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In diesem Beitrag werden die Bereitstellungskosten flexibler Systemkomponenten im deutschen Stromsystem analysiert, zu deren Quantifizierung eine einheitliche Methodik entwickelt wird. Dabei ist das Ziel des Beitrags, zeitlich differenzierte Kostenpotenzialkurven für die Jahre 2015 und 2030 zu erarbeiten, anhand derer die energiespezifischen Kosten der markt- und systemdienlichen Flexibilitätsbereitstellung verglichen und die einzelnen Flexibilitätsoptionen in einen Gesamtkontext eingeordnet werden können.
Der Einsatz flexibler Systemkomponenten wird hierzu in die drei Hauptphasen (1) Vorhaltung, (2) Abruf und (3) Einsatzfolgen unterteilt, woraus sich drei kongruente Kostengruppen ableiten lassen, nach denen die einzelnen Kostenbestandteile identifiziert und als Ergebnis die Bereitstellungskosten quantifiziert werden. Neben fossil-thermischen Kraftwerken werden dabei bspw. die Kraft-Wärme-Kopplung, Biogasanlagen, Pumpspeicher- und Laufwasserkraftwerke sowie steuerbare Lasten untersucht.
Zur anschließenden Abbildung der teils negativen Bereitstellungskosten wird die herkömmliche Darstellungsform der Merit Order entlang der Ordinate um die Abbildung negative Werte erweitert und die Abszisse für die Abbildung negativer Flexibilität in umgekehrter Reihenfolge angeordnet. Das Ergebnis sind zwei zusammenhängende Graphen, mittels derer sich die Bereitstellungskosten verschiedener Flexibilitätsoptionen gegenüberstellen und anschaulich vergleichen lassen.
Durch die Festlegung eines Rahmenszenarios zur Entwicklung des deutschen Stromsystems bis zum Jahr 2030 wird anschließend auch die zukünftige Perspektive der Flexibilitätsbereitstellung in Deutschland analysiert. Aus den Ergebnissen lässt sich ableiten, dass der deutsche Kraftwerkspark mit einem fortschreitenden Rückbau der Kohlekraftwerke nur dann zunehmend flexibler wird und auf höhere Schwankungen im Stromnetz reagieren kann, wenn von einem gleichzeitigen Zubau moderner erdgasbetriebener Kraftwerke ausgegangen wird. In diesem Fall steigen die Bereitstellungskosten positiver Flexibilität, was sich beispielsweise durch zukünftig steigende Brennstoffpreise bergründen lässt. Jedoch kann bspw. durch die Transformation der Kraft-Wärme-Kopplung hin zu einer grundsätzlich stromgeführten Fahrweise zukünftig eine vergleichsweise kostengünstige Flexibilitätsbereitstellung erschlossen und somit auch ein gleichbleibendes oder oftmals sogar höheres Flexibilitätsniveau am Markt erreicht werden.
The growing demand for active medical implantable devices requires data and or power links between the implant and the outside world. Every implant has to be encapsulated from the body by a specific housing and one of the most common materials used is titanium or titanium alloy. Titanium thas the necessary properties in terms of mechanical and chemical stability and biocompatibility. However, its electrical conductivity presents a challenge for the electromagnetic transmission of data and power. The proposed paper presents a fast and practical method to determine the necessary transmission parameters for titanium encapsulated implants. Therefore, the basic transformer-transmission-model is used with measured or calculated key values for the inductances. Those are then expanded with correction factors to determine the behavior with the encapsulation. The correction factors are extracted from finite element method simulations. These also enable the analysis of the magnetic field distribution inside of the housing. The simulated transmission properties are very close to the measured values. Additionally, based on lumped elements and magnetic field distribution, the influential parameters are discussed in the paper. The parameter discussion describes how to enhance the transmitted power, data-rate or distance, or to reduce the size of the necessary coils. Finally, an example application demonstrates the usage of the methods.
Electrolyte-gated transistors (EGTs) represent an interesting alternative to conventional dielectric-gating to reduce the required high supply voltage for printed electronic applications. Here, a type of ink-jet printable ion-gel is introduced and optimized to fabricate a chemically crosslinked ion-gel by self-assembled gelation, without additional crosslinking processes, e.g., UV-curing. For the self-assembled gelation, poly(vinyl alcohol) and poly(ethylene-alt-maleic anhydride) are used as the polymer backbone and chemical crosslinker, respectively, and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]) is utilized as an ionic species to ensure ionic conductivity. The as-synthesized ion-gel exhibits an ionic conductivity of ≈5 mS cm−1 and an effective capacitance of 5.4 µF cm−2 at 1 Hz. The ion-gel is successfully employed in EGTs with an indium oxide (In2O3) channel, which shows on/off-ratios of up to 1.3 × 106 and a subthreshold swing of 80.62 mV dec−1.
In den letzten Jahren sind verstärkt große Batteriespeichersysteme in der Mittel- und Hochspannungsebene in Deutschland installiert worden. Neben dem Einsatz für lokale Anwendungszwecke wie Eigenverbrauchsmaximierung oder Lastspitzenkappung sind seit 2016 etwa 250 MW aus Batteriespeichern für die Teilnahme am Markt für Primärregelleistung (PRL) präqualifiziert worden. Damit können bereits 40 % des aktuellen Bedarfs der deutschen Übertragungsnetzbetreiber (ÜNB) gedeckt werden. Für einen zuverlässigen Betrieb von Batteriespeichern sind intelligente Betriebsstrategien erforderlich, die im Rahmen dieser Analyse vorgestellt werden.
The Humboldt Portal has been designed and implemented as part of an ongoing research project to develop an information system on the Internet to share the documents and rare books of Alexander von Humboldt, a 19th century German scientist and explorer, who viewed the natural world holistically and described the harmony of nature among the diversity of the physical world. Even after more than two centuries he is admired for his ability to see the natural world and human nature in the context of a complex network of relationships. The design and implementation of the Humboldt Portal are also oriented to support further research on Humboldt’s intellectual perspective.
Although all of Humboldt's works can be found on the internet as digitized documents, the complexity and internal inter-connectivity of his vision of nature cannot be adequately represented only by digitized papers or scanned documents in digital libraries.
As a consequence a specific portal of the Humboldt's documents was developed, which extends the standards of digital libraries and offers a technical approach for the adequate presentation of highly interconnected data.
Due to the continuous scientific and literary research, new insights and requirements for the digital presentation of Humboldt documents are constantly emerging, so that this article only provides a summary of the concepts realized at now. Consequently, the design and implementation of the Humboldt Portal is both: a consequence of a continuing research project and oriented to support more research on Humboldt´s intellectual holistic perspective, which was an anticipation to the System Approach of the last Century.
Automatic Identification of Travel Locations in Rare Books - Object Oriented Information Management
(2017)
The digital content of the Internet is growing exponentially and mass digitization of printed media opens access to literature, in particular the genre of travel literature from the 18th and 19th century, which consists of diaries or travel books describing routes, observations or inspirations. The identification of described locations in the digital text is a long-standing challenge which requires information technology to supply dynamic links to sources by new forms of interaction and synthesis between humanistic texts and scientific observations.
Using object oriented information technology, a prototype of a software tool is developed which makes it possible to automatically identify geographic locations and travel routes mentioned in rare books. The information objects contain properties such as names and classification codes for populated places, streams, mountains and regions. Together, with the latitudes and longitudes of every single location, it is possible to geo-reference this information in order that all processed and filtered datasets can be displayed by a map application. This method has already been used in the Humboldt Digital Library to present Alexander von Humboldt’s maps and was tested in a case study to prove the correctness and reliability of the automatic identification of locations based on the work of Alexander von Humboldt and Johann Wolfgang von Goethe.
The results reveal numerous errors due to misspellings, change of location names, equality of terms and location names. But on the other hand it becomes very clear that results of the automatic object detection and recognition can be improved by error-free and comprehensive sources. As a result an increase in quality and usability of the service can be expected, accompanied by more options to detect unknown locations in the descriptions of rare books.
In the 19th century Alexander von Humboldt explored the nature and was conceived a new vision of nature that still influences the way we understand the new world. Humboldt believed in the importance of accurate measurements and precise description of observations. His vision of nature included not only facts but also emotions.
Nowadays smart solutions will be developed by using computer technology, which will influence our relationship to nature, our handling of the complexity and diversity of nature itself and the technological influences on the society. Could we avoid a new form of “Colonialism”, when a network of super computers will create a smarter world?
Enzyme‐assisted HPTLC method for the simultaneous analysis of inositol phosphates and phosphate
(2023)
Background
The analysis of myo‐inositol phosphates (InsPx) released by phytases during phytic acid degradation is challenging and time‐consuming, particularly in terms of sample preparation, isomer separation, and detection. However, a fast and robust analysis method is crucial when screening for phytases during protein engineering approaches, which result in a large number of samples, to ensure reliable identification of promising novel enzymes or target variants with improved characteristics, for example, pH range, thermal stability, and phosphate release kinetics.
Results
The simultaneous analysis of several InsPx (InsP1‐InsP4 and InsP5 + 6) as well as free phosphate was established on cellulose HPTLC plates using a buffered mobile phase. Inositol phosphates were subsequently stained using a novel enzyme‐assisted staining procedure. Immobilized InsPx were hydrolyzed by a phytase solution of Quantum® Blueliquid 5G followed by a molybdate reagent derivatization. Resulting blue zones were captured by DAD scan. The method shows good repeatability (intra‐day and intra‐lab) with maximum deviations of the Rf value of 0.01. The HPTLC method was applied to three commercially available phytases at two pH levels relevant to the gastrointestinal tract of poultry (pH 5.5 and pH 3.6) to observe their phytate degradation pattern and thus visualize their InsPx fingerprint.
