600 Technik, Medizin, angewandte Wissenschaften
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Biodegradable metals have entered the implant market in recent years, but still do not show fully satisfactory degradation behaviour and mechanical properties. In contrast, it has been shown that pure molybdenum has an excellent combination of the required properties in this respect. We report on PM based screen printing of thin-walled molybdenum tubes as a processing step for medical stent manufacture. We also present data on the in vivo degradation and biocompatibility of molybdenum. The degradation of molybdenum wires implanted in the aorta of rats was evaluated by SEM and EDX. Biocompatibility was assessed by histological investigation of organs and analysis of molybdenum levels in tissue extracts and body fluids. Degradation rates of up to 13.5 μm/y were observed after 12 months. No histological changes or elevated molybdenum levels in organ tissues were observed. In summary, the results further underline that molybdenum is a highly promising biodegradable metallic material.
Titanium and stainless steel are commonly known as osteosynthesis materials with high strength and good biocompatibility. However, they have the big disadvantage that a second operation for hardware removal is necessary. Although resorbable systems made of polymers or magnesium are increasingly used, they show some severe adverse foreign body reactions or unsatisfying degradation behavior. Therefore, we started to investigate molybdenum as a potential new biodegradable material for osteosynthesis in craniomaxillofacial surgery. To characterize molybdenum as a biocompatible material, we performed in vitro assays in accordance with ISO Norm 10993-5. In four different experimental setups, we showed that pure molybdenum and molybdenum rhenium alloys do not lead to cytotoxicity in human and mouse fibroblasts. We also examined the degradation behavior of molybdenum by carrying out long-term immersion tests (up to 6 months) with molybdenum sheet metal. We showed that molybdenum has sufficient mechanical stability over at least 6 months for implants on the one hand and is subject to very uniform degradation on the other. The results of our experiments are very promising for the development of new resorbable osteosynthesis materials for craniomaxillofacial surgery based on molybdenum.
During the coronavirus crisis, labs had to be offered in digital form in mechanical engineering at short notice. For this purpose, digital twins of more complex test benches in the field of fluid energy machines were used in the mechanical engineering course, with which the students were able to interact remotely to obtain measurement data. The concept of the respective lab was revised with regard to its implementation as a remote laboratory. Fortunately, real-world labs were able to be fully replaced by remote labs. Student perceptions of remote labs were mostly positive. This paper explains the concept and design of the digital twins and the lab as well as the layout, procedure, and finally the results of the accompanying evaluation. However, the implementation of the digital twins to date does not yet include features that address the tactile experience of working in real-world labs.
The energy system is changing since some years in order to achieve the climate goals from the Paris Agreement which wants to prevent an increase of the global temperature above 2 °C [1]. Decarbonisation of the energy system has become for governments a big challenge and different strategies are being stablished. Germany has set greenhouse gas reduction limits for different years and keeps track of the improvement made yearly. The expansion of renewable energy systems (RES) together with decarbonisation technologies are a key factor to accomplish this objective.
This research is done to analyse the effect of introducing biochar, a decarbonisation technology, and study how it will affect the energy system. Pyrolysis is the process from which biochar is obtained and it is modelled in an open-source energy system model. A sensibility analysis is done in order to assess the effect of changing the biomass potential and the costs for pyrolysis.
The role of pyrolysis is analysed in the form of different future scenarios for the year 2045 to evaluate the impact when the CO2 emission limit is zero. All scenarios are compared to the reference scenario, where pyrolysis is not considered.
Results show that biochar can be used to compensate the emissions from other conventional power plant and achieve an energy transition with lower costs. Furthermore, it was also found that pyrolysis can also reduce the need of flexibility. This study also shows that the biomass potential and the pyrolysis costs can strongly affect the behaviour of pyrolysis in the energy system.
