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Photovoltaic-heat pump (PV-HP) combinations with battery and energy management systems are becoming increasingly popular due to their ability to increase the autarchy and utilization of self-generated PV electricity. This trend is driven by the ongoing electrification of the heating sector and the growing disparity between growing electricity costs and reducing feed-in tariffs in Germany. Smart control strategies can be employed to control and optimize the heat pump operation to achieve higher self-consumption of PV electricity. This work presents the evaluation results of a smart-grid ready controlled PV-HP-battery system in a single-family household in Germany, using 1-minute-high-resolution field measurement data. Within 12 months evaluation period, a self-consumption of 43% was determined. The solar fraction of the HP amounts to 36%, enabled also due to higher set temperatures for space heating and domestic hot water production. Accordingly, the SPF decreases by 4.0% the space heating and by 5.7% in the domestic hot water mode. The combined seasonal performance factor for the heat pump system increases from 4.2 to 6.7, when only considering the electricity taken from the grid and disregarding the locally generated electricity supplied from photovoltaic and battery units.
This paper provides a comprehensive overview of approaches to the determination of isocontours and isosurfaces from given data sets. Different algorithms are reported in the literature for this purpose, which originate from various application areas, such as computer graphics or medical imaging procedures. In all these applications, the challenge is to extract surfaces with a specific isovalue from a given characteristic, so called isosurfaces. These different application areas have given rise to solution approaches that all solve the problem of isocontouring in their own way. Based on the literature, the following four dominant methods can be identified: the marching cubes algorithms, the tessellation-based algorithms, the surface nets algorithms and the ray tracing algorithms. With regard to their application, it can be seen that the methods are mainly used in the fields of medical imaging, computer graphics and the visualization of simulation results. In our work, we provide a broad and compact overview of the common methods that are currently used in terms of isocontouring with respect to certain criteria and their individual limitations. In this context, we discuss the individual methods and identify possible future research directions in the field of isocontouring.
Batteries typically consist of multiple individual cells connected in series. Here we demonstrate single-cell state of charge (SOC) and state of health (SOH) diagnosis in a 24 V class lithium-ion battery. To this goal, we introduce and apply a novel, highly efficient algorithm based on a voltage-controlled model (VCM). The battery, consisting of eight single cells, is cycled over a duration of five months under a simple cycling protocol between 20 % and 100 % SOC. The cell-to-cell standard deviations obtained with the novel algorithm were 1.25 SOC-% and 1.07 SOH-% at beginning of cycling. A cell-averaged capacity loss of 9.9 % after five months cycling was observed. While the accuracy of single-cell SOC estimation was limited (probably owed to the flat voltage characteristics of the lithium iron phosphate, LFP, chemistry investigated here), single-cell SOH estimation showed a high accuracy (2.09 SOH-% mean absolute error compared to laboratory reference tests). Because the algorithm does not require observers, filters, or neural networks, it is computationally very efficient (three seconds analysis time for the complete data set consisting of eight cells with approx. 780.000 measurement points per cell).
This thesis explores the feasibility and optimization of a solar-thermal sorption system mainly designed to provide cooling but also capable of heating functionalities. Through the development of a black-box model using Python programming, the study delves into the system's performance under various operation modes. Simulation results reveal the effectiveness of adaptive control strategies and pre-heating stages in optimizing efficiency, particularly in cooling modes. In heating assessments, superior performance is observed when utilizing the outdoor coil as the heat source for the heat pump. Challenges related to operational temperature bands are addressed, proposing parallel connections of the heat pump and outdoor coil to enhance performance. Future research directions include refining regression models and incorporating real-time measurement data for improved accuracy, as well as extending simulation duration for comprehensive evaluations. This study contributes valuable insights into the system’s capabilities and applications, laying the groundwork for advancements in heat-driven integrated sustainable energy systems.
Electrochemical pressure impedance spectroscopy (EPIS) has received the attention of researchers as a method to study mass transport processes in polymer electrolyte mem-brane fuel cells (PEMFC). It is based on analyzing the cell voltage response to a harmonic excitation of the gas phase pressure in the frequency domain. Several experiments with a single-cell fuel cell have shown that the spectra contain information in the frequency range typical for mass transport processes and are sensitive to specific operating condi-tions and structural fuel cell parameters. To further benefit from the observed features, it is essential to identify why they occur, which to date has not yet been accomplished. The aim of the present work, therefore, is to identify causal links between internal processes and the corresponding EPIS features.
To this end, the study follows a model-based approach, which allows the analysis of inter-nal states that are not experimentally accessible. The PEMFC model is a pseudo-2D model, which connects the mass transport along the gas channel with the mass transport through the membrane electrode assembly. A modeling novelty is the consideration of the gas vol-ume inside the humidifier upstream the fuel cell inlet, which proves to be crucial for the reproduction of EPIS. The PEMFC model is parametrized to a 100 cm² single cell of the French project partner, who provided the experimental EPIS results reproduced and in-terpreted in the present study.
The simulated EPIS results show a good agreement with the experiments at current den-sities ≤ 0.4 A cm–2, where they allow a further analysis of the observed features. At the lowest excitation frequency of 1 mHz, the dynamic cell voltage response approaches the static pressure-voltage response. In the simulated frequency range between 1 mHz – 100 Hz, the cell voltage oscillation is found to strongly correlate with the partial pressure oscillation of oxygen, whereas the influence of the water pressure is limited to the low frequency region.
The two prominent EPIS features, namely the strong increase of the cell voltage oscillation and the increase of phase shift with frequency, can be traced back via the oxygen pressure to the oscillation of the inlet flow rate. The phenomenon of the oscillating inlet flow rate is a consequence of the pressure change of the gas phase inside the humidifier and in-creases with frequency. This important finding enables the interpretation of experimen-tally observed EPIS trends for a variation of operational and structural fuel cell parame-ters by tracing them back to the influence of the oscillating inlet flow rate.
The separate simulation of the time-dependent processes of the PEMFC model through model reduction shows their individual influence on EPIS. The sluggish process of the wa-ter uptake by the membrane is visible below 0.1 Hz, while the charge and discharge of the double layer becomes visible above 1 Hz. The gas transport through the gas diffusion layer is only visible above 100 Hz. The simulation of the gas transport through the gas channel
without consideration of the humidifier becomes visible above 1 Hz. With consideration of the humidifier the gas transport through the gas channel is visible throughout the fre-quency range. The strong similarity of the spectra considering the humidifier with the spectra of the full model setup shows the dominant influence of the humidifier on EPIS.
A promising observation is the change in the amplitude relationship between the cell volt-age and the oxygen partial pressure oscillation as a function of the oxygen concentration in the catalyst layer. At a frequency where the influence of oxygen pressure on the cell voltage is dominant, for example at 1 Hz, the amplitude of the cell voltage oscillation could be used to indirectly measure the oxygen concentration in the catalyst layer.
This article presents the development, parameterization, and experimental validation of a pseudo-three-dimensional (P3D) multiphysics aging model of a 500 mAh high-energy lithium-ion pouch cell with graphite negative electrode and lithium nickel manganese cobalt oxide (NMC) positive electrode. This model includes electrochemical reactions for solid electrolyte interphase (SEI) formation at the graphite negative electrode, lithium plating, and SEI formation on plated lithium. The thermodynamics of the aging reactions are modeled depending on temperature and ion concentration and the reactions kinetics are described with an Arrhenius-type rate law. Good agreement of model predictions with galvanostatic charge/discharge measurements and electrochemical impedance spectroscopy is observed over a wide range of operating conditions. The model allows to quantify capacity loss due to cycling near beginning-of-life as function of operating conditions and the visualization of aging colormaps as function of both temperature and C-rate (0.05 to 2 C charge and discharge, −20 °C to 60 °C). The model predictions are also qualitatively verified through voltage relaxation, cell expansion and cell cycling measurements. Based on this full model, six different aging indicators for determination of the limits of fast charging are derived from post-processing simulations of a reduced, pseudo-two-dimensional isothermal model without aging mechanisms. The most successful aging indicator, compared to results from the full model, is based on combined lithium plating and SEI kinetics calculated from battery states available in the reduced model. This methodology is applicable to standard pseudo-two-dimensional models available today both commercially and as open source.
Variable refrigerant flow (VRF) and variable air volume (VAV) systems are considered among the best heating, ventilation, and air conditioning systems (HVAC) thanks to their ability to provide cooling and heating in different thermal zones of the same building. As well as their ability to recover the heat rejected from spaces requiring cooling and reuse it to heat another space. Nevertheless, at the same time, these systems are considered one of the most energy-consuming systems in the building. So, it is crucial to well size the system according to the building’s cooling and heating needs and the indoor temperature fluctuations. This study aims to compare these two energy systems by conducting an energy model simulation of a real building under a semi-arid climate for cooling and heating periods. The developed building energy model (BEM) was validated and calibrated using measured and simulated indoor air temperature and energy consumption data. The study aims to evaluate the effect of these HVAC systems on energy consumption and the indoor thermal comfort of the building. The numerical model was based on the Energy Plus simulation engine. The approach used in this paper has allowed us to reach significant quantitative energy saving along with a high level of indoor thermal comfort by using the VRF system compared to the VAV system. The findings prove that the VRF system provides 46.18% of the annual total heating energy savings and 6.14% of the annual cooling and ventilation energy savings compared to the VAV system.