Conclusion
This HPTLC method presents a semi‐high‐throughput analysis for the simultaneous analysis of phytic acid and the resulting lower inositol phosphates after its enzymatic hydrolysis and is also an effective tool to visualize the InsPx fingerprints and possible accumulations of inositol phosphates.
Over the last few decades, several grid coupling techniques for hierarchically refined Cartesian grids have been developed to provide the possibility of varying mesh resolution in lattice Boltzmann methods. The proposed schemes can be roughly categorized based on the individual grid transition interface layout they are adapted to, namely cell-vertex or cell-centered approaches, as well as a combination of both. It stands to reason that the specific properties of each of these grid-coupling algorithms influence the stability and accuracy of the numerical scheme. Consequently, this naturally leads to a curiosity regarding the extent to which this is the case. The present study compares three established grid-coupling techniques regarding their stability ranges by conducting a series of numerical experiments for a square duct flow, including various collision models. Furthermore the hybrid-recursive regularized collision model, originally introduced for cell-vertex algorithms with co-located coarse and fine grid nodes, has been adapted to cell-centered and combined methods.
Bio, vegan – oder was?
(2023)
Nachhaltigkeit als gesellschaftlicher Wert beeinflusst auch die Haltung der Konsumierenden gegenüber Fleisch- und Wurstkonsum und kann zum Umkippen bisheriger Konsummuster führen (Tipping-Point). Für EDEKA Südwestfleisch und Schwarzwaldhof erfordert dies – aufbauend auf der bisherigen Ausrichtung an Nachhaltigkeit – eine zukunftsorientierte Planung des Sortiments im veganen, vegetarischen, hybriden Sektor und im Bereich Bio-Produkte und Tierwohl. Hierfür muss auch die Kommunikationspolitik angepasst werden, um jüngere Zielgruppen zu erreichen, damit das Dilemma der Fleischwirtschaft (Tierwohl wird gefordert, aber nicht in gleichem Masse gekauft) nicht zu Lasten des Markterfolgs geht.
Deep learning approaches are becoming increasingly important for the estimation of the Remaining Useful Life (RUL) of mechanical elements such as bearings. This paper proposes and evaluates a novel transfer learning-based approach for RUL estimations of different bearing types with small datasets and low sampling rates. The approach is based on an intermediate domain that abstracts features of the bearings based on their fault frequencies. The features are processed by convolutional layers. Finally, the RUL estimation is performed using a Long Short-Term Memory (LSTM) network. The transfer learning relies on a fixed-feature extraction. This novel deep learning approach successfully uses data of a low-frequency range, which is a precondition to use low-cost sensors. It is validated against the IEEE PHM 2012 Data Challenge, where it outperforms the winning approach. The results show its suitability for low-frequency sensor data and for efficient and effective transfer learning between different bearing types.
Background:
Ankle braces aim to reduce lateral ankle sprains. Next to protection, factors influencing user compliance, such as sports performance, motion restriction, and users’ perceptions, are relevant for user compliance and thus injury prevention. Novel adaptive protection systems claim to change their mechanical behavior based on the intensity of motion (eg, the inversion velocity), unlike traditional passive concepts of ankle bracing.
Purpose:
To compare the performance of a novel adaptive brace with 2 passive ankle braces while considering protection, sports performance, freedom of motion, and subjective perception.
Study Design:
Controlled laboratory study.
Methods:
The authors analyzed 1 adaptive and 2 passive (one lace-up and one rigid brace) ankle braces, worn in a low-cut, indoor sports shoe, which was also the no-brace reference condition. We performed material testing using an artificial ankle joint system at high and low inversion velocities. Further, 20 male, young, healthy team sports athletes were analyzed using 3-dimensional motion analysis in sports-related movements to address protection, sports performance, and active range of motion dimensions. Participants rated subjective comfort, stability, and restriction experienced when using the products.
Results:
Subjective stability rating was not different between the adaptive and passive systems. The rigid brace was superior in restricting peak inversion during the biomechanical testing compared with the passive braces. However, in the material test, the adaptive brace increased its stiffness by approximately 400% during the fast compared with the slow inversion velocities, demonstrating its adaptive behavior and similar stiffness values to passive braces. We identified minor differences in sports performance tasks. The adaptive brace improved active ankle range of motion and subjective comfort and restriction ratings.
Conclusion:
The adaptive brace offered similar protective effects in high-velocity inversion situations to those of the passive braces while improving range of motion, comfort, and restriction rating during noninjurious motions.
Clinical Relevance:
Protection systems are only effective when used. Compared with traditional passive ankle brace technologies, the novel adaptive brace might increase user compliance by improving comfort and freedom of movement while offering similar protection in injurious situations.
The bandwidth behavior of graded-index multimode fibers (GI-MMFs) for different launching conditions is investigated to understand and characterize the effect of differential mode delay. In order to reduce the launch-power distribution the near field of a single-mode fiber is used to produce a controlled restricted launch. The baseband response is measured by observing the broadening of a narrow input pulse (time-domain measurement). The paper verifies the degradation in bandwidth due to profile distortion by scanning the spot of the single-mode fiber with a transversal offset from the center of the test sample. In addition, the impact of the launch-power distribution tuned by different spot-size diameters is demonstrated. Measurements were taken on ‘older’ 50-μm and 62.5-μm GI-MMFs as well as on laser-performance-optimized fibers more recently developed.
In this paper, the time- and temperature-dependent cyclic ratchetting plasticity of the nickel-based alloy IN100 is experimentally investigated in strain-controlled experiments in the temperature range from 300 °C to 1050 °C. To this end, uniaxial material tests are performed with complex loading histories designed to activate phenomena as strain rate dependency, stress relaxation as well as the Bauschinger effect, cyclic hardening and softening, ratchetting and recovery from hardening. Plasticity models with different levels of complexity are presented that consider these phenomena, and a strategy is derived to determine the multitude of temperature-dependent material properties of the models in a step-by-step procedure based on sub-sets of experimental data of isothermal experiments. The models and the material properties are validated based on the results of non-isothermal experiments. A good description of the time- and temperature-dependent cyclic ratchetting plasticity of IN100 is obtained for isothermal as well as non-isothermal loading with models including ratchetting terms in the kinematic hardening law and the material properties obtained with the proposed strategy.
Relationships between External, Wearable Sensor-Based, and Internal Parameters: A Systematic Review
(2023)
Micro electro-mechanical systems (MEMS) are used to record training and match play of intermittent team sport athletes. Paired with estimates of internal responses or adaptations to exercise, practitioners gain insight into players’ dose–response relationship which facilitates the prescription of the training stimuli to optimize performance, prevent injuries, and to guide rehabilitation processes. A systematic review on the relationship between external, wearable-based, and internal parameters in team sport athletes, compliant with the PRISMA guidelines, was conducted. The literature research was performed from earliest record to 1 September 2020 using the databases PubMed, Web of Science, CINAHL, and SportDISCUS. A total of 66 full-text articles were reviewed encompassing 1541 athletes. About 109 different relationships between variables have been reviewed. The most investigated relationship across sports was found between (session) rating of perceived exertion ((session-)RPE) and PlayerLoad™ (PL) with, predominantly, moderate to strong associations (r = 0.49–0.84). Relationships between internal parameters and highly dynamic, anaerobic movements were heterogenous. Relationships between average heart rate (HR), Edward’s and Banister’s training impulse (TRIMP) seem to be reflected in parameters of overall activity such as PL and TD for running-intensive team sports. PL may further be suitable to estimate the overall subjective perception. To identify high fine-structured loading—relative to a certain type of sport—more specific measures and devices are needed. Individualization of parameters could be helpful to enhance practicality.
In this paper, a temperature-dependent viscoplasticity model is presented that describes thermal and cyclic softening of the hot work steel X38CrMoV5-3 under thermomechanical fatigue loading. The model describes the softening state of the material by evolution equations, the material properties of which can be determined on the basis of a defined experimental program. A kinetic model is employed to capture the effect of coarsening carbides and a new isotropic cyclic softening model is developed that takes history effects during thermomechanical loadings into account. The temperature-dependent material properties of the viscoplasticity model are determined on the basis of experimental data measured in isothermal and thermomechanical fatigue tests for the material X38CrMoV5-3 in the temperature range between 20 and 650 ∘C. The comparison of the model and an existing model for isotropic softening shows an improved description of the softening behavior under thermomechanical fatigue loading. A good overall description of the experimental data is possible with the presented viscoplasticity model, so that it is suited for the assessment of operating loads of hot forging tools.
BACKGROUND
Various neutral and alkaline peptidases are commercially available for use in protein hydrolysis under neutral to alkaline conditions. However, the hydrolysis of proteins under acidic conditions by applying fungal aspartic peptidases (FAPs) has not been investigated in depth so far. The aim of this study, thus, was to purify a FAP from the commercial enzyme preparation, ROHALASE® BXL, determine its biochemical characteristics, and investigate its application for the hydrolysis of food and animal feed proteins under acidic conditions.
