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The combination of fossil-derived fuels with ethanol and methanol has acquired relevance and attention in several countries in recent years. This trend is strongly affected by market prices, constant geopolitical events, new sustainability policies, new laws and regulations, etc. Besides bio-fuels these materials also include different additives as anti-shock agents and as octane enhancer. Some of the chemical compounds in these additives may have harmful properties for both environment and public health (besides the inherent properties, like volatility). We present detailed Raman spectral information from toluene (C7H8) and ethanol (C2H6O) contained in samples of ElO gasoline-ethanol blends. The spectral information has been extracted by using a robust, high resolution Fourier-Transform Raman spectrometer (FT-Raman) prototype. This spectral information has been also compared with Raman spectra from pure additives and with standard Raman lines in order to validate its accuracy in frequency. The spectral information is presented in the range of 0 cm-1 to 3500 cm-1 with a resolution of 1.66cm-1. This allows resolving tight adjacent Raman lines like the ones observed around 1003cm-1 and 1030cm-1 (characteristic lines of toluene). The Raman spectra obtained show a reduced frequency deviation when compared to standard Raman spectra from different calibration materials. The FT-Raman spectrometer prototype used for the analysis consist basically of a Michelson interferometer and a self-designed photon counter cooled down on a Peltier element arrangement. The light coupling is achieved with conventional62.5/125μm multi-mode fibers. This FT-Raman setup is able to extract high resolution and frequency precise Raman spectra from the additives in the fuels analyzed. The proposed prototype has no additional complex hardware components or costly software modules. The mechanical and thermal disturbances affecting the FT-Raman system are mathematically compensated by accurately extracting the optical path information of the Michelson interferometer. This is accomplished by generating an additional interference pattern with a λ = 632.8 nm Helium-Neon laser (HeNe laser). It enables the FT-Raman system to perform reliable and clean spectral measurements from the materials under observation.
Raman spectra from three different binary gasoline-ethanol blends (with ratios 95:5, 90:10, and 85:15) have been obtained by using a low-cost, frequency precise Fourier-transform Raman spectrometer (FT-Raman) prototype. The spectral information is presented in the range of 0 to 3500 cm-1 with a resolution of 1.66 cm-1, which is greater than the required for most liquid and solid chemical samples. This set-up delivers spectral information about the sample with a reduced spectral deviation compared to theoretical values (less than 0.4 cm-1 without compensation for instrumental response). The robust and highly fexible FT-Raman prototype presented for the spectral analysis, consisting mainly of a Michelson interferometer and a self-designed photon counter, is able to deliver high resolution and frequency precise Raman spectra from the gasoline-ethanol blends comparable to the obtained by using commercial devices. This FT-Raman set-up does not need additional complex hardware or software control and relies on re-sampling and interpolation algorithms. The qualitative spectral information obtained has been used to calculate the proportion of gasoline and ethanol present in the used chemical samples without using extra calibrations methods or chemical markers.
IPv6 over LoRaWAN™
(2017)
Although short-range wireless communication explicitly targets local and regional applications, range continues to be a highly important issue. The range directly depends on the so-called link budget, which can be increased by the choice of modulation and coding schemes. The recent transceiver generation in particular comes with extensive and flexible support for software-defined radio (SDR). The SX127× family from Semtech Corp. is a member of this device class and promises significant benefits for range, robust performance, and battery lifetime compared to competing technologies. This contribution gives a short overview of the technologies to support Long Range (LoRa™) and the corresponding Layer 2 protocol (LoRaWAN™). It particularly describes the possibility to combine the Internet Protocol, i.e. IPv6, into LoRaWAN™, so that it can be directly integrated into a full-fledged Internet of Things (IoT). The proposed solution, which we name 6LoRaWAN, has been implemented and tested; results of the experiments are also shown in this paper.
