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Steroid hormones (SHs) are a rising concern due to their high bioactivity, ubiquitous nature, and prolonged existence as a micropollutants in water, they pose a potential risk to both human health and the environment, even at low concentrations. Estrogens, progesterone, and testosterone are the three important types of steroids essential for human development and maintaining multiorgan balance, are focus to this concern. These steroid hormones originate
from various sources, including human and livestock excretions, veterinary medications, agricultural runoff, and pharmaceuticals, contributing to their presence in the environment. According to the recommendation of WHO, the guidance value for estradiol (E2) is 1 ng/L. There are several methods been attempted to remove the SH micropollutant by conventional water and wastewater technologies which are still under research. Among the various methods, electrochemical membrane reactor (EMR) is one of the emerging technologies that can address the challenge of insufficient SHs removal from the aquatic environment by conventional treatment. The degradation of SHs can be significantly influenced by various factors when treated with EMR.
In this project, the removal of SH and the important mechanism for the removal using carbon nanotube CNT-EMR is studied and the efficiency of CNT-EMR in treating the SH micropollutant is identified. By varying different parameters this experiment is carried out with the (PES-CNTs) ultrafiltration membrane. The study is carried out depending upon the SH removal based on the limiting factor such as cell voltage, flux, temperature, concentration, and type of the SH.
This thesis focuses on the development and implementation of a Datagram Transport Layer Security (DTLS) communication framework within the ns-3 network simulator, specifically targeting the LoRaWAN model network. The primary aim is to analyse the behaviour and performance of DTLS protocols across different network conditions within a LoRaWAN context. The key aspects of this work include the following.
Utilization of ns-3: This thesis leverages ns-3’s capabilities as a powerful discrete event network simulator. This platform enables the emulation of diverse network environments, characterized by varying levels of latency, packet loss, and bandwidth constraints.
Emulation of Network Challenges: The framework specifically addresses unique challenges posed by certain network configurations, such as duty cycle limitations. These constraints, which limit the time allocated for data transmission by each device, are crucial in understanding the real-world performance of DTLS protocols.
Testing in Multi-client-server Scenarios: A significant feature of this framework is its ability to test DTLS performance in complex scenarios involving multiple clients and servers. This is vital for assessing the behaviour of a protocol under realistic network conditions.
Realistic Environment Simulation: By simulating challenging network conditions, such as congestion, limited bandwidth, and resource constraints, the framework provides a realistic environment for thorough evaluation. This allows for a comprehensive analysis of DTLS in terms of security, performance, and scalability.
Overall, this thesis contributes to a deeper understanding of DTLS protocols by providing a robust tool for their evaluation under various and challenging network conditions.
Global energy demand is still on an increase during the last decade, with a lot of impact on the climate change due to the intensive use of conventional fossil-based fuels power plants to cover this demand. Most recently, leaders of the globe met in 2015 to come out with the Paris Agreement, stating that the countries will start to take a more responsible and effective behaviour toward the global warming and climate change issues. Many studies have discussed how the future energy system will look like with respecting the countries’ targets and limits of greenhouse gases and their CO2 emissions. However, these studies rarely discussed the industry sector in detail even though it is one of the major role players in the energy sector. Moreover, many studies have simulated and modelled the energy system with huge jumps of intervals in terms of years and environmental goals. In the first part of this study, a model will be developed for the German electrical grid with high spatial and temporal resolutions and different scenarios of it will be analysed meticulously on shorter periods (annual optimization), with different flexibilities and used technologies and degrees of innovations within each scenario. Moreover, the challenge in this research is to adequately map the diverse and different characteristics of the medium-sized industrial sector. In order to be able to take a first step in assessing the relevance of the industrial sector in Germany for climate protection goals, the industrial sector will be mapped in PyPSA-Eur (an open-source model data set of the European energy system at the level of the transmission network) by detailing the demand for different types of industry and assigning flexibilities to the industrial types. Synthetically generated load profiles of various industrial types are available. Flexibilities in the industrial sector are described by the project partner Fraunhofer IPA in the GaIN project and can be used. Using a scenario analysis, the development of the industrial sector and the use of flexibilities are then to be assessed quantitatively.
This paper will introduce the open-source model MyPyPSA-Ger, a myopic optimization model developed to represent the German energy system with a detailed mapping of the electricity sector, on a highly disaggregated level, spatially and temporally, with regional differences and investment limitations. Furthermore, this paper will give new outlooks on the German federal government 2050 emissions goals of the electricity sector to become greenhouse gas neutral by proposing new CO2 allowance strategies. Moreover, the regional differences in Germany will be discussed, their role and impact on the energy transition, and which regions and states will drive the renewable energy utilization forward.