RESULTS
A Trichoderma reesei derived FAP, with an apparent molecular mass of 45.8 kDa (sodium dodecyl sulfate–polyacrylamide gel electrophoresis; SDS-PAGE) was purified 13.8-fold with a yield of 37% from ROHALASE® BXL. The FAP was identified as an aspartate protease (UniProt ID: G0R8T0) by inhibition and nano-LC-ESI-MS/MS studies. The FAP showed the highest activity at 50°C and pH 4.0. Monovalent cations, organic solvents, and reducing agents were tolerated well by the FAP. The FAP underwent an apparent competitive product inhibition by soy protein hydrolysate and whey protein hydrolysate with apparent Ki-values of 1.75 and 30.2 mg*mL−1, respectively. The FAP showed promising results in food (soy protein isolate and whey protein isolate) and animal feed protein hydrolyses. For the latter, an increase in the soluble protein content of 109% was noted after 30 min.
CONCLUSION
Our results demonstrate the applicability of fungal aspartic endopeptidases in the food and animal feed industry. Efficient protein hydrolysis of industrially relevant substrates such as acidic whey or animal feed proteins could be conducted by applying fungal aspartic peptidases. © 2022 Society of Chemical Industry.
This review provides an overview on the production and analysis techniques of antioxidative peptides from food proteins. Regarding the production of antioxidative peptides, interlinked factors must be considered. Depending on the protein substrate, different peptidases or peptidase systems containing multiple enzymes as well as a specific production process must be chosen. The antioxidative peptides might be produced in a batch process including multiple pre- and post-treatments, besides the hydrolyses with peptidases itself. As an alternative, the potential of continuous production systems is discussed in this review. Furthermore, robust analyses tools are needed to gain control of the process and final product properties. With no standardized methodology available for antioxidative peptide evaluation, pros and cons of various strategies for peptide separation and antioxidative measurement are discussed in this review. Therefore, this review provides a roadmap for antioxidative peptide generation from various sources for research and development as well as for potential industrial use.
Gas Analysis and Optimization of Debinding and Sintering Processes for Metallic Binder-Based AM*
(2022)
Binder-based additive manufacturing processes for metallic
AM components in a wide range of applications usually use
organic binders and process-related additives that must be
thermally removed before sintering. Debinding processes are
typically parameterized empirically and thus far from the optimum.
Since debinding based on thermal decomposition processes
of organic components and the subsequent thermochemical
reactions between process atmosphere and metal
powder materials make uncomplicated parameterization difficult,
in-situ instrumentation was introduced at Fraunhofer
IFAM. This measurement method relies on infrared spectroscopy
and mass spectrometry in various furnace concepts to
understand the gas processes of decomposition of organic
components and the subsequent thermochemical reactions
between the carrier gas atmosphere and the metal part, as well
as their kinetics. This method enables an efficient optimization
of the temperature-time profiles and the required atmosphere
composition to realize dense AM components with low contamination.
In the paper, the optimization strategy is presented,
and the achievable properties are illustrated using a fused
filament fabrication (FFF) component example made of 316L
stainless steel.
In the literature, many studies have described the 3D printing of ceramic-based scaffolds (e.g., printing with calcium phosphate cement) in the form of linear structures with layer rotations of 90°, although no right angles can be found in the human body. Therefore, this work focuses on the adaptation of biological shapes, including a layer rotation of only 1°. Sample shapes were printed with calcium phosphate cement using a 3D Bioplotter from EnvisionTec. Both straight and wavy spokes were printed in a round structure with 12 layers. Depending on the strand diameter (200 and 250 µm needle inner diameter) and strand arrangement, maximum failure loads of 444.86 ± 169.39 N for samples without subsequent setting in PBS up to 1280.88 ± 538.66 N after setting in PBS could be achieved.
Die Optimierung der Auftragsterminierung und Einsteuerungsreihenfolge hat großen Einfluss auf die Produktivität von Fertigungssystemen. Genetische Algorithmen und Simulation sind verbreitete Werkzeuge zur Optimierung. Dieser Beitrag beschreibt einen neuen Ansatz zur Optimierung durch einen genetischen Algorithmus und der Simulation in dynamischen Modellen. Eine illustrative Fallstudie validiert den Ansatz und zeigt das Potenzial zur ganzheitlichen Verbesserung von Fertigungssystemen auf.
Inadequate mechanical compliance of orthopedic implants can result in excessive strain of the bone interface, and ultimately, aseptic loosening. It is hypothesized that a fiber-based biometal with adjustable anisotropic mechanical properties can reduce interface strain, facilitate continuous remodeling, and improve implant survival under complex loads. The biometal is based on strategically layered sintered titanium fibers. Six different topologies are manufactured. Specimens are tested under compression in three orthogonal axes under 3-point bending and torsion until failure. Biocompatibility testing involves murine osteoblasts. Osseointegration is investigated by micro-computed tomography and histomorphometry after implantation in a metaphyseal trepanation model in sheep. The material demonstrates compressive yield strengths of up to 50 MPa and anisotropy correlating closely with fiber layout. Samples with 75% porosity are both stronger and stiffer than those with 85% porosity. The highest bending modulus is found in samples with parallel fiber orientation, while the highest shear modulus is found in cross-ply layouts. Cell metabolism and morphology indicate uncompromised biocompatibility. Implants demonstrate robust circumferential osseointegration in vivo after 8 weeks. The biometal introduced in this study demonstrates anisotropic mechanical properties similar to bone, and excellent osteoconductivity and feasibility as an orthopedic implant material.
Titanium and stainless steel are commonly known as osteosynthesis materials with high strength and good biocompatibility. However, they have the big disadvantage that a second operation for hardware removal is necessary. Although resorbable systems made of polymers or magnesium are increasingly used, they show some severe adverse foreign body reactions or unsatisfying degradation behavior. Therefore, we started to investigate molybdenum as a potential new biodegradable material for osteosynthesis in craniomaxillofacial surgery. To characterize molybdenum as a biocompatible material, we performed in vitro assays in accordance with ISO Norm 10993-5. In four different experimental setups, we showed that pure molybdenum and molybdenum rhenium alloys do not lead to cytotoxicity in human and mouse fibroblasts. We also examined the degradation behavior of molybdenum by carrying out long-term immersion tests (up to 6 months) with molybdenum sheet metal. We showed that molybdenum has sufficient mechanical stability over at least 6 months for implants on the one hand and is subject to very uniform degradation on the other. The results of our experiments are very promising for the development of new resorbable osteosynthesis materials for craniomaxillofacial surgery based on molybdenum.
Blockchain-IIoT integration into industrial processes promises greater security, transparency, and traceability. However, this advancement faces significant storage and scalability issues with existing blockchain technologies. Each peer in the blockchain network maintains a full copy of the ledger which is updated through consensus. This full replication approach places a burden on the storage space of the peers and would quickly outstrip the storage capacity of resource-constrained IIoT devices. Various solutions utilizing compression, summarization or different storage schemes have been proposed in literature. The use of cloud resources for blockchain storage has been extensively studied in recent years. Nonetheless, block selection remains a substantial challenge associated with cloud resources and blockchain integration. This paper proposes a deep reinforcement learning (DRL) approach as an alternative to solving the block selection problem, which involves identifying the blocks to be transferred to the cloud. We propose a DRL approach to solve our problem by converting the multi-objective optimization of block selection into a Markov decision process (MDP). We design a simulated blockchain environment for training and testing our proposed DRL approach. We utilize two DRL algorithms, Advantage Actor-Critic (A2C), and Proximal Policy Optimization (PPO) to solve the block selection problem and analyze their performance gains. PPO and A2C achieve 47.8% and 42.9% storage reduction on the blockchain peer compared to the full replication approach of conventional blockchain systems. The slowest DRL algorithm, A2C, achieves a run-time 7.2 times shorter than the benchmark evolutionary algorithms used in earlier works, which validates the gains introduced by the DRL algorithms. The simulation results further show that our DRL algorithms provide an adaptive and dynamic solution to the time-sensitive blockchain-IIoT environment.
Bislang gibt es keine Güterstraßenbahnsysteme, die im urbanen Warentransport im Realbetrieb eingesetzt werden. Bestehende Konzepte sind auf einzelne Branchen, ausgewählte Transportgüter oder einzelne Verlader ausgerichtet. Untersuchungen zu Güterstraßenbahnprojekten konzentrieren sich auf individuelle Kunden (zum Beispiel "CarGo Tram" Dresden). Für die Realisierung einer Güterstraßenbahn im urbanen Raum wäre zu klären, welche Anforderungen potenzielle Nutzer haben und wie diese Anforderungen in ein logistisches Konzept integriert werden können. In einer multiplen Fallstudie werden drei Unternehmen aus verschiedenen Branchen analysiert. Aufgrund heterogener Anforderungen wird ein modulares Logistikkonzept vorgeschlagen. Der Beitrag entstand im Rahmen des Projektes "LogIKTram: Logistikkonzept und IKT-Plattform für stadtbahnbasierten Gütertransport".
