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- „Eiserne Hand“, Götz von Berlichingen (1)
Institute
- Fakultät Medien und Informationswesen (M+I) (bis 21.04.2021) (564)
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Open Access
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Die Internationalisierung ist mittlerweile ein zentraler Aspekt der gegenwärtigen ökonomischen Debatte. Inzwischen sind nämlich immer mehr Unternehmungen von der internationalen Verschmelzung der Märkte und Branchen betroffen. Haben lange Zeit überwiegend Großunternehmen und Konzerne über die nationalen Grenzen hinweg agiert, stellt sich zunehmend auch der Mittelstand der Herausforderung der Internationalisierung. Schließlich bieten sich international tätigen Firmen durch die Erschließung neuer Märkte unter anderem eine Reihe von attraktiven Wachstumschancen.
Das Internet hat nicht nur neue Geschäftsmodelle in großer Zahl hervorgebracht, es ist auch bei der Erfindung neuer Werbeformen sehr kreativ. Neben die „klassische“ Bannerwerbung und die inzwischen auch schon intensiv weiter entwickelten Partnerprogramme (Affiliate-Marketing) treten in zunehmender Weise auch und gerade „getarnte“ Werbeformen, die mit Bezeichnungenwie „Stealth-Marketing“ schon vom Namen her für Furore sorgen sollen. Der Beitrag stellt einige dieser Werbeformen vor und beurteilt sie aus rechtlicher Sicht. Dabei erweisen sich diese Marketing-Varianten mitunter als nicht so neu wie ihre Anbieter behaupten.
The development of secure software systems is of ever-increasing importance. While software companies often invest large amounts of resources into the upkeeping and general security properties of large-scale applications when in production, they appear to neglect utilizing threat modeling in the earlier stages of the software development lifecycle. When applied during the design phase of development, and continuously throughout development iterations, threat modeling can help to establish a "Secure by Design" approach. This approach allows issues relating to IT security to be found early during development, reducing the need for later improvement – and thus saving resources in the long term. In this paper the current state of threat modeling is investigated. This investigation drove the derivation of requirements for the development of a new threat modelling framework and tool, called OVVL. OVVL utilizes concepts of established threat modeling methodologies, as well as functionality not available in existing solutions.
In the course of the last few years, our students are becoming increasingly unhappy. Sometimes they stop attending lectures and even seem not to know how to behave correctly. It feels like they are getting on strike. Consequently, drop-out rates are sky-rocketing. The lecturers/professors are not happy either, adopting an “I-don’t-care” attitude.
An interdisciplinary, international team set in to find out: (1) What are the students unhappy about? Why is it becoming so difficult for them to cope? (2) What does the “I-don’t-care” attitude of professors actually mean? What do they care or not care about? (3) How far do the views of the parties correlate? Could some kind of mutual understanding be achieved?
The findings indicate that, at least at our universities, there is rather a long way to go from “Engineering versus Pedagogy” to “Engineering Pedagogy”.
IPv6 over resource-constrained devices (6Lo) emerged as a de-facto standard for the Internet of Things (IoT) applications especially in home and building automation systems. We provide results of an investigation of the applicability of 6LoWPAN with RPL mesh networks for home and building automation use cases. The proper selection of Trickle parameters and neighbor reachable time-outs is important in the RPL protocol suite to respond efficiently to any path failure. These parameters were analyzed in the context of energy consumption w.r.t the number of control packets. The measurements were performed in an Automated Physical Testbeds (APTB). The results match the recommendation by RFC 7733 for selecting various parameters of RPL protocol suite. This paper shows the relationship between various RPL parameters and control traffic overhead during network rebuild. Comparative measurement results with Bluetooth Low Energy (BLE) in this work showed that 6Lo with RPL outperformed BLE in this use case with less control traffic overheads.
Im Jahr 1504 verlor der deutsche Ritter Gottfried („Götz“) von Berlichingen seine
rechte Hand. Schon während seiner Genesung dachte er daran, die Hand zu ersetzen,
und beauftragte bald darauf die erste Handprothese, die sogenannte „Eiserne Hand“.
Jahre später wurde die aufwändigere zweite „Eiserne Hand“ gebaut. Wir haben die erste
Prothese auf der Basis früherer Literaturdaten von
Quasigroch (1982) mit Hilfe von 3-D
Computer-Aided Design (CAD) rekonstruiert. Dazu mussten einige Abmessungen angepasst
und ein paar Annahmen für das CAD-Modell gemacht werden. Die historische passive
Prothese des Götz von Berlichingen ist für die moderne Neuroprothetik interessant, da sie
eine Alternative zu komplexen invasiven Brain-Machine-Interface-Konzepten darstellen
könnte, wo diese Konzepte nicht notwendig, möglich oder vom Patienten gewünscht sind.
In this study, we tested the function of a replica of the over 500-year-old original of the
famous Franconian Imperial Knight Götz von Berlichingen’s first “iron hand”, which we
reconstructed by computer-aided design (CAD) and recently printed using a multi-material
3D printer. In different everyday tasks, the artificial hand prosthesis proved to be remarkably
helpful. Thus, the hand could hold a wine glass, some grapes, or a smartphone. With a
suitable pencil, even writing was possible without any problem. Although for all these
functions the healthy other hand was necessary to assist at the beginning, the artificial hand
is an astonishing mechanical aid with many possibilities. Therefore, in certain cases, the
non-invasive approach of a passive mechanical hand replacement, which is an individual,
quick and cheap solution due to modern 3D printing, may always be worth considering
also for today’s requirements.
Auf Grundlage der Computer-Aided-Design (CAD)-rekonstruierten ersten „Eisernen Hand“ des Götz von Berlichingen wird ein umgebautes, controllergesteuertes sensomotorisches Fingersystem auf seine Funktionalität beim Greifen von unterschiedlichen Gegenständen beschrieben und geprüft. Die elektronischen Finger, die den „Pinzettengriff“ nachahmen und automatisch bei dem zuvor eingestellten Anpressdruck abschalten, bewiesen eine bemerkenswerte Alltagstauglichkeit. Das vorgestellte Grundkonzept könnte eine Alternative bei der Entwicklung einfacher und kostengünstiger, aber dennoch gut einsatzfähiger bionischer Hände sein und zeigt einmal mehr, wie historische Ideen in die Gegenwart transferiert werden können.
Technologie spielt im Sport schon immer eine große Rolle. Mit steigender Leistungsdichte im Spitzensport wird versucht mithilfe technischer Hilfsmittel dem Sportler die optimalen Umstände zu ermöglichen. Dazu gehört nicht nur Technik im Sportequiptment, sondern auch Sportuntersuchungen wie Leistungsdiagnostiken. Im Laufsport zählen dazu Ausdauer- und Krafttests. Bei Ausdauertests werden physiologische Parameter wie Laktat, Herzfrequenz oder Sauerstoffaufnahme gemessen. Zusätzlich wird die Lauftechnik für einen kurzen Zeitpunkt analysiert. Wie sich diese unter anhaltender Belastung verhält, wird nicht untersucht. Mit neuen Technologien im Bereich Bewegungsanalyse, können immer schneller größere Datensätze ausgewertet werden. Aus diesem Grund wird in dieser Studie die Lauftechnik über mehrere Zeitpunkte aufgezeichnet und nach Ermüdungserscheinungen untersucht.
Dazu wurde am Institut für angewandte Trainingswissenschaften (IAT) während einer komplexen Leistungsdiagnostik im März 2021 bei einem Laufbandstufentest (4x2000m oder 4x3000m) die Lauftechnik von 15 Elite- und Elitenachwuchsläufer:innen (m=8, w=7) mithilfe eines 3D-Bewegungsanalyse Systems nach Veränderungen in Winkelstellung und Bodenreaktionskraft untersucht. Als physiologische Vergleichsparameter wurde Herzfrequenz und Laktat aufgenommen.
Bei der Analyse der Daten wurden diese in der Gruppe betrachtet. Dabei haben sich schwach signifikante Veränderungen (p=0,047) der vertikalen Bodenreaktionskraft links am Ende der Stufe aufgezeigt. Weitere signifikante Unterschiede (p=0,020) sind im maximalen Kniehub links zu einem größerer Hüftwinkel am Ende sichtbar. Da sonst keine signifikanten Unterschiede zu sehen sind, lässt sich, bei dem hier durchgeführten Protokoll, nicht statistisch gesichert feststellen, ob auftretende Ermüdungserscheinungen die Lauftechnik beeinflussen und verändern. Um festzustellen, ob es geschlechts- oder protokollanhängige Effekte hinsichtlich einer ermüdungsbedingte Lauftechnikveränderung gibt, wurde auch dies statistisch untersucht.
Hier zeigten sich jeweils in einzelnen Parametern signifikante Unterschiede (Parameter TO\_knee\_left; p=0,026) in der Geschlechtsspezifik und in der protokollabhängigen Untersuchung (Parameter TSw\_hip\_left; p=0,04)
Für weitere Studien zur Untersuchung von Lauftechnikveränderung sollten umfangreichere physiologische Daten zur genaueren Betrachtung der Ermüdung verwendet werden. Grundsätzlich müsste das Protokoll auf eine maximale Ausbelastung (beispielsweise Dauerstufentest von 10-15km oder Ausbelastungs-/Abbruchtest) ausgelegt sein.
Grundlegend ist festzustellen, dass sich Simi-Shape als 3D-Bewegungsanalyse-Methode eignet, um spezifische Parameter in der Lauftechnik zu diagnostizieren, gerade hinsichtlich der Effizienz im Auswerteprozess.
3D-Druck für Privatanwender
(2014)
„It’s basically like a hot-glue gun that uses the same kind of plastic used to make Legos“
So beschreibt Bre Pettis, CEO von Makerbot Industries, das 3D-Druckverfahren welches bei den meisten 3D Druckern für den privaten Gebrauch verwendet wird. Was ist der 3D-Druck eigentlich? Wo kann er eingesetzt werden? Wird irgendwann ein 3D-Drucker in jedem Haushalt zu finden sein? Um Antworten auf diese Fragen zu finden, habe ich im Rahmen meiner Bachelorarbeit einen 3D-Drucker zusammengebaut und versucht mehr über diese spannende Zukunftstechnologie zu erfahren.
