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This thesis explores the feasibility and optimization of a solar-thermal sorption system mainly designed to provide cooling but also capable of heating functionalities. Through the development of a black-box model using Python programming, the study delves into the system's performance under various operation modes. Simulation results reveal the effectiveness of adaptive control strategies and pre-heating stages in optimizing efficiency, particularly in cooling modes. In heating assessments, superior performance is observed when utilizing the outdoor coil as the heat source for the heat pump. Challenges related to operational temperature bands are addressed, proposing parallel connections of the heat pump and outdoor coil to enhance performance. Future research directions include refining regression models and incorporating real-time measurement data for improved accuracy, as well as extending simulation duration for comprehensive evaluations. This study contributes valuable insights into the system’s capabilities and applications, laying the groundwork for advancements in heat-driven integrated sustainable energy systems.
Die fluktuierende Verfügbarkeit regenerativer Energiequellen stellt eine Herausforderung bei der Planung und Auslegung regenerativer Gebäudeenergiesysteme dar. Die in einem System benötigten Speicherkapazitäten hängen dabei sowohl von der eingesetzten Regelungsstrategie als auch von den temperaturabhängigen Wirkungsgraden der Anlagenkomponenten ab. Genauere Einblicke in das Betriebsverhalten eines Gesamtsystems können dynamische Simulationen liefern, die eine Analyse der Systemtemperaturen und von Teilenergiekennwerten ermöglichen.
We present an electrochemical model of a lithium iron phosphate/graphite (LFP/C6) cell that includes combined aging mechanisms: (i) Electrochemical formation of the solid electrolyte interphase (SEI) at the anode, leading to loss of lithium inventory, (ii) breaking of the SEI due to volume changes of the graphite particles, causing accelerated SEI growth, and (iii) loss of active material due to of loss percolation of the liquid electrolyte resulting from electrode dry-out. The latter requires the introduction of an activity-saturation relationship. A time-upscaling methodology is developed that allows to simulate large time spans (thousands of operating hours). The combined modeling and simulation framework is able to predict calendaric and cyclic aging up to the end of life of the battery cells. The aging parameters are adjusted to match literature calendaric and cyclic aging experiments, resulting in quantitative agreement of simulated nonlinear capacity loss with experimental data. The model predicts and provides an interpretation for the dependence of capacity loss on temperature, cycling depth, and average SOC. The introduction of a percolation threshold in the activity-saturation relationship allows to capture the strong nonlinearity of aging toward end of life (“sudden death”).
The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).