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Colored glass products with various printing technologies are becoming more important in industry. The aim is to achieve individual solution in a very short delivery time. Conventional thermal treatment of burning glasses in oven for tempered color printing has predominant issues with high time consumption, energy consumption and manufacturing cost. It requires alternative process development.
This paper proposes laser process to overcome issues in conventional treatment with the latest results of tempering colored glass. Samples have been analyzed with the scanning electron microscope (SEM). Two different laser systems have been applied and the glass has been printed with black paste.
The production of potable water in dry areas nowadays is mainly done by the desalination of seawater. State of the art desalination plants usually are built with high production capacities and consume a lot of electrical energy or energy from primary resources such as oil. This causes difficulties in rural areas, where no infrastructure is available neither for the plants’ energy supply nor the distribution of the produced potable water. To address this need, small, self-sustaining and locally operated desalination plants came into the focus of research. In this work, a novel flash evaporator design is proposed which can be driven either by solar power or by low temperature waste heat. It offers low operation costs as well as easy maintenance. The results of an experimental setup operated with water at a feed flow rate of up to 1,600 l/h are presented. It is shown that the proof of concept regarding efficient evaporation as well as efficient gas-liquid separation is provided successfully. The experimental evaporation yield counts for 98 % of the vapor content that is expected from the vapor pressure curve of water. Neither measurements of the electrical conductivity of the gained condensate, nor the analysis of the vapor flow by optical methods show significant droplet entrainment, so there are no concerns regarding the purity of the produced condensate for the use as drinking water.
Techno-economic comparison of membrane distillation and MVC in a zero liquid discharge application
(2018)
Membrane distillation (MD) is a thermally driven membrane process for the separation of vapour from a liquid stream through a hydrophobic, microporous membrane. However, a commercial breakthrough on a large scale has not been achieved so far. Specific developments on MD technology are required to adapt the technology for applications in which its properties can potentially outshine state of the art technologies such as standard evaporation. In order to drive these developments in a focused manner, firstly it must be shown that MD can be economically attractive in comparison to state of the art systems. Thus, this work presents a technological design and economic analysis for AGMD and v-AGMD for application in a zero liquid discharge (ZLD) process chain and compares it to the costs of mechanical vapour compression (MVC) for the same application. The results show that MD can potentially be ~40% more cost effective than MVC for a system capacity of 100 m3/day feed water, and up to ~75% more cost effective if the MD is driven with free waste heat.
Membrane distillation (MD) is a thermal separation process which possesses a hydrophobic, microporous
membrane as vapor space. A high potential application for MD is the concentration of hypersaline brines, such as
e.g. reverse osmosis retentate or other saline effluents to be concentrated to a near saturation level with a Zero
Liquid Discharge process chain. In order to further commercialize MD for these target applications, adapted MD
module designs are required along with strategies for the mitigation of membrane wetting phenomena. This
work presents the experimental results of pilot operation with an adapted Air Gap Membrane Distillation
(AGMD) module for hypersaline brine concentration within a range of 0–240 g NaCl /kg solution. Key performance
indicators such as flux, GOR and thermal efficiency are analyzed. A new strategy for wetting mitigation
by active draining of the air gap channel by low pressure air blowing is tested and analyzed. Only small reductions
in flux and GOR of 1.2% and 4.1% respectively, are caused by air sparging into the air gap channel.
Wetting phenomena are significantly reduced by avoiding stagnant distillate in the air gap making the air blower
a seemingly worth- while additional system component.
With the need for automatic control based supervisory controllers for complex energy systems, comes the need for reduced order system models representing not only the non-linear behaviour of the components but also certain unknown process dynamics like their internal control logic. At the Institute of Energy Systems Technology in Offenburg we have built a real-life microscale trigeneration plant and present in this paper a rational modelling procedure that satisfies the necessary characteristics for models to be applied in model predictive control for grid-reactive optimal scheduling of this complex energy system. These models are validated against experimental data and the efficacy of the methodology is discussed. Their application in the future for the optimal scheduling problem is also briefly motivated.