Eco-Feasibility Study and Application of Natural Inventive Principles in Chemical Engineering Design
(2022)
The early stages of the front-end process development are critical for the future success of projects involving new technologies. The application of eco-inventive principles identified in natural systems to the design of chemical processes and equipment allows one to find ways to mitigate or avoid secondary ecological problems such as, for example, higher consumption of raw materials or energy, generation of hazardous waste and pollution of the environment by toxic chemicals. However, before implementing a new technology in a real operational environment, it is necessary to completely investigate its undesirable ecological impact and to evaluate the future viability of this technology. Therefore, the research paper presents a study of ecological feasibility of an innovative process design utilising natural eco-inventive principles and analyses the correlations between applied inventive principles. Such eco-feasibility study can be considered as an important decision gate to determine whether the technology implementation should be moved forward. Furthermore, the study evaluates the practicability of natural inventive principles to the eco-friendly process design and is illustrated with an example of a sustainable technology for nickel extraction from pyrophyllite.
Additive manufacturing with plastics enables the production of lightweight and resilient components with a high degree of design freedom. In the low-cost sector, Material Extrusion as Fused Layer Modeling (FLM) has so far been the leading method, as it offers simple 3D printers and a variety of inexpensive 3D materials. However, printing times for 6FLM are very long and dimensional accuracy and surface finish are rather poor. Recently, new processes from the field of Vat Polymerization have appeared on the market, such as masked Stereolithography (mSLA), which offer a significant improvement in component quality and build speed at equally favorable machine costs.
This paper therefore analyzes the technical and economic capabilities of the two competing additive processes. For this purpose, the achievable dimensional and surface qualities are determined using a test specimen which represents various important geometry elements. In addition, the machine and material costs are determined and compared with each other. Finally, the resulting environmental impact is determined in the form of the CO2 footprint. In order to optimize the strength of the printed components, material properties of the tensile specimens produced additively with mSLA are determined. The use of ABS-like resins will also be investigated to determine optimal processing settings.
During the coronavirus crisis, labs had to be offered in digital form in mechanical engineering at short notice. For this purpose, digital twins of more complex test benches in the field of fluid energy machines were used in the mechanical engineering course, with which the students were able to interact remotely to obtain measurement data. The concept of the respective lab was revised with regard to its implementation as a remote laboratory. Fortunately, real-world labs were able to be fully replaced by remote labs. Student perceptions of remote labs were mostly positive. This paper explains the concept and design of the digital twins and the lab as well as the layout, procedure, and finally the results of the accompanying evaluation. However, the implementation of the digital twins to date does not yet include features which address the tactile experience of working in real-world labs.
In automotive parking scenario, where the curb shall be detected and classified to be traversable or not, radars play an important role. There are different approaches already proposed in other works to estimate the target height. This paper assesses and compares two methods. The first is based on Angle of Arrival (AoA) estimation of input signals of multiple antennas using the Multiple-Input-Multiple-Output (MIMO) principle. The second method uses the geometry in multipath propagation of the radar echo signal for one antenna input. In this work a modified method of calculation of the curb height based on the second method is proposed. The theory of approach is mathematically proved and effectiveness is demonstrated by evaluation of measurements with a 77 GHz Frequency Modulated Continuous Wave (FMCW) radar. In order to evaluate the performance of the introduced method the mean square error (MSE) is used in the proposed scenario. This method, using only one antenna input, produced up to 3.4 times better results for curb height detection in comparison with former methods.
In this study, various imaging algorithms for the localization of objects have been investigated. Therefore, an Ultra-Wideband (UWB) radar based experimental setup with a circular antenna array is designed as part of this work. This concept could be particularly useful in microwave medical imaging applications. In order to validate its applicability in microwave imaging, different imaging algorithms have been evaluated and compared by means of our experimental setup. Accurate imaging results have been achieved with our system under multiple test-scenarios.
In this study, an approach to a microwave-based radar system for the localization of objects has been proposed. This could be particularly useful in microwave imaging applications such as cardiac catheter detection. An experimental system is defined and realized with the selection of an appropriate antenna design. Hardware control functions and different imaging algorithms are implemented as well. The functionality of this measurement setup has been analyzed considering multiple testscenarios and it is proved to be capable of locating multiple objects as well as expanded objects.