Open Access

Astaxanthin is a keto-carotenoid, belongs to the chemical class of terpenes and is a yellow lipid soluble compound. The compound is present in marine animals like salmons and crustacean. Its colour is due to conjugated double bonds and these double bonds are responsible for its antioxidant effect. Its antioxidant activity is ten times stronger than other carotenoids and nearly 500 fold stronger than vitamin-E. We present a new thin layer chromatography (TLC) method to measure astaxanthin on TLC-plates (Merck, 1.05554) in the visible absorption range as well as by using chemiluminescence. For separation a solvent mixture of cyclohexane and acetone (10 + 2.4, v/v) was used. The RF-value of astaxanthin is 0.14.The limit of detection in vis-absorption is 64 ng / band and the limit of quantification is 92 ng/band. In chemiluminescence the values are 90 ng / band and 115 ng/band. The method offers two independently working measurement modes on a single plate which increase the accuracy of the quantification.

Modern society is more than ever striving for digital connectivity -- everywhere and at any time, giving rise to megatrends such as the Internet of Things (IoT). Already today, 'things' communicate and interact autonomously with each other and are managed in networks. In the future, people, data, and things will be interlinked, which is also referred to as the Internet of Everything (IoE). Billions of devices will be ubiquitously present in our everyday environment and are being connected over the Internet. As an emerging technology, printed electronics (PE) is a key enabler for the IoE offering novel device types with free form factors, new materials, and a wide range of substrates that can be flexible, transparent, as well as biodegradable. Furthermore, PE enables new degrees of freedom in circuit customizability, cost-efficiency as well as large-area fabrication at the point of use. These unique features of PE complement conventional silicon-based technologies. Additive manufacturing processes enable the realization of many envisioned applications such as smart objects, flexible displays, wearables in health care, green electronics, to name but a few. From the perspective of the IoE, interconnecting billions of heterogeneous devices and systems is one of the major challenges to be solved. Complex high-performance devices interact with highly specialized lightweight electronic devices, such as e.g. smartphones and smart sensors. Data is often measured, stored, and shared continuously with neighboring devices or in the cloud. Thereby, the abundance of data being collected and processed raises privacy and security concerns. Conventional cryptographic operations are typically based on deterministic algorithms requiring high circuit and system complexity, which makes them unsuitable for lightweight devices. Many applications do exist, where strong cryptographic operations are not required, such as e.g. in device identification and authentication. Thereby, the security level mainly depends on the quality of the entropy source and the trustworthiness of the derived keys. Statistical properties such as the uniqueness of the keys are of great importance to precisely distinguish between single entities. In the past decades, hardware-intrinsic security, particularly physically unclonable functions (PUFs), gained a lot of attraction to provide security features for IoT devices. PUFs use their inherent variations to derive device-specific unique identifiers, comparable to fingerprints in biometry. The potentials of this technology include the use of a true source of randomness, on demand key derivation, as well as inherent key storage. Combining these potentials with the unique features of PE technology opens up new opportunities to bring security to lightweight electronic devices and systems. Although PE is still far from being matured and from being as reliable as silicon technology, in this thesis we show that PE-based PUFs are promising candidates to provide key derivation suitable for device identification in the IoE. Thereby, this thesis is primarily concerned with the development, investigation, and assessment of PE-based PUFs to provide security functionalities to resource constrained printed devices and systems. As a first contribution of this thesis, we introduce the scalable PE-based Differential Circuit PUF (DiffC-PUF) design to provide secure keys to be used in security applications for resource constrained printed devices. The DiffC-PUF is designed as a hybrid system architecture incorporating silicon-based and inkjet-printed components. We develop an embedded PUF platform to enable large-scale characterization of silicon and printed PUF cores. In the second contribution of this thesis, we fabricate silicon PUF cores based on discrete components and perform statistical tests under realistic operating conditions. A comprehensive experimental analysis on the PUF security metrics is carried out. The results show that the silicon-based DiffC-PUF exhibits nearly ideal values for the uniqueness and reliability metrics. Furthermore, the identification capabilities of the DiffC-PUF are investigated and it is shown that additional post-processing can further improve the quality of the identification system. In the third contribution of this thesis, we firstly introduce an evaluation workflow to simulate PE-based DiffC-PUFs, also called hybrid PUFs. Hereof, we introduce a Python-based simulation environment to investigate the characteristics and variations of printed PUF cores based on Monte Carlo (MC) simulations. The simulation results show, that the security metrics to be expected from the fabricated devices are close to ideal at the best operating point. Secondly, we employ fabricated printed PUF cores for statistical tests under varying operating conditions including variations in ambient temperature, relative humidity, and supply voltage. The evaluations of the uniqueness, bit aliasing, and uniformity metrics are in good agreement with the simulation results. The experimentally determined mean reliability value is relatively low, which can be explained by the missing passivation and encapsulation of the printed transistors. The investigation of the identification capabilities based on the raw PUF responses shows that the pure hybrid PUF is not suitable for cryptographic applications, but qualifies for device identification tasks. The final contribution is to switch to the perspective of an attacker. To judge on the security capabilities of the hybrid PUF, a comprehensive security analysis in the manner of a cryptanalysis is performed. The analysis of the entropy of the hybrid PUF shows that its vulnerability against model-based attacks mainly depends on the selected challenge building method. Furthermore, an attack methodology is introduced to assess the performances of different mathematical cloning attacks on the basis of eavesdropped challenge-response pairs (CRPs). To clone the hybrid PUF, a sorting algorithm is introduced and compared with commonly used supervised machine learning (ML) classifiers including logistic regression (LR), random forest (RF), as well as multi-layer perceptron (MLP). The results show that the hybrid PUF is vulnerable against model-based attacks. The sorting algorithm benefits from shorter training times compared to the ML algorithms. If the eavesdropped CRPs are erroneous, the ML algorithms outperform the sorting algorithm.