Following a scenario-based analysis, the results point out the major keystones of the energy transition path from 2020 to 2050. Solar, onshore wind, and gas-fired power plants will play a fundamental role in the future electricity systems. Biomass, run of river, and offshore wind technologies will be utilized in the system as base-load generation technologies. Solar and onshore wind will be installed almost everywhere in Germany. However, due to the nature of Germany’s weather and geographical features, the southern and northern regions will play a more important role in the energy transition.
Higher CO2 allowance costs will help achieve the 1.5-degree-target of the electricity system and will allow for a rapid transition. Moreover, the more expensive, and the earlier the CO2 tax is applied to the system, the less it will cost for the energy transition, and the more emissions will be saved throughout the transition period. An earlier phase-out of coal power plants is not necessary with high CO2 taxes, due to the change in power plant’s unit commitment, as they prioritize gas before coal power plants. Having moderate to low CO2 allowance cost or no clear transition policy will be more expensive and the CO2 budget will be exceeded. Nonetheless, even with no policy, renewables still dominate the energy mix of the future.
However, maintaining the maximum historical installation rates of both national and regional levels, with the current emissions reduction strategy, will not be enough to reach the level of climate-neutral electricity system. Therefore, national and regional installation requirements to achieve the federal government emission reduction goals are determined. Energy strategies and decision makers will have to resolve great challenges in order to stay in line with the 1.5-degree-target.
Most recently, the federal government in Germany published new climate goals in order reach climate neutrality by 2045. This paper demonstrates a path to a cost optimal energy supply system for the German power grid until the year 2050. With special regard to regionality, the system is based on yearly myopic optimization with the required energy system transformation measures and the associated system costs. The results point out, that energy storage systems (ESS) are fundamental for renewables integration in order to have a feasible energy transition. Moreover, the investment in storage technologies increased the usage of the solar and wind technologies. Solar energy investments were highly accompanied with the installation of short-term battery storage. Longer-term storage technologies, such as H2, were accompanied with high installations of wind technologies. The results pointed out that hydrogen investments are expected to overrule short-term batteries if their cost continues to decrease sharply. Moreover, with a strong presence of ESS in the energy system, biomass energy is expected to be completely ruled out from the energy mix. With the current emission reduction strategy and without a strong presence of large scale ESS into the system, it is unlikely that the Paris agreement 2° C target by 2050 will be achieved, let alone the 1.5° C.
With recent developments in the Ukrainian-Russian conflict, many are discussing about Germany’s dependency on fossil fuel imports in its energy system, and how can the country proceed with reducing that dependency. With its wide-ranging consumption sectors, the electricity sector comes as the perfect choice to start with. Recent reports showed that the German federal government is already intending to have a fully renewable electricity by 2035 while exploiting all possible clean power options. This was published in the federal government’s climate emergency program (Easter Package) in early 2022. The aim of this package is to initiate a rapid transition and decarbonization of the electricity sector. The Easter Package expects an enormous growth of renewable energies to a completely new level, with already at least 80% renewable gross energy consumption, with extensive and broad deployment of different generation technologies on various scales. This paper will discuss this ambitious plan and outline some insights into this huge and rapidly increasing step, and show how much will Germany need in order to achieve this huge milestone towards a fully green supply of the electricity sector. Different scenarios and shares of renewables will be investigated in order to elaborate on preponed climate-neutral goal of the electricity sector by 2035. The results pointed out some promising aspects in achieving a 100% renewable power, with massive investments in both generation and storage technologies.
An import ban of Russian energy sources to Germany is currently being increasingly discussed. We want to support the discussion by showing a way how the electricity system in Germany can manage low energy imports in the short term and which measures are necessary to still meet the climate protection targets. In this paper, we examine the impact of a complete stop of Russian fossil fuel imports on the electricity sector in Germany, and how this will affect the climate coals of an earlier coal phase-out and climate neutrality by 2045.
Following a scenario-based analysis, the results gave a point of view on how much would be needed to completely rely on the scarce non-renewable energy resources in Germany. Huge amounts of investments would be needed in order to ensure a secure supply of electricity, in both generation energy sources (RES) and energy storage systems (ESS). The key findings are that a rapid expansion of renewables and storage technologies will significantly reduce the dependence of the German electricity system on energy imports. The huge integration of renewable energy does not entail any significant imports of the energy sources natural gas, hard coal, and mineral oil, even in the long term. The results showed that a ban on fossil fuel imports from Russia outlines huge opportunities to go beyond the German government's climate targets, where the 1.5-degree-target is achieved in the electricity system.
