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Steroid hormones (SHs) are a rising concern due to their high bioactivity, ubiquitous nature, and prolonged existence as a micropollutants in water, they pose a potential risk to both human health and the environment, even at low concentrations. Estrogens, progesterone, and testosterone are the three important types of steroids essential for human development and maintaining multiorgan balance, are focus to this concern. These steroid hormones originate
from various sources, including human and livestock excretions, veterinary medications, agricultural runoff, and pharmaceuticals, contributing to their presence in the environment. According to the recommendation of WHO, the guidance value for estradiol (E2) is 1 ng/L. There are several methods been attempted to remove the SH micropollutant by conventional water and wastewater technologies which are still under research. Among the various methods, electrochemical membrane reactor (EMR) is one of the emerging technologies that can address the challenge of insufficient SHs removal from the aquatic environment by conventional treatment. The degradation of SHs can be significantly influenced by various factors when treated with EMR.
In this project, the removal of SH and the important mechanism for the removal using carbon nanotube CNT-EMR is studied and the efficiency of CNT-EMR in treating the SH micropollutant is identified. By varying different parameters this experiment is carried out with the (PES-CNTs) ultrafiltration membrane. The study is carried out depending upon the SH removal based on the limiting factor such as cell voltage, flux, temperature, concentration, and type of the SH.
Globale Ereignisse politischen, wirtschaftlichen oder kulturellen Ursprungs führen dazu, dass Unternehmen sich gezwungen sehen zu handeln, um wettbewerbsfähig zu bleiben. In vielen Fällen wird dabei so vorgegangen, dass versteckte Preiserhöhungen vollzogen werden. Auch Unternehmen, die mit ihrem Angebot einen gesellschaftlichen Zusatznutzen erbringen, erhöhen die Preise, da nur so der verfolgte ökologische oder soziale Purpose erhalten werden kann, kommunizieren dies jedoch offen und erhöhen dadurch ihre Kundenloyalität. Dieses Vorgehen ist bislang jedoch überwiegend in den USA zu beobachten. Da das Thema Purpose auch in Deutschland immer höhere Relevanz erfährt, stellt sich die Frage der Übertragbarkeit. Die Forschungsfrage lautet deshalb: Inwiefern beeinflusst die Kommunikation von purpose-getriebenen Preissteigerungen das Markenimage von B2C-Unternehmen in Deutschland? Um der Forschungsfrage nachzugehen, wurde ein empirischer Forschungsansatz gewählt, der in Form einer quantitativen Studie umgesetzt wurde, die die Meinung der Studierendenschaft der Gen Z und Y der Hochschule Offenburg abbildet. Die Ergebnisse der Umfrage zeigten, dass die Glaubwürdigkeit und Akzeptanz von purpose-getriebenen Preiserhöhungen vom gegenwärtigen Markenimage bzw. dem übergeordneten Image einer Branche abhängen. Purpose wird eine hohe Bedeutung zugesprochen, die sich jedoch aufgrund der Preissensibilität der Zielgruppe nicht immer in der Markenwahl widerspiegelt. Dies verdeutlicht, dass Purpose das Potenzial besitzt, das Markenimage nachhaltig zu beeinflussen und zu prägen und die Zielgruppe der Gen Z und Y zukünftig an sich zu binden. Ferner wurde deutlich, dass bei der Umsetzung von Purpose bestimmte Kriterien verfolgt werden sollten, die bei der Kommunikation zu berücksichtigen sind, um eine authentische Wirkung zu erzielen.
The growing threat posed by multidrug-resistant (MDR) pathogens, such as Klebsiella pneumoniae (Kp), represents a significant challenge in modern medicine. Traditional antibiotic therapies are often ineffective against these pathogens, leading to high mortality rates. MDR Kp infections pose a novel challenge in military medical contexts, particularly in Medical Biodefense, as they can be deliberately spread, leading to resource-intensive care in military centres. Recognizing this issue, the European Defence Agency initiated a prioritised research project in 2023 (EDF Resilience PHAGE- SGA 2023). To address this challenge, the Bundeswehr Institute of Microbiology (IMB) leads BMBF- (Federal Ministry of Education and Research) and EU-funded projects on the use of bacteriophages as adjuvant therapy alongside antibiotics. Since 2017, the IMB has isolated and characterised Kp phages, collecting over 600 isolates and optimizing their production for therapy, in compliance with the EMA (European Medicine Agency) guidelines. This involves in vitro phage genome packaging to minimize endotoxin load, reduce manufacturing costs, and shorten production times. The goal of this work was to establish MinION sequencing (Oxford Nanopore Technology) as a quick and reliable way for initial identification and characterisation of phage genomes. Especially as a quick screening method for isolated on Kp, prior to more precise but also more expensive and time consuming sequencing methods like Illumina. This characterisation is crucial for developing a personalized pipeline aimed at producing magistral or Good Manufacturing Practice (GMP) quality medicinal phage solutions tailored individually for each patient. DNA extraction methods were compared to identify suitable input DNA for sequencing purposes. Additionally, the quality of this DNA was as- sessed to determine its suitability for in vitro phage packaging, which was successfully done achieving a phage titer of 103, confirming that the DNA used for MinION sequencing could indeed be used for acellular packaging. The created genomes were annotated and compared with Illumina sequencing, revealing high similarity in all five individually tested cases. Between the generated sequences only a 4% maximal percentual difference in genome size was observed, while simultaneously showing high similarity in the actual sequence. Throughout the course of this study, a total of 645.15 GB of sequencing data were generated. In total, 38 phages were successfully characterised, with 21 phage genomes assembled and annotated, and saved in the IMB database.