The paper focuses on the work of an interdisciplinary project between photonics and digital art. The result is a poster collection dedicated to the International Year of Light 2015. In addition, an internet platform was created that presents the project. It can be accessed at http://www.magic-of-light.org/iyl2015/index.htm. From the idea to the final realization, milestones with tasks and steps will be presented in the paper. As an interdisciplinary project, students from technological degree programs were involved as well as art program students. The 2015 Anniversaries: Alhazen (1015), De Caus (1615), Fresnel (1815), Maxwell (1865), Einstein (1905), Penzias Wilson, Kao (1965) and their milestone contributions in optics and photonics will be highlighted.

In this work, we evaluate two different image clustering objectives, k-means clustering and correlation clustering, in the context of Triplet Loss induced feature space embeddings. Specifically, we train a convolutional neural network to learn discriminative features by optimizing two popular versions of the Triplet Loss in order to study their clustering properties under the assumption of noisy labels. Additionally, we propose a new, simple Triplet Loss formulation, which shows desirable properties with respect to formal clustering objectives and outperforms the existing methods. We evaluate all three Triplet loss formulations for K-means and correlation clustering on the CIFAR-10 image classification dataset.

The aim of this study is to understand the effect of the various layers of biological tissues on electromagnetic radiation in a certain frequency range. Understanding these effects could prove crucial in the development of dynamic imaging systems under operating environments during catheter ablation in the heart. As the catheter passes through some arterial paths in the region of interest inside the heart through the aorta, a three-dimensional localization of the catheter is required. In this paper, a study is given on the detection of the catheter by using electromagnetic waves. Therefor, an appropriate model for the layers of the human torso is defined and simulated without and with an inserted electrode.

Generative adversarial networks are the state of the art approach towards learned synthetic image generation. Although early successes were mostly unsupervised, bit by bit, this trend has been superseded by approaches based on labelled data. These supervised methods allow a much finer-grained control of the output image, offering more flexibility and stability. Nevertheless, the main drawback of such models is the necessity of annotated data. In this work, we introduce an novel framework that benefits from two popular learning techniques, adversarial training and representation learning, and takes a step towards unsupervised conditional GANs. In particular, our approach exploits the structure of a latent space (learned by the representation learning) and employs it to condition the generative model. In this way, we break the traditional dependency between condition and label, substituting the latter by unsupervised features coming from the latent space. Finally, we show that this new technique is able to produce samples on demand keeping the quality of its supervised counterpart.

