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Multi-phase management is crucial for performance and durability of electrochemical cells such as batteries and fuel cells. In this paper we present a generic framework for describing the two-dimensional spatiotemporal evolution of gaseous, liquid and solid phases, as well as their interdependence with interfacial (electro-)chemistry and microstructure in a continuum description. The modeling domain consists of up to seven layers (current collectors, channels, electrodes, separator/membrane), each of which can consist of an arbitrary number of bulk phases (gas, liquid, solid) and connecting interfaces (two-phase or multi-phase boundaries). Bulk and interfacial chemistry is described using global or elementary kinetic reactions. Multi-phase management is coupled to chemistry and to mass and charge transport within bulk phases. The functionality and flexibility of this framework is demonstrated using four application areas in the context of post-lithium-ion batteries and fuel cells, that is, lithium-sulfur (Li-S) cells, lithium-oxygen (Li-O) cells, solid oxide fuel cells (SOFC) and polymer electrolyte membrane fuel cells (PEFC). The results are compared to models available in literature and properties of the generic framework are discussed.
In this paper, the multiaxial formulation of a mechanism-based model for fatigue life prediction is presented whichcan be applied to low-cycle fatigue (LCF) and thermomechanical fatigue (TMF) problems in which high-cycle fa-tigue loadings are superimposed. The model assumes that crack growth is the lifetime limiting mechanism and thatthe crack advance in a loading cycleda/dNcorrelates with the cyclic crack-tip opening displacement ΔCTOD.The multiaxial formulation makes use of fracture mechanics solutions and thus, does not need additional modelparameters quantifying the effect of the multiaxiality. Furthermore, the model includes contributions of HCF on ΔCTODand assesses the effect of the direction of the HCF loadings with respect to LCF or TMF loadings inthe life prediction. The model is implemented into the finite-element program ABAQUS. It is applied to predictthe fatigue life of a thermomechanically loaded notched specimen that should represent the situation between theinlet and outlet bore holes of cylinder heads. A good correlation of the predicted and the measured fatigue lives isobtained.
The newly synthesized Zn4O-based MOF 3∞[Zn4(μ4-O){(Metrz-pba)2mPh}3]·8 DMF (1·8 DMF) of rare tungsten carbide (acs) topology exhibits a porosity of 43% and remarkably high thermal stability up to 430 °C. Single crystal X-ray structure analyses could be performed using as-synthesized as well as desolvated crystals. Besides the solvothermal synthesis of single crystals a scalable synthesis of microcrystalline material of the MOF is reported. Combined TG-MS and solid state NMR measurements reveal the presence of mobile DMF molecules in the pore system of the framework. Adsorption measurements confirm that the pore structure is fully accessible for nitrogen molecules at 77 K. The adsorptive pore volume of 0.41 cm3 g−1 correlates well with the pore volume of 0.43 cm3 g−1 estimated from the single crystal structure.
In this paper, a complete passive transponder device has been discussed which is meant to monitor leakage in silicone breast implants. The passive tag operates in the HF frequency range of 13.56MHz using RFID ISO 15693 standard. The complete system consists of the transponder, reader and a PC. This paper focusses on the development of such a state of the art passive RFID transponder to monitor the wellness of the silicone breast implants periodically in order to detect leakage in the same. Keyword: RFID (Radio frequency identification device), EM (Electromagnetic) field, Passive Transponder, Silicone breast implants.
An isomorphous series of 10 microporous copper-based metal–organic frameworks (MOFs) with the general formulas ∞3[{Cu3(μ3-OH)(X)}4{Cu2(H2O)2}3(H-R-trz-ia)12] (R = H, CH3, Ph; X2– = SO42–, SeO42–, 2 NO32– (1–8)) and ∞3[{Cu3(μ3-OH)(X)}8{Cu2(H2O)2}6(H-3py-trz-ia)24Cu6]X3 (R = 3py; X2– = SO42–, SeO42– (9, 10)) is presented together with the closely related compounds ∞3[Cu6(μ4-O)(μ3-OH)2(H-Metrz-ia)4][Cu(H2O)6](NO3)2·10H2O (11) and ∞3[Cu2(H-3py-trz-ia)2(H2O)3] (12Cu), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.
