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Rotating flow systems are often used to study stability phenomena and structure developments. The closed spherical gap problem is generalized into an open flow system by superimposing a mass flux in meridional direction. The basic solutions at low Reynolds numbers are described by analytical methods. The nonlinear supercritical solutions are simulated numerically and realized in experiments. Novel steady and time-dependent modes of flows are obtained. The extensive results concern the stability behaviour, non-uniqueness of supercritical solutions, symmetry behaviour and transitions between steady and time-dependent solutions. The experimental investigations concern the visualization of the various instabilities and the quatitative description of the flow structures including the laminar-turbulent transition. A comparison between theoretical and experimental results shows good agreement within the limit of rotational symmetric solutions from the theory.
To do justice to the legacy of Alexander von Humboldt, a 19th century German scientist and explorer an information and knowledge management system is required to preserve the author’s original intent and promote an awareness of all his relevant works. Although all of Humboldt's works can be found on the internet as digitized papers, the complexity and internal interconnectivity of the writings is not very transparent. Humboldt's concepts of interaction cannot be adequately represented only by digitized papers or scanned documents.
The Humboldt Portal is an attempt to create a new generation of digital libraries, providing a new form of interaction and synthesis between humanistic texts and scientific observation. The digital version of his documents supplies dynamic links to sources, maps, images, graphs and relevant texts in accordance with his visions, because “everything is interconnectedness”.
Digitalisierung ist heute allgegenwärtig. Wo im Privaten bereitwillig neue digitale Tools, Apps und Funktionen genutzt werden, tun sich Unternehmen in der Umsetzung von Digitalisierungsprojekten oft schwer. Dieser Beitrag beleuchtet die Motive für Digitalisierungsvorhaben, ihre Hürden sowie die Auswirkung auf die Arbeitsbelastung von Mitarbeitenden und versucht in der Verknüpfung mit den Grundprinzipien des Kontinuierlichen Verbesserungsprozesses, Handlungsempfehlungen für eine erfolgreiche Umsetzung dieser abzuleiten.
Mayur, Manik ; Yagci, Mehmet C. ; Carelli, Serena ; Margulies, Peter ; Velten, Dirk ; Bessler, Wolfgang G.
The measurement of the active material volume fraction in composite electrodes of lithium-ion battery cells is difficult due to the small (sub-micrometer) and irregular structure and multi-component composition of the electrodes, particularly in the case of blend electrodes. State-of-the-art experimental methods such as focused ion beam/scanning electron microscopy (FIB/SEM) and subsequent image analysis require expensive equipment and significant expertise. We present here a simple method for identifying active material volume fractions in single-material and blend electrodes, based on the comparison of experimental equilibrium cell voltage curve (open-circuit voltage as function of charge throughput) with active material half-cell potential curves (half-cell potential as function of lithium stoichiometry). The method requires only (i) low-current cycling data of full cells, (ii) cell opening for measurement of electrode thickness and active electrode area, and (iii) literature half-cell potentials of the active materials. Mathematical optimization is used to identify volume fractions and lithium stoichiometry ranges in which the active materials are cycled. The method is particularly useful for model parameterization of either physicochemical (e.g., pseudo-two-dimensional) models or equivalent circuit models, as it yields a self-consistent set of stoichiometric and structural parameters. The method is demonstrated using a commercial LCO–NCA/graphite pouch cell with blend cathode, but can also be applied to other blends (e.g., graphite–silicon anode).