Lithium-ion battery cells exhibit a complex and nonlinear coupling of thermal, electrochemical,and mechanical behavior. In order to increase insight into these processes, we report the development of a pseudo-three-dimensional (P3D) thermo-electro-mechanical model of a commercial lithium-ion pouch cell with graphite negative electrode and lithium nickel cobalt aluminum oxide/lithium cobalt oxide blend positive electrode. Nonlinear molar volumes of the active materials as function of lithium stoichiometry are taken from literature and implemented into the open-source software Cantera for convenient coupling to battery simulation codes. The model is parameterized and validated using electrical, thermal and thickness measurements over a wide range of C-rates from 0.05 C to 10 C. The combined experimental and simulated analyses show that thickness change during cycling is dominated by intercalation-induced swelling of graphite, while swelling of the two blend components partially cancel each other. At C-rates above 2 C, electrochemistry-induced temperature increase significantly contributes to cell swelling due to thermal expansion. The thickness changes are nonlinearly distributed over the thickness of the electrode pair due to gradients in the local lithiation, which may accelerate local degradation. Remaining discrepancies between simulation and experiment at high C-rates might be attributed to lithium plating, which is not considered in the model at present.
Electrochemical pressure impedance spectroscopy (EPIS) is an emerging tool for the diagnosis of polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of the cell voltage with respect to an excitation of the gas-phase pressure. Several experimental studies in the past decade have shown the complexity of EPIS signals, and so far there is no agreement on the interpretation of EPIS features. The present study contributes to shed light into the physicochemical origin of EPIS features, by using a combination of pseudo-two-dimensional modeling and analytical interpretation. Using static simulations, the contributions of cathode equilibrium potential, cathode overpotential, and membrane resistance on the quasi-static EPIS response are quantified. Using model reduction, the EPIS responses of individual dynamic processes are predicted and compared to the response of the full model. We show that the EPIS signal of the PEMFC studied here is dominated by the humidifier. The signal is further analyzed by using transfer functions between various internal cell states and the outlet pressure excitation. We show that the EPIS response of the humidifier is caused by an oscillating oxygen molar fraction due to an oscillating mass flow rate.
A balcony photovoltaic (PV) system, also known as a micro-PV system, is a small PV system consisting of one or two solar modules with an output of 100–600 Wp and a corresponding inverter that uses standard plugs to feed the renewable energy into the house grid. In the present study we demonstrate the integration of a commercial lithium-ion battery into a commercial micro-PV system. We firstly show simulations over one year with one second time resolution which we use to assess the influence of battery and PV size on self-consumption, self-sufficiency and the annual cost savings. We then develop and operate experimental setups using two different architectures for integrating the battery into the micro-PV system. In the passive hybrid architecture, the battery is in parallel electrical connection to the PV module. In the active hybrid architecture, an additional DC-DC converter is used. Both architectures include measures to avoid maximum power point tracking of the battery by the module inverter. Resulting PV/battery/inverter systems with 300 Wp PV and 555 Wh battery were tested in continuous operation over three days under real solar irradiance conditions. Both architectures were able to maintain stable operation and demonstrate the shift of PV energy from the day into the night. System efficiencies were observed comparable to a reference system without battery. This study therefore demonstrates the feasibility of both active and passive coupling architectures.
Lithium-ion batteries exhibit slow voltage dynamics on the minute time scale that are usually associated with transport processes. We present a novel modelling approach toward these dynamics by combining physical and data-driven models into a Grey-box model. We use neural networks, in particular neural ordinary differential equations. The physical structure of the Grey-box model is borrowed from the Fickian diffusion law, where the transport domain is discretized using finite volumes. Within this physical structure, unknown parameters (diffusion coefficient, diffusion length, discretization) and dependencies (state of charge, lithium concentration) are replaced by neural networks and learnable parameters. We perform model-to-model comparisons, using as training data (a) a Fickian diffusion process, (b) a Warburg element, and (c) a resistor-capacitor circuit. Voltage dynamics during constant-current operation and pulse tests as well as electrochemical impedance spectra are simulated. The slow dynamics of all three physical models in the order of ten to 30 min are well captured by the Grey-box model, demonstrating the flexibility of the present approach.
This paper presents a framework for numerical building validation enhancement based on detailed building specifications from in-situ measurements and evidence-based validation assessment undertaken on a detached sustainable lightweight building in a semi-arid climate. The validation process has been undergone in a set of controlled experiments – a free-float period, and steady-state internal temperatures. The validation was conducted for a complete year with a 1-min time step for the hourly indoor temperature and the variable refrigerant flow (VRF) energy consumption. The initial baseline model was improved by three series of validation steps per three different field measurements including thermal transmittance, glazing thermal and optical properties, and airtightness. Then, the accurate and validated model was used for building energy efficiency assessment in 12 regions of Morocco. This study aims to assess the effect of accurate building characteristics values on the numerical model enhancement. The initial CV(RMSE) and NMBE have improved respectively from 14.58 % and −11.23 %–7.85 % and 1.86 % for the indoor temperature. Besides, from 31.17 % to 14.37 %–20.57 % and 9.77 % for energy consumption. The findings demonstrate that the lightweight construction with the use of a variable refrigerant flow system could be energy efficient in the southern regions of Morocco.
Predictive control has great potential in the home energy management domain. However, such controls need reliable predictions of the system dynamics as well as energy consumption and generation, and the actual implementation in the real system is associated with many challenges. This paper presents the implementation of predictive controls for a heat pump with thermal storage in a real single-family house with a photovoltaic rooftop system. The predictive controls make use of a novel cloud camera-based short-term solar energy prediction and an intraday prediction system that includes additional data sources. In addition, machine learning methods were used to model the dynamics of the heating system and predict loads using extensive measured data. The results of the real and simulated operation will be presented.
The variable refrigerant flow system is one of the best heating, ventilation, and air conditioning systems (HVAC) thanks to its ability to provide thermal comfort inside buildings. But, at the same time, these systems are considered one of the most energy-consuming systems in the building sector. Thus, it is crucial to well size the system according to the building’s cooling and heating needs and the indoor temperature fluctuations. Although many researchers have studied the optimization of the building energy performance considering heating or cooling needs, using air handling units, radiant floor heating, and direct expansion valves, few studies have considered the use of multi-objective optimization using only the thermostat setpoints of VRF systems for both cooling and heating needs. Thus, the main aim of this study is to conduct a sensitivity analysis and a multi-objective optimization strategy for a residential building containing a variable refrigerant flow system, to evaluate the effect of the building performance on energy consumption and improve the building energy efficiency. The numerical model was based on the EnergyPlus, jEPlus, and jEPlus+EA simulation engines. The approach used in this paper has allowed us to reach significant quantitative energy saving by varying the cooling and heating setpoints and scheduling scenarios. It should be stressed that this approach could be applied to several HVAC systems to reduce energy-building consumption.
Das Konzept der Thermoaktiven Bauteilsysteme (TABS) zur Heizung und Kühlung von Gebäuden gewinnt aufgrund seiner Kompatibilität mit erneuerbaren Energiequellen an Popularität. Die Steuerung von TABS und somit auch die Gewährleistung eines behaglichen Raumklimas erweist sich allerdings aufgrund der hohen Systemträgheit als komplex. Kurzfristige Witterungsänderungen sorgen für unerwünschte Raumtemperaturänderungen, die nur langsam korrigiert werden können. Bei Nichtwohngebäuden wie dem Regionalen Innovationszentrum für Energie (RIZ Energie) in Offenburg wird dieser Umstand durch die unregelmäßige Gebäudenutzung zusätzlich erschwert, da innere Wärmelasten stark variieren und nicht vorhersehbar sind.
Konventionelle TABS-Steuerungen können Störgrößen im TABS-Betrieb nur bedingt und zeitverzögert berücksichtigen, weswegen eine dauerhafte Gewährleistung des thermischen Komforts im Gebäude oft nicht erreichbar ist – dies ist auch am RIZ Energie der Fall. Als Lösung dient der Einsatz prädiktiver Steuerungsalgorithmen, die Störgrößen prognostizieren und den TABS-Betrieb dementsprechend anpassen können.