This thesis focuses on the development and implementation of a Datagram Transport Layer Security (DTLS) communication framework within the ns-3 network simulator, specifically targeting the LoRaWAN model network. The primary aim is to analyse the behaviour and performance of DTLS protocols across different network conditions within a LoRaWAN context. The key aspects of this work include the following.
Utilization of ns-3: This thesis leverages ns-3’s capabilities as a powerful discrete event network simulator. This platform enables the emulation of diverse network environments, characterized by varying levels of latency, packet loss, and bandwidth constraints.
Emulation of Network Challenges: The framework specifically addresses unique challenges posed by certain network configurations, such as duty cycle limitations. These constraints, which limit the time allocated for data transmission by each device, are crucial in understanding the real-world performance of DTLS protocols.
Testing in Multi-client-server Scenarios: A significant feature of this framework is its ability to test DTLS performance in complex scenarios involving multiple clients and servers. This is vital for assessing the behaviour of a protocol under realistic network conditions.
Realistic Environment Simulation: By simulating challenging network conditions, such as congestion, limited bandwidth, and resource constraints, the framework provides a realistic environment for thorough evaluation. This allows for a comprehensive analysis of DTLS in terms of security, performance, and scalability.
Overall, this thesis contributes to a deeper understanding of DTLS protocols by providing a robust tool for their evaluation under various and challenging network conditions.
This study investigates the impact of global payroll outsourcing on organizational efficiency and cost reduction based on the analysis of diverse implications stemming from thirty one (31) survey results. The findings reveal multifaceted challenges and benefitsassociated with outsourcing global payroll processing.
The research also unveils the most benefits of global payroll outsourcing. Notably, there's a consensus on the reduction in time-to-process payroll, cost per payroll processed, and improved payroll accuracy rate. Outsourcing streamlines processes, enhances operational efficiency, and contributes to faster, more accurate financial reporting.
Despite these benefits and challenges, statistical analysis reveals weak correlations between outsourcing global payroll and cost reduction or improved efficiency in various parameters, indicating a lack of a significant relationship. Consequently, the results, suggest no substantial correlation between global payroll outsourcing and enhanced efficiency or cost reduction based on this study's data.
Decarbonisation Strategies in Energy Systems Modelling: APV and e-tractors as Flexibility Assets
(2023)
This work presents an analysis of the impact of introducing Agrophotovoltaic technologies and electric tractors into Germany’s energy system. Agrophotovoltaics involves installing photovoltaic systems in agricultural areas, allowing for dual usage of the land for both energy generation and food production. Electric tractors, which are agricultural machinery powered by electric motors, can also function as energy storage units, providing flexibility to the grid. The analysis includes a sensitivity study to understand how the availability of agricultural land influences Agrophotovoltaic investments, followed by the examination of various scenarios that involve converting diesel tractors to electric tractors. These scenarios are based on the current CO2 emission reduction targets set by the German Government, aiming for a 65% reduction below 1990 levels by 2030 and achieving zero emissions by 2045. The results indicate that approximately 3% of available agricultural land is necessary to establish a viable energy mix in Germany. Furthermore, the expansion of electric tractors tends to reduce the overall system costs and enhances the energy-cost-efficiency of Agrophotovoltaic investments.
Truth is the first causality of war”, is a very often used statement. What rather intrigues the mind is what causes the causality of truth. If one dives deeper, one may also wonder why is this so-called truth the first target in a war. Who all see the truth before it dies. These questions rarely get answered as the media and general public tends to focus more on the human and economic losses in a war or war like situation. What many fail to realize is that these truthful pieces of information are critical to how a situation further develops. One correct information may change the course of the whole war saving millions and one mis-information may do the opposite.
Since its inception, some studies have been conducted to propose and develop new applications for OSINT in various fields. In addition to OSINT, Artificial Intelligence is a worldwide trend that is being used in conjunction witThe question here is, what is this information. Who transmits this and how? What is the source. Although, there has been an extensive use of the information provided by the secret services of any nation, which have come handy to many, another kind of information system is using the one that is publicly available, but in different pieces. This kind of information may come from people posting on social media, some publicly available records and much more. The key part in this publicly available information is that these are just pieces of information available across the globe from various different sources. This could be seen as small pieces of a puzzle that need to be put together to see the bigger picture. This is where OSINT comes in place.
