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Gas adsorption studies of CO2 and N2 in spatially aligned double-walled carbon nanotube arrays
(2013)
Gas adsorption studies (CO2 and N2) over a wide pressure range on vertically, highly aligned dense double-walled carbon nanotube arrays of high purity and high specific surface area are reported. At high pressures, the adsorption capacity of these materials was found to be comparable to those of metal organic frameworks and mesoporous molecular sieves. These highly aligned CNT arrays were chemically modified by treating with oxygen plasma and structurally modified by decreasing the diameter of individual carbon nanotubes. Oxygen plasma treatment led to grafting of a large number of C–O functional groups onto the CNT surface, which further increased the gas adsorption capacity. It was found that gas adsorption is dependent on tube diameter and increases with decrease of the individual CNT diameter in the CNT bundles. As results of our studies we have found that at lower pressure regimes, plasma functionalized carbon nanotubes exhibit better adsorption characteristics whereas at higher pressures, lower diameter carbon nanotube structures exhibited better gas adsorption characteristics.
Background: Increasing awareness of the importance of evidence-based medicine is demonstrated not only by an increasing number of articles addressing it but also by a specialty-wide evidence-based medicine initiative. The authors critically analyzed the quality of reporting of randomized controlled trials published in this Journal over a 21-year period (1990 to 2010).
Methods: A hand search was conducted, including all issues of Plastic and Reconstructive Surgery from January of 1990 to December of 2010. All randomized controlled trials published during this time period were identified with the Cochrane decision tree for identification of randomized controlled trials. To assess the quality of reporting, a modification of the checklist of the Consolidated Standard of Reporting Trials Statement was used.
Results: Of 7121 original articles published from 1990 to 2010 in the Journal, 159 (2.23 percent) met the Cochrane criteria. A significant increase in the absolute number of randomized controlled trials was seen over the study period (p < 0.0001). The median quality of these trials from 1990 to 2010 was "fair," with a trend toward improved quality of reporting over time (p = 0.127).
Conclusions: A favorable trend is seen with respect to an increased number of published randomized controlled trials in Plastic and Reconstructive Surgery. Adherence to standard reporting guidelines is recommended, however, to further improve the quality of reporting. Consideration may be given to providing information regarding the quality of reporting in addition to the "level of evidence pyramid," thus facilitating critical appraisal.
The design of control systems of concentrator photovoltaic power plants will be more challenging in the future. Reasons are cost pressure, the increasing size of power plants, and new applications for operation, monitoring and maintenance required by grid operators, manufacturers and plant operators. Concepts and products for fixed-mounted photovoltaic can only partly be adapted since control systems for concentrator photovoltaic are considerable more complex due to the required high accurate sun-tracking. In order to assure reliable operation during a lifetime of more than 20 years, robustness of the control system is one crucial design criteria. This work considers common engineering technics for robustness, safety and security. Potential failures of the control system are identified and their effects are analyzed. Different attack scenarios are investigated. Outcomes are design criteria that encounter both: failures of system components and malicious attacks on the control system of future concentrator photovoltaic power plants. Such design criteria are a transparent state management through all system layers, self-tests and update capabilities for security concerns. The findings enable future research to develop a more robust and secure control system for concentrator photovoltaics when implementing new functionalities in the next generation.
The communication system of a large-scale concentrator photovoltaic power plant is very challenging. Manufacturers are building power plants having thousands of sun tracking systems equipped with communication and distributed over a wide area. Research is necessary to build a scalable communication system enabling modern control strategies. This poster abstract describes the ongoing work on the development of a simulation model of such power plants in OMNeT++. The model uses the INET Framework to build a communication network based on Ethernet. First results and problems of timing and data transmission experiments are outlined. The model enables research on new communication and control approaches to improve functionality and efficiency of power plants based on concentrator photovoltaic technology.
