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Method and system for extractin metal and oxygen from powdered metal oxides (EP000004170066A2)
(2023)
A method for extracting metal and oxygen from powdered metal oxides in electrolytic cell is proposed, the electrolytic cell comprising a container, a cathode, an anode and an oxygen-ion-conducting membrane, the method comprising providing a solid oxygen ion conducting electrolyte powder into a container, providing a feedstock comprising at least one metal oxide in powdered form into the container, applying an electric potential across the cathode and the anode, the cathode being in communication with the electrolyte powder and the anode being in communication with the membrane in communication with the electrolyte powder, such that at least one respective metallic species of the at least one metal oxide is reduced at the cathode and oxygen is oxidized at the anode to form molecular oxygen, wherein the potential across the cathode and the anode is greater than the dissociation potential of the at least one metal oxide and less than the dissociation potential of the solid electrolyte powder and the membrane.
Erfinderisches Problemlösen mit TRIZ : Zielbeschreibung, Problemdefinition und Lösungspriorisierung
(2017)
Die Theorie des erfinderischen Problemlösens, TRIZ, ist eine Systematik von Annahmen, Regeln, Methoden und Werkzeugen zur innovativen Systemverbesserung z.B. von Produkten, Prozessen, Dienstleistungen oder Organisationen. Diese Richtlinie erläutert TRIZ-Werkzeuge und -Methoden, die insbesondere in den Phasen "Zielbeschreibung", "Problemdefinition" und "Lösungspriorisierung" des Problemlösungsprozesses eingesetzt werden. Die Detailtiefe der Beschreibung erlaubt eine Einschätzung der Werkzeuge und Methoden hinsichtlich Einsatzzwecken, Ergebnissen und Funktionsweise. Die jeweilige Beschreibung der Methoden und Werkzeuge enthält konkrete Aussagen über Zielsetzung und Ergebnis ihres Einsatzes.
To deal with frequent power outages in developing countries, people turn to solutions like uninterruptible power supply (UPS), which stores electric energy during normal operating hours and use it to meet energy needs during rolling blackout intervals. Locally produced UPSs of poorer power quality are widely accessible in the marketplaces, and they have a negative impact on power quality. The charging and discharging of the batteries in these UPSs generate significant amount of power losses in weak grid environments. The Smart-UPS is our proposed smart energy metering (SEM) solution for low voltage consumers that is provided by the distribution company. It does not require batteries, therefore there is no power loss or harmonic distortion due to corresponding charging and discharging. Through load flow and harmonic analysis of both traditional UPS and Smart-UPS systems on ETAP, this paper examines their impact on the harmonics and stability of the distribution grid. The simulation results demonstrate that Smart-UPS can assist fixing power quality issues in a developing country like Pakistan by providing cleaner energy than the battery-operated traditional UPSs.
Due to its potential in improving the efficiency of energy supply, smart energy metering (SEM) has become an area of interest with the surge in Internet of Things (IoT). SEM entails remote monitoring and control of the sensors and actuators associated with the energy supply system. This provides a flexible platform to conceive and implement new data driven Demand Side Management (DSM) mechanisms. The IoT enablement allows the data to be gathered and analyzed at requisite granularity. In addition to efficient use of energy resources and provisioning of power, developing countries face an additional challenge of temporal mismatch in generation capacity and load factors. This leads to widespread deployment of inefficient and expensive Uninterruptible Power Supply (UPS) solutions for limited power provisioning during resulting blackouts. Our proposed “Soft-UPS” allows dynamic matching of load and generation through a combination of managed curtailment. This eliminates inefficiencies in the energy and power value chain and allows a data-driven approach to solving a widespread problem in developing countries, simultaneously reducing both upfront and running costs of conventional UPS and storage. A scalable and modular platform is proposed and implemented in this paper. The architecture employs “WiMODino” using LoRaWAN with a “Lite Gateway” and SQLite repository for data storage. Role based access to the system through an android application has also been demonstrated for monitoring and control.
