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Rubber materials are characterized by a variety of inelasticities such as softening behavior, hysteresis loops and permanent set. In order to calculate the inelastic material behavior, constitutive models, that describe rubber as a homogeneous continuum, have to make use of damping or friction elements.
On the nanoscale, there is no need to adopt such rheological models. Inelastic material behavior can be explained and simulated by a continuous rearrangement of bonds, in particular, the van der Waals interactions, and by the polymer chains transitioning between cis and trans equilibrium torsion angles. The discrete molecular dynamics simulations presented in this paper are performed in an explicit FEM environment using nonlinear but elastic force field potentials. From a structural mechanics point of view, topological changes of the polymer network can be interpreted as a sequence of local material instability problems due to negative tangential bond stiffnesses.
In order to obtain representative results within reasonable computational time, the model is optimized with respect to the number of atoms and the loading velocity. It is shown that by increasing the model size, the stress–strain curves become independent of both the atoms initial state and the strain amplitudes.
The current methods used to assess the energy performance of ventilation devices do not consider all the aspects necessary for a comprehensive evaluation of decentralised ventilation concepts and can only be partially adapted to their needs. In order to improve the energy evaluation and to ensure the comparability of different systems, a calorimetric method was developed and implemented in test facilities for the evaluation of two decentralised devices: one equipped with a recuperative counter flow heat exchanger and one with a regenerative heat exchanger. This method, based on direct measurements of the heating load in an insulated test room, includes the effect of the electrical consumption of the fans on the energy performance of the ventilation devices. The calorimetric evaluation method was extended to a seasonal evaluation on the basis of a heating-degree-day method implemented for a warm, a cool and a moderate location in Europe: Athens, Strasbourg and Copenhagen. All the results are above 50% efficiency for both devices, even in Athens where the use of heat recovery ventilation is not usual.
Eine repräsentative Studie mit 2.400 deutschen Arbeitnehmern zeigt, dass Mitarbeiter seltener krank werden, wenn sie sich an ihr Unternehmen gebunden fühlen. Die Studie offenbart auch, dass die Intensität des Commitment maßgeblich von fünf Einflussfaktoren abhängt. Die Kenntnis dieser Faktoren ermöglicht es Personalmanagern, Mitarbeiter gezielter an das Unternehmen zu binden, um so den Krankenstand positiv zu beeinflussen.
In the present study, in vitro toxicity as well as biopersistence and photopersistence of four artificial sweeteners (acesulfame, cyclamate, saccharine, and sucralose) and five antibiotics (levofloxacin, lincomycin, linezolid, marbofloxacin, and sarafloxacin) and of their phototransformation products (PTPs) were investigated. Furthermore, antibiotic activity was evaluated after UV irradiation and after exposure to inocula of a sewage treatment plant. The study reveals that most of the tested compounds and their PTPs were neither readily nor inherently biodegradable in the Organisation for Economic Co-operation and Development (OECD)-biodegradability tests. The study further demonstrates that PTPs are formed upon irradiation with an Hg lamp (UV light) and, to a lesser extent, upon irradiation with a Xe lamp (mimics sunlight). Comparing the nonirradiated with the corresponding irradiated solutions, a higher chronic toxicity against bacteria was found for the irradiated solutions of linezolid. Neither cytotoxicity nor genotoxicity was found in human cervical (HeLa) and liver (Hep-G2) cells for any of the investigated compounds or their PTPs. Antimicrobial activity of the tested fluoroquinolones was reduced after UV treatment, but it was not reduced after a 28-day exposure to inocula of a sewage treatment plant. This comparative study shows that PTPs can be formed as a result of UV treatment. The study further demonstrated that UV irradiation can be effective in reducing the antimicrobial activity of antibiotics, and consequently may help to reduce antimicrobial resistance in wastewaters. Nevertheless, the study also highlights that some PTPs may exhibit a higher ecotoxicity than the respective parent compounds. Consequently, UV treatment does not transform all micropollutants into harmless compounds and may not be a large-scale effluent treatment option.
The state-of-the-art electrochemical impedance spectroscopy (EIS) calculations have not yet started from fully multi-dimensional modeling. For a polymer electrolyte membrane fuel cell (PEMFC) with long flow channel, the impedance plot shows a multi-arc characteristic and some impedance arcs could merge. By using a step excitation/Fourier transform algorithm, an EIS simulation is implemented for the first time based on the full 2D PEMFC model presented in the first part of this work. All the dominant transient behaviors are able to be captured. A novel methodology called ‘configuration of system dynamics’, which is suitable for any electrochemical system, is then developed to resolve the physical meaning of the impedance spectra. In addition to the high-frequency arc due to charge transfer, the Nyquist plots contain additional medium/low-frequency arcs due to mass transfer in the diffusion layers and along the channel, as well as a low-frequency arc resulting from water transport in the membrane. In some case, the impedance spectra appear partly inductive due to water transport, which demonstrates the complexity of the water management of PEMFCs and the necessity of physics-based calculations.
A two-dimensional single-phase model is developed for the steady-state and transient analysis of polymer electrolyte membrane fuel cells (PEMFC). Based on diluted and concentrated solution theories, viscous flow is introduced into a phenomenological multi-component modeling framework in the membrane. Characteristic variables related to the water uptake are discussed. A Butler–Volmer formulation of the current-overpotential relationship is developed based on an elementary mechanism of electrochemical oxygen reduction. Validated by using published V–I experiments, the model is then used to analyze the effects of operating conditions on current output and water management, especially net water transport coefficient along the channel. For a power PEMFC, the long-channel configuration is helpful for internal humidification and anode water removal, operating in counterflow mode with proper gas flow rate and humidity. In time domain, a typical transient process with closed anode is also investigated.
We present a 3D simulation approach utilising the diffuse interface representation of the phase-field method combined with a heat transfer equation to analyse the thermal conductivity in air-filled aluminium foams with complex cellular structures of different porosity. Algorithmic methods are introduced to create synthetic open-cell foam structures and to compute the thermal conductivity by means of phase-field modelling. A material law for the effective thermal conductivity is derived by determining the appropriate exponent depending on the relative density in the system. The results are compared with the thermal conductivity in massive aluminium and in pure air.
Lean und ERP - Synergie oder Widerspruch? Ein neuer Ansatz zur Steigerung der Unternehmenseffizienz
(2015)
Eine erfolgreiche Zusammenführung der Vorteile von ERP-Systemen mit den Vorzügen des Lean-Ansatzes kann zur Erschließung eines erheblichen Verbesserungspotenzials und damit zu signifikanten Wettbewerbsvorteilen einer Unternehmung führen. Da dieser Ansatz in der Praxis häufig kritisiert und bisher kaum adäquat verfolgt wird, zielt dieser Beitrag darauf ab, einen innovativen Lösungsweg vorzustellen, welcher nicht nur theoretisch, sondern auch anhand eines ERP-Einführungsprojekts in einem KMU empirisch aufzeigt, dass Lean und ERP nutzbringend miteinander kombiniert werden können und sollten.