Dieser Beitrag stellt die Möglichkeiten des 3D-Druckes unter der Berücksichtigung von Mensch-Roboter-Kollaborations-Anforderungen dar. Dabei werden die Vorteile mit besonderem Fokus auf die zusätzliche Gestaltungsfreiheit erläutert. Anhand von Beispielen wird der Stand der Technik bereits eingesetzter Sensorik sowie deren Notwendigkeit in Greifsystemen erläutert. Im weiteren Verlauf dieses Beitrags werden allgemeine Verfahren für die additive Verarbeitung von leitfähigen Materialien vorgestellt. Daran angeknüpft sind Beispiele speziell zur 3D-gedruckten Sensorik. Abgerundet wird der Beitrag mit einem Ausblick bezüglich 3D-gedruckter Sensorik in MRK-Greifsystemen.
Die Arbeit behandelt das Thema 3D-Gestensteuerungen als MIDI-Controller in Audioanwendungen. Es wird anhand der momentan verfügbaren 3D-Gesten-Steuerungstechnik erforscht, welche Einsatzmöglichkeiten im Bereich der Audiotechnik beziehungsweise im Sounddesign gegeben sind. Die Erforschung der technischen Grundlagen aus Software und Hardware-Modulen als auch die Performance-Bewertungen bilden die technischen Grundlagen ab, während anschliessend ausgewählte Audioanwendungen beschrieben werden, welche in einer Befragung auf ihre Nutzbarkeit überprüft werden. Es wird beschrieben wie man mit einer 3D-Gestensteuerung, wie dem Kinect-Sensor, Musik oder Sounds produzieren kann, und wie man diese Technik sinnvoll einsetzten kann.
Die vorliegende Bachelorthesis befasst sich mit der Reproduktion der ersten „eisernen Hand“ des Götz von Berlichingen. Die Aufgabenstellung ist es, einen Öffnungsmechanismus zu entwickeln, welcher die zwei Fingerblöcke in die geöffnete Grundstreckstellung zurückführt, wenn die Finger zur Handinnenfläche eingefahren sind. Außerdem sollen die Fingerblöcke in drei verschiedenen Positionen einrasten können, wenn sie nach innen gedrückt werden. Insgesamt soll die Mechanik der Fingerblöcke durch 3D-unterstützte Optimierung von Bauteilen verbessert und unterstützt werden.
Der neukonstruierte Öffnungsmechanismus beinhaltet eine Drehfeder pro Fingerblock. Zudem begünstigt die CAD-Optimierung des Daumensystems und des Fingersystems die Mechanik der Fingerblöcke.
The Internet of Things (IoT) application has becoming progressively in-demand, most notably for the embedded devices (ED). However, each device has its own difference in computational capabilities, memory usage, and energy resources in connecting to the Internet by using Wireless Sensor Networks (WSNs). In order for this to be achievable, the WSNs that form the bulk of the IoT implementation requires a new set of technologies and protocol that would have a defined area, in which it addresses. Thus, IPv6 Low Power Area Network (6LoWPAN) was designed by the Internet Engineering Task Force (IETF) as a standard network for ED. Nevertheless, the communication between ED and 6LoWPAN requires appropriate routing protocols for it to achieve the efficient Quality of Service (QoS). Among the protocols of 6LoWPAN network, RPL is considered to be the best protocol, however its Energy Consumption (EC) and Routing Overhead (RO) is considerably high when it is implemented in a large network. Therefore, this paper would propose the HRPL to enchance the RPL protocol in reducing the EC and RO. In this study, the researchers would present the performance of RPL and HRPL in terms of EC, Control traffic Overhead (CTO) and latency based on the simulation of the 6LoWPAN network in fixed environment using COOJA simulator. The results show HRPL protocol achieves better performance in all the tested topology in terms of EC and CTO. However, the latency of HRPL only improves in chain topology compared with RPL. We found that further research is required to study the relationship between the latency and the load of packet transmission in order to optimize the EC usage.
A simple measuring method for acquiring the radiation pattern of an ultrawide band Vivaldi antenna is presented. The measuring is performed by combining two identical Vivaldi antennas and some of the intrinsic properties of a stepped-frequency continue wave radar (SFCW radar) in the
range from 1.0 GHz to 6.0 GHz. A stepper-motor provided the azimuthal rotation for one of the antennas from 0 ◦ to 360 ◦. The tests have been performed within the conventional environment (laboratory / office) without using an anechoic chamber or absorbing materials. Special measuring devices have not been used either. This method has been tested with different pairs of Vivaldi antennas and it can be also used for different ones (with little or no change in the system), as long as their operational
bandwidth is within the frequency range of the SFCW radar.
Keywords — SFCW Radar, Antenna Gain Characterization,
Azimuthal Radiation Pattern
The demand of wireless solutions in industrial applications increases since the early nineties. This trend is not only ongoing, it is further pushed by developments in the area of software stacks like the latest Bluetooth Low Energy Stack. It is also pushed by new chip-designs and powerful and highly integrated electronic hardware. The acceptance of wireless technologies as a possible solution for industrial applications, has overcome the entry barrier [1]. The first step to see wireless as standard for many industrial applications is almost accomplished. Nevertheless there is nearly none acceptance of wireless technology for Safety applications. One highly challenging and demanding requirement is still unsolved: The aspect safety and robustness. Those topics have been addressed in many cases but always in a similar manner. WirelessHART as an example addresses this topic with redundant so called multiple propagation paths and frequency hopping to handle with interferences and loss of network participants. So far the pure peer to peer link is rarely investigated and there are less safety solutions available. One product called LoRa™ can be seen as one possible solution to address this lack of safety within wireless links. This paper focuses on the safety performance evaluation of a modem-chip-design. The use of diverse and redundant wireless technologies like LoRa can lead to an increase acceptance of wireless in safety applications. Many measurements in real industrial application have been carried out to be able to benchmark the new chip in terms of the safety aspects. The content of this research results can help to raise the level of confidence in wireless. In this paper, the term “safety” is used for data transmission reliability.
Threat Modeling is a vital approach to implementing ”Security by Design” because it enables the discovery of vulnerabilities and mitigation of threats during the early stage of the Software Development Life Cycle as opposed to later on when they will be more expensive to fix. This thesis makes a review of the current threat Modeling approaches, methods, and tools. It then creates a meta-model adaptation of a fictitious cloud-based shop application which is tested using STRIDE and PASTA to check for vulnerabilities, weaknesses, and impact risk. The Analysis is done using Microsoft Threat Modeling Tool and IriusRisk. Finally, an evaluation of the results is made to ascertain the effectiveness of the processes involved with highlights of the challenges in threat modeling and recommendations on how security developers can make improvements.
Due to a controversial enrollment policy in most engineering programs at German Universities of Applied Sciences (UAS), many freshmen show very low school grades in key subjects like Math and Physics. Nevertheless they expect to be entertained in the lectures and get demotivated easily. Despite initial reservations, a cheer-and-challenge approach was developed for teaching Mechanics to freshmen having very diverse school grades. When tested, it showed astonishing results.
Radio frequency identification (RFID) antennas are popular for high frequency (HF) RFID, energy transfer and near field communication (NFC) applications. Particularly for wireless measurement systems the RFID/NFC technology is a good option to implement a wireless communication interface. In this context, the design of corresponding reader and transmitter antennas plays a major role for achieving suitable transmission quality. This work proves the feasibility of the rapid prototyping of a RFID/NFC antenna, which is used for the wireless communication and energy harvesting at the required frequency of 13.56 MHz. A novel and low-cost direct ink writing (DIW) technology utilizing highly viscous silver nanoparticle ink is used for this process. This paper describes the development and analysis of low-cost printed flexible RFID/NFC antennas on cost-effective substrates for a microelectronic vital parameter measurement system. Furthermore, we compare the measured technical parameters with existing copper-based counterparts on a FR4 substrate.
The Raman spectra from the chemical compounds toluene and cyclohexane obtained using a Fourier Transform (FT)-Raman spectrometer prototype have been contrasted with the Raman spectra of these same materials collected with two different commercial FT-Raman devices. The FT-Raman spectrometer consist of a Michelson interferometer, a self-designed photon counter and a reference photo-detector. The evaluation methodology of the spectral information, contrary to the commercial devices that commonly use the zero-crossing method, is carried out by re-sampling the Raman scattering and by accurately extracting the optical path information of the Michelson interferometer. The FTRaman arrangement has been built using conventional parts without disregarding the spectral frequency precision that usually such a FTRaman instruments deliver. No additional complex hardware components or costly software modules have been included in this FT-Raman device. The main Raman lines from the spectra obtained with the three FT-Raman devices have been compared with the Raman lines from the standard Raman spectra of these two materials. The values obtained using the FT-Raman spectrometer prototype have shown a frequency accuracy comparable to that obtained with the commercial devices without facing the need for a large investment. Although the proposed FT-Raman prototype cannot be directly compared to the last generation of FT-Raman spectrometers from the commercial manufacturers, such a device could give an opportunity to users that require high frequency precision in their spectral analysis and are provided with rather scarce resources.
The Internet of Things is spreading significantly in every sector, including the household, a variety of industries, healthcare, and emergency services, with the goal of assisting all of those infrastructures by providing intelligent means of service delivery. An Internet of Vulnerabilities (IoV) has emerged as a result of the pervasiveness of the Internet of Things (IoT), which has led to a rise in the use of applications and devices connected to the IoT in our day-to-day lives. The manufacture of IoT devices are growing at a rapid pace, but security and privacy concerns are not being taken into consideration. These intelligent Internet of Things devices are especially vulnerable to a variety of attacks, both on the hardware and software levels, which leaves them exposed to the possibility of use cases. This master’s thesis provides a comprehensive overview of the Internet of Things (IoT) with regard to security and privacy in the area of applications, security architecture frameworks, a taxonomy of various cyberattacks based on various architecture models, such as three-layer, four-layer, and five-layer. The fundamental purpose of this thesis is to provide recommendations for alternate mitigation strategies and corrective actions by using a holistic rather than a layer-by-layer approach. We discussed the most effective solutions to the problems of privacy and safety that are associated with the Internet of Things (IoT) and presented them in the form of research questions. In addition to that, we investigated a number of further possible directions for the development of this research.