Angedockt und eingeloggt
(2012)
Since cabling is very complex and often causes reliability problems in aircrafts new approaches which base on wireless technologies are highly desired. In this paper an innovative communication system is proposed that uses the essential elements of the airframe for data transfer. The communication is based on the wireless standard for Digital Video Broadcasting (DVB) and enables high data rates, which are required for the in-flight entertainment system as an example of use.
Today's network landscape consists of many different network technologies, a wide range of end-devices with a large scale of capabilities and power, and an immense quantity of information and data represented in different formats. Research on 3D imaging, virtual reality and holographic techniques will result in new user interfaces (UI) for mobile devices and will increase their diversity and variety. In this paper software architecture has been proposed to establish device and content format independent communication, implemented in Language Learning Game (LLG).
The applicability of finite elements for molecular dynamic simulations depends on both the structure’s dimensions and the underlying force field type. Shell and continuum elements describe molecular structures only in an average sense, which is why they are not subject of this paper. In contrast, truss and beam elements are potentially attractive candidates when it comes to accurately reproducing the atomic interactions. However, special considerations are required for force fields that use not only two-body, but also multi-body potentials. For the example of bending and torsion energies it is shown how standard beam element models have to be extended to be equivalent to classical molecular dynamic simulations.
As a basis for the evaluation of hydrogen storage by physisorption, adsorption isotherms of H2 were experimentally determined for several porous materials at 77 K and 298 K at pressures up to 15 MPa. Activated carbons and MOFs were studied as the most promising materials for this purpose. A noble focus was given on how to determine whether a material is feasible for hydrogen storage or not, dealing with an assessment method and the pitfalls and problems of determining the viability. For a quantitative evaluation of the feasibility of sorptive hydrogen storage in a general analysis, it is suggested to compare the stored amount in a theoretical tank filled with adsorbents to the amount of hydrogen stored in the same tank without adsorbents. According to our results, an “ideal” sorbent for hydrogen storage at 77 K is calculated to exhibit a specific surface area of >2580 m2 g−1 and a micropore volume of >1.58 cm3 g−1.
Die Erfindung betrifft ein Behältnis (1) für ein flüssiges Medium (3), insbesondere Blutbeutel, mit einer flexiblen Außenwandung (5) und einer mit dem Behältnis (1) verbundenen Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten. Erfindungsgemäß ist die Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten innerhalb der flexiblen Außenwandung (5) angeordnet, wobei Positionierungsmittel (15) vorgesehen sind, welche die Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten bei mit dem flüssigen Medium (3) gefüllten Behältnis (1) schwimmend im flüssigen Medium (3) halten, und wobei die Vorrichtung (13) oder die Vorrichtung (13) und die Positionierungsmittel (15) so ausgebildet sind, dass die jeweils verdrängte Masse von flüssigem Medium (3) im Wesentlichen gleich der Masse der Vorrichtung (13) oder der Masse der Vorrichtung (13) und der Positionierungsmittel (15) ist.
Die Erfindung betrifft ein Behältnis (1) für ein flüssiges Medium (3), insbesondere Blutbeutel, mit einer flexiblen Außenwandung (5) und einer mit dem Behältnis (1) verbundenen Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten. Erfindungsgemäß ist die Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten innerhalb der flexiblen Außenwandung (5) angeordnet, wobei Positionierungsmittel (15) vorgesehen sind, welche die Vorrichtung (13) zur Erfassung und/oder Speicherung von Daten bei mit dem flüssigen Medium (3) gefüllten Behältnis (1) schwimmend im flüssigen Medium (3) halten, und wobei die Vorrichtung (13) oder die Vorrichtung (13) und die Positionierungsmittel (15) so ausgebildet sind, dass die jeweils verdrängte Masse von flüssigem Medium (3) im Wesentlichen gleich der Masse der Vorrichtung (13) oder der Masse der Vorrichtung (13) und der Positionierungsmittel (15) ist.
Buildings that are cooled and, if applicable, heated by thermo-active building systems (TABS) in combination with environmental energy have been established in the market during the last years. Many successful and efficient examples prove, that these systems can achieve a good thermal room comfort with a high energy efficiency of the plant system using environmental energy (mainly surface-near geothermal energy). However, operating experience and a systematic evaluation of several building projects demonstrate that there is potential improvement in the design, implementation, and operation of TABS systems. The article presents operating experience and a detailed evaluation of the operation performance of several non-residential buildings with thermo-active building systems with respect to thermal comfort and energy efficiency.
