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During pyrolysis, biomass is carbonised in the absence of oxygen to produce biochar with heat and/or electricity as co-products making pyrolysis one of the promising negative emission technologies to reach climate goals worldwide. This paper presents a simplified representation of pyrolysis and analyses the impact of this technology on the energy system. Results show that the use of pyrolysis can allow getting zero emissions with lower costs by making changes in the unit commitment of the power plants, e.g. conventional power plants are used differently, as the emissions will be compensated by biochar. Additionally, the process of pyrolysis can enhance the flexibility of energy systems, as it shows a correlation between the electricity generated by pyrolysis and the hydrogen installation capacity, being hydrogen used less when pyrolysis appears. The results indicate that pyrolysis, which is available on the market, integrates well into the energy system with a promising potential to sequester carbon.
Recent advances in spiked shoe design, characterized by increased longitudinal stiffness, thicker midsole foams, and reconfigured geometry are considered to improve sprint performance. However, so far there is no empirical data on the effects of advanced spikes technology on maximal sprinting speed (MSS) published yet. Consequently, we assessed MSS via ‘flying 30m’ sprints of 44 trained male (PR: 10.32 s - 12.08 s) and female (PR: 11.56 s - 14.18 s) athletes, wearing both traditional and advanced spikes in a randomized, repeated measures design. The results revealed a statistically significant increase in MSS by 1.21% on average when using advanced spikes technology. Notably, 87% of participants showed improved MSS with the use of advanced spikes. A cluster analysis unveiled that athletes with higher MSS may benefit to a greater extent. However, individual responses varied widely, suggesting the influence of multiple factors that need detailed exploration. Therefore, coaches and athletes are advised to interpret the promising performance enhancements cautiously and evaluate the appropriateness of the advanced spike technology for their athletes critically.
High-tech running shoes and spikes ("super-footwear") are currently being debated in sports. There is direct evidence that distance running super shoes improve running economy; however, it is not well established to which extent world-class performances are affected over the range of track and road running events.
This study examined publicly available performance datasets of annual best track and road performances for evidence of potential systematic performance effects following the introduction of super footwear. The analysis was based on the 100 best performances per year for men and women in outdoor events from 2010 to 2022, provided by the world governing body of athletics (World Athletics).
We found evidence of progressing improvements in track and road running performances after the introduction of super distance running shoes in 2016 and super spike technology in 2019. This evidence is more pronounced for distances longer than 1500 m in women and longer than 5000 m in men. Women seem to benefit more from super footwear in distance running events than men.
While the observational study design limits causal inference, this study provides a database on potential systematic performance effects following the introduction of super shoes/spikes in track and road running events in world-class athletes. Further research is needed to examine the underlying mechanisms and, in particular, potential sex differences in the performance effects of super footwear.
Objective: This paper deals with the design and the optimization of mechatronic devices.
Introduction: Comparing with existing works, the design approach presented in this paper aims to integrate optimization in the design phase of complex mechatronic systems in order to increase the efficiency of this method.
Methods: To solve this problem, a novel mechatronic system design approach has been developed in order to take the multidisciplinary aspect and to consider optimization as a tool that can be used within the embodiment design process to build mechatronic solutions from a set of solution concepts designed with innovative or routine design methods.
Conclusions: This approach has then been applied to the design and optimization of a wind turbine system that can be implemented to autonomously supply a mountain cottage.
Running shoes were categorized either as motion control, cushioned, or minimal footwear in the past. Today, these categories blur and are not as clearly defined. Moreover, with the advances in manufacturing processes, it is possible to create individualized running shoes that incorporate features that meet individual biomechanical and experiential needs. However, specific ways to individualize footwear to reduce individual injury risk are poorly understood. Therefore, the purpose of this scoping review was to provide an overview of (1) footwear design features that have the potential for individualization; (2) human biomechanical variability as a theoretical foundation for individualization; (3) the literature on the differential responses to footwear design features between selected groups of individuals. These purposes focus exclusively on reducing running-related risk factors for overuse injuries. We included studies in the English language on adults that analyzed: (1) potential interaction effects between footwear design features and subgroups of runners or covariates (e.g., age, gender) for running-related biomechanical risk factors or injury incidences; (2) footwear perception for a systematically modified footwear design feature. Most of the included articles (n = 107) analyzed male runners. Several footwear design features (e.g., midsole characteristics, upper, outsole profile) show potential for individualization. However, the overall body of literature addressing individualized footwear solutions and the potential to reduce biomechanical risk factors is limited. Future studies should leverage more extensive data collections considering relevant covariates and subgroups while systematically modifying isolated footwear design features to inform footwear individualization.
Objective: To identify and evaluate the evidence of the most relevant running-related risk factors (RRRFs) for running-related overuse injuries (ROIs) and to suggest future research directions.
Design: Systematic review considering prospective and retrospective studies. (PROSPERO_ID: 236832)
Data sources: Pubmed. Connected Papers. The search was performed in February 2021.
