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Gas adsorption studies of CO2 and N2 in spatially aligned double-walled carbon nanotube arrays
(2013)
Gas adsorption studies (CO2 and N2) over a wide pressure range on vertically, highly aligned dense double-walled carbon nanotube arrays of high purity and high specific surface area are reported. At high pressures, the adsorption capacity of these materials was found to be comparable to those of metal organic frameworks and mesoporous molecular sieves. These highly aligned CNT arrays were chemically modified by treating with oxygen plasma and structurally modified by decreasing the diameter of individual carbon nanotubes. Oxygen plasma treatment led to grafting of a large number of C–O functional groups onto the CNT surface, which further increased the gas adsorption capacity. It was found that gas adsorption is dependent on tube diameter and increases with decrease of the individual CNT diameter in the CNT bundles. As results of our studies we have found that at lower pressure regimes, plasma functionalized carbon nanotubes exhibit better adsorption characteristics whereas at higher pressures, lower diameter carbon nanotube structures exhibited better gas adsorption characteristics.
Many different methods, such as screen printing, gravure, flexography, inkjet etc., have been employed to print electronic devices. Depending on the type and performance of the devices, processing is done at low or high temperature using precursor- or particle-based inks. As a result of the processing details, devices can be fabricated on flexible or non-flexible substrates, depending on their temperature stability. Furthermore, in order to reduce the operating voltage, printed devices rely on high-capacitance electrolytes rather than on dielectrics. The printing resolution and speed are two of the major challenging parameters for printed electronics. High-resolution printing produces small-size printed devices and high-integration densities with minimum materials consumption. However, most printing methods have resolutions between 20 and 50 μm. Printing resolutions close to 1 μm have also been achieved with optimized process conditions and better printing technology.
The final physical dimensions of the devices pose severe limitations on their performance. For example, the channel lengths being of this dimension affect the operating frequency of the thin-film transistors (TFTs), which is inversely proportional to the square of channel length. Consequently, short channels are favorable not only for high-frequency applications but also for high-density integration. The need to reduce this dimension to substantially smaller sizes than those possible with today’s printers can be fulfilled either by developing alternative printing or stamping techniques, or alternative transistor geometries. The development of a polymer pen lithography technique allows scaling up parallel printing of a large number of devices in one step, including the successive printing of different materials. The introduction of an alternative transistor geometry, namely the vertical Field Effect Transistor (vFET), is based on the idea to use the film thickness as the channel length, instead of the lateral dimensions of the printed structure, thus reducing the channel length by orders of magnitude. The improvements in printing technologies and the possibilities offered by nanotechnological approaches can result in unprecedented opportunities for the Internet of Things (IoT) and many other applications. The vision of printing functional materials, and not only colors as in conventional paper printing, is attractive to many researchers and industries because of the added opportunities when using flexible substrates such as polymers and textiles. Additionally, the reduction of costs opens new markets. The range of processing techniques covers laterally-structured and large-area printing technologies, thermal, laser and UV-annealing, as well as bonding techniques, etc. Materials, such as conducting, semiconducting, dielectric and sensing materials, rigid and flexible substrates, protective coating, organic, inorganic and polymeric substances, energy conversion and energy storage materials constitute an enormous challenge in their integration into complex devices.
The suffix-free-prefix-free hash function construction and its indifferentiability security analysis
(2012)
In this paper, we observe that in the seminal work on indifferentiability analysis of iterated hash functions by Coron et al. and in subsequent works, the initial value (IV) of hash functions is fixed. In addition, these indifferentiability results do not depend on the Merkle–Damgård (MD) strengthening in the padding functionality of the hash functions. We propose a generic n-bit-iterated hash function framework based on an n-bit compression function called suffix-free-prefix-free (SFPF) that works for arbitrary IVs and does not possess MD strengthening. We formally prove that SFPF is indifferentiable from a random oracle (RO) when the compression function is viewed as a fixed input-length random oracle (FIL-RO). We show that some hash function constructions proposed in the literature fit in the SFPF framework while others that do not fit in this framework are not indifferentiable from a RO. We also show that the SFPF hash function framework with the provision of MD strengthening generalizes any n-bit-iterated hash function based on an n-bit compression function and with an n-bit chaining value that is proven indifferentiable from a RO.