Diese Arbeit überprüft das Potenzial von intelligenten TABS-Steuerungsalgorithmen für den Einsatz am RIZ Energie anhand der Umsetzung mit einem digitalen Zwilling des Gebäudes. Dabei konnte unter Verwendung der Algorithmen und Berücksichtigung von inneren und äußeren Störgrößen im TABS-Betrieb ein verbessertes Raumklima simuliert werden. Infolgedessen konnte zudem der digitale Zwilling optimiert werden.
Photovoltaic thermal (PVT) technology has been drawing attention recently. Electrification of the heating sector with heat pumps run by carbon-free electricity sources like photovoltaics is setting the ground for the interest. This article gives insight into PVT technologies and collector designs according to application and operating temperatures. For most conventional designs, examples like prototypes from Research & Development projects are presented. In addition, commercial products are listed along these categories, and the influence on the gross thermal and electrical yield is depicted based on Solar Keymark certification data. The process of certification is presented in a comprehensive way, showing current limitations, giving an outlook on the most recent approach for enhanced procedures and specifications. Finally, different system layouts are presented, and examples from installations combined with a heat pump are given with their specific performances. Real performance data of several PVT installations are compared to conventional heat pump systems. The identified seasonal performance factors are in a range from 3.4 to 4.2 and in between air source and ground source heat pumps. Continuous monitoring and derived data are enablers to discover the decisive influence of the system layout and dimensioning on performance indicators like, for example, operating temperatures over the year.
Ziel der vorliegenden Arbeit ist das netzdienliche Betreiben einer Wärmepumpe. Um diese Netzdienlichkeit zu erreichen, wird ein modellprädiktiver Regler entwickelt und implementiert, dessen Ziel es ist die Stromkosten einer Wärmepumpe zu senken. Dazu werden die Variablen Stromkosten und ein simulierter Heizbetrieb betrachtet.
Die Entwicklung eines modellprädiktiven Reglers setzt zunächst eine Modellierung der Komponenten des Heizsystems voraus. Ebenfalls muss eine Kostenfunktion formuliert werden, die es zu minimieren gilt. In einem Optimierungsproblem werden die Modelle als Randbedingungen und die Kostenfunktion als Zielfunktion der Optimierung formuliert. Dazu müssen gewisse Vereinfachungen getroffen werden, um das Optimierungsproblem zuverlässig und ohne enormen Rechenaufwand in einer Regelungsschleife lösen zu können.
Nun wird das Optimierungsproblem mit externen Modulen verknüpft, die eine Kommunikation mit der realen Wärmepumpen, Strompreisprognosen und Wettervorhersagen ermöglichen. Der dabei entwickelte Algorithmus wird auf einem Raspberry Pi Einplatinencomputer gespeichert und dort in einem regelmäßigen Zeitintervall von 15 Minuten ausgeführt, um den Betrieb der Wärmepumpe zu regeln.
Schließlich wird der modellprädiktive Regler in Betrieb genommen. Anschließend kann der modellprädiktive Betrieb mit dem konventionellen Betrieb verglichen werden. Aus dem Vergleich wird deutlich, dass eine modellprädiktive Regelung tatsächlich die Netzdienlichkeit einer Wärmepumpe verbessern kann. Andererseits werden auch die Entwicklungspotentiale identifiziert.
With the function RooTri(), we present a simple and robust calculation method for the approximation of the intersection points of a scalar field given as an unstructured point cloud with a plane oriented arbitrarily in space. The point cloud is approximated to a surface consisting of triangles whose edges are used for computing the intersection points. The function contourc() of Matlab is taken as a reference. Our experiments show that the function contourc() produces outliers that deviate significantly from the defined nominal value, while the quality of the results produced by the function RooTri() increases with finer resolution of the examined grid.
Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.
The use of biochar is an important tool to improve soil fertility, reduce the negative environmental impacts of agriculture, and build up terrestrial carbon sinks. However, crop yield increases by biochar amendment were not shown consistently for fertile soils under temperate climate. Recent studies show that biochar is more likely to increase crop yields when applied in combination with nutrients to prepare biochar-based fertilizers. Here, we focused on the root-zone amendment of biochar combined with mineral fertilizers in a greenhouse trial with white cabbage (Brassica oleracea convar. Capitata var. Alba) cultivated in a nutrient-rich silt loam soil originating from the temperate climate zone (Bavaria, Germany). Biochar was applied at a low dosage (1.3 t ha−1). The biochar was placed either as a concentrated hotspot below the seedling or it was mixed into the soil in the root zone representing a mixture of biochar and soil in the planting basin. The nitrogen fertilizer (ammonium nitrate or urea) was either applied on the soil surface or loaded onto the biochar representing a nitrogen-enhanced biochar. On average, a 12% yield increase in dry cabbage heads was achieved with biochar plus fertilizer compared to the fertilized control without biochar. Most consistent positive yield responses were observed with a hotspot root-zone application of nitrogen-enhanced biochar, showing a maximum 21% dry cabbage-head yield increase. Belowground biomass and root-architecture suggested a decrease in the fine root content in these treatments compared to treatments without biochar and with soil-mixed biochar. We conclude that the hotspot amendment of a nitrogen-enhanced biochar in the root zone can optimize the growth of white cabbage by providing a nutrient depot in close proximity to the plant, enabling efficient nutrient supply. The amendment of low doses in the root zone of annual crops could become an economically interesting application option for biochar in the temperate climate zone.
The lifetime of a battery is affected by various aging processes happening at the electrode scale and causing capacity and power fade over time. Two of the most critical mechanisms are the deposition of metallic lithium (plating) and the loss of lithium inventory to the solid electrolyte interphase (SEI). These side reactions compete with reversible lithium intercalation at the graphite anode. Here we present a comprehensive physicochemical pseudo-3D aging model for a lithium-ion battery cell, which includes electrochemical reactions for SEI formation on graphite anode, lithium plating, and SEI formation on plated lithium. The thermodynamics of the aging reactions are modeled depending on temperature and ion concentration, and the reactions kinetics are described with an Arrhenius-type rate law. The model includes also the positive feedback of plating on SEI growth, with the presence of plated lithium leading to a higher SEI formation rate compared to the values obtained in its absence at the same operating conditions. The model is thus able to describe cell aging over a wide range of temperatures and C-rates. In particular, it allows to quantify capacity loss due to cycling (here in % per year) as function of operating conditions. This allows the visualization of aging colormaps as function of both temperature and C-rate and the identification of critical operation conditions, a fundamental step for a comprehensive understanding of batteries performance and behavior. For example, the model predicts that at the harshest conditions (< –5 °C, > 3 C), aging is reduced compared to most critical conditions (around 0–5 °C) because the cell cannot be fully charged.
To achieve its climate goals, the German industry has to undergo a transformation toward renewable energies. To analyze this transformation in energy system models, the industry’s electricity demands have to be provided in a high temporal and sectoral resolution, which, to date, is not the case due to a lack of open-source data. In this paper, a methodology for the generation of synthetic electricity load profiles is described; it was applied to 11 industry types. The modeling was based on the normalized daily load profiles for eight electrical end-use applications. The profiles were then further refined by using the mechanical processes of different branches. Finally, a fluctuation was applied to the profiles as a stochastic attribute. A quantitative RMSE comparison between real and synthetic load profiles showed that the developed method is especially accurate for the representation of loads from three-shift industrial plants. A procedure of how to apply the synthetic load profiles to a regional distribution of the industry sector completes the methodology.
The significant market growth of stationary electrical energy storage systems both for private and commercial applications has raised the question of battery lifetime under practical operation conditions. Here, we present a study of two 8 kWh lithium-ion battery (LIB) systems, each equipped with 14 lithium iron phosphate/graphite (LFP) single cells in different cell configurations. One system was based on a standard configuration with cells connected in series, including a cell-balancing system and a 48 V inverter. The other system featured a novel configuration of two stacks with a parallel connection of seven cells each, no cell-balancing system, and a 4 V inverter. The two systems were operated as part of a microgrid both in continuous cycling mode between 30% and 100% state of charge, and in solar-storage mode with day–night cycling. The aging characteristics in terms of capacity loss and internal resistance change in the cells were determined by disassembling the systems for regular checkups and characterizing the individual cells under well-defined laboratory conditions. As a main result, the two systems showed cell-averaged capacity losses of 18.6% and 21.4% for the serial and parallel configurations, respectively, after 2.5 years of operation with 810 (serial operation) and 881 (parallel operation) cumulated equivalent full cycles. This is significantly higher than the aging of a reference single cell cycled under laboratory conditions at 20 °C, which showed a capacity loss of only 10% after 1000 continuous full cycles.