The need for the logistics sector to timely respond to the increasing requirements of a globalised and digitalised world relies greatly on the com- petences and skills of its labour force. It becomes therefore essential to reinforce the cooperation between universities and business partners in the logistics and supply chain management fields across the European region and to build a logistics knowledge cluster supported by a communication and collaboration platform to foster continuous learning, skill acquisition and experience sharing anytime anywhere. In this paper we focus on designing the conceptual and technical framework for a communication and collaboration platform with the aim to establish the communication pipelines between the partner institutions, facilitating user interactions and exchange, leading to the creation of new knowledge and innovation in the logistics field. This framework is based on the requirements of the three main stakeholders: students, lecturers and companies, and consists of four functional areas defined according to the platform opera- tional requirements. A working prototype of the platform was developed using the Moodle learning management system and its core tools to determine its applicability and possible enhancement requirements. In the next stages of the project some additional tools like a knowledge base and the integration of the partners’ learning management systems to form the logistics knowledge cluster will be implemented.
The monitoring of industrial environments ensures that highly automated processes run without interruption. However, even if the industrial machines themselves are monitored, the communication lines are currently not continuously monitored in todays installations. They are checked usually only during maintenance intervals or in case of error. In addition, the cables or connected machines usually have to be removed from the system for the duration of the test. To overcome these drawbacks, we have developed and implemented a cost-efficient and continuous signal monitoring of Ethernet-based industrial bus systems. Several methods have been developed to assess the quality of the cable. These methods can be classified to either passive or active. Active methods are not suitable if interruption of the communication is undesired. Passive methods, on the other hand, require oversampling, which calls for expensive hardware. In this paper, a novel passive method combined with undersampling targeting cost-efficient hardware is proposed.
The Go programming language is an increasingly popular language but some of its features lack a formal investigation. This article explains Go's resolution mechanism for overloaded methods and its support for structural subtyping by means of translation from Featherweight Go to a simple target language. The translation employs a form of dictionary passing known from type classes in Haskell and preserves the dynamic behavior of Featherweight Go programs.
This thesis focuses on the development and implementation of a Datagram Transport Layer Security (DTLS) communication framework within the ns-3 network simulator, specifically targeting the LoRaWAN model network. The primary aim is to analyse the behaviour and performance of DTLS protocols across different network conditions within a LoRaWAN context. The key aspects of this work include the following.
Utilization of ns-3: This thesis leverages ns-3’s capabilities as a powerful discrete event network simulator. This platform enables the emulation of diverse network environments, characterized by varying levels of latency, packet loss, and bandwidth constraints.
Emulation of Network Challenges: The framework specifically addresses unique challenges posed by certain network configurations, such as duty cycle limitations. These constraints, which limit the time allocated for data transmission by each device, are crucial in understanding the real-world performance of DTLS protocols.
Testing in Multi-client-server Scenarios: A significant feature of this framework is its ability to test DTLS performance in complex scenarios involving multiple clients and servers. This is vital for assessing the behaviour of a protocol under realistic network conditions.
Realistic Environment Simulation: By simulating challenging network conditions, such as congestion, limited bandwidth, and resource constraints, the framework provides a realistic environment for thorough evaluation. This allows for a comprehensive analysis of DTLS in terms of security, performance, and scalability.
Overall, this thesis contributes to a deeper understanding of DTLS protocols by providing a robust tool for their evaluation under various and challenging network conditions.
The aim of this study was to develop a biomechanically validated finite element model to predict the biomechanical behaviour of the human lumbar spine in compression.
For validation of the finite element model, an in vitro study was performed: Twelve human lumbar cadaveric spinal segments (six segments L2/3 and six segments L4/5) were loaded in axial compression using 600 N in the intact state and following surgical treatment using two different internal stabilisation devices. Range of motion was measured and used to calculate stiffness.
A finite element model of a human spinal segment L3/4 was loaded with the same force in intact and surgically altered state, corresponding to the situation of biomechanical in vitro study.
The results of the cadaver biomechanical and finite element analysis were compared. As they were close together, the finite element model was used to predict: (1) load-sharing within human lumbar spine in compression, (2) load-sharing within osteoporotic human lumbar spine in compression and (3) the stabilising potential of the different spinal implants with respect to bone mineral density.
A finite element model as described here may be used to predict the biomechanical behaviour of the spine. Moreover, the influence of different spinal stabilisation systems may be predicted.
Multi-phase management is crucial for performance and durability of electrochemical cells such as batteries and fuel cells. In this paper we present a generic framework for describing the two-dimensional spatiotemporal evolution of gaseous, liquid and solid phases, as well as their interdependence with interfacial (electro-)chemistry and microstructure in a continuum description. The modeling domain consists of up to seven layers (current collectors, channels, electrodes, separator/membrane), each of which can consist of an arbitrary number of bulk phases (gas, liquid, solid) and connecting interfaces (two-phase or multi-phase boundaries). Bulk and interfacial chemistry is described using global or elementary kinetic reactions. Multi-phase management is coupled to chemistry and to mass and charge transport within bulk phases. The functionality and flexibility of this framework is demonstrated using four application areas in the context of post-lithium-ion batteries and fuel cells, that is, lithium-sulfur (Li-S) cells, lithium-oxygen (Li-O) cells, solid oxide fuel cells (SOFC) and polymer electrolyte membrane fuel cells (PEFC). The results are compared to models available in literature and properties of the generic framework are discussed.
6LoWPAN (IPv6 over Low Power Wireless Personal Area Networks) is gaining more and more attraction for the seamless connectivity of embedded devices for the Internet of Things. It can be observed that most of the available solutions are following an open source approach, which significantly leads to a fast development of technologies and of markets. Although the currently available implementations are in a pretty good shape, all of them come with some significant drawbacks. It was therefore decided to start the development of an own implementation, which takes the advantages from the existing solutions, but tries to avoid the drawbacks. This paper discussed the reasoning behind this decision, describes the implementation and its characteristics, as well as the testing results. The given implementation is available as open-source project under [15].
A Gamified and Adaptive Learning System for Neurodivergent Workers in Electronic Assembling Tasks
(2020)
Learning and work-oriented assistive systems are often designed to fit the workflow of neurotypical workers. Neurodivergent workers and individuals with learning disabilities often present cognitive and sensorimotor characteristics that are better accommodated with personalized learning and working processes. Therefore, we designed an adaptive learning system that combines an augmented interaction space with user-sensitive virtual assistance to support step-by-step guidance for neurodivergent workers in electronic assembling tasks. Gamified learning elements were also included in the interface to provide self-motivation and praise whenever users progress in their learning and work achievements.
A highly scalable IEEE802.11p communication and localization subsystem for autonomous urban driving
(2013)
The IEEE802.11p standard describes a protocol for car-to-X and mainly for car-to-car-communication. It has found its place in hardware and firmware implementations and is currently tested in various field tests. In the research project Ko-TAG, which is part of the research initiative Ko-FAS, cooperative sensor technology is developed for the support of highly autonomous driving. A secondary radar principle based on communication signals enables localization of objects with simultaneous data transmission. It mainly concentrates on the detection of pedestrians and other vulnerable road users (VRU), but also supports pre crash safety applications. Thus it is mainly targeted for the support of traffic safety applications in intra-urban scenarios. This contribution describes the Ko-TAG part of the overall initiative, which develops a subsystem to improve the real-time characteristics of IEEE802.11p needed for precise time of flight real-time localization. In doing this, it still fits into the regulatory schemes. It discusses the approach for definition and verification of the protocol design, while maintaining the close coexistence with existing IEEE802.11p subsystems. System simulations were performed and hardware was implemented. Test results are shown in the last part of the paper.
Uncontrollable manufacturing variations in electrical hardware circuits can be exploited as Physical Unclonable Functions (PUFs). Herein, we present a Printed Electronics (PE)-based PUF system architecture. Our proposed Differential Circuit PUF (DiffC-PUF) is a hybrid system, combining silicon-based and PE-based electronic circuits. The novel approach of the DiffC-PUF architecture is to provide a specially designed real hardware system architecture, that enables the automatic readout of interchangeable printed DiffC-PUF core circuits. The silicon-based addressing and evaluation circuit supplies and controls the printed PUF core and ensures seamless integration into silicon-based smart systems. Major objectives of our work are interconnected applications for the Internet of Things (IoT).
We propose secure multi-party computation techniques for the distributed computation of the average using a privacy-preserving extension of gossip algorithms. While recently there has been mainly research on the side of gossip algorithms (GA) for data aggregation itself, to the best of our knowledge, the aforementioned research line does not take into consideration the privacy of the entities involved. More concretely, it is our objective to not reveal a node's private input value to any other node in the network, while still computing the average in a fully-decentralized fashion. Not revealing in our setting means that an attacker gains only minor advantage when guessing a node's private input value. We precisely quantify an attacker's advantage when guessing - as a mean for the level of data privacy leakage of a node's contribution. Our results show that by perturbing the input values of each participating node with pseudo-random noise with appropriate statistical properties (i) only a minor and configurable leakage of private information is revealed, by at the same time (ii) providing a good average approximation at each node. Our approach can be applied to a decentralized prosumer market, in which participants act as energy consumers or producers or both, referred to as prosumers.
A Localization System Using Inertial Measurement Units from Wireless Commercial Handheld Devices
(2013)
This paper describes a newly developed technology for the calculation of trajectories of mobile objects, which is based on commercially available sensors being integrated into modern mobile phones and other gadgets. First, a step counting technique was implemented. Second, a novel step length estimator is proposed. These two algorithms utilize the data from accelerometer sensor only. Third, the heading information was obtained using a gyroscope with complementary filter in quaternion form. The combined algorithm was implemented on a low-power ARM processor to provide the trajectory points relative to an initial point. The proposed technique was tested by 10 subjects, in different shoes with different paces. The dependence of the performance of the technology on the attaching point of the mobile device is weak. The proposed algorithms have better balance and estimation accuracy and depend in less degree on the variety in physical parameters of people in comparison with the existing techniques. In experiments inertial measurement units were mounted in different places, i.e. in the hand, in trousers or in T-shirt pockets. The return position error did not exceed 5% of the total travelled distance for all performed tests.