Um Simulationen schnell und kostengünstig sowie ergebnisträchtig durchzuführen, bedarf es einer sorgfältigen Vorbereitung. Der Artikel befaßt sich mit dem automatischen Ablauf einer Simulationstudie zum Materilafluß und erläutert die im Ablauf notwendigen Beiträge der Anwender. In den Einzelheiten wird über die automatische Vorgehensweise und Anwendung der Standard-Simulationsmodelle (SSM) sowie spezieller Simulationsmodule (SimDBC) berichtet. Entscheidend für eine breitere Anwendung von Simulationswerkzeugen ist die einfache Handhabung und leicht verständliche Definition der zu untersuchenden Szenarien.
This paper presents a system that uses a multi-stage AI analysis method for determining the condition and status of bicycle paths using machine learning methods. The approach for analyzing bicycle paths includes three stages of analysis: detection of the road surface, investigation of the condition of the bicycle paths, and identification of substrate characteristics. In this study, we focus on the first stage of the analysis. This approach employs a low-threshold data collection method using smartphone-generated video data for image recognition, in order to automatically capture and classify surface condition and status.
For the analysis convolutional neural networks (CNN) are employed. CNNs have proven to be effective in image recognition tasks and are particularly well-suited for analyzing the surface condition of bicycle paths, as they can identify patterns and features in images. By training the CNN on a large dataset of images with known surface conditions, the network can learn to identify common features and patterns and reliably classify them.
The results of the analysis are then displayed on digital maps and can be utilized in areas such as bicycle logistics, route planning, and maintenance. This can improve safety and comfort for cyclists while promoting cycling as a mode of transportation. It can also assist authorities in maintaining and optimizing bicycle paths, leading to more sustainable and efficient transportation system.
Since their dawning, space communications have been among the strongest driving applications for the development of error correcting codes. Indeed, space-to-Earth telemetry (TM) links have extensively exploited advanced coding schemes, from convolutional codes to Reed-Solomon codes (also in concatenated form) and, more recently, from turbo codes to low-density parity-check (LDPC) codes. The efficiency of these schemes has been extensively proved in several papers and reports. The situation is a bit different for Earth-to-space telecommand (TC) links. Space TCs must reliably convey control information as well as software patches from Earth control centers to scientific payload instruments and engineering equipment onboard (O/B) spacecraft. The success of a mission may be compromised because of an error corrupting a TC message: a detected error causing no execution or, even worse, an undetected error causing a wrong execution. This imposes strict constraints on the maximum acceptable detected and undetected error rates.
NEXCODE is a project promoted by the European Space Agency aimed at research design development and demonstration of a receiver chain for telecomm and links in space missions including the presence of new short low-density parity-check codes for error correction. These codes have excellent performance from the error rate viewpoint but also put new challenges as regards synchronization issues and implementation. In this paper after a short review of the results obtained through numerical simulations we present an overview of the breadboard designed for practical testing and the test-plan proposed for the verification of the breadboard and the validation of the new codes and novel synchronization techniques under relevant operation conditions.