Simulation based studies for operational energy system analysis play a significant role in evaluation of various new age technologies and concepts in the energy grid. Various modelling approaches already exist and in this original paper, four models representing these approaches are compared in two real-world hybrid energy system scenarios. The models, namely TransiEnt, µGRiDS, and OpSim (including pandaprosumer and mosaic) are classified into component-oriented or system-oriented approaches as deduced from the literature research. The methodology section describes their differences under standard conditions and the necessary parameterization for the purpose of creating a framework facilitating a closest possible comparison. A novel methodology for scenario generation is also explained. The results help to quantify primary differences in these approaches that are also identified in literature and qualify the influence of the accuracy of the models for application in a system-wide analysis. It is shown that a simplified model may be sufficient for the system-oriented approach especially when the objective is an optimization-based control or planning. However, from a field level operational point of view, the differences in the time series signify the importance of the component-oriented approaches.
Electrochemical pressure impedance spectroscopy (EPIS) has recently been developed as a potential diagnosis tool for polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of the cell voltage with respect to an excitation of the gas-phase pressure. We present here a combined modeling and experimental study of EPIS. A pseudo-twodimensional PEMFC model was parameterized to a 100 cm2 laboratory cell installed in its test bench, and used to reproduce steady-state cell polarization and electrochemical impedance spectra (EIS). Pressure impedance spectra were obtained both in experiment and simulation by applying a harmonic pressure excitation at the cathode outlet. The model shows good agreement with experimental data for current densities ⩽ 0.4 A cm−2. Here it allows a further simulative analysis of observed EPIS features, including the magnitude and shape of spectra. Key findings include a strong influence of the humidifier gas volume on EPIS and a substantial increase in oxygen partial pressure oscillations towards the channel outlet at the resonance frequency. At current densities ⩾ 0.8 A cm−2 the experimental EIS and EPIS data cannot be fully reproduced. This deviation might be associated with the formation and transport of liquid water, which is not included in the model.
Lithium-ion batteries show strongly nonlinear behaviour regarding the battery current and state of charge. Therefore, the modelling of lithium-ion batteries is complex. Combining physical and data-driven models in a grey-box model can simplify the modelling. Our focus is on using neural networks, especially neural ordinary differential equations, for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis for the grey-box model. Unknown parameters and dependencies are then replaced by learnable parameters and neural networks. We use experimental full-cycle data and data from pulse tests of a lithium iron phosphate cell to train the model. Finally, we test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.
Nowadays decarbonisation of the energy system is one of the main concerns for most governments. Renewable energy technologies, such as rooftop photovoltaic systems and home battery storage systems, are changing the energy system to be more decentralised. As a consequence, new ways of energy business models are emerging, e.g., peer-to-peer energy trading. This new concept provides an online marketplace where direct energy exchange can occur between its participants. The purpose of this study is to conduct a content analysis of the existing literature, ongoing research projects, and companies related to peer-to-peer energy trading. From this review, a summary of the most important aspects and journal papers is assessed, discussed, and classified. It was found that the different energy market types were named in various ways and a proposal for standard language for the several peer-to-peer market types and the different actors involved is suggested. Additionally, by grouping the most important attributes from peer-to-peer energy trading projects, an assessment of the entry barrier and scalability potential is performed by using a characterisation matrix.
This paper will introduce the open-source model MyPyPSA-Ger, a myopic optimization model developed to represent the German energy system with a detailed mapping of the electricity sector, on a highly disaggregated level, spatially and temporally, with regional differences and investment limitations. Furthermore, this paper will give new outlooks on the German federal government 2050 emissions goals of the electricity sector to become greenhouse gas neutral by proposing new CO2 allowance strategies. Moreover, the regional differences in Germany will be discussed, their role and impact on the energy transition, and which regions and states will drive the renewable energy utilization forward.
Following a scenario-based analysis, the results point out the major keystones of the energy transition path from 2020 to 2050. Solar, onshore wind, and gas-fired power plants will play a fundamental role in the future electricity systems. Biomass, run of river, and offshore wind technologies will be utilized in the system as base-load generation technologies. Solar and onshore wind will be installed almost everywhere in Germany. However, due to the nature of Germany’s weather and geographical features, the southern and northern regions will play a more important role in the energy transition.
Higher CO2 allowance costs will help achieve the 1.5-degree-target of the electricity system and will allow for a rapid transition. Moreover, the more expensive, and the earlier the CO2 tax is applied to the system, the less it will cost for the energy transition, and the more emissions will be saved throughout the transition period. An earlier phase-out of coal power plants is not necessary with high CO2 taxes, due to the change in power plant’s unit commitment, as they prioritize gas before coal power plants. Having moderate to low CO2 allowance cost or no clear transition policy will be more expensive and the CO2 budget will be exceeded. Nonetheless, even with no policy, renewables still dominate the energy mix of the future.
However, maintaining the maximum historical installation rates of both national and regional levels, with the current emissions reduction strategy, will not be enough to reach the level of climate-neutral electricity system. Therefore, national and regional installation requirements to achieve the federal government emission reduction goals are determined. Energy strategies and decision makers will have to resolve great challenges in order to stay in line with the 1.5-degree-target.
An import ban of Russian energy sources to Germany is currently being increasingly discussed. We want to support the discussion by showing a way how the electricity system in Germany can manage low energy imports in the short term and which measures are necessary to still meet the climate protection targets. In this paper, we examine the impact of a complete stop of Russian fossil fuel imports on the electricity sector in Germany, and how this will affect the climate coals of an earlier coal phase-out and climate neutrality by 2045.
Following a scenario-based analysis, the results gave a point of view on how much would be needed to completely rely on the scarce non-renewable energy resources in Germany. Huge amounts of investments would be needed in order to ensure a secure supply of electricity, in both generation energy sources (RES) and energy storage systems (ESS). The key findings are that a rapid expansion of renewables and storage technologies will significantly reduce the dependence of the German electricity system on energy imports. The huge integration of renewable energy does not entail any significant imports of the energy sources natural gas, hard coal, and mineral oil, even in the long term. The results showed that a ban on fossil fuel imports from Russia outlines huge opportunities to go beyond the German government's climate targets, where the 1.5-degree-target is achieved in the electricity system.
Auswirkung eines Importstopps russischer Energieträger auf die Klimaschutzziele in Deutschland
(2022)
Ein Importstopp russischer Energieträger nach Deutschland wird derzeit vermehrt diskutiert. Wir wollen die Diskussion unterstützen, indem wir einen Weg zeigen, wie das Elektrizitätssystem in Deutschland kurzfristig mit geringen Energieimporten auskommt und welche Maßnahmen notwendig sind, um die Klimaschutzziele trotzdem einzuhalten. Die Ergebnisse eines solchen Energiewendeszenarios mit reduzierter Importabhängigkeit werden mit dem Energiesystemmodell MyPyPSA-Ger berechnet. Die wichtigsten Erkenntnisse sind, dass ein zügiger Ausbau Erneuerbarer Energien und von Speichertechnologien • die Abhängigkeit des deutschen Elektrizitätssystems von Energieimporten deutlich reduziert. • auch langfristig keine wesentlichen Importe der Energieträger Erdgas, Steinkohle und Mineralöl nach sich zieht. • über die Klimaziele der Bundesregierung hinaus das 1,5-Grad-Ziel im Elektrizitätssystem erreicht wird.
Peer-to-peer energy trading and local electricity markets have been widely discussed as new options for the transformation of the energy system from the traditional centralized scheme to the novel decentralized one. Moreover, it has also been proposed as a more favourable alternative for already expiring feed in tariff policies that promote investment in renewable energy sources. Peer-to-peer energy trading is usually defined as the integration of several innovative technologies, that enable both prosumers and consumers to trade electricity, without intermediaries, at a consented price. Furthermore, the techno-economic aspects go hand in hand with the socio-economic aspects, which represent at the end significant barriers that need to be tackled to reach a higher impact on current power systems. Applying a qualitative analysis, two scalable peer-to-peer concepts are presented in this study and the possible participant´s entry probability into such concepts. Results show that consumers with a preference for environmental aspects have in general a higher willingness to participate in peer-to-peer energy trading. Moreover, battery storage systems are a key technology that could elevate the entry probability of prosumers into a peer-to-peer market.
To achieve Germany's climate targets, the industrial sector, among others, must be transformed. The decarbonization of industry through the electrification of heating processes is a promising option. In order to investigate this transformation in energy system models, high-resolution temporal demand profiles of the heat and electricity applications for different industries are required. This paper presents a method for generating synthetic electricity and heat load profiles for 14 industry types. Using this methodology, annual profiles with a 15-minute resolution can be generated for both energy demands. First, daily profiles for the electricity demand were generated for 4 different production days. These daily profiles are additionally subdivided into eight end-use application categories. Finally, white noise is applied to the profile of the mechanical drives. The heat profile is similar to the electrical but is subdivided into four temperature ranges and the two applications hot water and space heating. The space heating application is additionally adjusted to the average monthly outdoor temperature. Both time series were generated for the analysis of an electrification of industrial heat application in energy system modelling.