Recent advances in motion recognition allow the development of Context-Aware Assistive Systems (CAAS) for industrial workplaces that go far beyond the state of the art: they can capture a user's movement in real-time and provide adequate feedback. Thus, CAAS can address important questions, like Which part is assembled next? Where do I fasten it? Did an error occur? Did I process the part in time? These new CAAS can also make use of projectors to display the feedback within the corresponding area on the workspace (in-situ). Furthermore, the real-time analysis of work processes allows the implementation of motivating elements (gamification) into the repetitive work routines that are common in manual production. In this chapter, the authors first describe the relevant backgrounds from industry, computer science, and psychology. They then briefly introduce a precedent implementation of CAAS and its inherent problems. The authors then provide a generic model of CAAS and finally present a revised and improved implementation.

Using video game elements to improve user experience and user engagement in non-game applications is called "gamification". This method of enriching human-computer interaction has been applied successfully in education, health and general business processes. However, it has not been established in industrial production so far. After discussing the requirements specific for the production domain we present two workplaces augmented with gamification. Both implementations are based on a common framework for context-aware assistive systems but exemplify different approaches: the visualization of work performance is complex in System 1 and simple in System 2. Based on two studies in sheltered work environments with impaired workers, we analyze and compare the systems' effects on work and on workers. We show that gamification leads to a speed-accuracy-tradeoff if no quality-related feedback is provided. Another finding is that there is a highly significant raise in acceptance if a straightforward visualization approach for gamification is used.

Gamification is an ever more popular method to increase motivation and user experience in real-world settings. It is widely used in the areas of marketing, health and education. However, in production environments, it is a new concept. To be accepted in the industrial domain, it has to be seamlessly integrated in the regular work processes. In this work we make the following contributions to the field of gamification in production: (1) we analyze the state of the art and introduce domain-specific requirements; (2) we present two implementations gamifying production based on alternative design approaches; (3) these are evaluated in a sheltered work organization. The comparative study focuses acceptance, motivation and perceived happiness. The results reveal that a pyramid design showing each work process as a step on the way towards a cup at the top is strongly preferred to a more abstract approach where the processes are represented by a single circle and two bars.

Andreas Klasen analyses measures taken by European export-import banks (Exim-Banks) and export credit agencies (ECAs) aimed at exporters‘ pressing finance constraints.

PROBLEM TO BE SOLVED: To provide a method of producing a robot component, particularly a gripper, the method being capable of being applied multi-functionally and shortening a mounting time to a robot. SOLUTION: A method of producing a robot component, particularly a finger 5, applied to robotics by a three-dimensional printing method of this invention comes not to require other production processes such as attachment of a cover, etc. with a separate sensor or a material (soft, in many cases), etc., by simultaneously printing at least one sensor 7 by multi-material printing while printing the robot component.

This article combines two important areas of practical theology: Monastic rules and leadership in a cloistral organisation, using the Rule of Saint Francis as a prominent example. The aim of this research is to examine how living Christian tradition in a monastic order affects leadership today, discovering how the Rule and Franciscan spirituality impact managing a convent. The research question is answered within this inductive research applying the methodology of the ‘theology in four voices.’ Based on the results, it is possible to build a coherent leadership system based on Biblical and Franciscan sources.

The authors claim that location information of stationary ICT components can never be unclassified. They describe how swarm-mapping crowd sourcing is used by Apple and Google to worldwide harvest geo-location information on wireless access points and mobile telecommunication systems' base stations to build up gigantic databases with very exclusive access rights. After having highlighted the known technical facts, in the speculative part of this article, the authors argue how this may impact cyber deterrence strategies of states and alliances understanding the cyberspace as another domain of geostrategic relevance. The states and alliances spectrum of activities due to the potential existence of such databases may range from geopolitical negotiations by institutions understanding international affairs as their core business, mitigation approaches at a technical level, over means of cyber deterrence-by-retaliation.