Crowdinvesting als alternative Unternehmensfinanzierung - Grundlagen und Marktdaten in Deutschland
(2015)
Interne Revision: Anforderungen an die Wirksamkeit – ein Vergleich von IDW EPS 983 und MaRisk
(2017)
The invention relates to the field of transporting flat substrates such as silicon substrates. In particular, the invention relates to particularly protective and continuous transport of such substrates. The method according to the invention is used to transport a vertically aligned flat substrate (1) comprising two flat sides in a transport direction inside a transport channel (2) that is at least partially filled with a liquid medium (F), wherein said liquid medium (F) flows against at least one of the flat sides of the substrate (1) and has a supporting component, which lifts the sum of the weight and buoyancy force of the substrate (1), and an advancing component, which is directed in the transport direction, so that the substrate (1) is supported and transported without mechanical aids. The device according to the invention comprises a transport channel (2) for accommodating a liquid medium (F) and a substrate (1) to be guided in vertical alignment within said medium (F), wherein the transport channel (2) has inflow openings (5) in the walls (3, 4).
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
A two-dimensional single-phase model is developed for the steady-state and transient analysis of polymer electrolyte membrane fuel cells (PEMFC). Based on diluted and concentrated solution theories, viscous flow is introduced into a phenomenological multi-component modeling framework in the membrane. Characteristic variables related to the water uptake are discussed. A Butler–Volmer formulation of the current-overpotential relationship is developed based on an elementary mechanism of electrochemical oxygen reduction. Validated by using published V–I experiments, the model is then used to analyze the effects of operating conditions on current output and water management, especially net water transport coefficient along the channel. For a power PEMFC, the long-channel configuration is helpful for internal humidification and anode water removal, operating in counterflow mode with proper gas flow rate and humidity. In time domain, a typical transient process with closed anode is also investigated.
The state-of-the-art electrochemical impedance spectroscopy (EIS) calculations have not yet started from fully multi-dimensional modeling. For a polymer electrolyte membrane fuel cell (PEMFC) with long flow channel, the impedance plot shows a multi-arc characteristic and some impedance arcs could merge. By using a step excitation/Fourier transform algorithm, an EIS simulation is implemented for the first time based on the full 2D PEMFC model presented in the first part of this work. All the dominant transient behaviors are able to be captured. A novel methodology called ‘configuration of system dynamics’, which is suitable for any electrochemical system, is then developed to resolve the physical meaning of the impedance spectra. In addition to the high-frequency arc due to charge transfer, the Nyquist plots contain additional medium/low-frequency arcs due to mass transfer in the diffusion layers and along the channel, as well as a low-frequency arc resulting from water transport in the membrane. In some case, the impedance spectra appear partly inductive due to water transport, which demonstrates the complexity of the water management of PEMFCs and the necessity of physics-based calculations.
Synthesizing voice with the help of machine learning techniques has made rapid progress over the last years [1]. Given the current increase in using conferencing tools for online teaching, we question just how easy (i.e. needed data, hardware, skill set) it would be to create a convincing voice fake. We analyse how much training data a participant (e.g. a student) would actually need to fake another participants voice (e.g. a professor). We provide an analysis of the existing state of the art in creating voice deep fakes and align the identified as well as our own optimization techniques in the context of two different voice data sets. A user study with more than 100 participants shows how difficult it is to identify real and fake voice (on avg. only 37 percent can recognize a professor’s fake voice). From a longer-term societal perspective such voice deep fakes may lead to a disbelief by default.
Synthesizing voice with the help of machine learning techniques has made rapid progress over the last years. Given the current increase in using conferencing tools for online teaching, we question just how easy (i.e. needed data, hardware, skill set) it would be to create a convincing voice fake. We analyse how much training data a participant (e.g. a student) would actually need to fake another participants voice (e.g. a professor). We provide an analysis of the existing state of the art in creating voice deep fakes and align the identified as well as our own optimization techniques in the context of two different voice data sets. A user study with more than 100 participants shows how difficult it is to identify real and fake voice (on avg. only 37% can recognize a professor’s fake voice). From a longer-term societal perspective such voice deep fakes may lead to a disbelief by default.