Acoustic waves are investigated which are guided at the edge (apex line) of a wedge-shaped elastic body or at the edge of an elastic plate. The edges contain a periodic sequence of modifications, consisting either of indentations or inclusions with a different elastic material which gives rise to high acoustic mismatch. Dispersion relations are computed with the help of the finite element method. They exhibit zero-group velocity points on the dispersion branches of edge-localized acoustic modes. These special points also occur at Bloch-Floquet wavenumbers away from the Brillouin zone boundary. Deep indentations lead to flat branches corresponding to largely non-interacting, Einstein-oscillator like vibrations of the tongues between the grooves of the periodic structure. Due to the nonlinearity of the elastic media, quantified by their third-order elastic constants, an acoustic mode localized at a periodically modified edge generates a second harmonic which partly consists of surface and plate modes propagating into the elastic medium in the direction vertical to the edge. This acoustic radiation at the second-harmonic frequency is investigated for an elastic plate and a truncated sharp-angle wedge with periodic inclusions at their edges. Unlike nonlinear bulk wave generation by surface acoustic waves in an interdigital structure, surface and plate mode radiation by edge-localized modes can be visualized directly in laser-ultrasound experiments.
The impact of the circular economy on sustainable development: A European panel data approach
(2022)
The circular economy (CE) has attracted considerable attention because of its potential to help achieve sustainable development (SD). This paper presents a comprehensive analysis of the effect of the CE on the three dimensions of SD at the country level. We analysed the impact of each CE source of value (renewable energy, reuse, repair, recycling) and the influence of an overall factor-analysis-derived measure of the CE on the economic, environmental and social dimensions of SD. The aim was to compare the individual impacts and outcomes of the CE and its sources of value in a single study. Panel data analysis was performed using a sample of 25 European countries for the period 2010 to 2019. The findings show a major impact of the CE on achieving SD, which has positive
effects on the economy, environment and society. However, the results show that the impact of each CE value source on the three SD dimensions varies. While renewable energies and reuse reduce the impact on the environment, recycling has no effect, and repair increases GHG emissions. However, repair is the only CE source with a positive economic impact at the country level. Finally, renewable energy, repair and recycling reduce unemployment. Decision makers should conduct impact analysis to design suitable, efficient and targeted measures depending on each country's specific objectives.
Surface treatment intensity monitoring is still an open and challenging nondestructive testing problem. For the estimation of residual stress with ultrasonic measurements, local linear and nonlinear elastic constants are needed as input. In this paper, nonlinear elastic-wave interactions (also called wave mixing or scattering) — namely, the generation of secondary ultrasonic waves in a nonlinear medium — are considered as a prospective means for near-surface nonlinear elastic parameter evaluation. The allowed interactions between bulk and surface waves, as well as the dependence of the scattering efficiency on the frequency and angle between source waves, were investigated through an analytical model, then compared with FEM simulations and experimental results. Finally, possible future steps for the development of the applied methods for the determination of near-surface higher-order elastic constants are discussed. In addition, several problem-relevant data processing procedures are presented.
The integration of Internet of Things devices onto the Blockchain implies an increase in the transactions that occur on the Blockchain, thus increasing the storage requirements.
A solution approach is to leverage cloud resources for storing blocks within the chain. The paper, therefore, proposes two solutions to this problem. The first being an improved hybrid architecture design which uses containerization to create a side chain on a fog node for the devices connected to it and an Advanced Time‑variant Multi‑objective Particle Swarm Optimization Algorithm (AT‑MOPSO) for determining the optimal number of blocks that should be transferred to the cloud for storage. This algorithm uses time‑variant weights for the velocity of the particle swarm optimization and the non‑dominated sorting and mutation schemes from NSGA‑III. The proposed algorithm was compared with results from the original MOPSO algorithm, the Strength Pareto Evolutionary Algorithm (SPEA‑II), and the Pareto Envelope‑based Selection Algorithm with region‑based selection (PESA‑II), and NSGA‑III. The proposed AT‑MOPSO showed better results than the aforementioned MOPSO algorithms in cloud storage cost and query probability optimization. Importantly, AT‑MOPSO achieved 52% energy efficiency compared to NSGA‑III.
To show how this algorithm can be applied to a real‑world Blockchain system, the BISS industrial Blockchain architecture was adapted and modified to show how the AT‑MOPSO can be used with existing Blockchain systems and the benefits it provides.
Research is often conducted to investigate footwear mechanical properties and their effects on running biomechanics, but little is known about their influence on runner satisfaction, or how well the shoe is perceived. A tool to predict runner satisfaction in a shoe from its mechanical properties would be advantageous for footwear companies. Data in this study were from a database (n = 615 subject-shoe pairings) of satisfaction ratings (gathered after participants ran on a treadmill), and mechanical testing data for 87 unique subjects across 61 unique shoes. Random forest and elastic net logistic regression models were built to test if footwear mechanical properties and subject characteristics could predict runner satisfaction in 3 ways: degree-of-satisfaction on a 7-point Likert scale, overall satisfaction on a 3-point Likert scale, and willingness-to-purchase the shoe (yes/no response). Data were divided into training and validation sets, using an 80–20 split, to build the models and test their accuracy, respectively. Model accuracies were compared against the no-information rate (i.e. proportion of data belonging to the largest class). The models were not able to predict degree-of-satisfaction or overall satisfaction from footwear mechanical properties but could predict runner’s willingness to purchase with 68–75% accuracy. Midsole Gmax at the heel and forefoot appeared in the top five of variable importance rankings across both willingness-to-purchase models, suggesting its role as a major factor in purchase decisions. The negative regression coefficient for both heel and forefoot Gmax indicated that softer midsoles increase the likelihood of a shoe purchase. Future models to predict satisfaction may improve accuracy with the addition of more subject-specific parameters, such as running goals or foot proportions.
Background: Running overuse injuries (ROIs) occur within a complex, partly injury-specific interplay between training loads and extrinsic and intrinsic risk factors. Biomechanical risk factors (BRFs) are related to the individual running style. While BRFs have been reviewed regarding general ROI risk, no systematic review has addressed BRFs for specific ROIs using a standardized methodology.
Objective: To identify and evaluate the evidence for the most relevant BRFs for ROIs determined during running and to
suggest future research directions.
Design: Systematic review considering prospective and retrospective studies. (PROSPERO_ID: 236,832).
Data Sources: PubMed. Connected Papers. The search was performed in February 2021.
Eligibility Criteria: English language. Studies on participants whose primary sport is running addressing the risk for the seven most common ROIs and at least one kinematic, kinetic (including pressure measurements), or electromyographic BRF. A BRF needed to be identified in at least one prospective or two independent retrospective studies. BRFs needed to be determined during running.
Results: Sixty-six articles fulfilled our eligibility criteria. Levels of evidence for specific ROIs ranged from conflicting to moderate evidence. Running populations and methods applied varied considerably between studies. While some BRFs appeared for several ROIs, most BRFs were specific for a particular ROI. Most BRFs derived from lower-extremity joint kinematics and kinetics were located in the frontal and transverse planes of motion. Further, plantar pressure, vertical ground reaction force loading rate and free moment-related parameters were identified as kinetic BRFs.
Conclusion: This study offers a comprehensive overview of BRFs for the most common ROIs, which might serve as a starting point to develop ROI-specific risk profiles of individual runners. We identified limited evidence for most ROI-specific risk factors, highlighting the need for performing further high-quality studies in the future. However, consensus on data collection standards (including the quantification of workload and stress tolerance variables and the reporting of injuries) is warranted.
Background: Many countries have restricted public life in order to contain the spread of the novel coronavirus (SARS-CoV2). As a side effect of related measures, physical activity (PA) levels may have decreased.
Objective: We aimed (1) to quantify changes in PA and (2) to identify variables potentially predicting PA reductions.
Methods: A systematic review with random-effects multilevel meta-analysis was performed, pooling the standardized mean differences in PA measures before and during public life restrictions.
Results: A total of 173 trials with moderate methodological quality (modified Downs and Black checklist) were identified. Compared to pre-pandemic, total PA (SMD − 0.65, 95% CI − 1.10 to − 0.21) and walking (SMD − 0.52, 95% CI − 0.29 to − 0.76) decreased while sedentary behavior increased (SMD 0.91, 95% CI: 0.17 to 1.65). Reductions in PA affected all intensities (light: SMD − 0.35, 95% CI − 0.09 to − 0.61, p = .013; moderate: SMD − 0.33, 95% CI − 0.02 to − 0.6; vigorous: SMD − 0.33, − 0.08 to − 0.58, 95% CI − 0.08 to − 0.58) to a similar degree. Moderator analyses revealed no influence of variables such as sex, age, body mass index, or health status. However, the only continent without a PA reduction was Australia and cross-sectional trials yielded higher effect sizes (p < .05).
Conclusion: Public life restrictions associated with the COVID-19 pandemic resulted in moderate reductions in PA levels and large increases in sedentary behavior. Health professionals and policy makers should therefore join forces to develop strategies counteracting the adverse effects of inactivity.
Running footwear is continuously being modified and improved; however, running-related overuse injury rates remain high. Nevertheless, novel manufacturing processes enable the production of individualized running shoes that can fit the individual needs of runners, with the potential to reduce injury risk. For this reason, it is essential to investigate functional groups of runners, a collective of runners who respond similarly to a footwear intervention. Therefore, the objective of this study was to develop a framework to identify functional groups based on their individual footwear response regarding injury-specific running-related risk factors for Achilles tendinopathy, Tibial stress fractures, Medial tibial stress syndrome, and Patellofemoral pain syndrome. In this work, we quantified the footwear response patterns of 73 female and male participants when running in three different footwear conditions using unsupervised learning (k-means clustering). For each functional group, we identified the footwear conditions minimizing the injury-specific risk factors. We described differences in the functional groups regarding their running style, anthropometric, footwear perception, and demographics. The results implied that most functional groups showed a tendency for a single footwear condition to reduce most biomechanical risk factors for a specific overuse injury. Functional groups often differed in their hip and pelvis kinematics as well as their subjective rating of the footwear conditions. The footwear intervention only partially affected biomechanical risk factors attributed to more proximal joints. Due to its adaptive nature, the framework could be applied to other footwear interventions or performance-related biomechanical variables.