Decarbonisation Strategies in Energy Systems Modelling: Biochar as a Carbon Capture Technology
(2022)
The energy system is changing since some years in order to achieve the climate goals from the Paris Agreement which wants to prevent an increase of the global temperature above 2 °C. Decarbonisation of the energy system has become for governments a big challenge and different strategies are being stablished. Germany has set greenhouse gas reduction limits for different years and keeps track of the improvement made yearly. The expansion of renewable energy systems (RES) together with decarbonisation technologies are a key factor to accomplish this objective.
This research is done to analyse the effect of introducing biochar, a decarbonisation technology, and study how it will affect the energy system. Pyrolysis is the process from which biochar is obtained and it is modelled in an open-source energy system model. A sensibility analysis is made in order to assess the effect of changing the biomass potential and the costs for pyrolysis.
The role of pyrolysis is analysed in the form of different future scenarios to evaluate the impact. The CO2 emission limits from the years 2030 and 2045 are considered to create the scenarios, as well as the integration of flexibility technologies. Four scenarios in total are assessed and the result from the sensibility analysis considering pyrolysis are always compared to the reference scenario, where pyrolysis is not considered.
Results show that pyrolysis has a bigger impact in the energy system when the CO2 limit is low. Biochar can be used to compensate the emissions from other conventional power plant and achieve an energy transition with lower costs. Furthermore, it was also found that pyrolysis can also reduce the need of flexibility. This study also shows that the biomass potential and the pyrolysis costs can affect a lot the behaviour of pyrolysis in the energy system.
The energy system is changing since some years in order to achieve the climate goals from the Paris Agreement which wants to prevent an increase of the global temperature above 2 °C [1]. Decarbonisation of the energy system has become for governments a big challenge and different strategies are being stablished. Germany has set greenhouse gas reduction limits for different years and keeps track of the improvement made yearly. The expansion of renewable energy systems (RES) together with decarbonisation technologies are a key factor to accomplish this objective.
This research is done to analyse the effect of introducing biochar, a decarbonisation technology, and study how it will affect the energy system. Pyrolysis is the process from which biochar is obtained and it is modelled in an open-source energy system model. A sensibility analysis is done in order to assess the effect of changing the biomass potential and the costs for pyrolysis.
The role of pyrolysis is analysed in the form of different future scenarios for the year 2045 to evaluate the impact when the CO2 emission limit is zero. All scenarios are compared to the reference scenario, where pyrolysis is not considered.
Results show that biochar can be used to compensate the emissions from other conventional power plant and achieve an energy transition with lower costs. Furthermore, it was also found that pyrolysis can also reduce the need of flexibility. This study also shows that the biomass potential and the pyrolysis costs can strongly affect the behaviour of pyrolysis in the energy system.
The contribution of the RoofKIT student team to the SDE 21/22 competition is the extension of an existing café in Wuppertal, Germany, to create new functions and living space for the building with simultaneous energetic upgrading. A demonstration unit is built representing a small cut-out of this extension. The developed energy concept was thoroughly simulated by the student team in seminars using Modelica. The system uses mainly solar energy via PVT collectors as the heat source for a brine-water heat pump (space heating and hot water). Energy storage (thermal and electrical) is installed to decouple generation and consumption. Simulation results confirm that carbon neutrality is achieved for the building operation, consuming and generating around 60 kWh/m2a.
The sharp rise in electricity and oil prices due to the war in Ukraine has caused fluctuations in the results of the previous study about the economic analysis of electric buses. This paper shows how the increase in fuel prices affects the implementation of electric buses. This publication is constructing the Total Cost of Ownership (TCO) model in the small-mid-size city, Offenburg for the transition to electric buses. The future development of costs is estimated and a projection based on learning curves will be carried out. This study intends to introduce a new future prospect by presenting the latest data based on previous research. Through the new TCO result, the cost differences between the existing diesel bus and the electric bus are updated, and also the future prospects for the economic feasibility of the electric bus in a small and midsize city are presented.
This paper shows the results of an in-depth techno-economic analysis of the public transport sector in a small to midsize city and its surrounding area. Public battery-electric and hydrogen fuel cell buses are comparatively evaluated by means of a total cost of ownership (TCO) model building on historical data and a projection of market prices. Additionally, a structural analysis of the public transport system of a specific city is performed, assessing best fitting bus lines for the use of electric or hydrogen busses, which is supported by a brief acceptance evaluation of the local citizens. The TCO results for electric buses show a strong cost decrease until the year 2030, reaching 23.5% lower TCOs compared to the conventional diesel bus. The optimal electric bus charging system will be the opportunity (pantograph) charging infrastructure. However, the opportunity charging method is applicable under the assumption that several buses share the same station and there is a “hotspot” where as many as possible bus lines converge. In the case of electric buses for the year 2020, the parameter which influenced the most on the TCO was the battery cost, opposite to the year 2030 in where the bus body cost and fuel cost parameters are the ones that dominate the TCO, due to the learning rate of the batteries. For H2 buses, finding a hotspot is not crucial because they have a similar range to the diesel ones as well as a similar refueling time. H2 buses until 2030 still have 15.4% higher TCO than the diesel bus system. Considering the benefits of a hypothetical scaling-up effect of hydrogen infrastructures in the region, the hydrogen cost could drop to 5 €/kg. In this case, the overall TCO of the hydrogen solution would drop to a slightly lower TCO than the diesel solution in 2030. Therefore, hydrogen buses can be competitive in small to midsize cities, even with limited routes. For hydrogen buses, the bus body and fuel cost make up a large part of the TCO. Reducing the fuel cost will be an important aspect to reduce the total TCO of the hydrogen bus.
This work presents the results of experimental operation of a solar-driven climate system using mixed-integer nonlinear model predictive control (MPC). The system is installed in a university building and consists of two solar thermal collector fields, an adsorption cooling machine with different operation modes, a stratified hot water storage with multiple inlets and outlets as well as a cold water storage. The system and the applied modeling approach is described and a parallelized algorithm for mixed-integer nonlinear MPC and a corresponding implementation for the system are presented. Finally, we show and discuss the results of experimental operation of the system and highlight the advantages of the mixed-integer nonlinear MPC application.
Bifaziale Photovoltaikmodule werden durch ihre höhere Leistung, bezogen auf den Flächenbedarf immer attraktiver. Die meisten der bislang hergestellten Photovoltaik Module sind Monofazial ausgeführtund schöpfen damit nicht ihr vollständiges Potential aus. Weiterhin bestehen die konventionell hergestelltenPhotovoltaik(PV) Module aus einem Verbund aus Glas und Kunststoff sowie verschiedenen Metallen, was die Entsorgung oder ein Recycling kostenaufwendig und kompliziert gestaltet. Die Firma Apollon greift diese Punkte auf und versucht, beides in dem NICE-Modul(Siehe Anhang 12.1)zu vereinen,nämlich ein bifaziales Modul, bei dem die PV-Zellen zwischen zwei Glasplatten, anstelle von zwei Kunststoffen eingespannt werden. Die Hochschule Offenburg ist F&E-Partner der Firma Apollon und betreibt ein kleines Labor zur Herstellung von NICE-Modulen. Zu Testzwecken werden diese der Witterung ausgesetzt und so der Energieertrag,sowie deren Lebensdauer unter geltenden Witterungsbedingungen ermittelt. In der Masterarbeit von Benjamin Smith[1]stellte sich heraus, dass sich bei den Modulen nach weniger als zwei Wochen im Freien die Klebefläche zwischen den Glasplatten löste. Somit fielen die Module beim Witterungstest unter realen Bedingungen durch.Im Anschluss an die Arbeit von Benjamin Smith besteht diese Arbeit darin,einen Außenteststand zu konzipieren und aufzubauen, um das in Zwischenzeit neu entworfene Klebe-konzept, welches einem TC 50 Test standhielt, auf die Lebensdauer im Freien und das PV Modul selbst auf den elektrischen Ertrag zu untersuchen. Für den elektrischen Ertrag werden Strom-und Spannungsverlauf aufgezeichnet. Außerdem musste für eine Charakterisierung der Module die Bestrahlungsstärke,der Temperaturverlauf, sowie die Inho-mogenität der Bestrahlungsstärke auf der Rückseite und die Windgeschwindigkeit ermittelt werden. Um eine Alterung des Modulwechselrichters auszuschließen, werden speziell dafür die Wechselspannung und Leistung auf der Ausgangsseite des Modulwechselrichters aufgezeichnet. Sämtliche modulrelevanten Messwerte werden im 3-5 s Intervall abgespeichert und sind auf einem Webserver sowie für eine spätere Datenanalyse als .csv Datei abrufbar. Somit eignet sich die Messeinrichtung lediglich für eine Bilanzierung,nicht aber für eine Leistungsmessung.
Für den Außenteststand musste eine Unterkonstruktion, geeignet für bifaziale Module entworfen und aufgebaut werden. Die Konstruktion ist vollständig aufgebaut. Das Messsystem wurde auf deren Funktion erfolgreich geprüft und steht bis auf die Strahlungsinhomogenitätsmessung im Technikum am Campus Nord der Hochschule Offenburg bereit zur Inbetriebnahme.
