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The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
Die fluktuierende Verfügbarkeit regenerativer Energiequellen stellt eine Herausforderung bei der Planung und Auslegung regenerativer Gebäudeenergiesysteme dar. Die in einem System benötigten Speicherkapazitäten hängen dabei sowohl von der eingesetzten Regelungsstrategie als auch von den temperaturabhängigen Wirkungsgraden der Anlagenkomponenten ab. Genauere Einblicke in das Betriebsverhalten eines Gesamtsystems können dynamische Simulationen liefern, die eine Analyse der Systemtemperaturen und von Teilenergiekennwerten ermöglichen.