INES - Institut für nachhaltige Energiesysteme
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Das Projekt PHOTOPUR soll die Reduzierung von Pestiziden in Oberflächengewässern ermöglichen. In dieser Arbeit wird eine Automatisierung eines ersten Demosystems entwickelt, welches den gesamten Reinigungsprozess abbildet. Eine Projektierung der Automatisierung des Systems wird mit den dafür vorgesehenen Fließschemas und Gerätelisten durchgeführt. Darauf aufbauend wird die Ablaufsteuerung des Demosystems durch einen Ablauf-Funktionsplan umgesetzt. Um eine Systemüberwachung der Anlage zu gewährleisten wurde dazu eine Visualisierung ausgearbeitet. Zusätzlich wurden die Regelstrecken der Durchflussregelungen in den zwei Teilprozessen des Reinigungsprozesses bestimmt und durch unterschiedliche Einstellregeln der optimale Regler der Regelkreise ermittelt.
Die in dieser Arbeit entwickelte Software, beinhaltet die drei folgenden Umsetzungen: Realisierung der Ablaufsteuerung, Implementierung der Reglerparameter durch einen vorhandenen Regelalgorithmus und die Visualisierung des Demosystems.
Cell lifetime diagnostics and system be-havior of stationary LFP/graphite lithium-ion batteries
(2018)
Modelling detailed chemistry in lithium-ion batteries: Insight into performance, ageing and safety
(2018)
Lithium-ion pouch cells with lithium titanate (Li4Ti5O12, LTO) anode and lithium nickel cobalt aluminum oxide (LiNi0.8Co0.15Al0.05O2, NCA) cathode were investigated experimentally with respect to their electrical (0.1C…4C), thermal (5 °C…50 °C) and long-time cycling behavior. The 16 Ah cell exhibits an asymmetric charge/discharge behavior which leads to a strong capacity-rate effect, as well as a significantly temperature-dependent capacity (0.37 Ah ∙ K−1) which expresses as additional high-temperature feature in the differential voltage plot. The cell was cycled for 10,000 cycles inbetween the nominal voltage limits (1.7–2.7 V) with a symmetric 4C constant-current charge/discharge protocol, corresponding to approx. 3400 equivalent full cycles. A small (0.192 mΩ/1000 cycles) but continuous increase of internal resistance was observed. Using electrochemical impedance spectroscopy (EIS), this could be identified to be caused by the NCA cathode, while the LTO anode showed only minor changes during cycling. The temperature-corrected capacity during 4C cycling exhibited a decrease of 1.28%/1000 cycles. The 1C discharge capacity faded by only 4.0% for CC discharge and 2.3% for CCCV discharge after 10,000 cycles. The cell thus exhibits very good internal-resistance stability and excellent capacity retention even under harsh (4C continuous) cycling, demonstrating the excellent stability of LTO as anode material.
One of the bottlenecks hindering the usage of polymer electrolyte membrane fuel cell technology in automotive applications is the highly load-sensitive degradation of the cell components. The cell failure cases reported in the literature show localized cell component degradation, mainly caused by flow-field dependent non-uniform distribution of reactants. The existing methodologies for diagnostics of localized cell failure are either invasive or require sophisticated and expensive apparatus. In this study, with the help of a multiscale simulation framework, a single polymer electrolyte membrane fuel cell (PEMFC) model is exposed to a standardized drive cycle provided by a system model of a fuel cell car. A 2D multiphysics model of the PEMFC is used to investigate catalyst degradation due to spatio-temporal variations in the fuel cell state variables under the highly transient load cycles. A three-step (extraction, oxidation, and dissolution) model of platinum loss in the cathode catalyst layer is used to investigate the cell performance degradation due to the consequent reduction in the electro-chemical active surface area (ECSA). By using a time-upscaling methodology, we present a comparative prediction of cell end-of-life (EOL) under different driving behavior of New European Driving Cycle (NEDC) and Worldwide Harmonized Light Vehicles Test Cycle (WLTC).