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With recent developments in the Ukrainian-Russian conflict, many are discussing about Germany’s dependency on fossil fuel imports in its energy system, and how can the country proceed with reducing that dependency. With its wide-ranging consumption sectors, the electricity sector comes as the perfect choice to start with. Recent reports showed that the German federal government is already intending to have a fully renewable electricity by 2035 while exploiting all possible clean power options. This was published in the federal government’s climate emergency program (Easter Package) in early 2022. The aim of this package is to initiate a rapid transition and decarbonization of the electricity sector. The Easter Package expects an enormous growth of renewable energies to a completely new level, with already at least 80% renewable gross energy consumption, with extensive and broad deployment of different generation technologies on various scales. This paper will discuss this ambitious plan and outline some insights into this huge and rapidly increasing step, and show how much will Germany need in order to achieve this huge milestone towards a fully green supply of the electricity sector. Different scenarios and shares of renewables will be investigated in order to elaborate on preponed climate-neutral goal of the electricity sector by 2035. The results pointed out some promising aspects in achieving a 100% renewable power, with massive investments in both generation and storage technologies.
Erfinderisches Problemlösen mit TRIZ : Zielbeschreibung, Problemdefinition und Lösungspriorisierung
(2017)
Die Theorie des erfinderischen Problemlösens, TRIZ, ist eine Systematik von Annahmen, Regeln, Methoden und Werkzeugen zur innovativen Systemverbesserung z.B. von Produkten, Prozessen, Dienstleistungen oder Organisationen. Diese Richtlinie erläutert TRIZ-Werkzeuge und -Methoden, die insbesondere in den Phasen "Zielbeschreibung", "Problemdefinition" und "Lösungspriorisierung" des Problemlösungsprozesses eingesetzt werden. Die Detailtiefe der Beschreibung erlaubt eine Einschätzung der Werkzeuge und Methoden hinsichtlich Einsatzzwecken, Ergebnissen und Funktionsweise. Die jeweilige Beschreibung der Methoden und Werkzeuge enthält konkrete Aussagen über Zielsetzung und Ergebnis ihres Einsatzes.
BACKGROUND
Various neutral and alkaline peptidases are commercially available for use in protein hydrolysis under neutral to alkaline conditions. However, the hydrolysis of proteins under acidic conditions by applying fungal aspartic peptidases (FAPs) has not been investigated in depth so far. The aim of this study, thus, was to purify a FAP from the commercial enzyme preparation, ROHALASE® BXL, determine its biochemical characteristics, and investigate its application for the hydrolysis of food and animal feed proteins under acidic conditions.
RESULTS
A Trichoderma reesei derived FAP, with an apparent molecular mass of 45.8 kDa (sodium dodecyl sulfate–polyacrylamide gel electrophoresis; SDS-PAGE) was purified 13.8-fold with a yield of 37% from ROHALASE® BXL. The FAP was identified as an aspartate protease (UniProt ID: G0R8T0) by inhibition and nano-LC-ESI-MS/MS studies. The FAP showed the highest activity at 50°C and pH 4.0. Monovalent cations, organic solvents, and reducing agents were tolerated well by the FAP. The FAP underwent an apparent competitive product inhibition by soy protein hydrolysate and whey protein hydrolysate with apparent Ki-values of 1.75 and 30.2 mg*mL−1, respectively. The FAP showed promising results in food (soy protein isolate and whey protein isolate) and animal feed protein hydrolyses. For the latter, an increase in the soluble protein content of 109% was noted after 30 min.
CONCLUSION
Our results demonstrate the applicability of fungal aspartic endopeptidases in the food and animal feed industry. Efficient protein hydrolysis of industrially relevant substrates such as acidic whey or animal feed proteins could be conducted by applying fungal aspartic peptidases. © 2022 Society of Chemical Industry.