This work provides a series of methane adsorption isotherms and breakthrough curves on one 5A zeolite and one activated carbon. Breakthrough curves of CH4 were obtained from dynamic column measurements at different temperature and pressure conditions for concentrations of 4.4 – 17.3 mol.‐% in H2/CH4 mixtures. A simple model was developed to simulate the curves using measured and calculated data inputs. The results show that the model predictions agree very well with the experiments.
The separation of nitrogen and methane from hydrogen-rich mixtures is systematically investigated on a recently developed binder-free zeolite 5A. For this adsorbent, the present work provides a series of experimental data on adsorption isotherms and breakthrough curves of nitrogen and methane, as well as their mixtures in hydrogen. Isotherms were measured at temperatures of 283–313 K and pressures of up to 1.0 MPa. Breakthrough curves of CH4, N2, and CH4/N2 in H2 were obtained at temperatures of 300–305 K and pressures ranging from 0.1 to 6.05 MPa with different feed concentrations. An LDF-based model was developed to predict breakthrough curves using measured and calculated data as inputs. The number of parameters and the use of correlations were restricted to focus on the importance of measured values. For the given assumptions, the results show that the model predictions agree satisfactorily with the experiments under the different operating conditions applied.
Regarding the importance of adsorptive removal of carbon monoxide from hydrogen-rich mixtures for novel applications (e.g. fuel cells), this work provides a series of experimental data on adsorption isotherms and breakthrough curves of carbon monoxide. Three recently developed 5A zeolites and one commercial activated carbon were used as adsorbents. Isotherms were measured gravimetrically at temperatures of 278–313 K and pressures up to 0.85 MPa. Breakthrough curves of CO were obtained from dynamic column measurements at temperatures of 298–301 K, pressures ranging from 0.1 MPa to ca. 6 MPa and concentrations of CO in H2/CO mixtures of 5–17.5 mol%. A simple mathematical model was developed to simulate breakthrough curves on adsorbent beds using measured and calculated data as inputs. The number of parameters and the use of correlations to evaluate them were restricted in order to focus the importance of measured values. For the given assumptions and simplifications, the results show that the model predictions agree satisfactorily with the experimental data at the different operating conditions applied.
As a basis for the evaluation of hydrogen storage by physisorption, adsorption isotherms of H2 were experimentally determined for several porous materials at 77 K and 298 K at pressures up to 15 MPa. Activated carbons and MOFs were studied as the most promising materials for this purpose. A noble focus was given on how to determine whether a material is feasible for hydrogen storage or not, dealing with an assessment method and the pitfalls and problems of determining the viability. For a quantitative evaluation of the feasibility of sorptive hydrogen storage in a general analysis, it is suggested to compare the stored amount in a theoretical tank filled with adsorbents to the amount of hydrogen stored in the same tank without adsorbents. According to our results, an “ideal” sorbent for hydrogen storage at 77 K is calculated to exhibit a specific surface area of >2580 m2 g−1 and a micropore volume of >1.58 cm3 g−1.
In der genossenschaftlichen FinanzGruppe werden neben Verbundunternehmen wie zum Beispiel der DZ Bank rund 45 bis 50 Genossenschaftsbanken von der künftigen Berichtspflicht nach der sogenannten CSR-Richtlinie betroffen sein. Dieser Artikel gibt Hinweise zu Auswirkungen der neuen Gesetzeslage, aber auch zu Chancen und Potenzialen. Diskutiert wird insbesondere, was das neue Gesetz bzw. der Regierungsentwurf von 2016 besagt, und was die Vorgaben konkret für Genossenschaftsbanken bedeuten. Der Beitrag diskutiert zudem Synergien, Chancen und Potenziale: Das Thema Nachhaltigkeit kann wertvolle Impulse für eine zielgerichtete Weiterentwicklung des eigenen Geschäftsmodells bieten, beispielsweise wie neue Kundengruppen und/oder neue Ertragspotenziale mit Hilfe von neuen Produkten beziehungsweise Geschäftsfeldern erschlossen werden können.
