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A 2D-separation of 16 polyaromatic hydrocarbons (PAHs) according to the Environmental Protecting Agency (EPA) standard was introduced. Separation took place on a TLC RP-18 plate (Merck, 1.05559). In the first direction, the plate was developed twice using n-pentane at −20°C as the mobile phase. The mixture acetonitrile-methanol-acetone-water (12:8:3:3, v/v) was used for developing the plate in the second direction. Both developments were carried out over a distance of 43 mm. Further on in this publication, a specific and very sensitive indication method for benzo[a]pyrene and perylene was presented. The method can detect these hazardous compounds even in complicated PAH mixtures. These compounds can be quantified by a simple chemiluminescent reaction with a limit of detection (LOD) of 48 pg per band for perylene and 95 pg per band for benzo[a]pyrene. Although these compounds were separated from all other PAHs in the standard, a separation of both compounds was not possible from one another. The method is suitable for tracing benzo[a]pyrene and/or perylene. The proposed chemiluminescence screening test on PAHs is extremely sensitive but may indicate a false positive result for benzo[a]pyrene.
The state-of-the-art electrochemical impedance spectroscopy (EIS) calculations have not yet started from fully multi-dimensional modeling. For a polymer electrolyte membrane fuel cell (PEMFC) with long flow channel, the impedance plot shows a multi-arc characteristic and some impedance arcs could merge. By using a step excitation/Fourier transform algorithm, an EIS simulation is implemented for the first time based on the full 2D PEMFC model presented in the first part of this work. All the dominant transient behaviors are able to be captured. A novel methodology called ‘configuration of system dynamics’, which is suitable for any electrochemical system, is then developed to resolve the physical meaning of the impedance spectra. In addition to the high-frequency arc due to charge transfer, the Nyquist plots contain additional medium/low-frequency arcs due to mass transfer in the diffusion layers and along the channel, as well as a low-frequency arc resulting from water transport in the membrane. In some case, the impedance spectra appear partly inductive due to water transport, which demonstrates the complexity of the water management of PEMFCs and the necessity of physics-based calculations.
A two-dimensional single-phase model is developed for the steady-state and transient analysis of polymer electrolyte membrane fuel cells (PEMFC). Based on diluted and concentrated solution theories, viscous flow is introduced into a phenomenological multi-component modeling framework in the membrane. Characteristic variables related to the water uptake are discussed. A Butler–Volmer formulation of the current-overpotential relationship is developed based on an elementary mechanism of electrochemical oxygen reduction. Validated by using published V–I experiments, the model is then used to analyze the effects of operating conditions on current output and water management, especially net water transport coefficient along the channel. For a power PEMFC, the long-channel configuration is helpful for internal humidification and anode water removal, operating in counterflow mode with proper gas flow rate and humidity. In time domain, a typical transient process with closed anode is also investigated.
The main focus of this chapter is the theoretical and instrumental processes that underpin densitometric methods widely used in thin-layer chromatography (TLC). Densitometric methods include UV–vis, luminescence and fluorescence optical measurements as well as infrared and Raman spectroscopic measurements. The chapter is divided in two general parts: a theoretical part and a practical part. The systems for direct radioactivity measurements and the combination of TLC with mass spectrometry are also discussed. All these systems allow measuring an intensity distribution directly on a TLC plate. We call this “in situ detection” because no analyte is removed from the plate.