Following their success in visual recognition tasks, Vision Transformers(ViTs) are being increasingly employed for image restoration. As a few recent works claim that ViTs for image classification also have better robustness properties, we investigate whether the improved adversarial robustness of ViTs extends to image restoration. We consider the recently proposed Restormer model, as well as NAFNet and the "Baseline network" which are both simplified versions of a Restormer. We use Projected Gradient Descent (PGD) and CosPGD for our robustness evaluation. Our experiments are performed on real-world images from the GoPro dataset for image deblurring. Our analysis indicates that contrary to as advocated by ViTs in image classification works, these models are highly susceptible to adversarial attacks. We attempt to find an easy fix and improve their robustness through adversarial training. While this yields a significant increase in robustness for Restormer, results on other networks are less promising. Interestingly, we find that the design choices in NAFNet and Baselines, which were based on iid performance, and not on robust generalization, seem to be at odds with the model robustness.
State-of-the-art models for pixel-wise prediction tasks such as image restoration, image segmentation, or disparity estimation, involve several stages of data resampling, in which the resolution of feature maps is first reduced to aggregate information and then sequentially increased to generate a high-resolution output. Several previous works have investigated the effect of artifacts that are invoked during downsampling and diverse cures have been proposed that facilitate to improve prediction stability and even robustness for image classification. However, equally relevant, artifacts that arise during upsampling have been less discussed. This is significantly relevant as upsampling and downsampling approaches face fundamentally different challenges. While during downsampling, aliases and artifacts can be reduced by blurring feature maps, the emergence of fine details is crucial during upsampling. Blurring is therefore not an option and dedicated operations need to be considered. In this work, we are the first to explore the relevance of context during upsampling by employing convolutional upsampling operations with increasing kernel size while keeping the encoder unchanged. We find that increased kernel sizes can in general improve the prediction stability in tasks such as image restoration or image segmentation, while a block that allows for a combination of small-size kernels for fine details and large-size kernels for artifact removal and increased context yields the best results.
With the surge in global data consumption with proliferation of Internet of Things (IoT), remote monitoring and control is increasingly becoming popular with a wide range of applications from emergency response in remote regions to monitoring of environmental parameters. Mesh networks are being employed to alleviate a number of issues associated with single-hop communication such as low area coverage, reliability, range and high energy consumption. Low-power Wireless Personal Area Networks (LoWPANs) are being used to help realize and permeate the applicability of IoT. In this paper, we present the design and test of IEEE 802.15.4-compliant smart IoT nodes with multi-hop routing. We first discuss the features of the software stack and design choices in hardware that resulted in high RF output power and then present field test results of different baseline network topologies in both rural and urban settings to demonstrate the deployability and scalability of our solution.
Modeling of Random Variations in a Switched Capacitor Circuit based Physically Unclonable Function
(2020)
The Internet of Things (IoT) is expanding to a wide range of fields such as home automation, agriculture, environmental monitoring, industrial applications, and many more. Securing tens of billions of interconnected devices in the near future will be one of the biggest challenges. IoT devices are often constrained in terms of computational performance, area, and power, which demand lightweight security solutions. In this context, hardware-intrinsic security, particularly physically unclonable functions (PUFs), can provide lightweight identification and authentication for such devices. In this paper, random capacitor variations in a switched capacitor PUF circuit are used as a source of entropy to generate unique security keys. Furthermore, a mathematical model based on the ordinary least square method is developed to describe the relationship between random variations in capacitors and the resulting output voltages. The model is used to filter out systematic variations in circuit components to improve the quality of the extracted secrets.
BACKGROUND
Various neutral and alkaline peptidases are commercially available for use in protein hydrolysis under neutral to alkaline conditions. However, the hydrolysis of proteins under acidic conditions by applying fungal aspartic peptidases (FAPs) has not been investigated in depth so far. The aim of this study, thus, was to purify a FAP from the commercial enzyme preparation, ROHALASE® BXL, determine its biochemical characteristics, and investigate its application for the hydrolysis of food and animal feed proteins under acidic conditions.
RESULTS
A Trichoderma reesei derived FAP, with an apparent molecular mass of 45.8 kDa (sodium dodecyl sulfate–polyacrylamide gel electrophoresis; SDS-PAGE) was purified 13.8-fold with a yield of 37% from ROHALASE® BXL. The FAP was identified as an aspartate protease (UniProt ID: G0R8T0) by inhibition and nano-LC-ESI-MS/MS studies. The FAP showed the highest activity at 50°C and pH 4.0. Monovalent cations, organic solvents, and reducing agents were tolerated well by the FAP. The FAP underwent an apparent competitive product inhibition by soy protein hydrolysate and whey protein hydrolysate with apparent Ki-values of 1.75 and 30.2 mg*mL−1, respectively. The FAP showed promising results in food (soy protein isolate and whey protein isolate) and animal feed protein hydrolyses. For the latter, an increase in the soluble protein content of 109% was noted after 30 min.