A systematic toxicological analysis procedure using high-performance thin layer chromatography in combination with fibre optical scanning densitometry for identification of drugs in biological samples is presented. Two examples illustrate the practicability of the technique. First, the identification of a multiple intake of analgesics: codeine, propyphenazone, tramadol, flupirtine and lidocaine, and second, the detection of the sedative diphenhydramine. In both cases, authentic urine specimens were used. The identifications were carried out by an automatic measurement and computer-based comparison of in situ UV spectra with data from a compiled library of reference spectra using the cross-correlation function. The technique allowed a parallel recording of chromatograms and in situ UV spectra in the range of 197–612 nm. Unlike the conventional densitometry, a dependency of UV spectra by concentration of substance in a range of 250–1000 ng/spot was not observed.
This paper describes the Sweaty II humanoid adult size robot trying to qualify for the RoboCup 2018 adult size humanoid competition. Sweaty came 2nd in RoboCup 2017 adult size league. The main characteristics of Sweaty are described in the Team Description Paper 2017. The improvements that have been made or are planned to be implemented for RoboCup 2018 are described in this paper.
Passive solar elements for both direct and indirect gains, are systems used to maintain a comfortable living environment while saving energy, especially in the building energy retrofit and adaptation process. Sunspaces, thermal mass and glazing area and orientation have been often used in the past to guarantee adequate indoor conditions when mechanical devices were not available. After a period of neglect, nowadays they are again considered as appropriate systems to help face environmental issues in the building sector, and both international and national legislation takes into consideration the possibility of including them in the building planning tools, also providing economic incentives. Their proper design needs dynamic simulation, often difficult to perform and time consuming. Moreover, results generally suffer from several uncertainties, so quasi steady-state procedures are often used in everyday practice with good results, but some corrections are still needed. In this paper, a comparative analysis of different solutions for the construction of verandas in an existing building is presented, following the procedure provided by the slightly modified and improved Standard EN ISO 13790:2008. Advantages and disadvantages of different configurations considering thermal insulation, windows typology and mechanical ventilation systems are discussed and a general intervention strategy is proposed. The aim is to highlight the possibility of using sunspaces in order to increase the efficiency of the existing building stock, considering ease of construction and economic viability.
Energy Performance of Verandas in the Building Retrofit Process (PDF Download Available). Available from: https://www.researchgate.net/publication/303093420_Energy_Performance_of_Verandas_in_the_Building_Retrofit_Process [accessed Jul 5, 2017].
Linear acceleration is a key performance determinant and major training component of many sports. Although extensive research about lower limb kinetics and kinematics is available, consistent definitions of distinctive key body positions, the underlying mechanisms and their related movement strategies are lacking. The aim of this ‘Method and Theoretical Perspective’ article is to introduce a conceptual framework which classifies the sagittal plane ‘shin roll’ motion during accelerated sprinting. By emphasising the importance of the shin segment’s orientation in space, four distinctive key positions are presented (‘shin block’, ‘touchdown’, ‘heel lock’ and ‘propulsion pose’), which are linked by a progressive ‘shin roll’ motion during swing-stance transition. The shin’s downward tilt is driven by three different movement strategies (‘shin alignment’, ‘horizontal ankle rocker’ and ‘shin drop’). The tilt’s optimal amount and timing will contribute to a mechanically efficient acceleration via timely staggered proximal-to-distal power output. Empirical data obtained from athletes of different performance levels and sporting backgrounds are required to verify the feasibility of this concept. The framework presented here should facilitate future biomechanical analyses and may enable coaches and practitioners to develop specific training programs and feedback strategies to provide athletes with a more efficient acceleration technique.
MINT-College TIEFE
(2021)
Das Projekt MINT-College TIEFE konnte in der zweiten Förderperiode die verschiedenen Maßnahmen der vorangegangenen Förderperiode weiter ausbauen und verstetigen. Die Angebote im Rahmen des Projekts MINT-College TIEFE begleiteten die Studierenden über den Student-Life-Cycle hinweg über das komplette Studium der technischen Studiengänge, beginnend in der Schule und endend beim Übergang in den Beruf. Um die Qualität der Lehre an der Hochschule Offenburg zu verbessern, wurden darüber hinaus verschiedene digital unterstützte Lehrformate weiterentwickelt und ausgebaut. Zentrale Angebote des MINT-College, das 2019 zentrale Einrichtung der Hochschule Offenburg wurde, sind die für die Studieneingangsphase entwickelten Angebote der Einführungstage, des Mentorenprogramms, der Brückenkurse, des Lernzentrums und Angebote für den Übergang in den Beruf, wie das Gründerbüro. Die mediendidaktischen Unterstützungsangebote für Lehrende unterstützten den Lernkulturwandel an der Hochschule. Es wurden systematisch nachhaltige Strukturen aufgebaut, um Innovationen für das Lehren und das Lernen auch künftig entwickeln, erproben und etablieren zu können.
