.
To facilitate the planning process of energy systems, namely in the context of the increasing application of optimization techniques, there is a need for easy-to-parametrize component models with sufficient accuracy which allow a fast computation. In this paper, a model is proposed where the non-linear part load characteristics of the MGT are linearized by means of physical insight of the working principles of turbomachinery. Further, it is shown that the model can be parametrized by the data usually available in spec sheets. With this model a uniform description of MGTs from several manufacturers
covering an electrical power range from 30kW to 333kW can be obtained. The MGT model was
implemented by means of Modelica/Dymola. The resulting MGT system model, comprising further heat exchangers and hydraulic components, was validated using the experimental data of a 65kW MGT from a trigeneration energy system.
Polygeneration systems are a key technology for the reduction of primary energy usage and emissions. High costs, lack of flexibility and effort for parameterization hinder the wide usage of modeling tools during their conceptual design. This paper describes how planning tools can be structured for the conceptual design phase where only little information is available to the planner. A library concept was developed using the principles of object-oriented modeling to address the flexibility issue. With respect to cost and expandability, the open-source modeling language Modelica was chosen. Furthermore, easy-to-parameterize component models were developed. In addition to the improved library concept and novel component models, an easy-to-adapt control concept is proposed. The component models were validated and the applicability of the library was demonstrated by means of an example. It was shown that the data usually obtained from spec sheets are sufficient to parameterize the models. In addition to this, the control concept was approved.
Many commonly well-performing convolutional neural network models have shown to be susceptible to input data perturbations, indicating a low model robustness. To reveal model weaknesses, adversarial attacks are specifically optimized to generate small, barely perceivable image perturbations that flip the model prediction. Robustness against attacks can be gained by using adversarial examples during training, which in most cases reduces the measurable model attackability. Unfortunately, this technique can lead to robust overfitting, which results in non-robust models. In this paper, we analyze adversarially trained, robust models in the context of a specific network operation, the downsampling layer, and provide evidence that robust models have learned to downsample more accurately and suffer significantly less from downsampling artifacts, aka. aliasing, than baseline models. In the case of robust overfitting, we observe a strong increase in aliasing and propose a novel early stopping approach based on the measurement of aliasing.
Numerous 2,5-dimethoxy-N-benzylphenethylamines (NBOMe), carrying a variety of lipophilic substituents at the 4-position, are potent agonists at 5-hydroxytryptamine (5HT2A ) receptors and show hallucinogenic effects. The present study investigated the metabolism of 25D-NBOMe, 25E-NBOMe, and 25N-NBOMe using the microsomal model of pooled human liver microsomes (pHLM) and the microbial model of the fungi Cunninghamella elegans (C. elegans). Identification of metabolites was performed using liquid chromatography-high resolution-tandem mass spectrometry (LC-HR-MS/MS) with a quadrupole time-of-flight (QqToF) instrument. In total, 36 25D-NBOMe phase I metabolites, 26 25E-NBOMe phase I metabolites and 24 25N-NBOMe phase I metabolites were detected and identified in pHLM. Furthermore, 14 metabolites of 25D-NBOMe, 11 25E-NBOMe metabolites, and nine 25N-NBOMe metabolites could be found in C. elegans. The main biotransformation steps observed were oxidative deamination, oxidative N-dealkylation also in combination with hydroxylation, oxidative O-demethylation possibly combined with hydroxylation, oxidation of secondary alcohols, mono- and dihydroxylation, oxidation of primary alcohols, and carboxylation of primary alcohols. Additionally, oxidative di-O-demethylation for 25E-NBOMe and reduction of the aromatic nitro group and N-acetylation of the primary aromatic amine for 25N-NBOMe took place. The resulting 25N-NBOMe metabolites were unique for NBOMe compounds. For all NBOMes investigated, the corresponding 2,5-dimethoxyphenethylamine (2C-X) metabolite was detected. This study reports for the first time 25X-NBOMe N-oxide metabolites and hydroxylamine metabolites, which were identified for 25D-NBOMe and 25N-NBOMe and all three investigated NBOMes, respectively. C. elegans was capable of generating all main biotransformation steps observed in pHLM and might therefore be an interesting model for further studies of new psychoactive substances (NPS) metabolism.