Diese Arbeit befasst sich mit der Redigitalisierung von ausgedruckten Architektur-zeichnungen mit möglichst einfachen Mitteln. So sollen Fotos von herkömmlichen Smartphones die Grundlage für die Extraktion von Maßstab und Raumgeometrien sein.
Der erste der drei Schritte, die das Foto dabei durchläuft, ist die Beseitigung von perspektivischen Verzerrungen (Rektifizierung). Die hierfür benötigten Punkte werden durch ein, in dieser Arbeit trainiertes, Convolutional Neural Network (CNN) detektiert. Die so ermittelten Positionen stellen im zweiten Schritt, der Ermittlung eines Maßstabes, die Grundlage für das Auslesen der Maßzahlen mittels optical character recognition (OCR) dar. Da Räume nicht als solche in Bauzeichnungen eingezeichnet sind, werden im letzten Schritt, zuerst Wände, Türen und Fenster, durch mehrere mathematische Faltungen (convolutions) lokalisiert und innerhalb dieser Elemente, mittels wachsender Regionen, nach Räumen und Fluren gesucht.
Nach dem ein Foto diese Schritte durchlaufen hat, werden die ermittelten Geometrien sowie der Maßstab in einer Liste abgespeichert und im rektifizierten Bild, zusammen mit den berechneten Flächeninhalten, visualisiert. So kann ein Anwender schnell und einfach den Erfolg des Programmoutputs beurteilen.
Eine Versuchsreihe mit einigen Fotos ergab, dass ein Schattenwurf auf dem Papierplan bei Aufnahme des Lichtbildes zu vermeiden ist, da dieser sowohl bei der Auswertung durch das CNN, als auch innerhalb des OCR-Vorgangs zu Problemen führt, die in einigen Fällen eine Rektifizierung oder Maßstabsermittlung verhinderten.
Bei den übrigen fünf Fotos wurden durchschnittlich 31,8 von 32 Räumen detektiert, dabei wurde zwischen zwei und zwölf mal fälschlicherweise die Fensterbank als Fußboden detektiert. Die Standardabweichung der Flächeninhalte aller Räume betrug dabei 0,66 m², werden nur die Räume betrachtet, bei denen die Fensterbank korrekt erkannt wurde, beträgt die Standardabweichung lediglich 0,25 m².
Insgesamt werden die in dieser Arbeit erzielten Ergebnisse als „gut“ eingestuft, es bleiben jedoch auch einige Optimierungsmöglichkeiten an verschiedenen Stellen, besonders bei der Suche nach Räumen, bestehen.
Method and system for extractin metal and oxygen from powdered metal oxides (EP000004170066A2)
(2023)
A method for extracting metal and oxygen from powdered metal oxides in electrolytic cell is proposed, the electrolytic cell comprising a container, a cathode, an anode and an oxygen-ion-conducting membrane, the method comprising providing a solid oxygen ion conducting electrolyte powder into a container, providing a feedstock comprising at least one metal oxide in powdered form into the container, applying an electric potential across the cathode and the anode, the cathode being in communication with the electrolyte powder and the anode being in communication with the membrane in communication with the electrolyte powder, such that at least one respective metallic species of the at least one metal oxide is reduced at the cathode and oxygen is oxidized at the anode to form molecular oxygen, wherein the potential across the cathode and the anode is greater than the dissociation potential of the at least one metal oxide and less than the dissociation potential of the solid electrolyte powder and the membrane.
Erfinderisches Problemlösen mit TRIZ : Zielbeschreibung, Problemdefinition und Lösungspriorisierung
(2017)
Die Theorie des erfinderischen Problemlösens, TRIZ, ist eine Systematik von Annahmen, Regeln, Methoden und Werkzeugen zur innovativen Systemverbesserung z.B. von Produkten, Prozessen, Dienstleistungen oder Organisationen. Diese Richtlinie erläutert TRIZ-Werkzeuge und -Methoden, die insbesondere in den Phasen "Zielbeschreibung", "Problemdefinition" und "Lösungspriorisierung" des Problemlösungsprozesses eingesetzt werden. Die Detailtiefe der Beschreibung erlaubt eine Einschätzung der Werkzeuge und Methoden hinsichtlich Einsatzzwecken, Ergebnissen und Funktionsweise. Die jeweilige Beschreibung der Methoden und Werkzeuge enthält konkrete Aussagen über Zielsetzung und Ergebnis ihres Einsatzes.