We present a planar chromatographic separation method for the phytoestrogenic active compound equol, separated on RP-18 W (Merck, 1.14296) phase. It could be shown that an ethanolic cattle manure extract contains this phytoestrogenic active compound to a larger amount. As solvents for the mobile phase, hexane, ethyl acetate, and acetone (45:15:10, v/v); acetone and water (15:10, v/v); and n-hexane, CH2Cl2, ethyl acetate, methanol, and formic acid (40:40:20:5:1, v/v) have been used. After separation, a modified yeast estrogen screen (YES) test was applied, using the yeast strain Saccharomyces cerevisiae BJ3505 containing an estrogen receptor. Its activation by equol induces the reporter gene lacZ which encodes the enzyme β-galactosidase. The enzyme activity is measured directly on the TLC plate by using the substrate MUG (4-methylumbelliferyl-β-d-galactopyranoside) or the substrate X-β-Gal (5-bromo-4-chloro-3-indoxyl-β-d-galactopyranoside). β-Galactosidase cleaves MUG into a fluorescing compound. X-β- Gal is also hydrolyzed and then oxidized by oxygen forming the deep-blue dye 5,5′-dibromo-4,4′-dichloro-indigo. Both reactions in combination with a thin-layer chromatography (TLC) separation allow very specific detecting of equol in cattle manure, although that is a very challenging matrix. Preliminary results show that the average content of equol in liquid manure is roughly 60 μg g−1. The value for urine is 50 μg mL−1.
A Validated Quantification of Sudan Red Dyes in Spicery using TLC and a 16-bit Flatbed Scanner
(2018)
We present a video-densitometric quantification method for Sudan red dyes in spices and spice mixtures, separated by TLC. Application was done band-wise in small dots using a 5 μL glass pipette. For separation, the RP-18 plates (20 × 20 cm with fluorescent dye; Merck, Germany, 1.05559) were developed in a vertical developing chamber without vapor saturation from the starting point to a distance of 70 mm by using acetonitrile, methanol, and aqueous ammonia solution (25%; 8 + 1.8 + 0.2, v/v) as mobile phase. The quantification is based on direct measurements using an inexpensive 16-bit flatbed scanner for color measurements (in red, green, and blue). Evaluation of only the green channel makes the measurements very specific. For linearization, an extended Kubelka-Munk expression for data transformation was used. The range of linearity covers more than two magnitudes and lies between 20 and 500 ng. The extraction from a 2 g sample with acetonitrile, evaporation, and reconstitution to 200 μL with methanol and the band-wise application (7 mm) of a 10 μL sample allows a statistically defined LOD of less than 500 ppb of Sudan red dyes. To perform the analysis, a separation chamber, RP-18 plates, 5 μL glass pipettes, and a 16-bit flatbed scanner for 105 € are needed; therefore, the separation method is inexpensive, fast, and reliable.
Quantification of astaxanthin in salmons by chemiluminescence and absorption after TLC separation
(2018)
Astaxanthin is a keto-carotenoid, belongs to the chemical class of terpenes and is a yellow lipid soluble compound. The compound is present in marine animals like salmons and crustacean. Its colour is due to conjugated double bonds and these double bonds are responsible for its antioxidant effect. Its antioxidant activity is ten times stronger than other carotenoids and nearly 500 fold stronger than vitamin-E. We present a new thin layer chromatography (TLC) method to measure astaxanthin on TLC-plates (Merck, 1.05554) in the visible absorption range as well as by using chemiluminescence. For separation a solvent mixture of cyclohexane and acetone (10 + 2.4, v/v) was used. The RF-value of astaxanthin is 0.14.The limit of detection in vis-absorption is 64 ng / band and the limit of quantification is 92 ng/band. In chemiluminescence the values are 90 ng / band and 115 ng/band. The method offers two independently working measurement modes on a single plate which increase the accuracy of the quantification.
In this paper the yield surface of a recently presented microstructure-based volume element of the gray cast iron material GJL-250 is assessed after different plastic loading histories. The evolution of the yield surface is investigated for different volumetric, deviatoric and uniaxial loadings. The micromechanical material properties of the metallic matrix and the graphite inclusions are validated by means experimental stress-strain hysteresis loops. The metallic matrix is modeled as elastic-plastic with a non-linear kinematic hardening law. The graphite inclusions are described by means of a volumetric strain state dependent Young’s modulus. The results show that the shape of the yield surface does not change significantly in comparison to the initial yield surface after pure deviatoric loadings. After volumetric loadings, the dependence of the material on the Lode angle is significantly reduced. Uniaxial tensile preloadings result in a deformed yield surface, whereby the magnitude of the deformation depends on the applied load. Uniaxial preloadings to compression do not change the shape of the initial yield surface.