In the brain-cell microenvironment, diffusion plays an important role: apart from delivering glucose and oxygen from the vascular system to brain cells, it also moves informational substances between cells. The brain is an extremely complex structure of interwoven, intercommunicating cells, but recent theoretical and experimental works showed that the classical laws of diffusion, cast in the framework of porous media theory, can deliver an accurate quantitative description of the way molecules are transported through this tissue. The mathematical modeling and the numerical simulations are successfully applied in the investigation of diffusion processes in tissues, replacing the costly laboratory investigations. Nevertheless, modeling must rely on highly accurate information regarding the main parameters (tortuosity, volume fraction) which characterize the tissue, obtained by structural and functional imaging. The usual techniques to measure the diffusion mechanism in brain tissue are the radiotracer method, the real time iontophoretic method and integrative optical imaging using fluorescence microscopy. A promising technique for obtaining the values for characteristic parameters of the transport equation is the direct optical investigation using optical fibers. The analysis of these parameters also reveals how the local geometry of the brain changes with time or under pathological conditions. This paper presents a set of computations concerning the mass transport inside the brain tissue, for different types of cells. By measuring the time evolution of the concentration profile of an injected substance and using suitable fitting procedures, the main parameters characterizing the tissue can be determined. This type of analysis could be an important tool in understanding the functional mechanisms of effective drug delivery in complex structures such as the brain tissue. It also offers possibilities to realize optical imaging methods for in vitro and in vivo measurements using optical fibers. The model also may help in radiotracer biomarker models for the understanding of the mechanism of action of new chemical entities.
Betrugsmaschen werden wohl nie aussterben. Immer wieder wachsen neue Opfer nach, die unwissend, leichtgläubig oder schnell einzuschüchtern sind. Privatleute und Unternehmer werden dabei gleichermaßen Opfer von geschickten "Vertragsabschlusskonstruktionen", bei deren Durchsetzung zuweilen auch Juristen beteiligt sind. Dieser Beitrag befasst sich mit aktuellen Entwicklungen und Entscheidungen im deutschen Recht zu eben diesen Fällen.
Ein Beschluss des LG Duisburg (LG Duisburg, Beschl. v. 6.11.2012 – 32 Qs-245 UJs 89/11-49/12) und ein im Anschluss daran erlassener Haftbefehl des AG Duisburg gegen den Mitarbeiter eines Internetbewertungsportals wegen einer verweigerten Zeugenaussage hat eine heftige Debatte über die Reichweite des Zeugnisverweigerungsrechtes für die Mitarbeiter bestimmter Onlinedienste ausgelöst. Zur gleichen Zeit beschäftigte sich das LG Augsburg mit einem nicht unähnlichen Fall bezogen auf einen Eintrag im Onlineforum eines Verlagshauses. Die aufgeworfenen Fragen sind Gegenstand des folgenden Beitrags.
Häufig findet sich im Impressum eines Onlineangebots ein Hinweis auf eine der evtl. anwaltlichen Abmahnung vorzuschaltende Kontaktaufnahme mit dem Betreiber. Während ein solcher Disclaimer für den Abmahner grundsätzlich keine Rechtswirkung entfaltet, ist fraglich, ob sich für den Verwender selbst im Hinblick auf eigene Abmahnungen Konsequenzen aus einem derartigen Hinweis ergeben. Mit dieser Frage haben sich zwei Oberlandesgerichte auseinandergesetzt und sind zu gegenläufigen Ergebnissen gelangt.
The aim of the paper was to investigate the energy saved in the shift from separate generation of thermal and electrical energy to trigeneration at the energy facility in Offenburg University of Applied Sciences (HS OG). The energy facility at HS OG used a traditional heating system and electricity from grid until 2007 afterwhich they installed a trigeneration system to meet its continuously changing dynamic thermal and electrical demands. This paper highlights the methodology that had been derived to analyze and study the effect of this shift based on the energy consumption data available from 2004 to 2011, which were scarce due to the limited monitoring. From the energy analysis, we concluded that 8 % primary energy was saved in this shift at the energy facility of HS OG. And from economical perspective 5 % useful thermal energy and 39 % useful electrical energy was saved in this shift at the energy facility of HS OG. Nevertheless, the term energy saving, in general, is very relative and complex to define in such a changeover.
Zielvereinbarungen sollen SMART formuliert werden, um die Leistungsbereitschaft von Mitarbeitern optimal zu fördern - so wird es zumindest in der praxisorientierten betriebswirtschaftlichen Literatur propagiert. Ob Zielvereinbarungen, die spezifisch, messbar, erreichbar, relevant für das Unternehmen und zeitlich terminiert sind, wirklich eine höhere Leistungsbereitschaft zur Folge haben, wird im Folgenden auf Basis einer empirischen Untersuchung überprüft.
In den kreativen Industrien werden Innovationen traditionell in Clustern entwickelt und vermarktet, denken wir nur an die extrem arbeitsteilige Produktion und Vermarktung eines Spielfilms. Eine recht neue Entwicklung stellt jedoch die Einbindung von Rezipienten und Werbekunden in den innovativen Prozess dar. Offen ist, wie diese zu dauerhaften Partnern in einem Kreativecluster avancieren können. Dazu sollen im Folgenden einige aktuelle Entwicklungen im Mediensektor skizziert werden.