BFH "Umsatzsteuer bei ebay"
(2012)
BGH "Computer-Bild"
(2012)
BGH "Postfachanschrift"
(2012)
BGH Insertionsofferte
(2012)
BGH regierung-oberfranken.de
(2012)
The following paper presents the results of a feasibility study about Bluetooth Low Energy (BLE) based wireless sensors. The development of industrial wireless sensors leads to important demands for the wireless technologies like a low energy consumption and a resource saving simple protocol stack. Bluetooth Low Energy (BLE) is a rather new wireless standard which will completely fulfill these fundamental requirements. A self-designed BLE sensor system has been used to explore the common applicability of BLE for wireless sensor systems. The evaluation results of various analyses with the BLE sensor system are now presented in this paper.
Currently, QRS width and bundle branch block morphology are used as electrocardiographic guideline criterias to selectheart failure (HF) patients with interventricular desynchronization in sinus rhythm (SR) for cardiac resynchronisationtherapy (CRT). Nevertheless, up to 30% of these patients do not benefit from implantation of CRT systems. Esophagealleft ventricular electrogram (LVE) enables semi-invasive measurement of interventricular conduction delays (IVCD)even in patients with atrial fibrillation (AF). To routinely apply this method, a programmer based semi-invasiveautomatic quantification of IVCD should to be developed. Our aims were todefine interventricular conduction delaysby analyzing fractionated left ventricular (LV) deflections in the esophageal left ventricular electrogram of HF patientsin SR or AF.
In 66 HF patients (49 male,17 female, age 65 ± 10 years) a 5F TOslim electrode (Osypka AG, Germany) was perorallyapplied. Using BARD EP Lab, cardiac desynchronization was quantified as interval IVCD between onset of QRS insurface ECG and the investigator-determined onset of the left ventricular deflection in LVE. IVCD was compared withthe intervals between QRS onset and the first maximum (IVCDm1) and between QRS onset and the second maximum(IVCDm2) of the LV complex.
QRS of 173 ± 26 ms was linked with empirical IVCD of 75 ± 25 ms, at mean. First and second LV maximum could beascertained beyond doubt in all patients. Significant correlations of the p<0,01 level were found between IVCD and theIVCDm1 of 96 ± 28 ms as well as between IVCD and the IVCDm2 of 147 ± 31 ms, at mean. To standardize automatic measurement of interventricular conduction delays with respect to patients with fractionatedLV complexes, the first maximum of the LV deflection should be utilized to qualify the IVCD of HF patients with sinusrhythm and atrial fibrillation.
There is an increasing demand by an ever-growing number of mobile customers for transfer of rich media content. This requires very high bandwidth which either cannot be provided by the current cellular systems or puts pressure on the wireless networks, affecting customer service quality. This study introduces COARSE – a novel cluster-based quality-oriented adaptive radio resource allocation scheme, which dynamically and adaptively manages the radio resources in a cluster-based two-hop multi-cellular network, having a frequency reuse of one. COARSE is a cross-layer approach across physical layer, link layer and the application layer. COARSE gathers data delivery-related information from both physical and link layers and uses it to adjust bandwidth resources among the video streaming end-users. Extensive analysis and simulations show that COARSE enables a controlled trade-off between the physical layer data rate per user and the number of users communicating using a given resource. Significantly, COARSE provides 25–75% improvement in the computed user-perceived video quality compared with that obtained from an equivalent single-hop network.
In sicherheitskritschen Systemen darf kein Stück Code im Produktionsbetrieb ablaufen, ohne vorher intensive Tests durchlaufen zu haben. Aber auch zur Qualitätssicherung muss Software getestet werden. Um die Codeüberdeckung zu prüfen, sind zusätzliche Prüf-Instruktionen im Quellcode erforderlich. Auf kleinen Systemen mit wenig RAM kann sich der Entwickler dann etwas einfallen lassen, damit das funktioniert.
The invention relates to a container (1) for a liquid medium (3), in particular a blood bag, comprising a flexible outer wall (5) and a device (13) connected to the container (1) for acquiring and/or storing data. According to the invention, the device (13) for acquiring and/or storing data is arranged within the flexible outer wall (5), wherein positioning means (15) are provided which hold the device (13) for acquiring and/or storing data in a floating manner in the liquid medium when the container (1) is filled with said liquid medium (3), and wherein the device (13) or the device (13) and the positioning means (15) are designed such that the mass of liquid medium (3) which is displaced in each case is essentially equal to the mass of the device (13) or to the mass of the device (13) and the positioning means (15).