Systemic Constellations are a phenomenological approach to resolving personal, professional and organizational issues. They offer a way of mapping a present reality, working at the source of the hidden dynamics and moving to a resolution. This systemic approach often delivers surprising and unexpected insights while also offering the possibility to analyze and solve organizational problems. Rational analysis provides the whole picture of the problem which often turns out to be too complex for a decision making. Systemic constellations can help to simplify and clarify the situation and inform what has to happen next [8], [17]. The outcomes of systemic constellations as an additional resource for solving comprehensive technical problems have not yet been sufficiently investigated. In structural constellation work dealing with technical problems, the individuals who are involved in the problem situation are used to represent different system components, substances or fields. A moderator voices the feedback from the representatives concerning their feelings or intuitive movements, and points to possible solutions. For example, a moderator places the representatives somewhere in the room, develops a three-dimensional picture of the constellation of the analyzed situation and tries to expose the factors empowering or blocking the way towards constructive solutions [13]. This paper explores the theoretical background and practical outcomes of the systemic constellation method for technical problem solving. It presents some case study work which has been conducted in recent years, and then discusses its findings and implications. The research outlined in this paper demonstrates that the noteworthy contribution of structural constellation work for problem solving is typically the result of a combination of functional analysis and the feeling-as-information principle. The constellation work helps, at first, to reveal the subjective experiences, such as feelings, moods, emotions, and bodily sensations, and then to accept them as a source of objective information relevant to the decision making process. In accordance with the latest research [19], the use of feelings as a source of information follows the same principles as the use of any other information. This paper provides the structures of some standard templates and types of constellation work for technical problems, and discusses the preconditions for their application.
We present a 3D simulation approach utilising the diffuse interface representation of the phase-field method combined with a heat transfer equation to analyse the thermal conductivity in air-filled aluminium foams with complex cellular structures of different porosity. Algorithmic methods are introduced to create synthetic open-cell foam structures and to compute the thermal conductivity by means of phase-field modelling. A material law for the effective thermal conductivity is derived by determining the appropriate exponent depending on the relative density in the system. The results are compared with the thermal conductivity in massive aluminium and in pure air.
Photovoltaics Energy Prediction Under Complex Conditions for a Predictive Energy Management System
(2015)
The energy system of the future will transform from the current centralised fossil based to a decentralised, clean, highly efficient, and intelligent network. This transformation will require innovative technologies and ideas like trigeneration and the crowd energy concept to pave the way ahead. Even though trigeneration systems are extremely energy efficient and can play a vital role in the energy system, turning around their deployment is hindered by various barriers. These barriers are theoretically analysed in a multiperspective approach and the role decentralised trigeneration systems can play in the crowd energy concept is highlighted. It is derived from an initial literature research that a multiperspective (technological, energy-economic, and user) analysis is necessary for realising the potential of trigeneration systems in a decentralised grid. And to experimentally quantify these issues we are setting up a microscale trigeneration lab at our institute and the motivation for this lab is also briefly introduced.
Phosphate-based inorganic–organic hybrid nanoparticles (IOH-NPs) with the general composition [M]2+[Rfunction(O)PO3]2– (M = ZrO, Mg2O; R = functional organic group) show multipurpose and multifunctional properties. If [Rfunction(O)PO3]2– is a fluorescent dye anion ([RdyeOPO3]2–), the IOH-NPs show blue, green, red, and near-infrared fluorescence. This is shown for [ZrO]2+[PUP]2–, [ZrO]2+[MFP]2–, [ZrO]2+[RRP]2–, and [ZrO]2+[DUT]2– (PUP = phenylumbelliferon phosphate, MFP = methylfluorescein phosphate, RRP = resorufin phosphate, DUT = Dyomics-647 uridine triphosphate). With pharmaceutical agents as functional anions ([RdrugOPO3]2–), drug transport and release of anti-inflammatory ([ZrO]2+[BMP]2–) and antitumor agents ([ZrO]2+[FdUMP]2–) with an up to 80% load of active drug is possible (BMP = betamethason phosphate, FdUMP = 5′-fluoro-2′-deoxyuridine 5′-monophosphate). A combination of fluorescent dye and drug anions is possible as well and shown for [ZrO]2+[BMP]2–0.996[DUT]2–0.004. Merging of functional anions, in general, results in [ZrO]2+([RdrugOPO3]1–x[RdyeOPO3]x)2– nanoparticles and is highly relevant for theranostics. Amine-based functional anions in [MgO]2+[RaminePO3]2– IOH-NPs, finally, show CO2 sorption (up to 180 mg g–1) and can be used for CO2/N2 separation (selectivity up to α = 23). This includes aminomethyl phosphonate [AMP]2–, 1-aminoethyl phosphonate [1AEP]2–, 2-aminoethyl phosphonate [2AEP]2–, aminopropyl phosphonate [APP]2–, and aminobutyl phosphonate [ABP]2–. All [M]2+[Rfunction(O)PO3]2– IOH-NPs are prepared via noncomplex synthesis in water, which facilitates practical handling and which is optimal for biomedical application. In sum, all IOH-NPs have very similar chemical compositions but can address a variety of different functions, including fluorescence, drug delivery, and CO2 sorption.