CONCLUSION
Our results demonstrate the applicability of fungal aspartic endopeptidases in the food and animal feed industry. Efficient protein hydrolysis of industrially relevant substrates such as acidic whey or animal feed proteins could be conducted by applying fungal aspartic peptidases. © 2022 Society of Chemical Industry.
A novel peptidyl-lys metalloendopeptidase (Tc-LysN) from Tramates coccinea was recombinantly expressed in Komagataella phaffii using the native pro-protein sequence. The peptidase was secreted into the culture broth as zymogen (~38 kDa) and mature enzyme (~19.8 kDa) simultaneously. The mature Tc-LysN was purified to homogeneity with a single step anion-exchange chromatography at pH 7.2. N-terminal sequencing using TMTpro Zero and mass spectrometry of the mature Tc-LysN indicated that the pro-peptide was cleaved between the amino acid positions 184 and 185 at the Kex2 cleavage site present in the native pro-protein sequence. The pH optimum of Tc-LysN was determined to be 5.0 while it maintained ≥60% activity between pH values 4.5—7.5 and ≥30% activity between pH values 8.5—10.0, indicating its broad applicability. The temperature maximum of Tc-LysN was determined to be 60 °C. After 18 h of incubation at 80 °C, Tc-LysN still retained ~20% activity. Organic solvents such as methanol and acetonitrile, at concentrations as high as 40% (v/v), were found to enhance Tc-LysN’s activity up to ~100% and ~50%, respectively. Tc-LysN’s thermostability, ability to withstand up to 8 M urea, tolerance to high concentrations of organic solvents, and an acidic pH optimum make it a viable candidate to be employed in proteomics workflows in which alkaline conditions might pose a challenge. The nano-LC-MS/MS analysis revealed bovine serum albumin (BSA)’s sequence coverage of 84% using Tc-LysN which was comparable to the sequence coverage of 90% by trypsin peptides.
A systematic toxicological analysis procedure using high-performance thin layer chromatography in combination with fibre optical scanning densitometry for identification of drugs in biological samples is presented. Two examples illustrate the practicability of the technique. First, the identification of a multiple intake of analgesics: codeine, propyphenazone, tramadol, flupirtine and lidocaine, and second, the detection of the sedative diphenhydramine. In both cases, authentic urine specimens were used. The identifications were carried out by an automatic measurement and computer-based comparison of in situ UV spectra with data from a compiled library of reference spectra using the cross-correlation function. The technique allowed a parallel recording of chromatograms and in situ UV spectra in the range of 197–612 nm. Unlike the conventional densitometry, a dependency of UV spectra by concentration of substance in a range of 250–1000 ng/spot was not observed.
This paper describes the Sweaty II humanoid adult size robot trying to qualify for the RoboCup 2018 adult size humanoid competition. Sweaty came 2nd in RoboCup 2017 adult size league. The main characteristics of Sweaty are described in the Team Description Paper 2017. The improvements that have been made or are planned to be implemented for RoboCup 2018 are described in this paper.
Soccer simulation league is one of the founding leagues of RoboCup. In this paper we discuss the past, present and planned future achievements and changes. Also we summarize the connections and inter-league achievements of this league and provide an overview of the community contributions that made this league successful.
Blockchain-IIoT integration into industrial processes promises greater security, transparency, and traceability. However, this advancement faces significant storage and scalability issues with existing blockchain technologies. Each peer in the blockchain network maintains a full copy of the ledger which is updated through consensus. This full replication approach places a burden on the storage space of the peers and would quickly outstrip the storage capacity of resource-constrained IIoT devices. Various solutions utilizing compression, summarization or different storage schemes have been proposed in literature. The use of cloud resources for blockchain storage has been extensively studied in recent years. Nonetheless, block selection remains a substantial challenge associated with cloud resources and blockchain integration. This paper proposes a deep reinforcement learning (DRL) approach as an alternative to solving the block selection problem, which involves identifying the blocks to be transferred to the cloud. We propose a DRL approach to solve our problem by converting the multi-objective optimization of block selection into a Markov decision process (MDP). We design a simulated blockchain environment for training and testing our proposed DRL approach. We utilize two DRL algorithms, Advantage Actor-Critic (A2C), and Proximal Policy Optimization (PPO) to solve the block selection problem and analyze their performance gains. PPO and A2C achieve 47.8% and 42.9% storage reduction on the blockchain peer compared to the full replication approach of conventional blockchain systems. The slowest DRL algorithm, A2C, achieves a run-time 7.2 times shorter than the benchmark evolutionary algorithms used in earlier works, which validates the gains introduced by the DRL algorithms. The simulation results further show that our DRL algorithms provide an adaptive and dynamic solution to the time-sensitive blockchain-IIoT environment.