Lithium‐ion battery cells are multiscale and multiphysics systems. Design and material parameters influence the macroscopically observable cell performance in a complex and nonlinear way. Herein, the development and application of three methodologies for model‐based interpretation and visualization of these influences are presented: 1) deconvolution of overpotential contributions, including ohmic, concentration, and activation overpotentials of the various cell components; 2) partial electrochemical impedance spectroscopy, allowing a direct visualization of the origin of different impedance features; and 3) sensitivity analyses, allowing a systematic assessment of the influence of cell parameters on capacity, internal resistance, and impedance. The methods are applied to a previously developed and validated pseudo‐3D model of a high‐power lithium‐ion pouch cell. The cell features a blend cathode. The two blend components show strong coupling, which can be observed and interpreted using the results of overpotential deconvolution, partial impedance spectroscopy, and sensitivity analysis. The presented methods are useful tools for model‐supported lithium‐ion cell research and development.
This article presents a comparative experimental study of the electrical, structural and chemical properties of large‐format, 180 Ah prismatic lithium iron phosphate (LFP)/graphite lithium‐ion battery cells from two different manufacturers. These cells are particularly used in the field of stationary energy storage such as home‐storage systems. The investigations include (1) cell‐to‐cell performance assessment, for which a total of 28 cells was tested from each manufacturer, (2) electrical charge/discharge characteristics at different currents and ambient temperatures, (3) internal cell geometries, components, and weight analysis after cell opening, (4) microstructural analysis of the electrodes via light microscopy and scanning electron microscopy, (5) chemical analysis of the electrode materials using energy‐dispersive X‐ray spectroscopy, and (6) mathematical analysis of the electrode balances. The combined results give a detailed and comparative insight into the cell characteristics, providing essential information needed for system integration. The study also provides complete and self‐consistent parameter sets for the use in cells models needed for performance prediction or state diagnosis.
The increasing number of prosumers and the accompanying greater use of decentralised energy resources (DERs) bring new opportunities and challenges for the traditional electricity systems and the electricity markets. Microgrids, virtual power plants (VPPs), peer-to-peer (P2P) trading and federated power plants (FPPs) propose different schemes for prosumer coordination and have the potential of becoming the new paradigm of electricity market and power system operation. This paper proposes a P2P trading scheme for energy communities that negotiates power flows between participating prosumers with insufficient renewable power supply and prosumers with surplus supply in such a way that the community welfare is maximized while avoiding critical grid conditions. For this purpose, the proposed scheme is based on an Optimal Power Flow (OPF) problem with a Multi-Bilateral Economic Dispatch (MBED) formulation as an objective function. The solution is realized in a fully decentralized manner on the basis of the Relaxed Consensus + Innovations (RCI) algorithm. Network security is ensured by a tariff-based system organized by a network agent that makes use of product differentiation capabilities of the RCI algorithm. It is found that the proposed mechanism accurately finds and prevents hazardous network operations, such as over-voltage in grid buses, while successfully providing economic value to prosumers’ renewable generation within the scope of a P2P, free market.
Active participation of industrial enterprises in electricity markets - a generic modeling approach
(2021)
Industrial enterprises represent a significant portion of electricity consumers with the potential of providing demand-side energy flexibility from their production processes and on-site energy assets. Methods are needed for the active and profitable participation of such enterprises in the electricity markets especially with variable prices, where the energy flexibility available in their manufacturing, utility and energy systems can be assessed and quantified. This paper presents a generic model library equipped with optimal control for energy flexibility purposes. The components in the model library represent the different technical units of an industrial enterprise on material, media, and energy flow levels with their process constraints. The paper also presents a case study simulation of a steel-powder manufacturing plant using the model library. Its energy flexibility was assessed when the plant procured its electrical energy at fixed and variable electricity prices. In the simulated case study, flexibility use at dynamic prices resulted in a 6% cost reduction compared to a fixed-price scenario, with battery storage and the manufacturing system making the largest contributions to flexibility.
It is considered necessary to implement advanced controllers such as model predictive control (MPC) to utilize the technical flexibility of a building polygeneration system to support the rapidly expanding renewable electricity grid. These can handle multiple inputs and outputs, uncertainties in forecast data, and plant constraints, amongst other features. One of the main issues identified in the literature regarding deploying these controllers is the lack of experimental demonstrations using standard components and communication protocols. In this original work, the economic-MPC-based optimal scheduling of a real-world heat pump-based building energy plant is demonstrated, and its performance is evaluated against two conventional controllers. The demonstration includes the steps to integrate an optimization-based supervisory controller into a typical building automation and control system with off-the-shelf HVAC components and usage of state-of-art algorithms to solve a mixed integer quadratic problem. Technological benefits in terms of fewer constraint violations and a hardware-friendly operation with MPC were identified. Additionally, a strong dependency of the economic benefits on the type of load profile, system design and controller parameters was also identified. Future work for the quantification of these benefits, the application of machine learning algorithms, and the study of forecast deviations is also proposed.
A coordinated operation of decentralised micro-scale hybrid energy systems within a locally managed network such as a district or neighbourhood will play a significant role in the sector-coupled energy grid of the future. A quantitative analysis of the effects of the primary energy factors, energy conversion efficiencies, load profiles, and control strategies on their energy-economic balance can aid in identifying important trends concerning their deployment within such a network. In this contribution, an analysis of the operational data from five energy laboratories in the trinational Upper-Rhine region is evaluated and a comparison to a conventional reference system is presented. Ten exemplary data-sets representing typical operation conditions for the laboratories in different seasons and the latest information on their national energy strategies are used to evaluate the primary energy consumption, CO2 emissions, and demand-related costs. Various conclusions on the ecologic and economic feasibility of hybrid building energy systems are drawn to provide a toe-hold to the engineering community in their planning and development.
There is a strong interaction between the urban atmospheric canopy layer and the building energy balance. The urban atmospheric conditions affect the heat transfer through exterior walls, the long-wave heat transfer between the building surfaces and the surroundings, the short-wave solar heat gains, and the heat transport by ventilation. Considering also the internal heat gains and the heat capacity of the building structure, the energy demand for heating and cooling and the indoor thermal environment can be calculated based on the urban microclimatic conditions. According to the building energy concept, the energy demand results in an (anthropogenic) waste heat; this is directly transferred to the urban environment. Furthermore, the indoor temperature is re-coupled via the building envelope to the urban environment and affects indirectly the urban microclimate with a temporally lagged and damped temperature fluctuation. We developed a holistic building model for the combined calculation of indoor climate and energy demand based on an analytic solution of Fourier's equation and implemented this model into the PALM model.
A strong heat load in buildings and cities during the summer is not a new phenomenon. However, prolonged heat waves and increasing urbanization are intensifying the heat island effect in our cities; hence, the heat exposure in residential buildings. The thermophysiological load in the interior and exterior environments can be reduced in the medium and long term, through urban planning and building physics measures. In the short term, an increasingly vulnerable population must be effectively informed of an impending heat wave. Building simulation models can be favorably used to evaluate indoor heat stress. This study presents a generic simulation model, developed from monitoring data in urban multi-unit residential buildings during a summer period and using statistical methods. The model determines both the average room temperature and its deviations and, thus, consists of three sub-models: cool, average, and warm building types. The simulation model is based on the same mathematical algorithm, whereas each building type is described by a specific data set, concerning its building physical parameters and user behavior, respectively. The generic building model may be used in urban climate analyses with many individual buildings distributed across the city or in heat–health warning systems, with different building and user types distributed across a region. An urban climate analysis (with weather data from a database) may evaluate local differences in urban and indoor climate, whereas heat–health warning systems (driven by a weather forecast) obtain additional information on indoor heat stress and its expected deviations.
Der vorliegende Beitrag beschreibt die Motivation hinter den Forschungsarbeiten im Electric Mobility Competence Center (EMC^2) rund um elektrische Antriebskomponenten für die Elektromobilität sowie die Notwendigkeit, diese Forschungsarbeiten an Prüfständen zu testen und zu validieren. Zunächst wird näher auf die Charakteristik von elektrischen Maschinen eingegangen, um anschließend die verwendete Prüfstandtechnik vorzustellen.
Die Digitalisierung kann der Türöffner sein, um effizient die mittelständische Industrie und den Energiemarkt zu verbinden. Das Projekt GaIN hat das Ziel, mit hochaufgelösten Produktions- und Messdaten von zehn mittelständischen Industriebetrieben neuartige Tarife und angepasste Marktplattformen zu entwickeln, die Prognosegüte für Energiebedarf, Nachfrage und Flexibilitätsverfügbarkeit zu erhöhen, die Interaktion vieler flexibler Unternehmen im Verteilnetz und in dem Bilanzkreis zu bewerten und die Auswirkung einer Nutzung der Daten auf die Energiewende anhand einer Systemanalyse zu beurteilen.