Eligibility criteria: English language. Studies on participants whose primary sport is running addressing the risk for the seven most common ROIs and at least one kinematic, kinetic (including pressure measurements), or electromyographic RRRF. An RRRF needed to be identified in at least one prospective or two retrospective studies.
Results: Sixty-two articles fulfilled our eligibility criteria. Levels of evidence for specific ROIs ranged from conflicting to moderate evidence. Running populations and methods applied varied considerably between studies. While some RRRFs appeared for several ROIs, most RRRFs were specific for a particular ROI. The biomechanical measurements performed in many studies would have allowed for consideration of many more RRRFs than have been reported, highlighting a potential for more effective data usage in the future.
Conclusion: This study offers a comprehensive overview of RRRFs for the most common ROIs, which might serve as a starting point to develop ROI-specific risk profiles of individual runners. Future work should use macroscopic (big data) approaches involving long-term data collections in the real world and microscopic approaches involving precise stress calculations using recent developments in biomechanical modelling. However, consensus on data collection standards (including the quantification of workload and stress tolerance variables and the reporting of injuries) is warranted.
In order to make material design processes more efficient in the future, the underlying multidimensional process parameter spaces must be systematically explored using digitalisation techniques such as machine learning (ML) and digital simulation. In this paper we shortly review essential concepts for the digitalisation of electrodeposition processes with a special focus on chromium plating from trivalent electrolytes.
In the modern knowledge-based and digital economy, the value of knowledge is growing relative to other assets and new intellectual property is being created at an ever-increasing rate. Therefore, the ability to find non-trivial solutions, systematically generate new concepts, and create intellectual property rapidly become crucial to achieving competitive advantage and leveraging the intellectual potential of organizations.
Using patent information for identification of new product features with high market potential
(2014)
The Advanced Innovation Design Approach is a holistic methodology for enhancing innovative and competitive capability of industrial companies. AIDA can be considered as an open mindset, an individually adaptable range of strongest innovation techniques such as comprehensive front-end innovation process, advanced innovation methods, best tools and methods of the TRIZ methodology, organizational measures for accelerating innovation, IT-solutions for Computer-Aided Innovation, and other innovation methods, elaborated in the recent decade in the industry and academia
The European TRIZ Association ETRIA acts as a connecting link between scientific institutions, universities and other educational organizations, industrial companies and individuals concerned with conceptual and practical questions relating to organization of innovation process, invention methods, and innovation knowledge. In the meantime, more than TFC 1000 papers or presentation of scientists, educators, and practitioners from all over the world are available at the official ETRIA website. Numerous research projects were supported or funded by the European Commission.
Phenolic compounds, such as flavonoids and phenolic acids, are very important substances that occur in various medicinal plants. They show different pharmacological activities which might be useful in the therapy of many diseases. Phenolic compounds have achieved an increasing interest over the last years because these compounds are easily oxidized and, thus, act as strong antioxidants. We present the chemiluminescence of different phenolic compounds measured directly on high-performance thin-layer chromatography LiChrospher® plates using the oxalic acid derivative bis(2,4,6-trichlorophenyl) oxalate (TCPO) in conjunction with H2O2. Our results indicate that chemiluminescence intensity increases with an ascending number of phenolic groups in the molecule. The method can be used to detect phenolic compounds in beverages like coffee, tea, and wine.
We present a videodensitometric quantification method for methadone in syrup, separated by thin-layer chromatography (TLC). The quantification is based on a derivation reaction with Dragendorf reagent. Measurements were carried out using a 16-bit flatbed scanner. The range of linearity covers two magnitudes of power using the Kubelka-Munk expression for data transformation. The separation method is inexpensive, fast, and reliable.
The energy supply of Offenburg University of Applied Sciences (HS OG) was changed from separate generation to trigeneration in 2007/2008. Trigeneration was installed for supplying heat, cooling and electrical power at HS OG. In this paper, trigeneration process and its modes of operation along with the layout of the energy facility at HS OG were described. Special emphasis was given to the operation schemes and control strategies of the operation modes: winter mode, transition mode and summer mode. The components used in the energy facility were also outlined. Monitoring and data analysis of the energy system was carried out after the commissioning of trigeneration in the period from 2008 to 2011. Thus, valuable performance data was obtained.
The design of control systems in large-scale CPV power plants will be more challenging in the future. Reasons are the increasing size of power plants, the requirements of grid operators, new functions, and new technological trends in industrial automation or communication technology. Concepts and products from fixed-mounted PV can only partly be adopted since control systems for sun-tracking installations are considerable more complex due to the higher quantity of controllable entities. The objective of this paper is to deliver design considerations for next generation control systems. Therefore, the work identifies new applications of future control systems categorized into operation, monitoring and maintenance domains. The key-requirements of the technical system and the application layer are identified. In the resulting section, new strategies such as a more decentralized architecture are proposed and design criteria are derived. The contribution of this paper should allow manufacturers and research institutes to consider the design criteria in current development and to place further research on new functions and control strategies precisely.