Feng, Xiaowei ; Punckt, Christian ; Cadilha Marques, Gabriel ; Hefenbrock, Michael ; Tahoori, Mehdi Baradaran ; Aghassi-Hagmann, Jasmin
Electrolyte-gated, printed field-effect transistors exhibit high charge carrier densities in the channel and thus high on-currents at low operating voltages, allowing for the low-power operation of such devices. This behavior is due to the high area-specific capacitance of the device, in which the electrolyte takes the role of the dielectric layer of classical architectures. In this paper, we investigate intrinsic double-layer capacitances of ink-jet printed electrolyte-gated inorganic field-effect transistors in both in-plane and top-gate architectures by means of voltage-dependent impedance spectroscopy. By comparison with deembedding structures, we separate the intrinsic properties of the double-layer capacitance at the transistor channel from parasitic effects and deduce accurate estimates for the double-layer capacitance based on an equivalent circuit fitting. Based on these results, we have performed simulations of the electrolyte cutoff frequency as a function of electrolyte and gate resistances, showing that the top-gate architecture has the potential to reach the kilohertz regime with proper optimization of materials and printing process. Our findings additionally enable accurate modeling of the frequency-dependent capacitance of electrolyte/ion gel-gated devices as required in the small-signal analysis in the circuit simulation.
Impedance of the Surface Double Layer of LSCF/CGO Composite Cathodes: An Elementary Kinetic Model
(2014)
Various methods of Digital Manufacturing (DM) have been available for the manufacturing of physical architectural models for several years. This paper highlights the advantages of 3D printing for digital manufacturing of detailed architectural models. In particular, the representation of architectural details and textures is treated. Furthermore, two new methods are being developed in order to improve the conditions for the application of digital manufacturing of architectural models.
Rösch, Andres Georg ; Giunta, Fabian ; Mallick, Mofasser ; Franke, Leonard ; Gall, André ; Aghassi-Hagmann, Jasmin ; Schmalian, Jörg ; Lemmer, Uli
Effective medium theories (EMT) are powerful tools to calculate sample averaged thermoelectric material properties of composite materials. However, averaging over the heterogeneous spatial distribution of the phases can lead to incorrect estimates of the thermoelectric transport properties and the figure of merit ZT in compositions close to the percolation threshold. This is particularly true when the phases’ electronic properties are rather distinct leading to pronounced percolation effects. The authors propose an alternative model to calculate the thermoelectric properties of multi‐phased materials that are based on an expanded nodal analysis of random resistor networks (RRN). This method conserves the information about the morphology of the individual phases, allowing the study of the current paths through the phases and the influence of heterogeneous charge transport and cluster formation on the effective material properties of the composite. The authors show that in composites with strongly differing phases close to the percolation threshold the thermoelectric properties and the ZT value are always dominated exclusively by one phase or the other and never by an average of both. For these compositions, the individual samples display properties vastly different from EMT predictions and can be exploited for an increased thermoelectric performance.
International trade requires sufficient, reliable, and affordable sources of financing. Export credit agencies (ECAs) fill trade finance gaps by offering financing, insurance and guarantees to provide liquidity or mitigate risks. They help to create or secure jobs in the domestic economy. However, comprehensive government support is required to create significant impact. This includes ‘full faith and credit’ of the state. In the context of public foreign trade promotion, full faith and credit is defined as an explicit, direct or indirect, irrevocable, legal commitment to accept all liabilities of an ECA as unconditional obligations of the respective government. Our policy recommendations for countries with relatively young ECAs, for example in Ukraine, Armenia, and Malawi, are to establish a full guarantee in addition to an efficient legal set-up, sufficient capital, and sound risk management of the respective agency. Without full faith and credit, policy goals of fostering economic growth through foreign trade fall short.
Neural networks tend to overfit the training distribution and perform poorly on out-ofdistribution data. A conceptually simple solution lies in adversarial training, which introduces worst-case perturbations into the training data and thus improves model generalization to some extent. However, it is only one ingredient towards generally more robust models and requires knowledge about the potential attacks or inference time data corruptions during model training. This paper focuses on the native robustness of models that can learn robust behavior directly from conventional training data without out-of-distribution examples. To this end, we study the frequencies in learned convolution filters. Clean-trained models often prioritize high-frequency information, whereas adversarial training enforces models to shift the focus to low-frequency details during training. By mimicking this behavior through frequency regularization in learned convolution weights, we achieve improved native robustness to adversarial attacks, common corruptions, and other out-of-distribution tests. Additionally, this method leads to more favorable shifts in decision-making towards low-frequency information, such as shapes, which inherently aligns more closely with human vision.