Tryptamines can occur naturally in plants, mushrooms, microbes, and amphibians. Synthetic tryptamines are sold as new psychoactive substances (NPS) because of their hallucinogenic effects. When it comes to NPS, metabolism studies are of crucial importance, due to the lack of pharmacological and toxicological data. Different approaches can be taken to study in vitro and in vivo metabolism of xenobiotica. The zygomycete fungus Cunninghamella elegans (C. elegans) can be used as a microbial model for the study of drug metabolism. The current study investigated the biotransformation of four naturally occurring and synthetic tryptamines [N,N‐Dimethyltryptamine (DMT), 4‐hydroxy‐N‐methyl‐N‐ethyltryptamine (4‐HO‐MET), N,N‐di allyl‐5‐methoxy tryptamine (5‐MeO‐DALT) and 5‐methoxy‐N‐methyl‐N‐isoporpoyltryptamine (5‐MeO‐MiPT)] in C. elegans after incubation for 72 hours. Metabolites were identified using liquid chromatography–high resolution–tandem mass spectrometry (LC–HR–MS/MS) with a quadrupole time‐of‐flight (QqTOF) instrument. Results were compared to already published data on these substances. C. elegans was capable of producing all major biotransformation steps: hydroxylation, N‐oxide formation, carboxylation, deamination, and demethylation. On average 63% of phase I metabolites found in the literature could also be detected in C. elegans. Additionally, metabolites specific for C. elegans were identified. Therefore, C. elegans is a suitable complementary model to other in vitro or in vivo methods to study the metabolism of naturally occurring or synthetic tryptamines.
Synergieprognosen spielen bei der Begründung von Unternehmensübernahmen regelmäßig eine wichtige Rolle. Da diese Prognosen unsicher sind, bedürfen sie einer fundierten Beurteilung, was wiederum eine offene Diskussion innerhalb von Vorstand und Aufsichtsrat voraussetzt. Solche Diskussionen sind jedoch keine Selbstverständlichkeit, da Gruppen dazu neigen, problematische Entscheidungsaspekte nicht angemessen zu würdigen. Mit dem Tornado-Diagramm wird ein Instrument vorgestellt, das diesem Effekt entgegenwirkt und die Entscheider dazu motiviert, auch ungünstige Synergieprognosen zu diskutieren. Auf diese Weise kann die Übernahmeentscheidung auf eine bessere Informationsgrundlage gestellt werden.
Zielvereinbarungen sollen SMART formuliert werden, um die Leistungsbereitschaft von Mitarbeitern optimal zu fördern - so wird es zumindest in der praxisorientierten betriebswirtschaftlichen Literatur propagiert. Ob Zielvereinbarungen, die spezifisch, messbar, erreichbar, relevant für das Unternehmen und zeitlich terminiert sind, wirklich eine höhere Leistungsbereitschaft zur Folge haben, wird im Folgenden auf Basis einer empirischen Untersuchung überprüft.
Die Rolle des Aufsichtsrats wird zunehmend als eine strategische charakterisiert, ohne dies jedoch näher zu erläutern. Die aktuelle Diskussion zeigt, dass daraus Unschärfen in der Abgrenzung zur Rolle des Vorstands resultieren. In dem Beitrag wird die Rolle des Aufsichtsrats im Rahmen strategischer Entscheidungen präzisiert.
Lithium-oxygen cells with organic electrolyte suffer high overpotentials during charge, indicating asymmetric charge/discharge reaction mechanisms. We present a multi-physics dynamic modeling and simulation study of the Li/O2 cell cycling behavior. We present three different multi-step mechanisms of the 2 Li + O2 ⇄ Li2O2 cell reaction, (A) a reversible 5-step mechanism, (B) a partially irreversible 6-step mechanism, and (C) a partially irreversible 8-step mechanism that includes reactions of a redox mediator. Model predictions are compared to experimental galvanostatic cycling data of Swagelok cells without and with 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) as redox mediator. All mechanisms are able to predict the discharge behavior in good agreement to the experimental results. The experimentally observed high charge overpotentials as well as their reduction by using a redox mediator can be qualitatively reproduced with the irreversible reaction mechanisms. However, the particular shape of the experimental charge curve with continuously increasing charge overpotential cannot be reproduced with the present mechanisms.