Combined heat and power production (CHP) based on solid oxide fuel cells (SOFC) is a very promising technology to achieve high electrical efficiency to cover power demand by decentralized production. This paper presents a dynamic quasi 2D model of an SOFC system which consists of stack and balance of plant and includes thermal coupling between the single components. The model is implemented in Modelica® and validated with experimental data for the stack UI-characteristic and the thermal behavior. The good agreement between experimental and simulation results demonstrates the validity of the model. Different operating conditions and system configurations are tested, increasing the net electrical efficiency to 57% by implementing an anode offgas recycle rate of 65%. A sensitivity analysis of characteristic values of the system like fuel utilization, oxygen-to-carbon ratio and electrical efficiency for different natural gas compositions is carried out. The result shows that a control strategy adapted to variable natural gas composition and its energy content should be developed in order to optimize the operation of the system.
Instabilities of the interface between two thin liquid films under DC electroosmotic flow are investigated using linear stability analysis followed by an asymptotic analysis in the long-wave limit. The two-liquid system is bounded by two rigid plates which act as substrates. The Boltzmann charge distribution is considered for the two electrolyte solutions and gives rise to a potential distribution in these liquids. The effect of van der Waals interactions in these thin films is incorporated in the momentum equations through the disjoining pressure. Marginal stability and growth rate curves are plotted in order to identify the thresholds for the control parameters when instabilities set in. If the upper liquid is a dielectric, the applied electric field can have stabilizing or destabilizing effects depending on the viscosity ratio due to the competition between viscous and electric forces. For viscosity ratio equal to unity, the stability of the system gets disconnected from the electric parameters like interface zeta potential and electric double-layer thickness. As expected, disjoining pressure has a destabilizing effect, and capillary forces have stabilizing effect. The overall stability trend depends on the complex contest between all the above-mentioned parameters. The present study can be used to tune these parameters according to the stability requirement.
The following contribution deals with the experimental investigation and theoretical evaluation of fatigue crack growth under isothermal and non-isothermal conditions at the nickel alloy 617. The microstructure and mechanical properties of alloy 617 are influenced significantly by the thermal heat treatment and the following thermal exposure in service. Hence, a solution annealed and a long-time service exposed material condition is studied. The crack growth measurement is carried out by using an alternate current potential drop system, which is integrated into a thermomechanical fatigue (TMF) test facility. The measured fatigue crack growth rates results in a function of material condition, temperature and load waveform. Furthermore, the results of the non-isothermal tests depend on the phase between thermal and mechanical load (in-phase, out-of-phase). A fracture mechanic based, time dependent model is upgraded by an approach to consider environmental effects, where almost all model parameters represent directly measureable values. A consistent description of all results and a good correlation with the experimental data can be achieved.
Autonomous humanoid robots require light weight, high torque and high speed actuators to be able to walk and run. For conventional gears with a fixed gear ratio the product of torque and velocity is constant. On the other hand desired motions require maximum torque and speed. In this paper it is shown that with a variable gear ratio it is possible to vary the relation between torque and velocity. This is achieved by introducing systems of rods and levers to move the joints of our humanoid robot ”Sweaty II”. On the basis of a variable gear ratio low speed and high torque can be achieved for those joint angles, which require this motion mode, whereas high speed and low torque can be realized for those joint angles, where it is favorable for the desired motion.