High-performance thin-layer chromatography (HPTLC), as the modern form of TLC (thin-layer chromatography), is suitable for detecting pharmaceutically active compounds over a wide polarity range using the gradient multiple development (GMD) technique. Diode-array detection (DAD) in conjunction with HPTLC can simultaneously acquire ultraviolet‒visible (UV‒VIS) and fluorescence spectra directly from the plate. Visualization as a contour plot helps to identify separated zones. An orange peel extract is used as an example to show how GMD‒DAD‒HPTLC in seven different developments with seven different solvents can provide an overview of the entire sample. More than 50 compounds in the extract can be separated on a 6-cm HPTLC plate. Such separations take place in the biologically inert stationary phase of HPTLC, making it a suitable method for effect-directed analysis (EDA). HPTLC‒EDA can even be performed with living organism, as confirmed by the use of Aliivibrio fischeri bacteria to detect bioluminescence as a measure of toxicity. The combining of gradient multiple development planar chromatography with diode-array detection and effect-directed analysis (GMD‒DAD‒HPTLC‒EDA) in conjunction with specific staining methods and time-of-flight mass spectrometry (TOF‒MS) will be the method of choice to find new chemical structures from plant extracts that can serve as the basic structure for new pharmaceutically active compounds.
Two solvent mixtures for high-performance thin-layer chromatographic (HPTLC) separation of some compounds showing estrogenic activity in the yeast estrogen screen (YES) assay are presented. The new method, planar yeast estrogen screen (pYES) combines the YES assay and a chromatographic separation on silica gel HPTLC plates with the performance of the YES assay. For separation, the analytes were applied bandwise to HPTLC plates (10 × 20 cm) with fluorescent dye (Merck, Germany). The plates were developed in a vertical developing chamber after 30 min of chamber saturation over a separation distance of 70 mm, using cyclohexane‒methyl-ethyl ketone (2:1, V/V) or cyclohexane‒CPME (3:2, V/V) as solvents. Both solvents allow separation of estriol, daidzein, genistein, 17β-estradiol, 17α-ethinyl estradiol, estrone, 4-nonylphenol and bis(2-ethylhexyl) phthalate.
During the coronavirus crisis, labs had to be offered in digital form in mechanical engineering at short notice. For this purpose, digital twins of more complex test benches in the field of fluid energy machines were used in the mechanical engineering course, with which the students were able to interact remotely to obtain measurement data. The concept of the respective lab was revised with regard to its implementation as a remote laboratory. Fortunately, real-world labs were able to be fully replaced by remote labs. Student perceptions of remote labs were mostly positive. This paper explains the concept and design of the digital twins and the lab as well as the layout, procedure, and finally the results of the accompanying evaluation. However, the implementation of the digital twins to date does not yet include features which address the tactile experience of working in real-world labs.
Running stability is the ability to withstand naturally occurring minor perturbations during running. It is susceptible to external and internal running conditions such as footwear or fatigue. However, both its reliable measurability and the extent to which laboratory measurements reflect outdoor running remain unclear. This study aimed to evaluate the intra- and inter-day reliability of the running stability as well as the comparability of different laboratory and outdoor conditions. Competitive runners completed runs on a motorized treadmill in a research laboratory and overground both indoors and outdoors. Running stability was determined as the maximum short-term divergence exponent from the raw gyroscope signals of wearable sensors mounted to four different body locations (sternum, sacrum, tibia, and foot). Sacrum sensor measurements demonstrated the highest reliabilities (good to excellent; ICC = 0.85 to 0.91), while those of the tibia measurements showed the lowest (moderate to good; ICC = 0.55 to 0.89). Treadmill measurements depicted systematically lower values than both overground conditions for all sensor locations (relative bias = -9.8% to -2.9%). The two overground conditions, however, showed high agreement (relative bias = -0.3% to 0.5%; relative limits of agreement = 9.2% to 15.4%). Our results imply moderate to excellent reliability for both overground and treadmill running, which is the foundation of further research on running stability.
This paper aims to draw attention to an urgent need for reform of the regulatory framework of the broader export credit system to ensure a new and comprehensive "safe haven" for officially supported export credits. The purpose is to analyse the complex debate on disciplines of the World Trade Organization (WTO) and the Organisation for Economic Co-operation and Development (OECD), creating a point of reference for future analysis of and debates around the "carve-out clause" of the Agreement on Subsidies and Countervailing Measures (ASCM) and a "safe haven" in a broader sense.
Aerosol particles play an important role in the climate system by absorbing and scattering radiation and influencing cloud properties. They are also one of the biggest sources of uncertainty for climate modeling. Many climate models do not include aerosols in sufficient detail due to computational constraints. To represent key processes, aerosol microphysical properties and processes have to be accounted for. This is done in the ECHAM-HAM (European Center for Medium-Range Weather Forecast-Hamburg-Hamburg) global climate aerosol model using the M7 microphysics, but high computational costs make it very expensive to run with finer resolution or for a longer time. We aim to use machine learning to emulate the microphysics model at sufficient accuracy and reduce the computational cost by being fast at inference time. The original M7 model is used to generate data of input–output pairs to train a neural network (NN) on it. We are able to learn the variables’ tendencies achieving an average R² score of 77.1%. We further explore methods to inform and constrain the NN with physical knowledge to reduce mass violation and enforce mass positivity. On a Graphics processing unit (GPU), we achieve a speed-up of up to over 64 times faster when compared to the original model.
Many commonly well-performing convolutional neural network models have shown to be susceptible to input data perturbations, indicating a low model robustness. To reveal model weaknesses, adversarial attacks are specifically optimized to generate small, barely perceivable image perturbations that flip the model prediction. Robustness against attacks can be gained by using adversarial examples during training, which in most cases reduces the measurable model attackability. Unfortunately, this technique can lead to robust overfitting, which results in non-robust models. In this paper, we analyze adversarially trained, robust models in the context of a specific network operation, the downsampling layer, and provide evidence that robust models have learned to downsample more accurately and suffer significantly less from downsampling artifacts, aka. aliasing, than baseline models. In the case of robust overfitting, we observe a strong increase in aliasing and propose a novel early stopping approach based on the measurement of aliasing.
This paper has the objective of creating a framework for a different cultural dimension of corporate entrepreneurship leading to corporate entrepreneurial culture (CEC). The analysis of CEC is based on a review of existing concepts of organisational culture and entrepreneurship. They are combined to create a framework of CEC, including macro- and microlevels and examples of subcultures. Core ideas of the framework are validated by qualitative interviews with ten experts. The identified organisational category of the CEC framework is defined by the levels of micro-cultures or subcultures and includes the upper levels of the hierarchy, including the industry level. Geographic categories such as regional or national culture are also part of the system. The individual category of the CEC framework is characterised by competencies (including aspects such as motivation, creativity, mobilising others, coping with uncertainty, teamwork and social competencies) and entrepreneurial personalities. The results of the interviews show the importance of these individual competencies for a lively CEC. The different levels, such as national and professional cultures, as a dimension of the organisational category of the framework are also confirmed by the interviews. The findings indicate that the individual category of CEC could be used for job satisfaction or engagement and the degree of CEC of an organisation could be defined and developed by the organisational category. The identified framework contributes to an understanding of this complex topic and supports companies in the implementation of entrepreneurial ideas in different organisational contexts.
Im Beitrag wird ein zweistufiges Verfahren für den Entwurf eines Störgrößenbeobachters für lineare, zeitinvariante Systeme vorgestellt. Hierbei wird davon ausgegangen, dass die Beobachterrückführung für den Beobachter ohne Störmodell bereits vorliegt. Es wird dargestellt, wie darauf basierend mit einfachen formelmäßigen Zusammenhängen die Rückführkoeffizienten für den Störgrößenbeobachter ermittelt werden können. Die beschriebene Methode erhöht die Übersichtlichkeit hinsichtlich des Einflusses des Störmodells auf die Beobachterrückführkoeffizienten und ist außerdem für Modelle mit geringer Systemordnung rechenzeitsparender.
This paper will introduce the open-source model MyPyPSA-Ger, a myopic optimization model developed to represent the German energy system with a detailed mapping of the electricity sector, on a highly disaggregated level, spatially and temporally, with regional differences and investment limitations. Furthermore, this paper will give new outlooks on the German federal government 2050 emissions goals of the electricity sector to become greenhouse gas neutral by proposing new CO2 allowance strategies. Moreover, the regional differences in Germany will be discussed, their role and impact on the energy transition, and which regions and states will drive the renewable energy utilization forward.
Following a scenario-based analysis, the results point out the major keystones of the energy transition path from 2020 to 2050. Solar, onshore wind, and gas-fired power plants will play a fundamental role in the future electricity systems. Biomass, run of river, and offshore wind technologies will be utilized in the system as base-load generation technologies. Solar and onshore wind will be installed almost everywhere in Germany. However, due to the nature of Germany’s weather and geographical features, the southern and northern regions will play a more important role in the energy transition.