A novel Bluetooth Low Energy advertising scan algorithm is presented for hybrid radios that are additionally capable to measure energy on Bluetooth channels, e.g. as they would need to be compliant with IEEE 802.15.4. Scanners applying this algorithm can achieve a low latency whilst consuming only a fraction of the power that existing mechanisms can achieve at a similar latency. Furthermore, the power consumption can scale with the incoming network traffic and in contrast to the existing mechanisms, scanners can operate without any frame loss given ideal network conditions. The algorithm does not require any changes to advertisers, hence, stays compatible with existing devices. Performance evaluated via simulation and experiments on real hardware shows a 37 percent lower power consumption compared to the best existing scan setting while even achieving a slightly lower latency which proves that this algorithm can be used to improve the quality of service of connection-less Bluetooth communication or reduce the connection establishment time of connection-oriented communication.
Cryptographic protection of messages requires frequent updates of the symmetric cipher key used for encryption and decryption, respectively. Protocols of legacy IT security, like TLS, SSH, or MACsec implement rekeying under the assumption that, first, application data exchange is allowed to stall occasionally and, second, dedicated control messages to orchestrate the process can be exchanged. In real-time automation applications, the first is generally prohibitive, while the second may induce problematic traffic patterns on the network. We present a novel seamless rekeying approach, which can be embedded into cyclic application data exchanges. Although, being agnostic to the underlying real-time communication system, we developed a demonstrator emulating the widespread industrial Ethernet system PROFINET IO and successfully use this rekeying mechanism.
High temperature components in internal combustion engines and exhaust systems must withstand severe mechanical and thermal cyclic loads throughout their lifetime. The combination of thermal transients and mechanical load cycling results in a complex evolution of damage, leading to thermomechanical fatigue (TMF) of the material. Analytical tools are increasingly employed by designers and engineers for component durability assessment well before any hardware testing. The DTMF model for TMF life prediction, which assumes that micro-crack growth is the dominant damage mechanism, is capable of providing reliable predictions for a wide range of high-temperature components and materials in internal combustion engines. Thus far, the DTMF model has employed a local approach where surface stresses, strains, and temperatures are used to compute damage for estimating the number of cycles for a small initial defect or micro-crack to reach a critical length. In the presence of significant gradients of stresses, strains, and temperatures, the use of surface field values could lead to very conservative estimates of TMF life when compared with reported lives from hardware testing. As an approximation of gradient effects, a non-local approach of the DTMF model is applied. This approach considers through-thickness fields where the micro-crack growth law is integrated through the thickness considering these variable fields. With the help of software tools, this method is automated and applied to components with complex geometries and fields. It is shown, for the TMF life prediction of a turbocharger housing, that the gradient correction using the non-local approach leads to more realistic life predictions and can distinguish between surface cracks that may arrest or propagate through the thickness and lead to component failure.
When designing and installing Indoor Positioning Systems, several interrelated tasks have to be solved to find an optimum placement of the Access Points. For this purpose, a mathematical model for a predefined number of access points indoors is presented. Two iterative algorithms for the minimization of localization error of a mobile object are described. Both algorithms use local search technique and signal level probabilities. Previously registered signal strengths maps were used in computer simulation.
Quantifying the midsole material characteristics of athletic footwear is a standard task in footwear research and development. Current material testing protocols primarily focus on the determination of cushioning properties of the heel region or the quantification of the midsole properties as one assembly. However, midsoles possess different spatial material properties that have not been quantified from previous methodologies. Therefore, new material testing methods are required to quantify the local material response of athletic footwear. We developed a cyclical force-controlled material testing protocol for the determination of non-homogeneously distributed material stiffness with a high spatial resolution. In five prototype shoes varying in their stiffness distribution, we found that the material properties can be reliably measured across the midsole. Furthermore, we observed a characteristic non-linear material response regardless of the midsole location. We found that the material stiffness increased with an increase of the applied force and that this effect is further intensified by higher testing cycles. Additionally, the obtained midsole stiffness depends on the geometry of the midsole. We explored different approaches to reduce the measurement time of the testing protocol and found that the number of measurements can be reduced by 70% using 2 D-interpolation procedures. Determining the spatial material properties of midsoles needs to be considered to understand foot-shoe interactions. Furthermore, this measurement protocol can be used for quality control within the footwear and can be adapted for considering the effects of different running styles or speeds on ground force application characteristics.
Uptakes of 9.2 mmol g−1 (40.5 wt %) for CO2 at 273 K/0.1 MPa and 15.23 mmol g−1 (3.07 wt %) for H2 at 77 K/0.1 MPa are among the highest reported for metal–organic frameworks (MOFs) and are found for a novel, highly microporous copper‐based MOF (see picture; Cu turquoise, O red, N blue). Thermal analyses show a stability of the flexible framework up to 250 °C.
Metal–organic frameworks (MOFs) as highly porous materials have gained increasing interest because of their distinct adsorption properties.1–3 They exhibit a high potential for applications in gas separation and storage,4 as sensors5 as well as in heterogeneous catalysis.6 In the last few years, the H2 storage capacity of MOFs has been considerably increased. Mesoporous MOFs show high adsorption capacities for CH4, CO2, and H2 at high pressures.2, 3, 7–10 To increase the uptake of H2 and CO2 by physisorption at ambient pressure, adsorbents with small micropores as well as high specific surface areas and micropore volumes are required.11, 12 Such microporous materials seem to be more appropriate for gas‐mixture separation by physisorption than mesoporous materials. For gas separation in MOFs the interactions between the fluid adsorptive and “open metal sites” (coordinatively unsaturated binding sites) or the ligands are regarded as important.13 Industrial processes, such as natural‐gas purification or biogas upgrading, can be improved with those materials during a vapor‐pressure swing adsorption cycle (VPSA cycle) or a temperature swing adsorption cycle (TSA cycle).14 The microporous MOF series CPO‐27‐M (M=Mg, Co, Ni, Zn), for example, shows very high CO2 uptakes at low pressures (<0.1 MPa).15, 16 Concerning H2 adsorption, the microporous MOF PCN‐12 offers with 3.05 wt % the highest uptake at ambient pressure and 77 K reported to date.17
Herein, we present a novel microporous copper‐based MOF equation image[Cu(Me‐4py‐trz‐ia)] (1; Me‐4py‐trz‐ia2−=5‐(3‐methyl‐5‐(pyridin‐4‐yl)‐4H‐1,2,4‐triazol‐4‐yl)isophthalate) with extraordinarily high CO2 and H2 uptakes at ambient pressure, the H2 uptake being similar to that in PCN‐12. The ligand Me‐4py‐trz‐ia2−, which can be obtained from cheap starting materials by a three‐step synthesis in good yield, combines carboxylate, triazole, and pyridine functions and is adopted from a recently presented series of linkers,18 for which up to now only a few coordination polymers are known.
The transition from college to university can have a variety of psychological effects on students who need to cope with daily obligations by themselves in a new setting, which can result in loneliness and social isolation. Mobile technology, specifically mental health apps (MHapps), have been seen as promising solutions to assist university students who are facing these problems, however, there is little evidence around this topic. My research investigates how a mobile app can be designed to reduce social isolation and loneliness among university students. The Noneliness app is being developed to this end; it aims to create social opportunities through a quest-based gamified system in a secure and collaborative network of local users. Initial evaluations with the target audience provided evidence on how an app should be designed for this purpose. These results are presented and how they helped me to plan the further steps to reach my research goals. The paper is presented at MobileHCI 2020 Doctoral Consortium.
In rural low voltage grid networks, the use of battery in the households with a grid connected Photovoltaic (PV) system is a popular solution to shave the peak PV feed-in to the grid. For a single electricity price scenario, the existing forecast based control approaches together with a decision based control layer uses weather and load forecast data for the on–off schedule of the battery operation. These approaches do bring cost benefit from the battery usage. In this paper, the focus is to develop a Model Predictive Control (MPC) to maximize the use of the battery and shave the peaks in the PV feed-in and the load demand. The solution of the MPC allows to keep the PV feed-in and the grid consumption profile as low and as smooth as possible. The paper presents the mathematical formulation of the optimal control problem along with the cost benefit analysis . The MPC implementation scheme in the laboratory and experiment results have also been presented. The results show that the MPC is able to track the deviation in the weather forecast and operate the battery by solving the optimal control problem to handle this deviation.
In this work a method for the estimation of current slopes induced by inverters operating interior permanent magnet synchronous machines is presented. After the derivation of the estimation algorithm, the requirements for a suitable sensor setup in terms of accuracy, dynamic and electromagnetic interference are discussed. The boundary conditions for the estimation algorithm are presented with respect to application within high power traction systems. The estimation algorithm is implemented on a field programmable gateway array. This moving least-square algorithm offers the advantage that it is not dependent on vectors and therefore not every measured value has to be stored. The summation of all measured values leads to a significant reduction of the required storage units and thus decreases the hardware requirements. The algorithm is designed to be calculated within the dead time of the inverter. Appropriate countermeasures for disturbances and hardware restrictions are implemented. The results are discussed afterwards.
This paper presents the use of model predictive control (MPC) based approach for peak shaving application of a battery in a Photovoltaic (PV) battery system connected to a rural low voltage gird. The goals of the MPC are to shave the peaks in the PV feed-in and the grid power consumption and at the same time maximize the use of the battery. The benefit to the prosumer is from the maximum use of the self-produced electricity. The benefit to the grid is from the reduced peaks in the PV feed-in and the grid power consumption. This would allow an increase in the PV hosting and the load hosting capacity of the grid.
The paper presents the mathematical formulation of the optimal control problem
along with the cost benefit analysis. The MPC implementation scheme in the
laboratory and experiment results have also been presented. The results show
that the MPC is able to track the deviation in the weather forecast and operate
the battery by solving the optimal control problem to handle this deviation.