Die Zuverlässigkeit und Betriebssicherheit von Feldgeräten ist für den sicheren und wirtschaftlichen Betrieb prozesstechnischer Anlagen unerlässlich. Ein entscheidender Faktor ist die Widerstandskraft der Geräte gegen die herrschenden Umgebungsbedingungen. Durch Korrosionsschäden hervorgerufene Anlagenstillstände zeigen, dass diesem Thema nicht immer die notwendige Aufmerksamkeit gewidmet wird, obwohl die korrosionsbedingten wirtschaftlichen Schäden immens sind. Wie man mit dem Thema Korrosionsschutz ernsthaft umgehen kann, zeigt dieser Beitrag am Beispiel elektrischer Stellantriebe.
In this paper we present a model of the discharge of a lithium–oxygen battery with aqueous electrolyte. Lithium–oxygen batteries (Li–O2) have recently received great attention due to their large theoretical specific energy. Advantages of the aqueous design include the stability of the electrolyte, the long experience with gas diffusion electrodes (GDEs), and the solubility of the reaction product lithium hydroxide. However, competitive specific energies can only be obtained if the product is allowed to precipitate. Here we present a dynamic one-dimensional model of a Li–O2 battery including a GDE and precipitation of lithium hydroxide. The model is parameterized using experimental data from the literature. We demonstrate that GDEs remove power limitations due to slow oxygen transport in solutions and that lithium hydroxide tends to precipitate on the anode side. We discuss the system architecture to engineer where nucleation and growth predominantly occurs and to optimize for discharge capacity.
A variety of different additive manufacturing processes have been available for the last three decades. Some of these technologies are very energy-intensive, e.g. laser technology and the manufacture of metal powder. In many areas, the detailed investigation of the energy and material consumption of these new manufacturing methods is still in the beginning. This paper investigates energy and material consumption using 3D colour printing (3DP) as an example. The specific energy required for the layering can be determined from this. This then forms the basis for a comparison of the specific energy consumption with other generative (e.g. Fused Layer Modelling—FLM) and also conventional production processes (e.g. milling and grinding). Thus process selection is facilitated by introducing the specific energy for layering. In addition several variables, in which resource consumption can be reduced are also investigated and compared. For example the influence of the geometry or the positioning of the 3D-printed part in the design space on the consumption are investigated. But also the measuring of different batch sizes is compared. Using the results found, the use of 3D printing can initially be optimized so that less energy, resources and manufacturing time are required.
Mit längerfristigen Nutzerbefragungen in zwei unmittelbar benachbarten Bürogebäuden in Freiburg wurden das Temperaturempfinden der Nutzer und deren Zufriedenheit mit dem thermischen Raumkomfort zweimal täglich erfasst. Ein Bürogebäude wird im Sommer mit einem maschinellen Nachtlüftungskonzept konditioniert und das zweite verfügt über eine Betonkerntemperierung und eine Zu‐ und Abluftanlage. Auf Basis der vorhandenen Daten aus der Erhebung wurde mit Hilfe von Regressionsanalysen ein Modell zur Vorhersage der Komforttemperatur berechnet und mit den Modellen in DIN EN 15251 verglichen.
A series of isostructural 3D coordination polymers (3)∞[M(tdc)(bpy)] (M(2+) = Zn(2+), Cd(2+), Co(2+), Fe(2+); tdc(2-) = 2,5-thiophenedicarboxylate; bpy = 4,4'-bipyridine) was synthesized and characterized by X-ray diffraction, thermal analysis, and gas adsorption measurements. The materials show high thermal stability up to approximately 400 °C and a solvent induced phase transition. Single crystal X-ray structure determination was successfully performed for all compounds after the phase transition. In the zinc-based coordination polymer, various amounts of a second type of metal ions such as Co(2+) or Fe(2+) could be incorporated. Furthermore, the catalytic behavior of the homo- and heteronuclear 3D coordination polymers in an oxidation model reaction was investigated.