Higher CO2 allowance costs will help achieve the 1.5-degree-target of the electricity system and will allow for a rapid transition. Moreover, the more expensive, and the earlier the CO2 tax is applied to the system, the less it will cost for the energy transition, and the more emissions will be saved throughout the transition period. An earlier phase-out of coal power plants is not necessary with high CO2 taxes, due to the change in power plant’s unit commitment, as they prioritize gas before coal power plants. Having moderate to low CO2 allowance cost or no clear transition policy will be more expensive and the CO2 budget will be exceeded. Nonetheless, even with no policy, renewables still dominate the energy mix of the future.
However, maintaining the maximum historical installation rates of both national and regional levels, with the current emissions reduction strategy, will not be enough to reach the level of climate-neutral electricity system. Therefore, national and regional installation requirements to achieve the federal government emission reduction goals are determined. Energy strategies and decision makers will have to resolve great challenges in order to stay in line with the 1.5-degree-target.
Linear acceleration is a key performance determinant and major training component of many sports. Although extensive research about lower limb kinetics and kinematics is available, consistent definitions of distinctive key body positions, the underlying mechanisms and their related movement strategies are lacking. The aim of this ‘Method and Theoretical Perspective’ article is to introduce a conceptual framework which classifies the sagittal plane ‘shin roll’ motion during accelerated sprinting. By emphasising the importance of the shin segment’s orientation in space, four distinctive key positions are presented (‘shin block’, ‘touchdown’, ‘heel lock’ and ‘propulsion pose’), which are linked by a progressive ‘shin roll’ motion during swing-stance transition. The shin’s downward tilt is driven by three different movement strategies (‘shin alignment’, ‘horizontal ankle rocker’ and ‘shin drop’). The tilt’s optimal amount and timing will contribute to a mechanically efficient acceleration via timely staggered proximal-to-distal power output. Empirical data obtained from athletes of different performance levels and sporting backgrounds are required to verify the feasibility of this concept. The framework presented here should facilitate future biomechanical analyses and may enable coaches and practitioners to develop specific training programs and feedback strategies to provide athletes with a more efficient acceleration technique.
Anterior cruciate ligament (ACL) ruptures are frequent in the age group of 15–19 years, particularly for female athletes. Although injury-prevention programs effectively reduce severe knee injuries, little is known about the underlying mechanisms and changes of biomechanical risk factors. Thus, this study analyzes the effects of a neuromuscular injury-prevention program on biomechanical parameters associated with ACL injuries in elite youth female handball players. In a nonrandomized, controlled intervention study, 19 players allocated to control (n = 12) and intervention (n = 7) group were investigated for single- and double-leg landings as well as unanticipated side-cutting maneuvers before and after a 12-week study period. The lower-extremity motion of the athletes was captured using a three-dimensional motion capture system consisting of 12 infrared cameras. A lower-body marker set of 40 markers together with a rigid body model, including a forefoot, rearfoot, shank, thigh, and pelvis segment in combination with two force plates was used to determine knee joint angles, resultant external joint moments, and vertical ground reaction forces. The two groups did not differ significantly during pretesting. Only the intervention group showed significant improvements in the initial knee abduction angle during single leg landing (p = 0.038: d = 0.518), knee flexion moment during double-leg landings (p = 0.011; d = −1.086), knee abduction moment during single (p = 0.036; d = 0.585) and double-leg landing (p = 0.006; d = 0.944) and side-cutting (p = 0.015;d = 0.561) as well as vertical ground reaction force during double-leg landing (p = 0.004; d = 1.482). Control group demonstrated no significant changes in kinematics and kinetics. However, at postintervention both groups were not significantly different in any of the biomechanical outcomes except for the normalized knee flexion moment of the dominant leg during single-leg landing. This study provides first indications that the implementation of a training intervention with specific neuromuscular exercises has positive impacts on biomechanical risk factors associated with ACL injury risk and, therefore, may help prevent severe knee injuries in elite youth female handball players.
In this project, different calcification methods for collagen and collagen coatings were compared in terms of their applicability for 3D printing and production of collagen-coated scaffolds. For this purpose, scaffolds were printed from polycaprolactone PCL using the EnvisionTec 3D Bioplotter and then coated with collagen. Four different coating methods were then applied: hydroxyapatite (HA) powder directly in the collagen coating, incubation in 10× SBF, coating with alkaline phosphatase (ALP), and coating with poly-L-aspartic acid. The results were compared by ESEM, µCT, TEM, and EDX. HA directly in the collagen solution resulted in a pH change and thus an increase in viscosity, leading to clumping on the scaffolds. As a function of incubation time in 10× SBF as well as in ALP, HA layer thickness increased, while no coating on the collagen layer was apparently observed with poly-L-aspartic acid. Only ultrathin sections and TEM with SuperEDX detected nano crystalline HA in the collagen layer. Exclusively the incubation in poly-L-aspartic acid led to HA crystals within the collagen coating compared to all other methods where the HA layers formed in different forms only at the collagen layer.
In the last years, social robots have become a trending topic. Indeed, robots which communicate with us and mimic human behavior patterns are fascinating. However, while there is a massive body of research on their design and acceptance in different fields of application, their market potential has been rarely investigated. As their future integration in society may have a vast disruptive potential, this work aims at shedding light on the market potential, focusing on the assistive health domain. A study with 197 persons from Italy (age: M = 67.87; SD = 8.87) and Germany (age: M = 62.15; SD = 6.14) investigates cultural acceptance, desired functionalities, and purchase preferences. The participants filled in a questionnaire after watching a video illustrating some examples of social robots. Surprisingly, the individual perception of health status, social status as well as nationality did hardly influence the attitude towards social robots, although the German group was somewhat more reluctant to the idea of using them. Instead, there were significant correlations with most dimensions of the Almere model (like perceived enjoyment, sociability, usefulness and trustworthiness). Also, technology acceptance resulted strongly correlated with the individual readiness to invest money. However, as most persons consider social robots as “Assistive Technological Devices” (ATDs), they expected that their provision should mirror the usual practices followed in the two Countries for such devices. Thus, to facilitate social robots’ future visibility and adoption by both individuals and health care organisations, policy makers would need to start integrating them into official ATDs databases.
Nowadays decarbonisation of the energy system is one of the main concerns for most governments. Renewable energy technologies, such as rooftop photovoltaic systems and home battery storage systems, are changing the energy system to be more decentralised. As a consequence, new ways of energy business models are emerging, e.g., peer-to-peer energy trading. This new concept provides an online marketplace where direct energy exchange can occur between its participants. The purpose of this study is to conduct a content analysis of the existing literature, ongoing research projects, and companies related to peer-to-peer energy trading. From this review, a summary of the most important aspects and journal papers is assessed, discussed, and classified. It was found that the different energy market types were named in various ways and a proposal for standard language for the several peer-to-peer market types and the different actors involved is suggested. Additionally, by grouping the most important attributes from peer-to-peer energy trading projects, an assessment of the entry barrier and scalability potential is performed by using a characterisation matrix.
Bach, Gas, Strom und Wasser
(2022)
In this paper, the influence of the material hardening behavior on plasticity-induced fatigue crack closure is investigated for strain-controlled loading and fully plastic, large-scale yielding conditions by means of the finite element method. The strain amplitude and the strain ratio are varied for given Ramberg–Osgood material properties representing materials with different hardening behavior. The results show a pronounced influence of the hardening behavior on crack closure, while no significant effect is found from the considered strain amplitude and strain ratio. The effect of the hardening behavior on the crack opening stress cannot be described by existing crack opening stress equations.
In this paper, the effect of the polycrystalline microstructure on crack-tip opening displacement and crack closure is investigated for microstructural short plane strain fatigue cracks using the finite-element method. To this end, cracks are introduced in synthetically generated microstructures and the grain properties are described using a single crystal plasticity model with kinematic hardening. Additionally, finite-element calculations without resolved microstructure and von Mises plasticity with kinematic hardening are performed. Fully-reversed strain-controlled cyclic loadings are considered under large-scale yielding conditions as typical for low-cycle fatigue problems. The crack opening stress and the cyclic crack-tip opening displacement are significantly influenced by the local grain structure. While the stabilized crack opening stresses obtained with the microstructure-based finite-element model are in good accordance with the von Mises plasticity results, the differences in the cyclic crack opening displacement are addressed to the asymmetric plastic strain fields in the plastic wake behind the crack-tip of the microstructure-based model. The asymmetric plastic strain fields result in discontinuous and premature contact of the crack flanks.
In this paper, a concept for an anthropomorphic replacement hand cast with silicone with an integrated sensory feedback system is presented. In order to construct the personalized replacement hand, a 3D scan of a healthy hand was used to create a 3D-printed mold using computer-aided design (CAD). To allow for movement of the index and middle fingers, a motorized orthosis was used. Information about the applied force for grasping and the degree of flexion of the fingers is registered using two pressure sensors and one bending sensor in each movable finger. To integrate the sensors and additional cavities for increased flexibility, the fingers were cast in three parts, separately from the rest of the hand. A silicone adhesive (Silpuran 4200) was examined to combine the individual parts afterwards. For this, tests with different geometries were carried out. Furthermore, different test series for the secure integration of the sensors were performed, including measurements of the registered information of the sensors. Based on these findings, skin-toned individual fingers and a replacement hand with integrated sensors were created. Using Silpuran 4200, it was possible to integrate the needed cavities and to place the sensors securely into the hand while retaining full flexion using a motorized orthosis. The measurements during different loadings and while grasping various objects proved that it is possible to realize such a sensory feedback system in a replacement hand. As a result, it can be stated that the cost-effective realization of a personalized, anthropomorphic replacement hand with an integrated sensory feedback system is possible using 3D scanning and 3D printing. By integrating smaller sensors, the risk of damaging the sensors through movement could be decreased.