The durability of polymer electrolyte membrane fuel cells (PEMFC) is governed by a nonlinear coupling between system demand, component behavior, and physicochemical degradation mechanisms, occurring on timescales from the sub-second to the thousand-hour. We present a simulation methodology for assessing performance and durability of a PEMFC under automotive driving cycles. The simulation framework consists of (a) a fuel cell car model converting velocity to cell power demand, (b) a 2D multiphysics cell model, (c) a flexible degradation library template that can accommodate physically-based component-wise degradation mechanisms, and (d) a time-upscaling methodology for extrapolating degradation during a representative load cycle to multiple cycles. The computational framework describes three different time scales, (1) sub-second timescale of electrochemistry, (2) minute-timescale of driving cycles, and (3) thousand-hour-timescale of cell ageing. We demonstrate an exemplary PEMFC durability analysis due to membrane degradation under a highly transient loading of the New European Driving Cycle (NEDC).
An algorithm is presented that has successfully been utilized in practice for several years. It improves data analysis in chromatography. The program runs in an extremely reliable way and evaluates chromatographic raw data with an acceptable error. The algorithm requires a minimum of preliminaries and integrates even unsmoothed noisy data correctly.
We report improved separation of the highly toxic contact herbicides paraquat, diquat, difenzoquat, mepiquat, and chloromequat by HPTLC. Quantification was based on a new derivatization reaction using sodium tetraphenylborate. Measurements were in the wavelength range from 440 to 480 nm or from 440 to 590 nm. An LED emitting very intense light at 365 nm was used for excitation. The quantification limits of paraquat and diquat in water, using improved solid-phase extraction, was in the low ng L −1 range. The linear range covered more than two orders of magnitude. Recovery was investigated for all the compounds, and was insufficient, ranging from 11 to 92%, but the method is inexpensive, rapid, and works reliably.
Signal detection and bandwidth estimation, also known as channel segmentation or information channel estimation, is a perpetual topic in communication systems. In the field of radio monitoring this issue is extremely challenging, since unforeseeable effects like fading occur accidentally. In addition, most radio monitoring devices normally scan a wide frequency range of several hundred MHz and have to detect a multitude of different signals, varying in signal power, bandwidth and spectral shape. Since narrowband sensing techniques cannot be directly applied, most radio monitoring devices use Nyquist wideband sensing to discover the huge frequency range. In practice, sensing is normally conducted by an FFT sweep spectrum analyzer that delivers the power spectral density (PSD) values to the radio monitoring system. The channel segmentation is the initial step of a comprehensive signal analysis in a radio monitoring system based on the PSD values. In this paper, a novel approach for channel segmentation is presented that is based on a quantization and a histogram evaluation of the measured PSD. It will be shown that only the combination of both evaluations will lead to an successful automatic channel segmentation. The performance of the proposed algorithm is shown in a real radio monitoring szenario.
A Novel Approach of High Dynamic Current Control of Interior Permanent Magnet Synchronous Machines
(2019)
Harmonic-afflicted effects of permanent magnet synchronous machines with high power density are hardly faced by traditional current PI controllers, due to limited controller bandwidth. As a consequence, currents and lastly torque ripples appear. In this paper, a new deadbeat current controller architecture has been presented, which is capable to encounter the effects of these harmonics. This new control algorithm, here named “Hybrid-Deadbeat-Controller”, combines the stability and the low steady-state errors offered by common PI regulators with the high dynamic offered by the deadbeat control. Therefore, a novel control algorithm is proposed, capable of either compensating the current harmonics in order to get smoother currents or to control a varying reference value to achieve a smoother torque. The information needed to calculate the optimal reference currents is based on an online parameter estimation feeding an optimization algorithm to achieve an optimal torque output and will be investigated in future research. In order to ensure the stability of the controller over the whole area of operation even under the influence of effects changing the system’s parameter, this work as well focusses on the robustness of the “hybrid” dead beat controller.
Synthesis and crystal structure of a novel copper-based MOF material are presented. The tetragonal crystal structure of [ ∞ 3 ( Cu 4 ( μ 4 -O ) ( μ 2 -OH ) 2 ( Me 2 trz p ba ) 4 ] possesses a calculated solvent-accessible pore volume of 57%. Besides the preparation of single crystals, synthesis routes to microcrystalline materials are reported. While PXRD measurements ensure the phase purity of the as-synthesized material, TD-PXRD measurements and coupled DTA–TG–MS analysis confirm the stability of the network up to 230 °C. The pore volume of the microcrystalline material determined by nitrogen adsorption at 77 K depends on the synthetic conditions applied. After synthesis in DMF/H2O/MeOH the pores are blocked for nitrogen, whereas they are accessible for nitrogen after synthesis in H2O/EtOH and subsequent MeOH Soxhleth extraction. The corresponding experimental pore volume was determined by nitrogen adsorption to be V Pore = 0.58 cm 3 g - 1 . In order to characterize the new material and to show its adsorption potential, comprehensive adsorption studies with different adsorptives such as nitrogen, argon, carbon dioxide, methanol and methane at different temperatures were carried out. Unusual adsorption–desorption isotherms with one or two hysteresis loops are found – a remarkable feature of the new flexible MOF material.
This paper presents a novel low-jitter interface between a low-cost integrated IEEE802.11 chip and a FPGA. It is designed to be part of system hardware for ultra-precise synchronization between wireless stations. On physical level, it uses Wi-Fi chip coexistence signal lines and UART frame encoding. On its basis, we propose an efficient communication protocol providing precise timestamping of incoming frames and internal diagnostic mechanisms for detecting communication faults. Meanwhile it is simple enough to be implemented both in low-cost FPGA and commodity IEEE802.11 chip firmware. The results of computer simulation shows that developed FPGA implementation of the proposed protocol can precisely timestamp incoming frames as well as detect most of communication errors even in conditions of high interference. The probability of undetected errors was investigated. The results of this analysis are significant for the development of novel wireless synchronization hardware.
Advances in printed electronics (PE) enables new applications, particularly in ultra-low-cost domains. However, achieving high-throughput printing processes and manufacturing yield is one of the major challenges in the large-scale integration of PE technology. In this article, we present a programmable printed circuit based on an efficient printed lookup table (pLUT) to address these challenges by combining the advantages of the high-throughput advanced printing and maskless point-of-use final configuration printing. We propose a novel pLUT design which is more efficient in PE realization compared to existing LUT designs. The proposed pLUT design is simulated, fabricated, and programmed as different logic functions with inkjet printed conductive ink to prove that it can realize digital circuit functionality with the use of programmability features. The measurements show that the fabricated LUT design is operable at 1 V.
A novel approach of a testbed for embedded networking nodes has been conceptualized and implemented. It is based on the use of virtual nodes in a PC environment, where each node executes the original embedded code. Different nodes are running in parallel and are connected via so-called virtual interfaces. The presented approach is very efficient and allows a simple description of test cases without the need of a network simulator. Furthermore, it speeds up the process of developing new features.
The following describes a new method for estimating the parameters of an interior permanent magnet synchronous machine (IPMSM). For the estimation of the parameters the current slopes caused by the switching of the inverter are used to determine the unknowns of the system equations of the electrical machine. The angle and current dependence of the machine parameters are linearized within a PWM cycle. By considering the different switching states of the inverter, several system equations can be derived and a solution can be found within one PWM cycle. The use of test signals and filter-based approaches is avoided. The derived algorithm is explained and validated with measurements on a test bench.
There are additional long-term effects which also change the micro-structure of the polymer network and consequently the effective number of polymer chains in the material. These effects are summarized by ageing processes and will be used in the following to explain the basic assumptions of the model which can be generalized to simulate the viscous behaviour of the material. An implementation of these concepts into FEM codes is straightforward and has been carried out to the solver ABAQUS, Baaser & Ziegler (2006), Baaser et al. (2009).
Time-Sensitive Networking (TSN) is the most promising time-deterministic wired communication approach for industrial applications. To extend TSN to "IEEE 802.11" wireless networks two challenging problems must be solved: synchronization and scheduling. This paper is focused on the first one. Even though a few solutions already meet the required synchronization accuracies, they are built on expensive hardware that is not suited for mass market products. While next Wi-Fi generation might support the required functionalities, this paper proposes a novel method that makes possible high-precision wireless synchronization using commercial low-cost components. With the proposed solution, a standard deviation of synchronization error of less than 500 ns can be achieved for many use cases and system loads on both CPU and network. This performance is comparable to modern wired real-time field busses, which makes the developed method a significant contribution for the extension of the TSN protocol to the wireless domain.
Printed electronics (PE) enables disruptive applications in wearables, smart sensors, and healthcare since it provides mechanical flexibility, low cost, and on-demand fabrication. The progress in PE raises trust issues in the supply chain and vulnerability to reverse engineering (RE) attacks. Recently, RE attacks on PE circuits have been successfully performed, pointing out the need for countermeasures against RE, such as camouflaging. In this article, we propose a printed camouflaged logic cell that can be inserted into PE circuits to thwart RE. The proposed cell is based on three components achieved by changing the fabrication process that exploits the additive manufacturing feature of PE. These components are optically look-alike, while their electrical behaviors are different, functioning as a transistor, short, and open. The properties of the proposed cell and standard PE cells are compared in terms of voltage swing, delay, power consumption, and area. Moreover, the proposed camouflaged cell is fabricated and characterized to prove its functionality. Furthermore, numerous camouflaged components are fabricated, and their (in)distinguishability is assessed to validate their optical similarities based on the recent RE attacks on PE. The results show that the proposed cell is a promising candidate to be utilized in camouflaging PE circuits with negligible overhead.
The formation and analysis of ten microporous triazolyl isophthalate based MOFs, including nine isomorphous and one isostructural compound is presented. The compounds 1 M – 3 M with the general formula [ M ( R 1 - R 2 - trz - ia ) ] ∞ 3 ·x H 2 O (M 2+ = Co 2+ , Cu 2+ , Zn 2+ , Cd 2+ ; R 1 = H, Me; R 2 = 2py, 2pym, prz (2py = 2-pyridinyle; 2pym = 2-pyrimidinyle; prz = pyrazinyle)) crystallize with rtl topology. They are available as single crystals and also easily accessible in a multi-gram scale via refluxing the metal salts and the protonated ligands in a solvent. Their isomorphous structures facilitate the synthesis of heteronuclear MOFs; in case of 2 M , Co 2+ ions could be gradually substituted by Cu 2+ ions. The Co 2+ :Cu 2+ ratios were determined by ICP-OES spectroscopy, the distribution of Co 2+ and Cu 2+ in the crystalline samples are investigated by SEM-EDX analysis leading to the conclusions that Cu 2+ is more favorably incorporated into the framework compared to Co 2+ and, moreover, that the distribution of the two metal ions between the crystals and within the crystals is inhomogeneous if the crystals were grown slowly. The various compositions of the heteronuclear materials lead to different colors and the sorption properties for CO 2 and N 2 are dependent on the integrated metal ions.