Sowohl die Entwicklung neuer als auch die Weiterentwicklung bestehender Quartiere sind mit vielfältigen Herausforderungen verbunden. Durch weitere Klimaschutzmaßnahmen und ein zunehmendes Umweltbewusstsein steigen die energetischen Anforderungen an Wohn- und Gewerbeimmobilien. Die besonders für Deutschland ungünstige demografische Entwicklung bedingt eine weiter zunehmende Urbanisierung, bedingt durch Migration und Zuzug älterer Menschen in Städte, die künftig noch mehr altersgerechte Wohnungen und Pflegeeinrichtungen etablieren müssen. Hinzu kommen die steigenden Anforderungen aus der digitalen Transformation und einer Informationsgesellschaft, die sich mit Konnektivität, Schnelllebigkeit, Individualisierungstendenzen und veränderten Konsumgewohnheiten auseinandersetzen muss.
Die Coronakrise hat weltweit das Wirtschafts- und Gesellschaftsleben in bisher ungekannter Weise verändert. Die ohnehin bereits komplexen Herausforderungen in Zeiten des Klimawandels sind damit noch gestiegen. Genossenschaftliche Innovationsökosysteme können Lösungsansätze für die gravierenden Veränderungen im unternehmerischen, kommunalen und gesellschaftlichen Umfeld schaffen.
Eine Mitte November veröffentlichte EU-Richtlinie sieht vor, dass ab 2017 Unternehmen mit durchschnittlich mehr als 500 Mitarbeitern bestimmte Nachhaltigkeitsangaben im Lagebericht veröffentlichen müssen. Auf den ersten Blick scheint hier weiterer administrativer Ballast für die wenigen betroffenen Genossenschaftsbanken zu entstehen. Doch daraus ergeben sich für die Institute auch Chancen. Es lohnt sich zu prüfen, ob ein aktives Nachhaltigkeitsmanagement sinnvoll erscheint.
Nachhaltigkeit in der DNA
(2014)
Der demografische Wandel wird betriebs- und volkswirtschaftlich vielfach mit dem Fachkräftemangel in Zusammenhang gebracht. Diese Sichtweise scheint jedoch verkürzt. Die Alterung der Gesellschaft wird die Geschäftsmodelle von Finanzdienstleistern in den nächsten Jahren auf den Prüfstand stellen. Dies gilt vor allem für regionalverankerte Institute. Ein frühzeitiges Gegensteuern auf den Ebenen Strategie, Kunden- und Mitgliederstruktur, Produktportfolio sowie Marketing und Vertrieb kann jedoch den Markterfolg langfristig sichern.
Sind Mitglieder eine aussterbende Spezies? Der demografische Wandel zeigt dringenden Handlungsbedarf
(2012)
Wurzeln, Werte und Visionen
(2018)
Massive Umwälzungen im Marktumfeld, verstärkt durch disruptive Technologien, stellen viele Unternehmen vor die existenzielle Frage, wie sie ihr etabliertes Geschäftsmodell zukunftsfähig weiterentwickeln können beziehungsweise wie sie sich unter Umständen grundlegend neu aufstellen müssen. Volatilität, Unsicherheit, Komplexität und Ambiguität (kurz VUKA) sind in diesem Kontext jene ungünstigen Begleiterscheinungen, die auch genossenschaftliche Unternehmen beeinflussen. Die vielfältigen Herausforderungen im Unternehmensumfeld, wie beispielsweise ungünstige demografische Entwicklungen, eine zunehmende Urbanisierung bei steigendem Bedarf an regionaler Daseinsvorsorge, Wettbewerbsdruck durch neue Geschäftsmodelle und Konkurrenten infolge der Künstlichen Intelligenz beziehungsweise Digitalisierung – zum Beispiel durch FinTechs – bedingen die Suche nach Orientierung, nach einem strategischen Kompass sowohl für Politik, Wirtschaft und Gesellschaft.