In this paper the fatigue life of three cast iron materials, namely EN-GJS-700, EN-GJV-450 and EN-GJL-250, is predicted for combined thermomechanical fatigue and high cycle fatigue loading. To this end, a mechanism-based model is used, which is based on microcrack growth. The model considers crack growth due to low frequency loading (thermomechanical and low cycle fatigue) and due to high cycle fatigue. To determine the model parameters for the cast iron materials, fatigue tests are performed under combined loading and crack growth is measured at room temperature using the replica technique. Superimposed high cycle fatigue leads to an accelerated crack growth as soon as a critical crack length and thus the threshold stress intensity factor is exceeded. The model takes this effect into account and predicts the fatigue lives of all cast iron materials investigated under combined loadings very well.
In this paper, an unconditionally stable algorithm for the numerical integration and finite-element implementation of a class of pressure dependent plasticity models with nonlinear isotropic and kinematic hardening is presented. Existing algorithms are improved in the sense that the number of equations to be solved iteratively is significantly reduced. This is achieved by exploitation of the structure of Armstrong-Frederik-type kinematic hardening laws. The consistent material tangent is derived analytically and compared to the numerically computed tangent in order to validate the implementation. The performance of the new algorithm is compared to an existing one that does not consider the possibility of reducing the number of unknowns to be iterated. The algorithm is used to implement a time and temperature dependent cast iron plasticity model, which is based on the pressure dependent Gurson model, in the finite-element program ABAQUS. The implementation is applied to compute stresses and strains in a large-scale finite-element model of a three cylinder engine block. This computation proofs the applicability of the algorithm in industrial practice that is of interest in applied sciences.
A Localization System Using Inertial Measurement Units from Wireless Commercial Handheld Devices
(2013)
This paper describes a newly developed technology for the calculation of trajectories of mobile objects, which is based on commercially available sensors being integrated into modern mobile phones and other gadgets. First, a step counting technique was implemented. Second, a novel step length estimator is proposed. These two algorithms utilize the data from accelerometer sensor only. Third, the heading information was obtained using a gyroscope with complementary filter in quaternion form. The combined algorithm was implemented on a low-power ARM processor to provide the trajectory points relative to an initial point. The proposed technique was tested by 10 subjects, in different shoes with different paces. The dependence of the performance of the technology on the attaching point of the mobile device is weak. The proposed algorithms have better balance and estimation accuracy and depend in less degree on the variety in physical parameters of people in comparison with the existing techniques. In experiments inertial measurement units were mounted in different places, i.e. in the hand, in trousers or in T-shirt pockets. The return position error did not exceed 5% of the total travelled distance for all performed tests.
Ranging errors are inevitable in all local positioning systems, including those based on Time-of-Flight (ToF) technique. Results of experiments show that the major cause for these errors is a signal degradation from multipath propagation. This effect is especially critical in case of Non-Light-of-Sight (NLOS) conditions. This paper describes causes that affects ranging errors for nanoLOC™-TOF-technology and presents estimations for the probability density functions of such errors under different NLOS conditions. The provided estimations allow the improvement of the accuracy of the localization through the subsequent mitigation of the ranging errors from the measurements. Additionally, it is proposed to increase the number of cases of NLOS-conditions for the improvement of the accuracy.
The lifetime and performance of solid-oxide fuel cells (SOFC) and electrolyzer cells (SOEC) can be significantly degraded by oxidation of nickel within the electrode and support structures. This paper documents a detailed computational model describing nickel oxide (NiO) formation as a growing film layer on top of the nickel phase in Ni/YSZ composite electrodes. The model assumes that the oxidation rate is controlled by transport of ions across the film (Wagner's theory). The computational model, which is implemented in a two-dimensional continuum framework, facilitates the investigation of alternative chemical reaction and transport mechanisms. Model predictions agree well with a literature experimental measurement of oxidation-layer growth. In addition to providing insight in interpreting experimental observations, the model provides a quantitative predictive capability for improving electrode design and controlling operating conditions.