Robots and automata are key elements of every vision and forecast of life in the near and distant future. However, robots and automata also have a long history, which reaches back into antiquity. Today most historians think that one of the key roles of robots and automata was to amaze or even terrify the audience: They were designed to express something mythical, magical, and not explainable. Moreover, the visions of robots and their envisioned fields of application reflect the different societies. Therefore, this short history of robotics and (especially) anthropomorphic automata aims to give an overview of several historical periods and their perspective on the topic. In a second step, this work aims to encourage readers to reflect on the recent discussion about fields of application as well as the role of robotics today and in the future.
A Simple and Reliable HPTLC Method for the Quantification of the Intense Sweetener Sucralose®
(2003)
This paper describes a simple and fast thin layer chromatography (TLC) method for the monitoring of the relatively new intense sweetener Sucralose® in various food matrices. The method requires little or no sample preparation to isolate or concentrate the analyte. The Sucralose® extract is separated on amino‐TLC‐plates, and the analyte is derivatized “reagent‐free” by heating the developed plate for 20 min at 190°C. Spots can be measured either in the absorption or fluorescence mode. The method allows the determination of Sucralose® at the levels of interest regarding foreseen European legislation (>50 mg/kg) with excellent repeatability (RSD = 3.4%) and recovery data (95%).
In medical applications wireless technologies are not widely spread. Today they are mainly used in non latency-critical applications where reliability can be guaranteed through retransmission protocols and error correction mechanisms. By using retransmission protocols within the disturbed shared wireless channel latency will increase. Therefore retransmission protocols are not sufficient for removing latency-critical wired connections within operating rooms such as foot switches. Todays research aims to improve reliability through the physical characteristics of the wireless channel by using diversity methods and more robust modulation. In this paper an Architecture for building up a reliable network is presented. The Architecture offers the possibility for devices with different reliability, latency and energy consumption requirements to participate. Furthermore reliability, latency and energy consumption are scalable for every single participant.
We present an improved quantification method for urethane found in spirits. The quantification is based on a derivatization reaction using cinnamaldehyde in combination with phosphoric acid. Measurements were carried out in the wavelength range from 445 to 460 nm using a diode-TLC device. An LED was used for illumination purposes. It emits very dense light at 365 nm. The quantification range of urethane is in the lower ng range. By applying 20 µL of sprits, the urethane quantification range is from 320 µg/L to 8.1 mg urethane per litre of spirit. The range of linearity covers nearly two magnitudes. The method is cheap, fast and reliable, and is able to monitor all European legislation limits without time-consuming sample pre-treatments.
A new, small, and optimized for low power processor core named SIRIUS has been developed, simulated, synthesized to a netlist and verified. From this netlist, containing only primitives like gates and flip-flops, a mapping to an ASIC - or FPGA technology can easily be done with existing synthesizer tools, allowing very complex SOC designs with several blocks. Emulation via FPGA can be done on already simple setups and cheap hardware because of the small core size. The performance is estimated 50 MIPS on Cyclone II FPGA and about 100 MIPS on a 0.35 CMOS 5M2P technology with 4197 primitives used for the core, including a 16 x 16 multiplier. An example design of the ASIC for an electronic ePille device currently in development is shown.
A printed electronics technology has the advantage of additive and extremely low-cost fabrication compared with the conventional silicon technology. Specifically, printed electrolyte-gated field-effect transistors (EGFETs) are attractive for low-cost applications in the Internet-of-Things domain as they can operate at low supply voltages. In this paper, we propose an empirical dc model for EGFETs, which can describe the behavior of the EGFETs smoothly and accurately over all regimes. The proposed model, built by extending the Enz-Krummenacher-Vittoz model, can also be used to model process variations, which was not possible previously due to fixed parameters for near threshold regime. It offers a single model for all the operating regions of the transistors with only one equation for the drain current. Additionally, it models the transistors with a less number of parameters but higher accuracy compared with existing techniques. Measurement results from several fabricated EGFETs confirm that the proposed model can predict the I-V more accurately compared with the state-of-the-art models in all operating regions. Additionally, the measurements on the frequency of a fabricated ring oscillator are only 4.7% different from the simulation results based on the proposed model using values for the switching capacitances extracted from measurement data, which shows more than 2× improvement compared with the state-of-the-art model.
With increasing flexible AC transmission system (FACTS) devices in operation, like the most versatile unified power flow controller (UPFC), the AC/DC transmission flexibility and power system stability have been suffering unprecedented challenge. This paper introduces the user-defined modeling (UDM) method into the UPFC dynamic modeling process, to deal with the challenging requirements of power system operation. This has also been verified using a leading-edge stability analysis software named DSATools TM in the IEEE-39 bus benchmark system. The characteristics of steady-state and dynamic responses are compared and analyzed under different conditions. Furthermore, simulation results prove the feasibility and effectiveness of the proposed UPFC in terms of both the independent regulation of power flow and the improvement of transient stability.
It is important to minimize the unscheduled downtime of machines caused by outages of machine components in highly automated production lines. Considering machine tools such as, grinding machines, the bearing inside of spindles is one of the most critical components. In the last decade, research has increasingly focused on fault detection of bearings. In addition, the rise of machine learning concepts has also intensified interest in this area. However, up to date, there is no single one-fits-all solution for predictive maintenance of bearings. Most research so far has only looked at individual bearing types at a time.
This paper gives an overview of the most important approaches for bearing-fault analysis in grinding machines. There are two main parts of the analysis presented in this paper. The first part presents the classification of bearing faults, which includes the detection of unhealthy conditions, the position of the error (e.g. at the inner or at the outer ring of the bearing) and the severity, which detects the size of the fault. The second part presents the prediction of remaining useful life, which is important for estimating the productive use of a component before a potential failure, optimizing the replacement costs and minimizing downtime.
Hot work tools are subjected to complex thermal and mechanical loads during hot forming processes. Locally, the stresses can exceed the material’s yield strength in highly loaded areas as e.g. in small radii in die cavities. To sustain the high loads, the hot forming tools are typically made of martensitic hot work steels. While temperatures for annealing of the tool steels usually lie in the range between 400 and 600 °C, the steels may experience even higher temperatures during hot forming, resulting in softening of the material due to coarsening of strengthening particles. In this paper, a temperature dependent cyclic plasticity model for the martensitic hot work tool steel 1.2367 (X38CrMoV5-3) is presented that includes softening due to particle coarsening and that can be applied in finite-element calculations to assess the effect of softening on the thermomechanical fatigue life of hot work tools. To this end, a kinetic model for the evolution of the mean size of secondary carbides based on Ostwald ripening is coupled with a cyclic plasticity model with kinematic hardening. Mechanism-based relations are developed to describe the dependency of the mechanical properties on carbide size and temperature. The material properties of the mechanical and kinetic model are determined on the basis of tempering hardness curves as well as monotonic and cyclic tests.
The DMFC is a promising option for backup power systems and for the power supply of portable devices. However, from the modeling point of view liquid-feed DMFC are challenging systems due to the complex electrochemistry, the inherent two-phase transport and the effect of methanol crossover. In this paper we present a physical 1D cell model to describe the relevant processes for DMFC performance ranging from electrochemistry on the surface of the catalyst up to transport on the cell level. A two-phase flow model is implemented describing the transport in gas diffusion layer and catalyst layer at the anode side. Electrochemistry is described by elementary steps for the reactions occurring at anode and cathode, including adsorbed intermediate species on the platinum and ruthenium surfaces. Furthermore, a detailed membrane model including methanol crossover is employed. The model is validated using polarization curves, methanol crossover measurements and impedance spectra. It permits to analyze both steady-state and transient behavior with a high level of predictive capabilities. Steady-state simulations are used to investigate the open circuit voltage as well as the overpotentials of anode, cathode and electrolyte. Finally, the transient behavior after current interruption is studied in detail.
We present a videodensitometric quantification method for methadone in syrup, separated by thin-layer chromatography (TLC). The quantification is based on a derivation reaction with Dragendorf reagent. Measurements were carried out using a 16-bit flatbed scanner. The range of linearity covers two magnitudes of power using the Kubelka-Munk expression for data transformation. The separation method is inexpensive, fast, and reliable.
This chapter portrays the historical and mathematical background of dynamic and procedural content generation (PCG). We portray and compare various PCG methods and analyze which mathematical approach is suited for typical applications in game design. In the next step, a structural overview of games applying PCG as well as types of PCG is presented. As abundant PCG content can be overwhelming, we discuss context-aware adaptation as a way to adapt the challenge to individual players’ requirements. Finally, we take a brief look at the future of PCG.
… nicht nur in der Energiewirtschaft, sondern auch im positiven und wahrsten Sinne des Wortes in der Fachgruppe PM Windenergie. In über 40 Jahren GPM wurde immer wieder deutlich, dass Projekte und Programme in Wirtschaft und Gesellschaft nicht nur begleitet, sondern auch aus der GPM heraus mitgestaltet werden. Die Entwicklung und die Ergebnisse der Fachgruppe Windenergie machen dies besonders deutlich.
Betrugsmaschen werden wohl nie aussterben. Immer wieder wachsen neue Opfer nach, die unwissend, leichtgläubig oder schnell einzuschüchtern sind. Privatleute und Unternehmer werden dabei gleichermaßen Opfer von geschickten "Vertragsabschlusskonstruktionen", bei deren Durchsetzung zuweilen auch Juristen beteiligt sind. Dieser Beitrag befasst sich mit aktuellen Entwicklungen und Entscheidungen im deutschen Recht zu eben diesen Fällen.