Virtual reality (VR) offers the opportunity to create virtual worlds that could replace real experiences. This research investigates the influence of user motivation, temporal distance and experience type on the satisfaction with the VR experience, and the degree of acceptance of a VR experience as a substitute for a real experience. The results suggest that the degree of acceptance of a VR experience as a substitute for a real experience is higher for passive VR experiences compared to active VR experiences. Furthermore, the results support the assumption that users are more satisfied with passive VR experiences.
Non-contact anterior cruciate ligament injuries typically occur during cutting maneuvers and are associated with high peak knee abduction moments (KAM) within early stance. To screen athletes for injury risk or quantify the efficacy of prevention programs, it may be necessary to design tasks that mimic game situations. Thus, this study compared KAMs and ranking consistency of female handball players in three sport-specific fake-and-cut tasks of increasing complexity. The biomechanics of female handball players (n = 51, mean ± SD: 66.9 ± 7.8 kg, 1.74 ± 0.06 m, 19.2 ± 3.4 years) were recorded with a 3D motion capture system and force plates during three standardized fake-and-cut tasks. Task 1 was designed as a simple pre-planned cut, task 2 included catching a ball before a pre-planned cut in front of a static defender, and task 3 was designed as an unanticipated cut with three dynamic defenders involved. Inverse dynamics were used to calculate peak KAM within the first 100 ms of stance. KAM was decomposed into the frontal plane knee joint moment arm and resultant ground reaction force. RANOVAs (α ≤ 0.05) were used to reveal differences in the KAM magnitudes, moment arm, and resultant ground reaction force for the three tasks. Spearman's rank correlations were calculated to test the ranking consistency of the athletes' KAMs. There was a significant task main effect on KAM (p = 0.02; ηp2 = 0.13). The KAM in the two complex tasks was significantly higher (task 2: 1.73 Nm/kg; task 3: 1.64 Nm/kg) than the KAM in the simplest task (task 1: 1.52 Nm/kg). The ranking of the peak KAM was consistent regardless of the task complexity. Comparing tasks 1 and 2, an increase in KAM resulted from an increased frontal plane moment arm. Comparing tasks 1 and 3, higher KAM in task 3 resulted from an interplay between both moment arm and the resultant ground reaction force. In contrast to previous studies, unanticipated cutting maneuvers did not produce the highest KAMs. These findings indicate that the players have developed an automated sport-specific cutting technique that is utilized in both pre-planned and unanticipated fake-and-cut tasks.
As emissions reach record levels, governments must implement and strengthen climate policies for the global pathway to net‐zero emissions by 2050. Climate finance plays a crucial role in the net‐zero transition. It refers to local, national, or transnational financing seeking to support mitigation and adaptation actions that address climate change. Public export–import banks (EXIMs) and government export credit agencies (ECAs) are highly influential actors for climate action. Although there is no consensus among EXIMs and ECAs on how to define climate finance, 20 institutions assessed in this research give evidence that they strongly support climate‐action‐related transactions: EXIM and ECA financing, guarantees, and insurance amounted to EUR 6.7–8.4 billion in 2020, much more than estimated by the Climate Policy Initiative (CPI). However, the results also reveal that EXIM and ECA lending, guarantee, and insurance activities must rise substantially in order to contribute to climate finance volumes required by 2030 as estimated by CPI. To retain their current proportion relative to other climate finance flows, assessed institutions would need to increase their climate financing 6.8 times to up to EUR 57.4 billion by 2030.
Making innovation, trade, investment and environment policy goals mutually supportive creates challenges for internationally‐oriented firms, financial institutions, governments and other stakeholders. Will the Ukraine war derail the green energy transition? How can governments and the financial system work together to broaden, deepen, and accelerate the global transition to net‐zero? What are innovation, trade and investment opportunities for green growth? How to refocus government financing instruments to support countries and trade partners meet their climate targets in times of crisis? The IfTI Global Symposium 2022 hosted by the Institute of Trade and Innovation (IfTI) at Offenburg University discussed challenges to trade in a new global order, as well as opportunities and threats of the green transition. This Special Section brings together practitioner commentaries of key symposium speakers.
Die Corona-Semester erforderten die Übertragung der Brückenkurse Mathematik in ein digitales Lehr-format. Gerade beim Studieneinstieg spielen persönliche Unterstützung und soziale Eingebundenheit für Studierende eine besonders wichtige Rolle. Deshalb lag die besondere Herausforderung bei der Übertragung in ein digitales Format darin, die wegfallenden üblichen Kennenlern- und Kommunika-tionsmöglichkeiten, die sich in Präsenzformaten beispielsweise in den Pausen oder im Gespräch mit den Sitznachbarn ergeben, zu kompensieren. Vorliegender Beitrag stellt vor, inwieweit der Transfer in ein digitales Format gelungen ist. Das digitale Brückenkurskonzept wurde in ein didaktisches Entwurfsmuster übertragen, um durch die strukturierte und nachvollziehbare Darstellung den Transfer und die Vergleichbarkeit der Ergebnisse zu erleichtern.
The laser ultrasound (LU) technique has been used to determine dispersion curves for surface acoustic waves (SAW) propagating in AlScN/Al2O3 systems. Polar and non-polar Al0.77Sc0.23N thin films were prepared by magnetron sputter epitaxy on Al2O3 substrates and coated with a metal layer. SAW dispersion curves have been measured for various propagation directions on the surface. This is easily achieved in LU measurements since no additional surface structures need to be fabricated, which would be required if elastic properties are determined with the help of SAW resonators. Variation of the propagation direction allows for efficient use of the system’s anisotropy when extracting information on elastic properties. This helps to overcome the complexity caused by a large number of elastic constants in the film material. An analysis of the sensitivity of the SAW phase velocities (with respect to the elastic moduli and their dependence on SAW propagation direction) reveals that the non-polar AlScN films are particularly well suited for the extraction of elastic film properties. Good agreement is found between experiment and theoretical predictions, validating LU as a non-destructive and fast technique for the determination of elastic constants of piezoelectric thin films.
Cloud computing is the emerging technology providing IT as a utility through internet. The benefits of cloud computing are but not limited to service based, scalable, elastic, shared pool of resources, metered by use. Due to mentioned benefits the concept of cloud computing fits very well with the concept of m-learning which differs from other forms of e-learning, covers a wide range of possibilities opened up by the convergence of new mobile technologies, wireless communication structure and distance learning development. The concept of cloud computing like any other concept has not only benefits but also introduces myriad of security issues, such as transparency between cloud user and provider, lack of standards, security concerns related to identity, Service Level Agreements (SLA) inadequacy etc. Providing secure, transparent, and reliable services in cloud computing environment is an important issue. This paper introduces a secured three layered architecture with an advance Intrusion Detection System (advIDS), which overcomes different vulnerabilities on cloud deployed applications. This proposed architecture can reduce the impact of different attacks by providing timely alerts, rejecting the unauthorized access over services, and recording the new threat profiles for future verification. The goal of this research is to provide more control over data and applications to the cloud user, which are now mainly controlled by Cloud Service Provider (CSP).
Positioning mobile systems with high accuracy is a prerequisite for intelligent autonomous behavior, both in industrial environments and in field robotics. This paper describes the setup of a robotic platform and its use for the evaluation of simultaneous localization and mapping (SLAM) algorithms. A configuration using a mobile robot Husky A200, and a LiDAR (light detection and ranging) sensor was used to implement the setup. For verification of the proposed setup, different scan matching methods for odometry determination in indoor and outdoor environments are tested. An assessment of the accuracy of the baseline 3D-SLAM system and the selected evaluation system is presented by comparing different scenarios and test situations. It was shown that the hdl_graph_slam in combination with the LiDAR OS1 and the scan matching algorithms FAST_GICP and FAST_VGICP achieves good mapping results with accuracies up to 2 cm.
Young female handball players represent a high-risk population for anterior cruciate ligament (ACL) injuries. While the external knee abduction moment (KAM) is known to be a risk factor, it is unclear how cutting technique affects KAMs in sport-specific cutting maneuvers. Further, the effect of added game specificity (e.g., catching a ball or faking defenders) on KAMs and cutting technique remains unknown. Therefore, this study aimed: (i) to test if athletes grouped into different clusters of peak KAMs produced during three sport-specific fake-and-cut tasks of different complexities differ in cutting technique, and (ii) to test whether technique variables change with task complexity. Fifty-one female handball players (67.0 ± 7.7 kg, 1.70 ± 0.06 m, 19.2 ± 3.4 years) were recruited. Athletes performed at least five successful handball-specific sidestep cuts of three different complexities ranging from simple pre-planned fake-and-cut maneuvers to catching a ball and performing an unanticipated fake-and-cut maneuver with dynamic defenders. A k-means cluster algorithm with squared Euclidean distance metric was applied to the KAMs of all three tasks. The optimal cluster number of koptimal = 2 was calculated using the average silhouette width. Statistical differences in technique variables between the two clusters and the tasks were analyzed using repeated-measures ANOVAs (task complexity) with nested groupings (clusters). KAMs differed by 64.5%, on average, between clusters. When pooling all tasks, athletes with high KAMs showed 3.4° more knee valgus, 16.9% higher downward and 8.4% higher resultant velocity at initial ground contact, and 20.5% higher vertical ground reaction forces at peak KAM. Unlike most other variables, knee valgus angle was not affected by task complexity, likely due to it being part of inherent movement strategies and partly determined by anatomy. Since the high KAM cluster showed higher vertical center of mass excursions and knee valgus angles in all tasks, it is likely that this is part of an automated motor program developed over the players' careers. Based on these results, reducing knee valgus and downward velocity bears the potential to mitigate knee joint loading and therefore ACL injury risk.