This article sets the focus on methods of information technology in the Humboldt Portal, which represents an ongoing research project to develop a virtual research environment on the Internet for the legacy of Alexander von Humboldt. Based on the experiences of developing and providing the Humboldt Digital Library (www.avhumboldt.net) for more than a decade, we defined a working plan to create an Internet portal for comprehensive access to Humboldt’s writings, no matter if documents are provided as PDF files, scan images or XML-TEI documents on external archives (Google Books, Internet Archive, Deutsches Textarchiv, Bibliotheque National de France). Going far beyond services of a digital library we will provide an information network with multimedia assets, which are containing objects like terms, paragraphs, data tables, scan images, or illustrations, together with correlated properties like thematic linkage to other objects, relevant keywords with optional synonyms and dynamic hyperlinks to related translations in different languages. So the Humboldt Portal can contribute to the key question, how to present interconnected data in an appropriate form using information technologies on the Web.
The transformation of the building energy sector to a highly efficient, clean, decentralised and intelligent system requires innovative technologies like microscale trigeneration and thermally activated building structures (TABS) to pave the way ahead. The combination of such technologies however presents a scientific and engineering challenge. Scientific challenge in terms of developing optimal thermo-electric load management strategies based on overall energy system analysis and an engineering challenge in terms of implementing these strategies through process planning and control. Initial literature research has pointed out the need for a multiperspective analysis in a real life laboratory environment. To this effect an investigation is proposed wherein an analytical model of a microscale trigeneration system integrated with TABS will be developed and compared with a real life test-rig corresponding to building management systems. Data from the experimental analysis will be used to develop control algorithms using model predictive control for achieving the thermal comfort of occupants in the most energy efficient and grid reactive manner. The scope of this work encompasses adsorption cooling based microscale trigeneration systems and their deployment in residential and light commercial buildings.
Skills, abilities and capability of our freshmen are increasingly heterogeneous, regarding age, attained levels of education and motivational aspects. Additionally, students tend to recoil from subjects dealing with mathematical backgrounds. As a result high, drop-out numbers are a huge problem in technical degree programs.
Since mechanics is based on physics and mathematics our students face enormous difficulties. To deal with them, a form of teaching and learning has been developed that is composed of the following arrangements:
1. Problems and tasks of different levels are solved during lessons. The access to theoretical issues is being developed by or rather as a result of solving these problems. By doing so, especially students with yet insufficient skills are enabled to develop their methodological skills.
2. Challenging students to independently transfer these skills on other problems is helpful. At the end of each lecture two students are selected randomly. Each of them is faced with an exercise they have to solve and present at the beginning of the next lecture. Because of small student numbers, chances are high that every student participates at least once by the end of semester. Surveys show that particularly weaker students benefit from that kind of model learning.
3. We are surrounded by mechanical issues. Given that, students are presented with “every-day-life” problems which students can apply their theoretical knowledge on. The problems are analyzed by groups of students, which leads to an enhanced and reflective perception of each and every one. Some examples are: “A broomstick in equilibrium”, “Sensitive cups”, “Transforming a roman basilica into a gothic cathedral”.
4. All lectures have been filmed by the staff of the Information Center of the Offenburg University during the previous term. Additionally to the notes taken by the students individually during the lectures, these recordings are helpful in the process of preparation and post-processing of the material. The recordings are accessible via the university’s learning management system “Moodle”.
Surveys show that students benefit from the great variety of the provided, interactive learning arrangements. It is interesting to discover that students not only take positive advantages in the lecture “mechanics 1/statics” but tend to transfer these positive experiences on other subjects.