Die Kenntnis der Messunsicherheit verbessert die Aussagekraft von Einsatzhärtungstiefe-Messungen. Ausgehend von der Definition in der DIN EN ISO 2639:2002 wird unter Anwendung des „Guide to the Expression of Uncertainty in Measurement“ die Messunsicherheit abgeschätzt. Dazu werden die Einflüsse der Härteprüfung, der Positionierung der Prüfpunkte und der Probe berücksichtigt. Das Verfahren wird an zwei Beispielen angewendet: Zunächst werden die gemäß Norm zulässigen Toleranzen vollständig ausgenutzt, anschließend die Unsicherheit eines automatisierten Härteprüfers experimentell ermittelt. In beiden Fällen dominiert der Probeneinfluss das Ergebnis.
The paper recommends an approach to estimate effectively the probability of buffer overflow in high-speed communication networks, capable of carrying diverse traffic, including self-similar teletraffic, and supporting diverse levels of quality of service. Simulations with stochastic, long-range dependent self-similar traffic source models are conducted. A new efficient algorithm, based on a variant of the RESTART/LRE method, is developed and applied to accelerate the buffer overflow simulation in a finite buffer single server model under long-range dependent self-similar traffic load with different buffer sizes. Numerical examples and simulation results are shown
Subspace clustering aims to find all clusters in all subspaces of a high-dimensional data space. We present a massively data-parallel approach that can be run on graphics processing units. It extends a previous density-based method that scales well with the number of dimensions. Its main computational bottleneck consists of (sequentially) generating a large number of minimal cluster candidates in each dimension and using hash collisions in order to find matches of such candidates across multiple dimensions. Our approach parallelizes this process by removing previous interdependencies between consecutive steps in the sequential generation process and by applying a very efficient parallel hashing scheme optimized for GPUs. This massive parallelization gives up to 70x speedup for
the bottleneck computation when it is replaced by our approach and run on current GPU hardware. We note that depending on data size and choice of parameters, the parallelized part of the algorithm can take different percentages of the overall runtime of the clustering process, and thus, the overall clustering speedup may vary significantly between different cases. However, even
in our ”worst-case” test, a small dataset where the computation makes up only a small fraction of the overall clustering time, our parallel approach still yields a speedup of more than 3x for the complete run of the clustering process. Our method could also be combined with parallelization of other parts of the clustering algorithm, with an even higher potential gain in processing speed.
The authentication method of electronic devices, based on individual forms of correlograms of their internal electric noises, is well-known. Specific physical differences in the components – for example, caused by variations in production quality – cause specific electrical signals, i.e. electric noise, in the electronic device. It is possible to obtain this information and to identify the specific differences of the individual devices using an embedded analog-to-digital converter (ADC). These investigations confirm the possibility to identify and authenticate electronic devices using bit templates, calculated from the sequence of values of the normalized autocorrelation function of noise. Experiments have been performed using personal computers. The probability of correct identification and authentication increases with increasing noise recording duration. As a result of these experiments, an accuracy of 98.1% was achieved for a 1 second-long registration of EM for a set of investigated computers.
Achieving Positive Hospitality Experiences through Technology: Findings from Singapore and Malaysia
(2021)
Customers’ experience is one of the most impactful factors in the tourism industry. Only by offering customers an excellent experience is it possible to build and ensure long-term customer loyalty. In today’s world, technology plays a key role in providing customers with an excellent customer experience. This study has the objective of analyzing how a positive customer experience can be achieved, and which technologies are necessary to ensure this. Results were collected through a literature review, and qualitative interviews with managers of selected hotels, as well as of attractions in Malaysia and Singapore. The analysis of these hotels and attractions is based on a set of criteria to determine the extent of the adoption of the new standards that contribute to positive online customer experiences. As a conclusion, different perspectives are compared, and positive and negative aspects of the use of modern technologies in the tourism industry are specified and discussed.
Das fortwährende Streben nach Steigerung der Genauigkeit und Effizienz von industriellen Bearbeitungs- und Prüfprozessen führt bei elektrischen Antrieben zu immer höheren Forderungen an ihre dynamischen Eigenschaften. Hierbei kommt dem Stromregelkreis als dem am weitesten unterlagerten Regelkreis eines elektrischen Antriebs eine entscheidende Bedeutung zu. Mit zunehmender Dynamikerhöhung des Stromregelkreises treten jedoch aufgrund von Parameterunsicherheiten und von Messfehlem immer deutlicher Probleme der Regelkreisrobustheit und der Geräuschemission in den Vordergrund, die es oft nicht gestatten, die theoretisch erhaltenen Lösungen in vollem Umfang zu realisieren. Gegenüber der optimalen Lösung müssen dann Abstriche hinsichtlich der erreichbaren Dynamik gemacht werden. Wie diese Abstriche durch das Ausschöpfen verborgener Freiheitsgrade reduziert werden können, wird im vorliegenden Beitrag gezeigt. Als Lösungsansatz wird hierfür ein achsenunsymmetrischer Statorstromzustandsregler gewählt, der es erlaubt, in der d- und q-Achse eine unterschiedliche Dynamik einzustellen. Hierbei wird zunächst im Kapitel 2 ein kurzer Überblick über die Entwicklungsgeschichte und den Stand der Technik von pulsweitenmodulierten Stromregelverfahren für Drehstromantriebe in den zurückliegenden Jahrzehnten gegeben. Anschließend wird am Beispiel einer frequenzumrichtergespeisten Asynchronmaschine das zeitdiskrete Modell der Statorstromregelstrecke vorgestellt, das dem hier erläuterten Verfahren zugrunde liegt. Wegen des Zusammenhangs zwischen Dynamikerhöhung und Empfindlichkeitszunahme ist es naheliegend, die Dynamik des Statorstromregelkreises nur so weit zu steigern, wie es erforderlich ist. Diesbezüglich ist insbesondere zu gewährleisten, dass ein angefordertes Drehmoment möglichst schnellst eingeprägt wird. Die Änderungsgeschwindigkeit des Flusses spielt hingegen eine untergeordnetere Rolle. Demzufolge sollte die drehmomentbildende Statorstrom-q-Komponente in der Praxis eine höhere Dynamik aufweisen als die flussbildende Statorstrom-d-Komponente. Um hierbei die aufwändige reelle Rechnung so weit wie möglich zu vermeiden, wird der Reglerentwurf in zwei Schritten durchgeführt. Im ersten Schritt wird ein schiefsymmetrisches, komplex beschreibbares Regelgesetz entworfen, das zwar zu einer möglichst einfachen Darstellbarkeit des geschlossenen Statorstromregelkreises führt, das jedoch noch nicht die endgültige Dynamik zur Folge haben muss. Insbesondere muss nach Abschluss dieses ZwischenSchritts bereits eine vollständige Entkopplung der d- und der q-Komponente des Statorstromraumzeigers vollzogen sein. Im zweiten Schritt wird dann ein weiterer Regler entworfen, der auf der Grundlage des im ersten Schritt erhaltenen entkoppelten Systems jeder Stromkomponente eine separate Dynamik zuweisen kann. Die Verkettung beider Teilregler führt schließlich zum gesuchten Statorstromregler, der zum einen relativ einfach berechenbar ist und der zum anderen alle an ihn gestellten Dynamikanforderungen erfüllt. Im vierten Kapitel wird schließlich der Entwurf des achsenunsymmetrischen Statorstromzustandsreglers skizziert und die daraus hervorgehenden Regelalgorithmen vorgestellt. Die Leistungsfähigkeit des beschriebenen Zustandsreglers wird anhand von aufgenommenen Zeitverläufen eines Laborantriebs demonstriert, mit dem der Drehmomentverlauf von Verbrennungsmotoren nachgebildet wird.
This paper gives an overview of the implementation of an Active Noise Control system on the TMS320C6713 Digital Signal Processor from Texas Instruments in the Digital Signal Processing Lab at Hochschule Offenburg, Germany. This system is implemented considering some non-ideal environmental conditions on a real system instead of being limited to computer simulations. Changes over time on the physical acoustical path as well as reverberation and variation on the power of the reference signal can strongly degrade the performance of the system or even lead to instability. In order to try to minimize these effects, the Active Noise Control system was designed to support a fast and easy implementation and evaluation of different algorithms on the DSP in real-time. In Section 1 a brief introduction about active noise control system is given and in section 2 the basic algorithm is described. In section 3 the implementation of the system is described and in section 4 some final considerations are given.
In dieser Abschlussarbeit wurde die bisherige Spielstrategie des RoboCup3D-Clients an die durch den FatProxy möglich gewordenen perfekten Kicks angepasst. Dazu wurde die aktive Entscheidungslogik am Ball komplett überarbeitet und eine neue Positionierungsstrategie anhand der bisher verwendeten Architektur entwickelt.
Die neue aktive Entscheidungslogik verwendet dabei eine neue, von den Mitspielerpositionen abhängige, Positionsberechnung und mehrere neue Bewertungsmethoden, die diese Positionen bewerten. Zusätzlich gibt es nun auch eine Funktionalität, die den neu benötigten vertikalen Schusswinkel für jede Position bestimmt. Für die neue Positionierung wurde eine Rautenformation gewählt, bei der die verschiedenen Rollen jetzt eigene Spielfeldbereiche zugewiesen bekommen, die sich teilweise überlappen. Diese Bereiche sind nötig geworden, da die Rollen sich jetzt weniger am Ball und mehr direkt am Spielfeld orientieren.
Bei der zum Schluss durchgeführten Evaluation der Spielergebnisse zwischen neuen und alten Strategiekonfigurationen hat sich ergeben, dass die komplett neue Strategiezusammenstellung mit durchschnittlich zwei Toren Vorsprung gegen die alte Strategie gewinnt und damit besser mit den neuen Möglichkeiten interagiert. Mischt man neue und alte Strategiekomponenten hat das jedoch den gegenteiligen Effekt, da die Mischvarianten gegen die alte Strategie verlieren. Die neuen Komponenten benötigen also das gegenseitige Zusammenspiel, um effizient zu funktionieren.