h other areas (AI). AI is the branch of computer science that is in charge of developing intelligent systems. In terms of contribution, this work presents a 9-step systematic literature review as well as consolidated data to support future OSINT studies. It was possible to understand where the greatest concentration of publications was, which countries and continents developed the most research, and the characteristics of these publications using this information. What are the trends for the next OSINT with AI studies? What AI subfields are used with OSINT? What are the most popular keywords, and how do they relate to others over time?A timeline describing the application of OSINT is also provided. It was also clear how OSINT was used in conjunction with AI to solve problems in various areas with varying objectives. Private investigators and journalists are no longer the primary users of open-source intelligence gathering and analysis (OSINT) techniques. Approximately 80-90 percent of data analysed by intelligence agencies is now derived from publicly available sources. Furthermore, the massive expansion of the internet, particularly social media platforms, has made OSINT more accessible to civilians who simply want to trawl the Web for information on a specific individual, organisation, or product. The General Data Protection Regulation (GDPR) of the European Union was implemented in the United Kingdom in May 2018 through the new Data Protection Act, with the goal of protecting personal data from unauthorised collection, storage, and exploitation. This document presents a preliminary review of the literature on GDPR-related work.
The reviewed literature is divided into six sections: ’What is OSINT?’, ’What are the risks?’ and benefits of OSINT?’, ’What is the rationale for data protection legislation?’, ’What are the current legislative frameworks in the UK and Europe?’, ’What is the potential impact of the GDPR on OSINT?’, and ’Have the views of civilian and commercial stakeholders been sought and why is this important?’. Because OSINT tools and techniques are available to anyone, they have the unique ability to be used to hold power accountable. As a result, it is critical that new data protection legislation does not impede civilian OSINT capabilities.
In this paper we see how OSINT has played an important role in the wars across the globe in the past. We also see how OSINT is used in our everyday life. We also gain insights on how OSINT is playing a role in the current war going on between Russia and Ukraine. Furthermore, we look into some of these OSINT tools and how they work. We also consider a use case where OSINT is used as an anti terrorism tool. At the end, we also see how OSINT has evolved over the years, and what we can expect in the future as to what OSINT may look like.
This research presents a comprehensive exploration of hydroponic systems and their practical applications, with a focus on innovative solutions for managing environmental and analytical sensors in hydroponic setups. Hydroponic systems, which enable soilless cultivation, have gained increasing importance in modern agriculture due to their resource-efficient and high-yield nature.
The study delves into the development and deployment of the SensVert system, an adaptable solution tailored for hydroponic environments. SensVert offers adaptability and accessibility to farmers across various agricultural domains, addressing contemporary challenges in supervising and managing environmental and analytical sensors within hydroponic setups. Leveraging LoRa technology for seamless wireless data transmission, SensVert empowers users with a feature-rich dashboard for real-time monitoring and control. The study showcases the practical implementation of SensVert through a single sensor node, seamlessly integrating temperature, humidity, pressure, light, and pH sensors. The system automates pH regulation, employing the Henderson-Hasselbalch equation, and precisely controls liquid dosing using a PID controller. At the core of SensVert lies an architecture comprising The Things Stack as the network server, Node-Red as the application server, and Grafana as the user interface. These components synergize within a local network hosted on a Raspberry Pi; effectively mitigating challenges associated with data packet transmission in areas with limited internet connectivity.
As part of ongoing research, this work also paves the way for future advancements. These include the establishment of a wireless sensor network (WSN) utilizing LoRa technology, enabling seamless over-the-air sensor node updates for maintenance or replacement scenarios. These enhancements promise to further elevate the system's reliability and functionality within hydroponic cultivation, fostering sustainable agricultural practices.
As the population grows, so does the amount of biowaste. As demand for energy grows, biogas is a promising solution to the problem. Lignocellulosic materials are challenged of slow degradability due to the presence of polymers such as cellulose, lignin and hemicellulose. There are several pretreatment methods available to enhance the degradability of such materials, including enzymatic pretreatment. In this pretreatment, there are few parameters that can influence the results, the most important being the enzyme to solid ratio and the solid to liquid ratio. During this project, experiments were conducted to determine the optimal conditions for those two factors. It was discovered that a solid to liquid ratio of 31 g of buffer per 1 gram of organic dry matter produced the highest reducing sugar release in flasks when combined with 34 mg of protein per 1 gram of organic dry mass. Additionally, another experiment was carried out to investigate the impact of enzymatic pretreatment on biogas production using artificial biowaste as a substrate. Artificial biowaste produced 577,9 NL/kg oDM, while enzymatically pretreated biowaste produced 639,3 NL/kg oDM. This resulted in a 10,6% rise in cumulative biogas production compared to its use without enzymatic pretreatment. By the conclusion of the investigation, specific cumulative dry methane yields of 364,7 NL/kg oDM and 426,3 NL/kg oDM were obtained from artificial biowaste without and with enzymatic pretreatment, respectively. This resulted in a methane production boost of 16,9%. Additionally in case of the reactors with enzymatically pretreated substrate kinetic constant was lower more than double, where maximum volume of biogas increased, comparing to the reactors without enzymatic pretreatment.