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The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
The formation and analysis of ten microporous triazolyl isophthalate based MOFs, including nine isomorphous and one isostructural compound is presented. The compounds 1 M – 3 M with the general formula [ M ( R 1 - R 2 - trz - ia ) ] ∞ 3 ·x H 2 O (M 2+ = Co 2+ , Cu 2+ , Zn 2+ , Cd 2+ ; R 1 = H, Me; R 2 = 2py, 2pym, prz (2py = 2-pyridinyle; 2pym = 2-pyrimidinyle; prz = pyrazinyle)) crystallize with rtl topology. They are available as single crystals and also easily accessible in a multi-gram scale via refluxing the metal salts and the protonated ligands in a solvent. Their isomorphous structures facilitate the synthesis of heteronuclear MOFs; in case of 2 M , Co 2+ ions could be gradually substituted by Cu 2+ ions. The Co 2+ :Cu 2+ ratios were determined by ICP-OES spectroscopy, the distribution of Co 2+ and Cu 2+ in the crystalline samples are investigated by SEM-EDX analysis leading to the conclusions that Cu 2+ is more favorably incorporated into the framework compared to Co 2+ and, moreover, that the distribution of the two metal ions between the crystals and within the crystals is inhomogeneous if the crystals were grown slowly. The various compositions of the heteronuclear materials lead to different colors and the sorption properties for CO 2 and N 2 are dependent on the integrated metal ions.
Adsorption of N2 and CO2 on Activated Carbon, AlO(OH) Nanoparticles, and AlO(OH) Hollow Spheres
(2015)
Adsorption behaviors of nitrogen and CO2 on Norit R1 Extra and AlO(OH) nanoparticles and hollow spheres were measured under different temperature and pressure conditions using a magnetic suspension balance. Independent from the substrate investigated, all isotherms increase at lower pressure, reach a maximum, and then decrease with increasing pressure. In addition, selected experimental data were correlated with different model approaches and compared with reliable literature data. In case of CO2 on AlO(OH), capillary condensation was observed at two defined temperatures. The results suggest that the conversion of the liquid into a supercritical adsorbate phase does not take place suddenly.
Alexander von Humboldt, a German scientist and explorer of the 19th century, viewed the natural world holistically and described the harmony of nature among the diversity of the physical world as a conjoining between all physical disciplines. He noted in his diary: “Everything is interconnectedness.”
The main feature of Humboldt’s pioneering work was later named “Humboldtian science”, meaning the accurate study of interconnected real phenomena in order to find a definite law and a dynamic cause.
Following Humboldt's idea of nature, an Internet edition of his works must preserve the author’s original intention, retain an awareness of all relevant works, and still adhere to the requirements of scholarly edition.
At the present time, however, the highly unconventional form of his publications has undermined the awareness and a comprehensive study of Humboldt’s works.
Digital libraries should supply dynamic links to sources, maps, images, graphs and relevant texts. New forms of interaction and synthesis between humanistic texts and scientific observation need to be created.
Information technology is the only way to do justice to the broad range of visions, descriptions and the idea of nature of Humboldt’s legacy. It finally leads to virtual research environments as an adequate concept to redesign our digital archives, not only for Humboldt’s documents, but for all interconnected data.
An Extraction Method for 17α-Ethinylestradiol from Water using a new kind of monolithic Stir-bar
(2015)
Mit der neuen Abgasnorm Euro VI und den steigenden Kraftstoffpreisen müssen Nutzfahrzeugantriebe eine Reduzierung der CO2-Emission und eine höhere Effizienz vorweisen (Umweltbundesamt, 2015). Um diese Anforderungen erfüllen zu können, wird bei vielen Nutzfahrzeugherstellern intensiv an Systemen zur Rückgewinnung von Abgasenergie, den sogenannten Waste-Heat-Recovery-Systemen, geforscht. Eine Kraftstoffersparnis von rund 5 % wird dabei angestrebt.
Das System basiert auf einem ORC-Prozess. Bei diesem thermodynamischen Kreisprozess wird die Abwärme des Abgases über einen Wärmetauscher geführt, der das organische Arbeitsfluid Ethanol in einem geschlossenen Kreislauf erhitzt. Durch den Dampfdruckaufbau wird eine Turbine angetrieben. Zur Transformation der Enthalpie des Ethanoldampfes in mechanische Energie sind Drehzahlen von bis zu 120000 U/min notwendig, um eine hohe Effizienz des Systems vorweisen zu können. Systemdrücke bis 50 bar und Temperaturen des Ethanoldampfes von maximal 300 °C treten im WHR-System auf und führen zu extremen Beanspruchungen. Eine besondere Herausforderung stellen hierbei die Wellendichtungen, vor allem bei nutzfahrzeugtypischen Lebensdauern, dar. Als interessante Alternative zeigt sich die Zentrifugal-Wellendichtung, um die hohen Dichtungsanforderungen über die geforderten Laufzeiten zuverlässig zu erfüllen.
Durch methodisch stufenweise ablauforientiertes Vorgehen wird die Analyse der Zentrifugal-Wellendichtungen durchgeführt. Hierbei wird zuallererst das Wirkprinzip untersucht. Ein besonderes Augenmerk wird dabei auf die Wärmeeinträge aus der Umgebung und Verwendung unterschiedlicher Sperrfluide gelegt.
Für eine Testdrehzahl von 15000 U/min ergibt sich, bei einer beidseitig glatten Scheibe mit einem Scheibenradius von 8,7 mm, eine maximal abdichtbare Druckdifferenz von 0,04 bar. Im Sperrfluid herrschen hierbei Temperaturen von rund 50 °C. Die Versuche zeigen Korrelationen zu den bekannten theoretischen Ansätzen von Ketola und McGrey. Die maximale Druckdifferenz beträgt in diesem Fall 0,043 bar. Nachdem stationäre Betrachtungen ausreichend untersucht werden, widmet sich diese Arbeit dem Anfahr- und Not-Aus-Verhalten. Die Optimierung des Projekts wird durch abschließende Verbesserungsvorschläge, für die Realisierung höherer Sperrdrücke, erzielt.