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Cell lifetime diagnostics and system be-havior of stationary LFP/graphite lithium-ion batteries
(2018)
Battery degradation is a complex physicochemical process that strongly depends on operating conditions and environment. We present a model-based analysis of lithium-ion battery degradation in smart microgrids, in particular, a single-family house and an office tract with photovoltaics generator. We use a multi-scale multi-physics model of a graphite/lithium iron phosphate (LiFePO4, LFP) cell including SEI formation as ageing mechanism. The cell-level model is dynamically coupled to a system-level model consisting of photovoltaics, inverter, power consumption profiles, grid interaction, and energy management system, fed with historic weather data. The behavior of the cell in terms of degradation propensity, performance, state of charge and other internal states is predicted over an annual operation cycle. As result, we have identified a peak in degradation rate during the battery charging process, caused by charging overpotentials. Ageing strongly depends on the load situation, where the predicted annual capacity fade is 1.9 % for the single-family house and only 1.3 % for the office tract.
Combined heat and power production (CHP) based on solid oxide fuel cells (SOFC) is a very promising technology to achieve high electrical efficiency to cover power demand by decentralized production. This paper presents a dynamic quasi 2D model of an SOFC system which consists of stack and balance of plant and includes thermal coupling between the single components. The model is implemented in Modelica® and validated with experimental data for the stack UI-characteristic and the thermal behavior. The good agreement between experimental and simulation results demonstrates the validity of the model. Different operating conditions and system configurations are tested, increasing the net electrical efficiency to 57% by implementing an anode offgas recycle rate of 65%. A sensitivity analysis of characteristic values of the system like fuel utilization, oxygen-to-carbon ratio and electrical efficiency for different natural gas compositions is carried out. The result shows that a control strategy adapted to variable natural gas composition and its energy content should be developed in order to optimize the operation of the system.
The conversion of space heating for private households to climate-neutral energy sources is an essential component of the energy transition, as this sector as of 2018 was responsible for 9.4 % of Germany’s carbon dioxide emissions. In addition to reducing demand through better insulation, the use of heat pumps fed with electricity from renewable energy sources, such as on-site photovoltaics (PV) systems, is an important solution approach.
Advanced energy management and control can help to make optimal use of such heating systems. Optimal here can e.g. refer to maximizing self-consumption of self-generated PV power, extended component lifetime or a grid-friendly behavior that avoids load peaks. A powerful method for this is model predictive control (MPC), which calculates optimal schedules for the controllable influence variables based on models of the system dynamics, current measurements of system states and predictions of future external influence parameters.
In this paper, we will discuss three different use cases that show how artificial intelligence can contribute to the realization of such an MPC-based energy management and control system. This will be done using the example of a real inhabited single family home that has provided the necessary data for this purpose and where the methods are implemented and tested. The heating system consists of an air-water heat pump with direct condensation, a thermal stratified storage tank, a pellet burner and a heating rod and provides both heating and hot water. The house generates a significant portion of its electricity needs through a rooftop PV system.
Model-based analysis of Electrochemical Pressure Impedance Spectroscopy (EPIS) for PEM Fuel Cells
(2019)
Electrochemical impedance spectroscopy (EIS) is a widely-used diagnostic technique to characterize electrochemical processes. It is based on the dynamic analysis of two electrical observables, that is, current and voltage. Electrochemical cells with gaseous reactants or products, in particular fuel cells, offer an additional observable, that is, the gas pressure. The dynamic coupling of current or voltage with gas pressure gives rise to a number of additional impedance definitions, for which we have previously introduced the term electrochemical pressure impedance spectroscopy (EPIS) [1,2]. EPIS shows a particular sensitivity towards transport processes of gas-phase or dissolved species, in particular, diffusion coefficients and transport pathway lengths. It is as such complementary to standard EIS, which is mainly sensitive towards electrochemical processes. First EPIS experiments on PEM fuel cells have recently been shown [3].
We present a detailed modeling and simulation analysis of EPIS of a PEM fuel cell. We use a 1D+1D continuum model of a fuel/air channel pair with GDL and MEA. Backpressure is dynamically varied, and the resulting simulated oscillation in cell voltage is evaluated to yield the ▁Z_( V⁄p_ca ) EPIS signal. Results are obtained for different transport situations of the fuel cell, giving rise to very complex EPIS shapes in the Nyquist plot. This complexity shows the necessity of model-based interpretation of the complex EPIS shapes. Based on the simulation results, specific features in the EPIS spectra can be assigned to different transport domains (gas channel, GDL, membrane water transport).
The humanoid Sweaty was the finalist in this year’s robocup soccer championship(adult size). For the optimization of the gait and the stability, data concerning forces and torques in the ankle joints would be helpful. In the following paper the development of a six-axis force and torque sensor for the humanoid robot Sweaty is described. Since commercial sensors do not meet the demands for the sensors in Sweatys ankle joints, a new sensor was developed. As a measuring devices we used strain gauges and custom electronics based on an acam PS09. The geometry was analyzed with the FEM program ANSYS to get optimal dimensions for the measuring beams. In addition ANSYS was used to optimize the position for the strain gauges on the beam.
The transformation of the building energy sector to a highly efficient, clean, decentralised and intelligent system requires innovative technologies like microscale trigeneration and thermally activated building structures (TABS) to pave the way ahead. The combination of such technologies however presents a scientific and engineering challenge. Scientific challenge in terms of developing optimal thermo-electric load management strategies based on overall energy system analysis and an engineering challenge in terms of implementing these strategies through process planning and control. Initial literature research has pointed out the need for a multiperspective analysis in a real life laboratory environment. To this effect an investigation is proposed wherein an analytical model of a microscale trigeneration system integrated with TABS will be developed and compared with a real life test-rig corresponding to building management systems. Data from the experimental analysis will be used to develop control algorithms using model predictive control for achieving the thermal comfort of occupants in the most energy efficient and grid reactive manner. The scope of this work encompasses adsorption cooling based microscale trigeneration systems and their deployment in residential and light commercial buildings.