Power systems are increasingly built from distributed generation units and smart consumers that are able to react to grid conditions. Managing this large number of decentralized electricity sources and flexible loads represent a very huge optimization problem. Both from the regulatory and the computational perspective, no one central coordinator can optimize this overall system. Decentralized control mechanisms can, however, distribute the optimization task through price signals or market-based mechanisms. This chapter presents the concepts that enable a decentralized control of demand and supply while enhancing overall efficiency of the electricity system. It highlights both technological and business challenges that result from the realization of these concepts, and presents the state-of-the-art in the respective domains.
This paper analyzes the applicability of existing communication technology on the Smart Grid. In particular it evaluates how networks, e.g. Peer-to-Peer (P2P) and decentralized Virtual Private Network (VPN) can help set up an agent-based system. It is expected that applications on Smart Grid devices will become more powerful and be able to operate without a central control instance. We analyze which requirements agents and Smart Grid devices place on communication systems and validate promising approaches. The main focus is to create a logical overlay network that provides direct communication between network nodes. We provide a comparison of different approaches of P2P networks and mesh-VPNs. Finally the advantages of mesh-VPN for agent-based systems are worked out.
Die Weltwirtschaftskrise 2008 hat mit ihrer zeitweisen Verknappung von Acetonitril eindringlich gezeigt, dass man nicht nur auf eine einzige chromatographische Methode setzten sollte. Genau dies wird aber im Augenblick getan, denn Industrie und Forschung setzen mehrheitlich auf die High Performance Liquid Chromatography (HPLC) als die Trennmethode ihrer Wahl. Für viele Anwendungen in der Pharmazie, in der Umweltanalytik, der Lebensmittelanalytik, aber auch in der Inprozesskontrolle gibt es mit der Dünnschichtchromatografie eine Alternative.
Seit den ersten Projekten der 90er Jahre arbeiten Hochschulen daran, geeignete Servicestrukturen für E-Learning zu etablieren, die die erforderliche technische, didaktische und organisatorische Unterstützung hochschulweit zur Verfügung stellen. Ging es zunächst darum, Services überhaupt dauerhaft zu sichern, steht heute die Frage des „wie“ im Vordergrund. Dabei wird am Bereich E-Learning ein eigentlich viel allgemeineres Problem deutlich: Die bisher überwiegende Organisation der Hochschule nach funktionellen Einheiten stößt an ihre Grenzen. Wir schlagen eine stärker prozessorientierte Sichtweise vor, analog zu Entwicklungen bei der Organisation von Unternehmen.
Unter dem europäischen Programm Intelligent Energy for Europe (IEE) fanden sich acht europäische Partner zusammen, um im Rahmen des Projektes ThermCo Lüftungs‐ und Kühlenergiekonzepte für Nichtwohngebäude mit niedrigem Energieeinsatz im Hinblick auf die Energieeffizienz und den thermischen Raumkomfort zu bewerten. Die Analyse erfolgte auf Basis von detaillierten Langzeitmessungen über ein Betriebsjahr in acht Demonstrationsgebäuden in unterschiedlichen klimatischen Zonen Europas und einer standardisierten Datenauswertung. Im Quervergleich aller acht Gebäude werden die Kühlkonzepte gleichermaßen nach dem thermischen Kühlenergiebezug, dem thermischen Raumkomfort und dem Primärenergieeinsatz für die technische Gebäudeausrüstung und die Beleuchtung bewertet. Ein Energiekonzept ist erst dann zufriedenstellend, wenn mit möglichst geringem Energieeinsatz und bei hoher Anlageneffizienz ein guter thermischer Raumkomfort zur Verfügung gestellt werden kann. Mit entsprechenden Gebäudesignaturen werden diese Parameter in einen Zusammenhang gebracht und die Zielstellung überprüft. Detaillierte Komfortuntersuchungen nach der europäischen Komfortnorm DIN EN 15251:2007‐08 geben Hinweise auf die Wirksamkeit der eingesetzten Kühltechnologien in den jeweiligen Klimazonen. Daraus lassen sich Handlungsempfehlungen ableiten.
EuGH "Football Dataco"
(2012)
EuGH "Meister"
(2012)