Ziel des Pilotprojektes EnMa-HAW ist die Erarbeitung und Erprobung technisch und organisatorisch übertragbarer Konzepte für ein automationsgestütztes Energiemanagement an allen Hochschulen für angewandte Wissenschaften im Land Baden-Württemberg. Das Energiemanagement wird technisch mittels Messtechnik, Datenerfassung, Datenspeicherung und Visualisierung umgesetzt und organisatorisch mit einem Energiezirkel in den Hochschulen verankert.
Im Batterielabor der Hochschule Offenburg wurde ein neues Verfahren zur Bestimmung von Ladezustand und Gesundheitszustand von Lithium-Ionen-Batterien entwickelt. Es beruht auf der Auswertung von Spannungs- und Strommessungen mit einem mathematischen Batteriemodell. Das Verfahren ist genauer und robuster als Standardverfahren, die auf Ladungszählung beruhen. Zudem ist es numerisch einfacher umzusetzen als andere modellbasierte Verfahren. Wir demonstrieren die Methode mit einer Heimspeicherzelle und einer Elektrofahrzeugzelle.
Grey-box modelling combines physical and data-driven models to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling, as differential equations given by physical laws and neural networks can be combined in a single modelling framework. This simplifies the simulation and optimization and allows to consider irregularly-sampled data during training and evaluation of the model. We demonstrate this approach using two levels of model complexity; first, a simple parallel resistor-capacitor circuit; and second, an equivalent circuit model of a lithium-ion battery cell, where the change of the voltage drop over the resistor-capacitor circuit including its dependence on current and State-of-Charge is implemented as NODE. After training, both models show good agreement with analytical solutions respectively with experimental data.
Most recently, the federal government in Germany published new climate goals in order reach climate neutrality by 2045. This paper demonstrates a path to a cost optimal energy supply system for the German power grid until the year 2050. With special regard to regionality, the system is based on yearly myopic optimization with the required energy system transformation measures and the associated system costs. The results point out, that energy storage systems (ESS) are fundamental for renewables integration in order to have a feasible energy transition. Moreover, the investment in storage technologies increased the usage of the solar and wind technologies. Solar energy investments were highly accompanied with the installation of short-term battery storage. Longer-term storage technologies, such as H2, were accompanied with high installations of wind technologies. The results pointed out that hydrogen investments are expected to overrule short-term batteries if their cost continues to decrease sharply. Moreover, with a strong presence of ESS in the energy system, biomass energy is expected to be completely ruled out from the energy mix. With the current emission reduction strategy and without a strong presence of large scale ESS into the system, it is unlikely that the Paris agreement 2° C target by 2050 will be achieved, let alone the 1.5° C.
Global energy demand is still on an increase during the last decade, with a lot of impact on the climate change due to the intensive use of conventional fossil-based fuels power plants to cover this demand. Most recently, leaders of the globe met in 2015 to come out with the Paris Agreement, stating that the countries will start to take a more responsible and effective behaviour toward the global warming and climate change issues. Many studies have discussed how the future energy system will look like with respecting the countries’ targets and limits of greenhouse gases and their CO2 emissions. However, these studies rarely discussed the industry sector in detail even though it is one of the major role players in the energy sector. Moreover, many studies have simulated and modelled the energy system with huge jumps of intervals in terms of years and environmental goals. In the first part of this study, a model will be developed for the German electrical grid with high spatial and temporal resolutions and different scenarios of it will be analysed meticulously on shorter periods (annual optimization), with different flexibilities and used technologies and degrees of innovations within each scenario. Moreover, the challenge in this research is to adequately map the diverse and different characteristics of the medium-sized industrial sector. In order to be able to take a first step in assessing the relevance of the industrial sector in Germany for climate protection goals, the industrial sector will be mapped in PyPSA-Eur (an open-source model data set of the European energy system at the level of the transmission network) by detailing the demand for different types of industry and assigning flexibilities to the industrial types. Synthetically generated load profiles of various industrial types are available. Flexibilities in the industrial sector are described by the project partner Fraunhofer IPA in the GaIN project and can be used. Using a scenario analysis, the development of the industrial sector and the use of flexibilities are then to be assessed quantitatively.
Im Projekt MOBCOM wird ein neues Verfahren zur Zustandsüberwachung von elektrischen Betriebsmitteln in Niederspannungsnetzen und Anlagen entwickelt. Mittels PLC (power line communication) Technologie werden hochfrequente transiente Vorgänge auf dem Stromkanal und dessen Übertragungseigenschaften erfasst und bewertet. Durch Ableiten bestimmter Parameter soll zustandsbedingte Wartung vorhergesagt und so der Ausfall von Betriebsmittel vermieden werden.
Fast charging of lithium-ion batteries remains one of the most delicate challenges for the automotive industry, being seriously affected by the formation of lithium metal in the negative electrode. Here we present a physicochemical pseudo-3D model that explicitly includes the plating reaction as side reaction running in parallel to the main intercalation reaction. The thermodynamics of the plating reaction are modeled depending on temperature and ion concentration, which differs from the often-used assumption of a constant plating condition of 0 V anode potential. The reaction kinetics are described with an Arrhenius-type rate law parameterized from an extensive literature research. Re-intercalation of plated lithium was modeled to take place either via reverse plating (solution-mediated) or via an explicit interfacial reaction (surface-mediated). At low temperatures not only the main processes (intercalation and solid-state diffusion) become slow, but also the plating reaction itself becomes slower. Using this model, we are able to predict typical macroscopic experimental observables that are indicative of plating, that is, a voltage plateau during discharge and a voltage drop upon temperature increase. A spatiotemporal analysis of the internal cell states allows a quantitative insight into the competition between intercalation and plating. Finally, we calculate operation maps over a wide range of C-rates and temperatures that allow to assess plating propensity as function of operating condition.
PHOTOPUR hat die Entwicklung eines photokatalytischen Prozesses zur Beseitigung von Pflanzenschutzmitteln (PSM) aus dem Reinigungswasser von Spritzgeräten zum Ziel. Am INES wurde eine Energieversorgung für die photokatalytische Reinigung in zwei Bachelorarbeiten entwickelt und als Demosystem aufgebaut. Das Gesamtsystem ist nun als mobile Einheit verfügbar und wurde zuletzt um das Reaktormodul für den photokatalytischen Prozeß erweitert und den Partnern für intensive Tests übergeben.
This article presents the development, parameterization, and experimental validation of a pseudo-three-dimensional (P3D) multiphysics model of a 350 mAh high-power lithium-ion pouch cell with graphite anode and lithium cobalt oxide/lithium nickel cobalt aluminum oxide (LCO/NCA) blend cathode. The model describes transport processes on three different scales: Heat transport on the macroscopic scale (cell), mass and charge transport on the mesoscopic scale (electrode pair), and mass transport on the microscopic scale (active material particles). A generalized description of electrochemistry in blend electrodes is developed, using the open-source software Cantera for calculating species source terms. Very good agreement of model predictions with galvanostatic charge/discharge measurements, electrochemical impedance spectroscopy, and surface temperature measurements is observed over a wide range of operating conditions (0.05C to 10C charge and discharge, 5°C to 35°C). The behavior of internal states (concentrations, potentials, temperatures) is discussed. The blend materials show a complex behavior with both intra-particle and inter-particle non-equilibria during cycling.
Techno-economic comparison of membrane distillation and MVC in a zero liquid discharge application
(2018)
Membrane distillation (MD) is a thermally driven membrane process for the separation of vapour from a liquid stream through a hydrophobic, microporous membrane. However, a commercial breakthrough on a large scale has not been achieved so far. Specific developments on MD technology are required to adapt the technology for applications in which its properties can potentially outshine state of the art technologies such as standard evaporation. In order to drive these developments in a focused manner, firstly it must be shown that MD can be economically attractive in comparison to state of the art systems. Thus, this work presents a technological design and economic analysis for AGMD and v-AGMD for application in a zero liquid discharge (ZLD) process chain and compares it to the costs of mechanical vapour compression (MVC) for the same application. The results show that MD can potentially be ~40% more cost effective than MVC for a system capacity of 100 m3/day feed water, and up to ~75% more cost effective if the MD is driven with free waste heat.
Das Projekt PHOTOPUR soll die Reduzierung von Pestiziden in Oberflächengewässern ermöglichen. In dieser Arbeit wird eine Automatisierung eines ersten Demosystems entwickelt, welches den gesamten Reinigungsprozess abbildet. Eine Projektierung der Automatisierung des Systems wird mit den dafür vorgesehenen Fließschemas und Gerätelisten durchgeführt. Darauf aufbauend wird die Ablaufsteuerung des Demosystems durch einen Ablauf-Funktionsplan umgesetzt. Um eine Systemüberwachung der Anlage zu gewährleisten wurde dazu eine Visualisierung ausgearbeitet. Zusätzlich wurden die Regelstrecken der Durchflussregelungen in den zwei Teilprozessen des Reinigungsprozesses bestimmt und durch unterschiedliche Einstellregeln der optimale Regler der Regelkreise ermittelt.