Covert- and side-channels as well as techniques to establish them in cloud computing are in focus of research for quite some time. However, not many concrete mitigation methods have been developed and even less have been adapted and concretely implemented by cloud providers. Thus, we recently conceptually proposed C 3 -Sched a CPU scheduling based approach to mitigate L2 cache covert-channels. Instead of flushing the cache on every context switch, we schedule trusted virtual machines to create noise which prevents potential covert-channels. Additionally, our approach aims on preserving performance by utilizing existing instead of artificial workload while reducing covert-channel related cache flushes to cases where not enough noise has been achieved. In this work we evaluate cache covert-channel mitigation and performance impact of our integration of C 3 -Sched in the XEN credit scheduler. Moreover, we compare it to naive solutions and more competitive approaches.

Antennas for Radio Frequency Identification (RFID) provide benefits for high frequencies (HF) and wireless data transmission via Near Field Communication (NFC) and many other applications. In this case, various requirements for the design of the reader and transmitter antennas must be met in order to achieve a suitable transmission quality. In this work, a miniaturized cost-effective RFID/NFC antenna for a microelectronic measurement system is designed and printed on different flexible carrier substrates using a new and low-cost Direct Ink Writing (DIW) technology. Various practical aspects such as reflection and impedance magnitude as well as the behavior of the printed RFID/NFC antennas are analyzed and compared to an identical copper-based antenna of the same size. The results are presented in this paper. Furthermore, the problems during the printing process itself on the different substrates are evaluated. The effects of the characteristics on the antenna under kink-free bending tests are examined and subsequently long-term measurements are carried out.

Cross-industry innovation is commonly understood as identification of analogies and interdisciplinary transfer or copying of technologies, processes, technical solutions, working principles or models between industrial sectors. In general, creative thinking in analogies belongs to the efficient ideation techniques. However, engineering graduates and specialists frequently lack the skills to think across the industry boundaries systematically. To overcome this drawback an easy-to-use method based on five analogies has been evaluated through its applications by students and engineers in numerous experiments and industrial case studies. The proposed analogies help to identify and resolve engineering contradictions and apply approaches of the Theory of Inventive Problem Solving TRIZ and biomimetics. The paper analyses the outcomes of the systematized analogies-based ideation and outlines that its performance continuously grows with the engineering experience. It defines metrics for ideation efficiency and ideation performance function.

Sustainable design of equipment for process intensification requires a comprehensive and correct identification of relevant stakeholder requirements, design problems and tasks crucial for innovation success. Combining the principles of the Quality Function Deployment with the Importance-Satisfaction Analysis and Contradiction Analysis of requirements gives an opportunity to define a proper process innovation strategy more reliably and to develop an optimal process intensification technology with less secondary engineering and ecological problems.

The authentication method of electronic devices, based on individual forms of correlograms of their internal electric noises, is well-known. Specific physical differences in the components – for example, caused by variations in production quality – cause specific electrical signals, i.e. electric noise, in the electronic device. It is possible to obtain this information and to identify the specific differences of the individual devices using an embedded analog-to-digital converter (ADC). These investigations confirm the possibility to identify and authenticate electronic devices using bit templates, calculated from the sequence of values of the normalized autocorrelation function of noise. Experiments have been performed using personal computers. The probability of correct identification and authentication increases with increasing noise recording duration. As a result of these experiments, an accuracy of 98.1% was achieved for a 1 second-long registration of EM for a set of investigated computers.