Diode-array planar chromatography is a versatile tool for identification of pharmaceutical substances In this paper thirty-three compounds with benzodiazepine properties were investigated and the separating conditions for silica gel HPTLC plates and three mobile phases were optimized. Diode-array HPTLC makes it possible to identify all the compounds with high certainty down to a level of 20 ng. An algorithm for spectral recognition which is combined with R F values from the three separation steps into one fit factor is presented. This set of data is unique for each of the compounds investigated and enables unequivocal identification. The method is rapid, inexpensive, and sensitive down to a level of 20 ng mL −1.
In thin-layer chromatography the development step distributes the sample throughout the layer, a process which strongly affects the reflection signals. The essential requirement for quantitative thinlayer chromatography is not a constant sample concentration but constant sample distribution in each sample spot. This makes evaporation of the mobile phase extremely important, because all tracks of a TLC plate must be dried uniformly. This paper shows that quantitative TLC is possible even if the concentration of the sample is not constant throughout the layer or if the distribution of the sample is not known. With uniform sample distribution, classical Kubelka-Munk theory is valid for isotropic scattering only. In the absence of this constraint classical Kubelka-Munk theory must be extended to situations where scattering is asymmetric. This can be achieved by modification of the original Kubelka-Munk equation. Extended theory is presented which is not only capable of describing asymmetrical scattering in TLC layers but also includes a formula for absorption and fluorescence in diode-array TLC. With this new theory all different formulas for diode-array thin-layer chromatographic evaluation are combined in one expression.
Geothermal Energy in Germany
(2009)
An interlaboratory comparison was carried out to evaluate the effectiveness of a method based on HPTLC in which reagent-free derivatization is followed by UV/fluorescence detection. The method was tested for the determination of sucralose (C12H19C13O8; (2R,3R,4R,5S,6R)-2-[(2R,3S,4S,5S)-2,5-bis(chloromethyl)-3,4-dihydroxyoxolan-2-yl]oxy-5-chloro-6-hydroxymethyl)oxane-3, 4-diol; CAS Registry No. 56038-13-2) in carbonated and still beverages at the proposed European regulatory limits. For still beverages, a portion of the sample was diluted with methanol-water. For carbonated beverages, a portion of the sample was degassed in an ultrasonic bath before dilution. Turbid beverages were filtered after dilution through an HPLC syringe filter. The separation of sucralose was performed by direct application on amino-bonded (NH2) silica gel HPTLC plates (no cleanup needed) with the mobile phase acetonitrile-water. Sucralose was determined after reagent-free derivatization at 190 degrees C; it was quantified by measurements of both UV absorption and fluorescence. The samples, both spiked and containing sucralose, were sent to 14 laboratories in five different countries. Test portions of a sample found to contain no sucralose were spiked at levels of 30.5, 100.7, and 299 mg/L. Recoveries ranged from 104.3 to 124.6% and averaged 112% for determination by UV detection; recoveries ranged from 98.4 to 101.3% and averaged 99.9% for determination by fluorescence detection. On the basis of the results for spiked samples (blind duplicates at three levels), as well as sucralose-containing samples (blind duplicates at three levels and one split level), the values for the RSDr ranged from 10.3 to 31.4% for determinations by UV detection and from 8.9 to 15.9% for determinations by fluorescence detection. The values for the RSDR values ranged from 13.5 to 31.4% for determinations by UV detection and from 8.9 to 20.7% for determinations by fluorescence detection.
Specific prototypes of sedimentation field flow fractionation devices (SdFFF) have been developed with relative success for cell sorting. However, no data are available to compare these apparatus with commercial ones. In order to compare with other devices mainly used for non-biological species, biocompatible systems were used for standard particle (latex: 3–10 μm of different size dispersities) separation development. In order to enhance size dependent separations, channels of reduced thickness were used (80 and 100 μm) and channel/carrier-phase equilibration procedures were necessary. For sample injection, the use of inlet tubing linked to the FFF accumulation wall, common for cell sorting, can be extended to latex species when they are eluted in the Steric Hyperlayer elution mode. It avoids any primary relaxation steps (stop flow injection procedure) simplifying series of elution processing. Mixtures composed of four different monodispersed latex beads can be eluted in 6 min with 100 μm channel thickness.
The three wavelength extinction method (3-WEM) was applied for the on-line particle analysisof suspensions of monodisperse latex beads and polydisperse metal oxide particles of industrialinterest. Comparative measurements were performed by photon correlation spectroscopy (PCS). Thedata of latex particles obtained by 3-WEM and PCS are in good agreement with the manufacture’svalues. Also, the values of oxide particles measured by means of the two techniques are in reasonableagreement despite of the irregular particle shape.Discrepancies are observed by comparing the oxideparticle size results with those of scanning electron microscopy, which is due to the broad sampledistributions and shape irregularities.