To deal with frequent power outages in developing countries, people turn to solutions like uninterruptible power supply (UPS), which stores electric energy during normal operating hours and use it to meet energy needs during rolling blackout intervals. Locally produced UPSs of poorer power quality are widely accessible in the marketplaces, and they have a negative impact on power quality. The charging and discharging of the batteries in these UPSs generate significant amount of power losses in weak grid environments. The Smart-UPS is our proposed smart energy metering (SEM) solution for low voltage consumers that is provided by the distribution company. It does not require batteries, therefore there is no power loss or harmonic distortion due to corresponding charging and discharging. Through load flow and harmonic analysis of both traditional UPS and Smart-UPS systems on ETAP, this paper examines their impact on the harmonics and stability of the distribution grid. The simulation results demonstrate that Smart-UPS can assist fixing power quality issues in a developing country like Pakistan by providing cleaner energy than the battery-operated traditional UPSs.
Due to its potential in improving the efficiency of energy supply, smart energy metering (SEM) has become an area of interest with the surge in Internet of Things (IoT). SEM entails remote monitoring and control of the sensors and actuators associated with the energy supply system. This provides a flexible platform to conceive and implement new data driven Demand Side Management (DSM) mechanisms. The IoT enablement allows the data to be gathered and analyzed at requisite granularity. In addition to efficient use of energy resources and provisioning of power, developing countries face an additional challenge of temporal mismatch in generation capacity and load factors. This leads to widespread deployment of inefficient and expensive Uninterruptible Power Supply (UPS) solutions for limited power provisioning during resulting blackouts. Our proposed “Soft-UPS” allows dynamic matching of load and generation through a combination of managed curtailment. This eliminates inefficiencies in the energy and power value chain and allows a data-driven approach to solving a widespread problem in developing countries, simultaneously reducing both upfront and running costs of conventional UPS and storage. A scalable and modular platform is proposed and implemented in this paper. The architecture employs “WiMODino” using LoRaWAN with a “Lite Gateway” and SQLite repository for data storage. Role based access to the system through an android application has also been demonstrated for monitoring and control.
Following their success in visual recognition tasks, Vision Transformers(ViTs) are being increasingly employed for image restoration. As a few recent works claim that ViTs for image classification also have better robustness properties, we investigate whether the improved adversarial robustness of ViTs extends to image restoration. We consider the recently proposed Restormer model, as well as NAFNet and the "Baseline network" which are both simplified versions of a Restormer. We use Projected Gradient Descent (PGD) and CosPGD for our robustness evaluation. Our experiments are performed on real-world images from the GoPro dataset for image deblurring. Our analysis indicates that contrary to as advocated by ViTs in image classification works, these models are highly susceptible to adversarial attacks. We attempt to find an easy fix and improve their robustness through adversarial training. While this yields a significant increase in robustness for Restormer, results on other networks are less promising. Interestingly, we find that the design choices in NAFNet and Baselines, which were based on iid performance, and not on robust generalization, seem to be at odds with the model robustness.
State-of-the-art models for pixel-wise prediction tasks such as image restoration, image segmentation, or disparity estimation, involve several stages of data resampling, in which the resolution of feature maps is first reduced to aggregate information and then sequentially increased to generate a high-resolution output. Several previous works have investigated the effect of artifacts that are invoked during downsampling and diverse cures have been proposed that facilitate to improve prediction stability and even robustness for image classification. However, equally relevant, artifacts that arise during upsampling have been less discussed. This is significantly relevant as upsampling and downsampling approaches face fundamentally different challenges. While during downsampling, aliases and artifacts can be reduced by blurring feature maps, the emergence of fine details is crucial during upsampling. Blurring is therefore not an option and dedicated operations need to be considered. In this work, we are the first to explore the relevance of context during upsampling by employing convolutional upsampling operations with increasing kernel size while keeping the encoder unchanged. We find that increased kernel sizes can in general improve the prediction stability in tasks such as image restoration or image segmentation, while a block that allows for a combination of small-size kernels for fine details and large-size kernels for artifact removal and increased context yields the best results.
With the surge in global data consumption with proliferation of Internet of Things (IoT), remote monitoring and control is increasingly becoming popular with a wide range of applications from emergency response in remote regions to monitoring of environmental parameters. Mesh networks are being employed to alleviate a number of issues associated with single-hop communication such as low area coverage, reliability, range and high energy consumption. Low-power Wireless Personal Area Networks (LoWPANs) are being used to help realize and permeate the applicability of IoT. In this paper, we present the design and test of IEEE 802.15.4-compliant smart IoT nodes with multi-hop routing. We first discuss the features of the software stack and design choices in hardware that resulted in high RF output power and then present field test results of different baseline network topologies in both rural and urban settings to demonstrate the deployability and scalability of our solution.