The Raman spectra from the chemical compounds toluene and cyclohexane obtained using a Fourier Transform (FT)-Raman spectrometer prototype have been contrasted with the Raman spectra of these same materials collected with two different commercial FT-Raman devices. The FT-Raman spectrometer consist of a Michelson interferometer, a self-designed photon counter and a reference photo-detector. The evaluation methodology of the spectral information, contrary to the commercial devices that commonly use the zero-crossing method, is carried out by re-sampling the Raman scattering and by accurately extracting the optical path information of the Michelson interferometer. The FTRaman arrangement has been built using conventional parts without disregarding the spectral frequency precision that usually such a FTRaman instruments deliver. No additional complex hardware components or costly software modules have been included in this FT-Raman device. The main Raman lines from the spectra obtained with the three FT-Raman devices have been compared with the Raman lines from the standard Raman spectra of these two materials. The values obtained using the FT-Raman spectrometer prototype have shown a frequency accuracy comparable to that obtained with the commercial devices without facing the need for a large investment. Although the proposed FT-Raman prototype cannot be directly compared to the last generation of FT-Raman spectrometers from the commercial manufacturers, such a device could give an opportunity to users that require high frequency precision in their spectral analysis and are provided with rather scarce resources.
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things. It can be observed that most of the available solutions are following an open source approach, which significantly leads to a fast development of technologies and of markets. Although the currently available implementations are in a pretty good shape, all of them come with some significant drawbacks. It was therefore decided to start the development of an own implementation, which takes the advantages from the existing solutions, but tries to avoid the drawbacks. This paper discussed the reasoning behind this decision, describes the implementation and its characteristics, as well as the testing results. The given implementation is available as open-source project under [15].
La industria del bacanora en Sonora, México, enfrenta la influencia de una compleja red de factores culturales, tecnológicos, económicos y legales que inhiben su desarrollo. Ello ocurre pese al esfuerzo institucional por radicar un marco normativo que elimine la práctica de los métodos informales de elaboración que derivan en calidades heterogéneas de licor. El conseguirlo se complica ante la dificultad que enfrentan los actores de esta industria para implementar prácticas efectivas de verificación de las normas vigentes en los confines de la geografía de la Denominación de Origen. En este documento se describe el uso de un prototipo de espectrómetro Raman por transformada de Fourier para analizar cualitativamente muestras desconocidas de bacanora. Este dispositivo se construyó con el uso de un interferómetro Michelson convencional, un contador de fotones de diseño propio y un foto-detector de referencia. Los resultados del trabajo confirman que dada su naturaleza de diseño y construcción, este instrumento de medición y su efectiva técnica de operación a bajo costo, constituye una alternativa viable, adaptable fácilmente a las necesidades de los actores productivos e institucionales, para asistirlos en la elaboración de bacanora y a la verificación de su calidad conforme a los criterios de la normatividad.
In dieser Bachelorthesis werden On-Premise und Cloud Lösungen miteinander verglichen und eine bereits bestehende On-Premise Reklamationsverwaltung, die Teil eines ganzen ERP-Systems ist, wird mithilfe des Reengineerings, als cloudbasierte App neu implementiert.
Im ersten Abschnitt wird der Vergleich durchgeführt. Dabei werden die Hauptmerkmale beider Lösungen und ihre Vor- und Nachteile herausgearbeitet. Zum Schluss wird überprüft, welche der beiden Lösungen besser zu den Anforderungen passen. Da die neue Reklamationsverwaltung als App umgesetzt werden soll, wurde sich für die Cloud Lösung entschieden. Diese ist deutlich flexibler und für kleinere Kunden kostengünstiger.
Im zweiten Abschnitt wird ein Reengineering der alten On-Premise Lösungen als cloudbasierte App durchgeführt. Dabei werden alle Anforderungen und Kriterien an die App aufgezeigt. Danach werden alle Schritte des Reengineerings, wie beispielsweise die Analyse der Datenstruktur und Erstellung von Aktivitätsdiagrammen, genauer beschrieben und für die App angewendet. Mithilfe des Reengineerings konnte die Datenstruktur angepasst werden. Auch wurden viele überflüssige Funktionen aus der alten Lösung entfernt und nur die wichtigsten Funktionen sind geblieben.