Experimental Investigation of the Air Exchange Effectiveness of Push-Pull Ventilation Devices
(2020)
The increasing installation numbers of ventilation units in residential buildings are driven by legal objectives to improve their energy efficiency. The dimensioning of a ventilation system for nearly zero energy buildings is usually based on the air flow rate desired by the clients or requested by technical regulations. However, this does not necessarily lead to a system actually able to renew the air volume of the living space effectively. In recent years decentralised systems with an alternating operation mode and fairly good energy efficiencies entered the market and following question was raised: “Does this operation mode allow an efficient air renewal?” This question can be answered experimentally by performing a tracer gas analysis. In the presented study, a total of 15 preliminary tests are carried out in a climatic chamber representing a single room equipped with two push-pull devices. The tests include summer, winter and isothermal supply air conditions since this parameter variation is missing till now for push-pull devices. Further investigations are dedicated to the effect of thermal convection due to human heat dissipation on the room air flow. In dependence on these boundary conditions, the determined air exchange efficiency varies, lagging behind the expected range 0.5 < εa < 1 in almost all cases, indicating insufficient air exchange including short-circuiting. Local air exchange values suggest inhomogeneous air renewal depending on the distance to the indoor apertures as well as the temperature gradients between in- and outdoor. The tested measurement set-up is applicable for field measurements.
We present a 3D simulation approach utilising the diffuse interface representation of the phase-field method combined with a heat transfer equation to analyse the thermal conductivity in air-filled aluminium foams with complex cellular structures of different porosity. Algorithmic methods are introduced to create synthetic open-cell foam structures and to compute the thermal conductivity by means of phase-field modelling. A material law for the effective thermal conductivity is derived by determining the appropriate exponent depending on the relative density in the system. The results are compared with the thermal conductivity in massive aluminium and in pure air.
Bud type carbon nanohorns (CNHs) are composed of carbon and have a closed conical tip at one end protruding from an aggregate structure. By employing a simple oxidation process in CO2 atmosphere, it is possible to open the CNH tips which increases their specific surface area by four fold. These tip opened CNHs combine the microporous nature of activated carbons and the crystalline mesoporous character of carbon nanotubes. The results for the high pressure CO2 gas adsorption of tip opened CNHs are reported herein for the first time and are found to be superior to traditional CO2 adsorbents like zeolites. The modified CNHs are also found to be promising materials for lithium ion batteries and the performance is found to be on a par with carbon nanotubes and carbon nanofibers.
Gas adsorption studies of CO2 and N2 in spatially aligned double-walled carbon nanotube arrays
(2013)
Gas adsorption studies (CO2 and N2) over a wide pressure range on vertically, highly aligned dense double-walled carbon nanotube arrays of high purity and high specific surface area are reported. At high pressures, the adsorption capacity of these materials was found to be comparable to those of metal organic frameworks and mesoporous molecular sieves. These highly aligned CNT arrays were chemically modified by treating with oxygen plasma and structurally modified by decreasing the diameter of individual carbon nanotubes. Oxygen plasma treatment led to grafting of a large number of C–O functional groups onto the CNT surface, which further increased the gas adsorption capacity. It was found that gas adsorption is dependent on tube diameter and increases with decrease of the individual CNT diameter in the CNT bundles. As results of our studies we have found that at lower pressure regimes, plasma functionalized carbon nanotubes exhibit better adsorption characteristics whereas at higher pressures, lower diameter carbon nanotube structures exhibited better gas adsorption characteristics.