The combination of fossil-derived fuels with ethanol and methanol has acquired relevance and attention in several countries in recent years. This trend is strongly affected by market prices, constant geopolitical events, new sustainability policies, new laws and regulations, etc. Besides bio-fuels these materials also include different additives as anti-shock agents and as octane enhancer. Some of the chemical compounds in these additives may have harmful properties for both environment and public health (besides the inherent properties, like volatility). We present detailed Raman spectral information from toluene (C7H8) and ethanol (C2H6O) contained in samples of ElO gasoline-ethanol blends. The spectral information has been extracted by using a robust, high resolution Fourier-Transform Raman spectrometer (FT-Raman) prototype. This spectral information has been also compared with Raman spectra from pure additives and with standard Raman lines in order to validate its accuracy in frequency. The spectral information is presented in the range of 0 cm-1 to 3500 cm-1 with a resolution of 1.66cm-1. This allows resolving tight adjacent Raman lines like the ones observed around 1003cm-1 and 1030cm-1 (characteristic lines of toluene). The Raman spectra obtained show a reduced frequency deviation when compared to standard Raman spectra from different calibration materials. The FT-Raman spectrometer prototype used for the analysis consist basically of a Michelson interferometer and a self-designed photon counter cooled down on a Peltier element arrangement. The light coupling is achieved with conventional62.5/125μm multi-mode fibers. This FT-Raman setup is able to extract high resolution and frequency precise Raman spectra from the additives in the fuels analyzed. The proposed prototype has no additional complex hardware components or costly software modules. The mechanical and thermal disturbances affecting the FT-Raman system are mathematically compensated by accurately extracting the optical path information of the Michelson interferometer. This is accomplished by generating an additional interference pattern with a λ = 632.8 nm Helium-Neon laser (HeNe laser). It enables the FT-Raman system to perform reliable and clean spectral measurements from the materials under observation.
Raman spectra from three different binary gasoline-ethanol blends (with ratios 95:5, 90:10, and 85:15) have been obtained by using a low-cost, frequency precise Fourier-transform Raman spectrometer (FT-Raman) prototype. The spectral information is presented in the range of 0 to 3500 cm-1 with a resolution of 1.66 cm-1, which is greater than the required for most liquid and solid chemical samples. This set-up delivers spectral information about the sample with a reduced spectral deviation compared to theoretical values (less than 0.4 cm-1 without compensation for instrumental response). The robust and highly fexible FT-Raman prototype presented for the spectral analysis, consisting mainly of a Michelson interferometer and a self-designed photon counter, is able to deliver high resolution and frequency precise Raman spectra from the gasoline-ethanol blends comparable to the obtained by using commercial devices. This FT-Raman set-up does not need additional complex hardware or software control and relies on re-sampling and interpolation algorithms. The qualitative spectral information obtained has been used to calculate the proportion of gasoline and ethanol present in the used chemical samples without using extra calibrations methods or chemical markers.
In the dual membrane fuel cell (DM-Cell), protons formed at the anode and oxygen ions formed at the cathode migrate through their respective dense electrolytes to react and form water in a porous composite layer called dual membrane (DM). The DM-Cell concept was experimentally proven (as detailed in Part I of this paper). To describe the electrochemical processes occurring in this novel fuel cell, a mathematical model has been developed which focuses on the DM as the characteristic feature of the DM-Cell. In the model, the porous composite DM is treated as a continuum medium characterized by effective macro-homogeneous properties. To simulate the polarization behavior of the DM-Cell, the potential distribution in the DM is related to the flux of protons and oxygen ions in the conducting phases by introducing kinetic and transport equations into charge balances. Since water pressure may affect the overall formation rate, water mass balances across the DM and transport equations are also considered. The satisfactory comparison with available experimental results suggests that the model provides sound indications on the effects of key design parameters and operating conditions on cell behavior and performance.
Unter dem europäischen Programm Intelligent Energy for Europe (IEE) fanden sich acht europäische Partner zusammen, um im Rahmen des Projektes ThermCo Lüftungs‐ und Kühlenergiekonzepte für Nichtwohngebäude mit niedrigem Energieeinsatz im Hinblick auf die Energieeffizienz und den thermischen Raumkomfort zu bewerten (siehe Teil 1 dieser Veröffentlichung in Bauphysik 34 (2012), Heft 6. Mit Hilfe einer Simulationsstudie für ein typisches Bürogebäude wird das Potenzial unterschiedlicher Lüftungs‐ und Kühlstrategien unter Berücksichtigung von Energieeffizienz und Raumkomfort für verschiedene europäische Klimazonen bewertet. Die Ergebnisse weisen eine hohe Wirksamkeit von Nachtlüftungskonzepten im nord‐europäischen Sommerklima mit verhältnismäßig niedrigen Außentemperaturen nach. Im mitteleuropäischen Sommerklima bietet das Erdreich ein ausreichend niedriges Temperaturniveau für den effizienten Einsatz von wassergeführten Flächentemperiersystemen. Im südeuropäischen Sommerklima kann eine aktive Kühlung über Luft die hohen und schnell fluktuierenden Kühllasten effizient abführen.