Lithium–oxygen cells with nonaqueous electrolyte show high overpotentials during charge, indicating asymmetric charge/discharge reaction mechanisms. We present a kinetic modeling and simulation study of the lithium–oxygen cell cycling behavior. The model includes a multistep reaction mechanism of the cell reaction (2Li + O2 ⇄ Li2O2) forming lithium peroxide by precipitation, coupled to a 1D porous-electrode transport model. We apply the model to study the asymmetric discharge/charge characteristics and analyze the influence of a redox mediator dissolved homogeneously in the liquid electrolyte. Model predictions are compared to experimental galvanostatic cycling data of cells without and with 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) as redox mediator. The predicted discharge behavior shows good agreement with the experimental results. A spatiotemporal analysis of species concentrations reveals inhomogeneous distributions of dissolved oxygen and reaction products within the cathode during discharge. The experimentally observed charge overpotentials as well as their reduction by using a redox mediator can be qualitatively reproduced with a partially irreversible reaction mechanism. However, the proposed models fail to reproduce the particular shape of the experimental charge curve with continuously increasing charge overpotential, which implies that part of the reaction mechanism is still open for investigation in future work.
Seven cell design concepts for aqueous (alkaline) lithium–oxygen batteries are investigated using a multi-physics continuum model for predicting cell behavior and performance in terms of the specific energy and specific power. Two different silver-based cathode designs (a gas diffusion electrode and a flooded cathode) and three different separator designs (a porous separator, a stirred separator chamber, and a redox-flow separator) are compared. Cathode and separator thicknesses are varied over a wide range (50 μm–20 mm) in order to identify optimum configurations. All designs show a considerable capacity-rate effect due to spatiotemporally inhomogeneous precipitation of solid discharge product LiOH·H2O. In addition, a cell design with flooded cathode and redox-flow separator including oxygen uptake within the external tank is suggested. For this design, the model predicts specific power up to 33 W/kg and specific energy up to 570 Wh/kg (gravimetric values of discharged cell including all cell components and catholyte except housing and piping).
Electrochemical impedance spectroscopy (EIS) is a widely-used diagnostic technique to characterize electrochemical processes. It is based on the dynamic analysis of two electrical observables, that is, current and voltage. Electrochemical cells with gaseous reactants or products (e.g., fuel cells, metal/air cells, electrolyzers) offer an additional observable, that is, the gas pressure. The dynamic coupling of current and/or voltage with gas pressure gives rise to a number of additional impedance definitions, for which we use the term electrochemical pressure impedance. It also gives rise to different experimental probing approaches. In this article we present a model-based study of electrochemical pressure impedance spectroscopy (EPIS). Possible quantifications and realizations of EPIS are discussed. The study of generic cell geometries consisting of gas reservoir, diffusion layer(s) and electrochemically active layer(s) reveals distinct spiral-shaped features in the Nyquist plot. Using the example of a sodium/oxygen (Na/O2) cell, the dynamic spatiotemporal behavior of the state variables is quantified and interpreted. Results are compared to first experimental EPIS measurements by Hartmann et al. [J. Phys. Chem. C118, 1461, 2014]. A sensitivity analysis highlights the properties of EPIS with respect to geometric, transport, and kinetic parameters. We demonstrate that EPIS is sensitive to transport parameters that are not well-accessible with standard EIS.
We report improved separation of the highly toxic contact herbicides paraquat, diquat, difenzoquat, mepiquat, and chloromequat by HPTLC. Quantification was based on a new derivatization reaction using sodium tetraphenylborate. Measurements were in the wavelength range from 440 to 480 nm or from 440 to 590 nm. An LED emitting very intense light at 365 nm was used for excitation. The quantification limits of paraquat and diquat in water, using improved solid-phase extraction, was in the low ng L −1 range. The linear range covered more than two orders of magnitude. Recovery was investigated for all the compounds, and was insufficient, ranging from 11 to 92%, but the method is inexpensive, rapid, and works reliably.