There is a growing trend for the use of thermo-active building systems (TABS) for the heating and cooling of buildings, because these systems are known to be very economical and efficient. However, their control is complicated due to the large thermal inertia, and their parameterization is time-consuming. With conventional TABS-control strategies, the required thermal comfort in buildings can often not be maintained, particularly if the internal heat sources are suddenly changed. This paper shows measurement results and evaluations of the operation of a novel adaptive and predictive calculation method, based on a multiple linear regression (AMLR) for the control of TABS. The measurement results are compared with the standard TABS strategy. The results show that the electrical pump energy could be reduced by more than 86%. Including the weather adjustment, it could be demonstrated that thermal energy savings of over 41% could be reached. In addition, the thermal comfort could be improved due to the possibility to specify mean room set-point temperatures. With the AMLR, comfort category I of the comfort norms ISO 7730 and DIN EN 15251 are observed in about 95% of occasions. With the standard TABS strategy, only about 24% are within category I.
Adaptive predictive control of thermo-active building systems (TABS) based on a multiple regression algorithm: First practical test. Available from: https://www.researchgate.net/publication/305903009_Adaptive_predictive_control_of_thermo-active_building_systems_TABS_based_on_a_multiple_regression_algorithm_First_practical_test [accessed Jul 7, 2017].
Various rapid prototyping methods have been available for the production of physical architectural models for a few years. This paper highlights in particular the advantages of 3D printing and Fused Layer Modeling for the production of detailed architectural models. In addition, the current challenges for the creation and transfer of CAAD-data are explained. Furthermore, new methods are being developed in order to improve both the technical and economic boundary conditions for the application of 3DP und FLM. This makes the production of models with very detailed interior rooms possible. The internal details are made visible by dividing the complex overall model into individual models connected by means of an innovative plug-in system. In addition, three case studies are shown in which the developed methods are applied in order to implement detailed architectural models. Finally manufacturing time and costs of the architectural models in the three case studies are compared.
Additive manufacturing is a rapidly growing manufacturing process for which many new processes and materials are currently being developed. The biggest advantage is that almost any shape can be produced, while conventional manufacturing methods reach their limits. Furthermore, a lot of material is saved because the part is created in layers and only as much material is used as necessary. In contrast, in the case of machining processes, it is not uncommon for more than half of the material to be removed and disposed of. Recently, new additive manufacturing processes have been on the market that enables the manufacturing of components using the FDM process with fiber reinforcement. This opens up new possibilities for optimizing components in terms of their strength and at the same time increasing sustainability by reducing materials consumption and waste. Within the scope of this work, different types of test specimens are to be designed, manufactured and examined. The test specimens are tensile specimens, which are used both for standardized tensile tests and for examining a practical component from automotive engineering used in student project. This project is a vehicle designed to compete in the Shell Eco-marathon, one of the world’s largest energy efficiency competitions. The aim is to design a vehicle that covers a certain distance with as little fuel as possible. Accordingly, it is desirable to manufacture the components with the lowest possible weight, while still ensuring the required rigidity. To achieve this, the use of fiber-reinforced 3D-printed parts is particularly suitable due to the high rigidity. In particular, the joining technology for connecting conventionally and additively manufactured components is developed. As a result, the economic efficiency was assessed, and guidelines for the design of components and joining elements were created. In addition, it could be shown that the additive manufacturing of the component could be implemented faster and more sustainably than the previous conventional manufacturing.
The fast and cost-effective manufacturing of tools for thermoforming is an essential requirement to shorten the development time of products. Thus, additive processes are used increasingly in tooling for thermoforming of plastic sheets. However, a disadvantage of many additive methods is that they are highly cost-intensive, since complex systems based on laser technology and expensive metal powders are needed. Therefore, this paper examines how to work with favorable additive methods, e.g. Binder Jetting, to manufacture tools, which provide sufficient strength for thermoforming. The use of comparatively low-priced inkjet technology for the layer construction and a polymer plaster as material can be expected to result in significant cost reductions. Based on a case study using a cowling (engine bonnet) for an Unmanned Aerial Vehicle (UAV), the development of a complex tool for thermoforming is demonstrated. The object in this study is to produce a tool for a complex-shaped component in small numbers and high quality in a short time and at reasonable costs. Within the tooling process, integrated vacuum channels are implemented in additive tooling without the need for additional post-processing (for example, drilling). In addition, special technical challenges, such as the demolding of undercuts or the parting of the tool are explained. All process steps from tool design to the use of the additively manufactured tool are analyzed. Based on the manufacturing of a small series of cowlings for a UAV made of plastic sheets (ABS), it is shown, that the Binder Jetting offers sufficient mechanical and thermal strength for additive tooling. In addition, an economic evaluation of the tool manufacturing and a detailed consideration of the required manufacturing times for the different process steps are carried out. Finally, a comparison is made with conventional and alternative additive methods of tooling.
Wer als Pädagoge und Wissenschaftler das Thema „Digitalisierung und Unterricht“ kritisch reflektiert, stellt fest, dass nur Wenige die Tragweite der schon lange beabsichtigten Transformation von Bildungseinrichtungen zu IT-konformen, algorithmisch gesteuerten Lernfabriken realisieren. Die Corona-Pandemie ist nur der aktuelle Anlass, seit langem bekannte Digitalisierungsstrategien nur schneller umzusetzen. Dabei ist der Wechsel von ursprünglich pädagogischen Prämissen als Basis von Lehr- und Lernprozessen hin zum Paradigma der datengestützte Schulentwicklung und der empirischer Bildungsforschung wesentlich. Daten und Statistik dominieren das Individuum wie das Unterrichtsgeschehen. Es bedeutet sachlogisch, möglichst viele Daten der Schülerinnen und Schüler zu sammeln, auszuwerten und zur Grundlage von Entscheidungen über Lerninhalte und -prozessen zu machen. Lehren und Lernen wird wieder einmal als, heute digital, steuerbarer Prozess behauptet, wie schon beim programmierten Lernen in den 1950er Jahren. Was sind mögliche Alternativen?
The separation of nitrogen and methane from hydrogen-rich mixtures is systematically investigated on a recently developed binder-free zeolite 5A. For this adsorbent, the present work provides a series of experimental data on adsorption isotherms and breakthrough curves of nitrogen and methane, as well as their mixtures in hydrogen. Isotherms were measured at temperatures of 283–313 K and pressures of up to 1.0 MPa. Breakthrough curves of CH4, N2, and CH4/N2 in H2 were obtained at temperatures of 300–305 K and pressures ranging from 0.1 to 6.05 MPa with different feed concentrations. An LDF-based model was developed to predict breakthrough curves using measured and calculated data as inputs. The number of parameters and the use of correlations were restricted to focus on the importance of measured values. For the given assumptions, the results show that the model predictions agree satisfactorily with the experiments under the different operating conditions applied.
Adsorption of N2 and CO2 on Activated Carbon, AlO(OH) Nanoparticles, and AlO(OH) Hollow Spheres
(2015)
Adsorption behaviors of nitrogen and CO2 on Norit R1 Extra and AlO(OH) nanoparticles and hollow spheres were measured under different temperature and pressure conditions using a magnetic suspension balance. Independent from the substrate investigated, all isotherms increase at lower pressure, reach a maximum, and then decrease with increasing pressure. In addition, selected experimental data were correlated with different model approaches and compared with reliable literature data. In case of CO2 on AlO(OH), capillary condensation was observed at two defined temperatures. The results suggest that the conversion of the liquid into a supercritical adsorbate phase does not take place suddenly.
Eine neue Prozessidee zur Auftrennung racemischer Wirkstoffe unter Verwendung nanoskaliger AlO(OH)‐Hohlkugeln als Adsorbens und überkritischen Kohlenstoffdioxides (sc‐CO2) als Lösungsmittel wird vorgestellt. Zur Auslegung des Prozesses werden Untersuchungen zur Abscheidung der racemischen Wirkstoffe (RS)‐Flurbiprofen, (RS)‐Ibuprofen, (RS)‐Ketoprofen und den reinen Enantiomeren (R)‐Flurbiprofen, (S)‐Ibuprofen und (S)‐Ketoprofen an AlO(OH)‐Hohlkugeln präsentiert und bewertet. Zudem werden Adsorptionsdaten von gasförmigem CO2 an den Hohlkugeln und kommerziellen AlO(OH)‐Partikeln, die mit einer Magnetschwebewaage ermittelt wurden, verglichen. Abschließend werden erste Ergebnisse von orientierenden Versuchen zur Adsorption von racemischem Flurbiprofen aus sc‐CO2 an den Hohlkugeln vorgestellt.
A systematic toxicological analysis procedure using high-performance thin layer chromatography in combination with fibre optical scanning densitometry for identification of drugs in biological samples is presented. Two examples illustrate the practicability of the technique. First, the identification of a multiple intake of analgesics: codeine, propyphenazone, tramadol, flupirtine and lidocaine, and second, the detection of the sedative diphenhydramine. In both cases, authentic urine specimens were used. The identifications were carried out by an automatic measurement and computer-based comparison of in situ UV spectra with data from a compiled library of reference spectra using the cross-correlation function. The technique allowed a parallel recording of chromatograms and in situ UV spectra in the range of 197–612 nm. Unlike the conventional densitometry, a dependency of UV spectra by concentration of substance in a range of 250–1000 ng/spot was not observed.
Wireless communication technologies play a major role to enable megatrends like Internet of Things (IoT) and Industry 4.0. The Narrowband Wireless WAN (NBWWAN) introduced to meet the long range and low power requirements of spatially distributed wireless communication use cases. These networks introduce additional challenges in testing because the network topology and RF characteristics become particularly complex and thus a multitude of different scenarios must be tested. This paper describes the infrastructure for automated testing of radio communication and for systematic measurements of the network performance of NBWWAN.
What emotional effects does gamification have on users who work or learn with repetitive tasks? In this work, we use biosignals to analyze these affective effects of gamification. After a brief discussion of related work, we describe the implementation of an assistive system augmenting work by projecting elements for guidance and gamification. We also show how this system can be extended to analyse users' emotions. In a user study, we analyse both biosignals (facial expressions and electrodermal activity), and regular performance measures (error rate and task completion time).
For the performance measures, the results confirm known effects like increased speed and slightly increased error rate. In addition, the analysis of the biosignals provides strong evidence for two major affective effects: the gamification of work and learning tasks incites highly significantly more positive emotions and increases emotionality altogether. The results add to the design of assistive systems, which are aware of the physical as well as the affective context.
AG Köln "Kuh-Fotos"
(2010)