Die in dieser Arbeit entwickelte Software, beinhaltet die drei folgenden Umsetzungen: Realisierung der Ablaufsteuerung, Implementierung der Reglerparameter durch einen vorhandenen Regelalgorithmus und die Visualisierung des Demosystems.
We present an electrochemical model of a lithium iron phosphate/graphite (LFP/C6) cell that includes combined aging mechanisms: (i) Electrochemical formation of the solid electrolyte interphase (SEI) at the anode, leading to loss of lithium inventory, (ii) breaking of the SEI due to volume changes of the graphite particles, causing accelerated SEI growth, and (iii) loss of active material due to of loss percolation of the liquid electrolyte resulting from electrode dry-out. The latter requires the introduction of an activity-saturation relationship. A time-upscaling methodology is developed that allows to simulate large time spans (thousands of operating hours). The combined modeling and simulation framework is able to predict calendaric and cyclic aging up to the end of life of the battery cells. The aging parameters are adjusted to match literature calendaric and cyclic aging experiments, resulting in quantitative agreement of simulated nonlinear capacity loss with experimental data. The model predicts and provides an interpretation for the dependence of capacity loss on temperature, cycling depth, and average SOC. The introduction of a percolation threshold in the activity-saturation relationship allows to capture the strong nonlinearity of aging toward end of life (“sudden death”).
Das Projektvorhaben "Energienetzmanagement dezentraler KWK‐Anlagen mit diversen Verbraucherstrukturen", das vom Innovationsfonds der badenova AG & Co KG von Mai 2012 bis Juli 2016 unter der Fördernummer 2012‐09 gefördert wurde kann aus Sicht des Projektnehmers Hochschule Offenburg und seiner Partner Stadt Offenburg und G. und M. Zapf Energie GbR mbH als sehr erfolgreich umgesetztes Fördervorhaben bezeichnet werden. Während der ca. vier Jahre Projektlaufzeit konnten mehrere Reallabore geschaffen werden, die an die Eigenschaften eines Subnetzes in einem Smart Grid sehr nah herangeführt wurden. Alle Objekte bzw. Netzstrukturen verfügen über typische Komponenten eines Microgrids mit Energiequellen, Speichern und Senken. Auch wurde die Trigeneration als Netzvariante mit Strom‐ Wärme und Kältebereitstellung aufgegriffen und für Verteilnetzmodelle der Niederspannungsebene beschrieben. Ausgehend von einem Mikronetzmodell für jede Energieart kann hinter jeder Trafostation eine beliebig komplexe Energieversorgungsstruktur aufgespannt werden.
One of the practical bottlenecks associated with commercialization of lithium-air cells is the choice of an appropriate electrolyte that provides the required combination of cell performance, cyclability and safety. With the help of a two-dimensional multiphysics model, we attempt to narrow down the electrolyte choice by providing insights into the effect of the transport properties of electrolyte, electrode saturation (flooded versus gas diffusion), and electrode thickness on a single discharge performance of a lithium-air button cell cathode for five different electrolytes including water, ionic liquid, carbonate, ether, and sulfoxide. The 2D distribution of local current density and concentrations of electrochemically active species (O2 and Li+) in the cathode is also discussed w.r.t electrode saturation. Furthermore, the efficacy of species transport in the cathode is quantified by introducing two parameters, firstly, a transport efficiency that gives local insight into the distribution of mass transfer losses, and secondly, an active electrode volume that gives global insight into the cathode volume utilization at different current densities. A detailed discussion is presented toward understanding the design-induced performance limitations in a Li-air button cell prototype.
Lithium-ion batteries show a complex thermo-electrochemical performance and aging behavior. This paper presents a modeling and simulation framework that is able to describe both multi-scale heat and mass transport and complex electrochemical reaction mechanisms. The transport model is based on a 1D + 1D + 1D (pseudo-3D or P3D) multi-scale approach for intra-particle lithium diffusion, electrode-pair mass and charge transport, and cell-level heat transport, coupled via boundary conditions and homogenization approaches. The electrochemistry model is based on the use of the open-source chemical kinetics code CANTERA, allowing flexible multi-phase electrochemistry to describe both main and side reactions such as SEI formation. A model of gas-phase pressure buildup inside the cell upon aging is added. We parameterize the model to reflect the performance and aging behavior of a lithium iron phosphate (LiFePO4, LFP)/graphite (LiC6) 26650 battery cell. Performance (0.1–10 C discharge/charge at 25, 40 and 60°C) and calendaric aging experimental data (500 days at 30°C and 45°C and different SOC) from literature can be successfully reproduced. The predicted internal cell states (concentrations, potential, temperature, pressure, internal resistances) are shown and discussed. The model is able to capture the nonlinear feedback between performance, aging, and temperature.
Der sommerliche Wärmeschutz von Schulgebäuden im Oberrheingraben und die Bereitstellung von Kühlenergie wurden bereits untersucht und finden Aufnahme im Leitfaden „Natürliche Gebäudeklimatisierung in Klassenzimmern des südlichen Oberrheins“. Im Rahmen der Arbeiten zur Minderung der sommerlichen Überhitzung wurde durch den Einbau und die damit verbundene kontinuierliche Aufzeichnung der CO2‐Konzentrationen der Raumluft festgestellt, dass besonders im Winterhalbjahr eine Verbesserung der Luftqualität erreicht werden muss.
Meeting the requirements of smart grids local, decentralized subnets will offer additional potentials to stabilize and compensate the utility grid mainly on the low voltage level. In a quite complex configuration these decentralized energy systems are combined power, heat and cooling power distributions. According to the regional and local availability of renewable energy sources advanced energy management concepts should consider climatic conditions as well as the state of the interacting utility grid and consumption profiles. The approach uses demonstrational setups to develop a forecast based energy management for trigeneration subnets by taking into account the running conditions of local electrical and thermal energy conversion units. This should lead to the best coverage of the demand and supporting/stabilizing the utility grid at the same time. For the first of three demonstrational projects the priorities of the subnet are given with the maximization of the CHP operation to substitute a major part of the heating and cooling power delivered by electric heaters or compression chillers.
Der vorliegende Leitfaden „Natürliche Gebäudeklimatisierung in Klassenzimmern“ greift einen nachhaltigen Ansatz zur deutlichen Reduzierung der sommerlichen Wärmebelastung in Klassenzimmern auf. Insbesondere die ersten sechs Jahre des 21. Jahrhunderts zeigten verstärkt Überhitzungstendenzen in sehr vielen Schulgebäuden der Region südlicher Oberrhein. In Verbindung mit der Umstellung des Schulbetriebs auf die Ganztagsschule und der deutlichen Verstärkung der Überhitzungstendenz in sanierten Gebäuden, die mit einem modernisierten Wärmeschutz versehen sind, zeigte sich für die Stadt Offenburg ein wichtiger Handlungsbedarf auf.
Aus der Kooperation der Stadt Offenburg mit der Hochschule Offenburg entwickelten sich mehrere Maßnahmenpakete bestehend aus einer Kombination bekannter physikalischer Sachverhalte und Verfahren, die mit den Möglichkeiten einer Gebäudeautomation gekoppelt werden und durch Einbindung der Nutzer in das Betriebskonzept zu einem thermisch verbesserten Arbeits- und Lernklima führen.
In vielen Schulgebäuden der Region südlicher Oberrhein zeigte sich seit Beginn dieses Jahrhunderts eine verstärkte Überhitzungstendenz. Besonders bei energetisch sanierten Schulen und durch die Umstellung des Schulbetriebs auf den Ganztagsunterricht zeigt sich eine stärkere Wärmebelastung durch die sommerlichen Temperaturen. Die Stadt Offenburg sah hier einen wichtigen Handlungsbedarf, um Klassenräume ohne den Einsatz energieintensiver Kältemaschinen thermisch zu entlasten. Durch einen deutlichen Anstieg beim Energieeinsatz für Kühlmaßnahmen würden die starken Einspareffekte bei den Heizkosten im Sommer neutralisiert. Interessant waren deshalb nachhaltige Lösungen die bei niedrigem Primärenergieeinsatz ein hohes Reduktionspotenzial bei der Kühllast bewirken. Verfahren der natürlichen Gebäudeklimatisierung führten in Zusammenarbeit mit der Forschungsgruppe nachhaltige Energietechnik der Hochschule Offenburg zu unterschiedlichen Nachtlüftungsstrategien zusammen mit ergänzenden Wärmeschutzmaßnahmen.