An Overview of Technologies for Improving Storage Efficiency in Blockchain-Based IIoT Applications
(2022)
Since the inception of blockchain-based cryptocurrencies, researchers have been fascinated with the idea of integrating blockchain technology into other fields, such as health and manufacturing. Despite the benefits of blockchain, which include immutability, transparency, and traceability, certain issues that limit its integration with IIoT still linger. One of these prominent problems is the storage inefficiency of the blockchain. Due to the append-only nature of the blockchain, the growth of the blockchain ledger inevitably leads to high storage requirements for blockchain peers. This poses a challenge for its integration with the IIoT, where high volumes of data are generated at a relatively faster rate than in applications such as financial systems. Therefore, there is a need for blockchain architectures that deal effectively with the rapid growth of the blockchain ledger. This paper discusses the problem of storage inefficiency in existing blockchain systems, how this affects their scalability, and the challenges that this poses to their integration with IIoT. This paper explores existing solutions for improving the storage efficiency of blockchain–IIoT systems, classifying these proposed solutions according to their approaches and providing insight into their effectiveness through a detailed comparative analysis and examination of their long-term sustainability. Potential directions for future research on the enhancement of storage efficiency in blockchain–IIoT systems are also discussed.
Linux and Linux-based operating systems have been gaining more popularity among the general users and among developers. Many big enterprises and large companies are using Linux for servers that host their websites, some even require their developers to have knowledge about Linux OS. Even in embedded systems one can find many Linux-based OS that run them. With its increasing popularity, one can deduce the need to secure such a system that many personnel rely on, be it to protect the data that it stores or to protect the integrity of the system itself, or even to protect the availability of the services it offers. Many researchers and Linux enthusiasts have been coming up with various ways to secure Linux OS, however new vulnerabilities and new bugs are always found, by malicious attackers, with every update or change, which calls for the need of more ways to secure these systems.
This Thesis explores the possibility and feasibility of another way to secure Linux OS, specifically securing the terminal of such OS, by altering the commands of the terminal, getting in the way of attackers that have gained terminal access and delaying, giving more time for the response teams and for forensics to stop the attack, minimize the damage, restore operations, and to identify collect and store evidence of the cyber-attack. This research will discuss the advantages and disadvantages of various security measures and compare and contrast with the method suggested in this research.
This research is significant because it paints a better picture of what the state of the art of Linux and Linux-based operating systems security looks like, and it addresses the concerns of security enthusiasts, while exploring new uncharted area of security that have been looked at as a not so significant part of protecting the OSes out of concern of the various limitations and problems it entails. This research will address these concerns while exploring few ways to solve them, as well as addressing the ideal areas and situations in which the proposed method can be used, and when would such method be more of a burden than help if used.
Soiling is an important issue in the renewable energy sector since it can result in significant yield losses, especially in regions with higher pollution or dust levels. To mitigate the impact of soiling on photovoltaic (PV) plants, it is essential to regularly monitor and clean the panels, as well as develop accurate soiling predictions that can affect cleaning strategies and enhance the overall performance of PV power plants. This research focuses on the problem of soiling loss in photovoltaic power plants and the potential to improve the accuracy of soiling predictions. The study examines how soiling can affect the efficiency and productivity of the modules and how to measure and predict soiling using machine learning (ML) algorithms. The research includes analyzing real data from large-scale ground-mounted PV sites and comparing different soiling measurement methods. It was observed that there were some deviations in the real soiling loss values compared to the expected values for some projects in southern Spain, thus, the main goal of this work is to develop machine learning models that could predict the soiling more accurately. The developed models have a low mean square error (MSE), indicating the accuracy and suitability of the models to predict the soiling rates. The study also investigates the impact of different cleaning strategies on the performance of PV power plants and provides a powerful application to predict both the soiling and the number of cleaning cycles.