The invention relates to the field of transporting flat substrates such as silicon substrates. In particular, the invention relates to particularly protective and continuous transport of such substrates. The method according to the invention is used to transport a vertically aligned flat substrate (1) comprising two flat sides in a transport direction inside a transport channel (2) that is at least partially filled with a liquid medium (F), wherein said liquid medium (F) flows against at least one of the flat sides of the substrate (1) and has a supporting component, which lifts the sum of the weight and buoyancy force of the substrate (1), and an advancing component, which is directed in the transport direction, so that the substrate (1) is supported and transported without mechanical aids. The device according to the invention comprises a transport channel (2) for accommodating a liquid medium (F) and a substrate (1) to be guided in vertical alignment within said medium (F), wherein the transport channel (2) has inflow openings (5) in the walls (3, 4).
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
Die Erfindung betrifft das Gebiet des Transports flacher Substrate wie beispielsweise Siliziumsubstrate. Insbesondere betrifft die Erfindung den besonders schonenden und kontinuierlichen Transport solcher Substrate. Das erfindungsgemäße Verfahren dient dem Transport eines vertikal ausgerichteten flachen Substrats (1) in eine Transportrichtung innerhalb eines mit einem flüssigen Medium (F) gefüllten Transportkanals (2), wobei das flüssige Medium (F) gegen mindestens eine der Flachseiten des Substrats (1) strömt und eine die Summe aus Gewichts- und Auftriebskraft des Substrats (1) aufhebende Tragekomponente, sowie eine in Transportrichtung gerichtete Vorschubkomponente aufweist, so dass das Substrat (1) ohne mechanische Hilfsmittel getragen und transportiert wird. Die erfindungsgemäße Vorrichtung umfasst einen Transportkanal (2) zur Aufnahme eines flüssiges Mediums (F) sowie eines innerhalb dieses Mediums (F) in vertikaler Ausrichtung zu führenden Substrats (1), wobei der Transportkanal (2) in seinem Wandbereich (3, 4) Einströmöffnungen (5) aufweist.
A two-dimensional single-phase model is developed for the steady-state and transient analysis of polymer electrolyte membrane fuel cells (PEMFC). Based on diluted and concentrated solution theories, viscous flow is introduced into a phenomenological multi-component modeling framework in the membrane. Characteristic variables related to the water uptake are discussed. A Butler–Volmer formulation of the current-overpotential relationship is developed based on an elementary mechanism of electrochemical oxygen reduction. Validated by using published V–I experiments, the model is then used to analyze the effects of operating conditions on current output and water management, especially net water transport coefficient along the channel. For a power PEMFC, the long-channel configuration is helpful for internal humidification and anode water removal, operating in counterflow mode with proper gas flow rate and humidity. In time domain, a typical transient process with closed anode is also investigated.
The state-of-the-art electrochemical impedance spectroscopy (EIS) calculations have not yet started from fully multi-dimensional modeling. For a polymer electrolyte membrane fuel cell (PEMFC) with long flow channel, the impedance plot shows a multi-arc characteristic and some impedance arcs could merge. By using a step excitation/Fourier transform algorithm, an EIS simulation is implemented for the first time based on the full 2D PEMFC model presented in the first part of this work. All the dominant transient behaviors are able to be captured. A novel methodology called ‘configuration of system dynamics’, which is suitable for any electrochemical system, is then developed to resolve the physical meaning of the impedance spectra. In addition to the high-frequency arc due to charge transfer, the Nyquist plots contain additional medium/low-frequency arcs due to mass transfer in the diffusion layers and along the channel, as well as a low-frequency arc resulting from water transport in the membrane. In some case, the impedance spectra appear partly inductive due to water transport, which demonstrates the complexity of the water management of PEMFCs and the necessity of physics-based calculations.
This work provides a series of methane adsorption isotherms and breakthrough curves on one 5A zeolite and one activated carbon. Breakthrough curves of CH4 were obtained from dynamic column measurements at different temperature and pressure conditions for concentrations of 4.4 – 17.3 mol.‐% in H2/CH4 mixtures. A simple model was developed to simulate the curves using measured and calculated data inputs. The results show that the model predictions agree very well with the experiments.