During the day-to-day exploitation of localization systems in mines, the technical staff tends to incorrectly rearrange radio equipment: positions of devices may not be accurately marked on a map or their positions may not correspond to the truth. This situation may lead to positioning inaccuracies and errors in the operation of the localization system.This paper presents two Bayesian algorithms for the automatic corrections of positions of the equipment on the map using trajectories restored by the inertial measurement units mounted to mobile objects, like pedestrians and vehicles. As a basis, a predefined map of the mine represented as undirected weighted graph was used as input. The algorithms were implemented using the Simultaneous Localization and Mapping (SLAM) approach.The results prove that both methods are capable to detect misplacement of access points and to provide corresponding corrections. The discrete Bayesian filter outperforms the unscented Kalman filter, which, however, requires more computational power.

The number of use cases for autonomous vehicles is increasing day by day especially in commercial applications. One important application of autonomous vehicles can be found within the parcel delivery section. Here, autonomous cars can massively help to reduce delivery efforts and time by supporting the courier actively. One important component of course is the autonomous vehicle itself. Nevertheless, beside the autonomous vehicle, a flexible and secure communication architecture also is a crucial key component impacting the overall performance of such system since it is required to allow continuous interactions between the vehicle and the other components of the system. The communication system must provide a reliable and secure architecture that is still flexible enough to remain practical and to address several use cases. In this paper, a robust communication architecture for such autonomous fleet-based systems is proposed. The architecture provides a reliable communication between different system entities while keeping those communications secure. The architecture uses different technologies such as Bluetooth Low Energy (BLE), cellular networks and Low Power Wide Area Network (LPWAN) to achieve its goals.

Time-Sensitive Networking (TSN) is the most promising time-deterministic wired communication approach for industrial applications. To extend TSN to "IEEE 802.11" wireless networks two challenging problems must be solved: synchronization and scheduling. This paper is focused on the first one. Even though a few solutions already meet the required synchronization accuracies, they are built on expensive hardware that is not suited for mass market products. While next Wi-Fi generation might support the required functionalities, this paper proposes a novel method that makes possible high-precision wireless synchronization using commercial low-cost components. With the proposed solution, a standard deviation of synchronization error of less than 500 ns can be achieved for many use cases and system loads on both CPU and network. This performance is comparable to modern wired real-time field busses, which makes the developed method a significant contribution for the extension of the TSN protocol to the wireless domain.

The Metering Bus, also known as M-Bus, is a European standard EN13757-3 for reading out metering devices, like electricity, water, gas, or heat meters. Although real-life M-Bus networks can reach a significant size and complexity, only very simple protocol analyzers are available to observe and maintain such networks. In order to provide developers and installers with the ability to analyze the real bus signals easily, a web-based monitoring tool for the M-Bus has been designed and implemented. Combined with a physical bus interface it allows for measuring and recording the bus signals. For this at first a circuit has been developed, which transforms the voltage and current-modulated M-Bus signals to a voltage signal that can be read by a standard ADC and processed by an MCU. The bus signals and packets are displayed using a web server, which analyzes and classifies the frame fragments. As an additional feature an oscilloscope functionality is included in order to visualize the physical signal on the bus. This paper describes the development of the read-out circuit for the Wired M-Bus and the data recovery.

Partial substitution of Al atoms with Sc in wurtzite AlN crystals increases the piezoelectric constants. This leads to an increased electromechanical coupling, which is required for high bandwidths in piezo-acoustic filters. The crystal bonds in Ah-xScxN (AlScN) are softened as function of Sc atomic percentage x, leading to reduction of phase velocity in the film. Combining high Sc content AlScN films with high velocity substrates favors higher order guided surface acoustic wave (SAW) modes [1]. This study investigates higher order SAW modes in epitaxial AlScN on sapphire (Al2O3). Their dispersion for Pt metallized epitaxial AlScN films on Al2O3was computed for two different propagation directions. Computed phase velocity dispersion branches were experimentally verified by the characterization of fabricated SAW resonators. The results indicated four wave modes for the propagation direction (0°, 0°, 0°), featuring 3D polarized displacement fields. The sensitivity of the wave modes to the elastic constants of AlScN was investigated. It was shown that due to the 3D polarization of the waves, all elastic constants have an influence on the phase velocity and can be measured by suitable weighting functions in material constant extraction procedures.