Memento mori!
(2022)
Das plötzliche Ende des romantischen Komponisten Felix Mendelssohn Bartholdy (1809–1847) gibt uns auch heute noch Rätsel auf. Einiges deutet auf ein rupturiertes zerebrales Aneurysma mit konsekutiver Subarachnoidalblutung hin. Das Quellenmaterial zu den Symptomen seiner Todeskrankheit wird in dieser Arbeit ausführlich vorgestellt und diskutiert. Eine mögliche familiäre Disposition im Sinne eines Ehlers-Danlos-Syndroms Typ IV wird erörtert.
Dieser Beitrag beschreibt, wie mit Campbells Schema der „Heldenreise“ personalisierte Narrative der obersten Führungsebene aufgebaut werden können, um für interne und externe Stakeholder eine Orientierung zu bieten und die Unternehmenskultur bewusst zu prägen und zu beeinflussen. Das Beispiel der Preisträgerportraits des Manager Magazins zeigt, dass diese Methode breite Anwendung findet und dabei auch unterschiedliche funktionale Zuschreibungen der Führungsrolle erfolgen können.
In dem ersten Teil dieses Beitrags, welcher in der Industrie 4.0 Management Ausgabe 5/2021 erschienen ist, wurde das Referenzmodell bereits in seinen wesentlichen Grundzügen erläutert [1]. Im zweiten Teil soll die Weiterentwicklung zu einem flexiblen Referenzmodell aufgezeigt werden. Der Fokus liegt auf die Implementierung von weiteren Planungstools, und die Implementierung von KI-Tools zur Erreichung eines dynamischen Produktionsengineerings in Form einer ganzheitlichen und integrierten Fabrikplanung.
An Overview of Technologies for Improving Storage Efficiency in Blockchain-Based IIoT Applications
(2022)
Since the inception of blockchain-based cryptocurrencies, researchers have been fascinated with the idea of integrating blockchain technology into other fields, such as health and manufacturing. Despite the benefits of blockchain, which include immutability, transparency, and traceability, certain issues that limit its integration with IIoT still linger. One of these prominent problems is the storage inefficiency of the blockchain. Due to the append-only nature of the blockchain, the growth of the blockchain ledger inevitably leads to high storage requirements for blockchain peers. This poses a challenge for its integration with the IIoT, where high volumes of data are generated at a relatively faster rate than in applications such as financial systems. Therefore, there is a need for blockchain architectures that deal effectively with the rapid growth of the blockchain ledger. This paper discusses the problem of storage inefficiency in existing blockchain systems, how this affects their scalability, and the challenges that this poses to their integration with IIoT. This paper explores existing solutions for improving the storage efficiency of blockchain–IIoT systems, classifying these proposed solutions according to their approaches and providing insight into their effectiveness through a detailed comparative analysis and examination of their long-term sustainability. Potential directions for future research on the enhancement of storage efficiency in blockchain–IIoT systems are also discussed.
Biomechanical Risk Factors of Injury-Related Single-Leg Movements in Male Elite Youth Soccer Players
(2022)
Altered movement patterns during single-leg movements in soccer increase the risk of lower-extremity non-contact injuries. The identification of biomechanical parameters associated with lower-extremity injuries can enrich knowledge of injury risks and facilitate injury prevention. Fifty-six elite youth soccer players performed a single-leg drop landing task and an unanticipated side-step cutting task. Three-dimensional ankle, knee and hip kinematic and kinetic data were obtained, and non-contact lower-extremity injuries were documented throughout the season. Risk profiling was assessed using a multivariate approach utilising a decision tree model (classification and regression tree method). The decision tree model indicated peak knee frontal plane angle, peak vertical ground reaction force, ankle frontal plane moment and knee transverse plane angle at initial contact (in this hierarchical order) for the single-leg landing task as important biomechanical parameters to discriminate between injured and non-injured players. Hip sagittal plane angle at initial contact, peak ankle transverse plane angle and hip sagittal plane moment (in this hierarchical order) were indicated as risk factors for the unanticipated cutting task. Ankle, knee and hip kinematics, as well as ankle and hip kinetics, during single-leg high-risk movements can provide a good indication of injury risk in elite youth soccer players.
Note: In lieu of an abstract, this is an excerpt from the first page.
Recently, we reported the three-dimensional computer-aided design (3D-CAD) reconstruction of the first “Iron Hand” of the famous Franconian knight, Götz von Berlichingen (1480–1562), who lost his right hand by a cannon ball splinter injury in 1504 in the War of the Succession of Landshut [...]
The accurate diagnosis of state of charge (SOC) and state of health (SOH) is of utmost importance for battery users and for battery manufacturers. State diagnosis is commonly based on measuring battery current and using it in Coulomb counters or as input for a current-controlled model. Here we introduce a new algorithm based on measuring battery voltage and using it as input for a voltage-controlled model. We demonstrate the algorithm using fresh and pre-aged lithium-ion battery single cells operated under well-defined laboratory conditions on full cycles, shallow cycles, and a dynamic battery electric vehicle load profile. We show that both SOC and SOH are accurately estimated using a simple equivalent circuit model. The new algorithm is self-calibrating, is robust with respect to cell aging, allows to estimate SOH from arbitrary load profiles, and is numerically simpler than state-of-the-art model-based methods.
The mobile devices related industries are subject to rapid change, driven by technological advances and dynamic consumer behaviour. Hence, the understanding of the mobile devices markets is an important step in the analysis phase of mobile applications development. In this paper, a brief description of the different markets is introduced followed by an analysis of the main features of the markets leaders' devices which are important in the development process of mobile web applications. Finally, approaches are proposed to deal with the mobile devices diversity.
Simulation based studies for operational energy system analysis play a significant role in evaluation of various new age technologies and concepts in the energy grid. Various modelling approaches already exist and in this original paper, four models representing these approaches are compared in two real-world hybrid energy system scenarios. The models, namely TransiEnt, µGRiDS, and OpSim (including pandaprosumer and mosaic) are classified into component-oriented or system-oriented approaches as deduced from the literature research. The methodology section describes their differences under standard conditions and the necessary parameterization for the purpose of creating a framework facilitating a closest possible comparison. A novel methodology for scenario generation is also explained. The results help to quantify primary differences in these approaches that are also identified in literature and qualify the influence of the accuracy of the models for application in a system-wide analysis. It is shown that a simplified model may be sufficient for the system-oriented approach especially when the objective is an optimization-based control or planning. However, from a field level operational point of view, the differences in the time series signify the importance of the component-oriented approaches.
A novel method for quasi-continuous tar monitoring in hot syngas from biomass gasification is reported. A very small syngas stream is extracted from the gasifier output, and the oxygen demand for tar combustion is determined by a well-defined dosage of synthetic air. Assuming the total oxidation of all of the combustible components at the Pt-electrode of a lambda-probe, the difference of the residual oxygen concentrations from successive operations with and without tar condensation represents the oxygen demand. From experiments in the laboratory with H2/N2/naphthalene model syngas, the linear sensitivity and a lower detection limit of about 70 ± 5 mg/m3 was estimated, and a very good long-term stability can be expected. This extremely sensitive and robust monitoring concept was evaluated further by the extraction of a small, constant flow of hot syngas as a sample (9 L/h) using a Laval nozzle combined with a metallic filter (a sintered metal plate (pore diameter 10 µm)) and a gas pump (in the cold zone). The first tests in the laboratory of this setup—which is appropriate for field applications—confirmed the excellent analysis results. However, the field tests concerning the monitoring of the tar in syngas from a woodchip-fueled gasifier demonstrated that the determination of the oxygen demand by the successive estimation of the oxygen concentration with/without tar trapping is not possible with enough accuracy due to continuous variation of the syngas composition. A method is proposed for how this constraint can be overcome.
In asymmetric treatment of hearing loss, processing latencies of the modalities typically differ. This often alters the reference interaural time difference (ITD) (i.e., the ITD at 0° azimuth) by several milliseconds. Such changes in reference ITD have shown to influence sound source localization in bimodal listeners provided with a hearing aid (HA) in one and a cochlear implant (CI) in the contralateral ear. In this study, the effect of changes in reference ITD on speech understanding, especially spatial release from masking (SRM) in normal-hearing subjects was explored. Speech reception thresholds (SRT) were measured in ten normal-hearing subjects for reference ITDs of 0, 1.75, 3.5, 5.25 and 7 ms with spatially collocated (S0N0) and spatially separated (S0N90) sound sources. Further, the cues for separation of target and masker were manipulated to measure the effect of a reference ITD on unmasking by A) ITDs and interaural level differences (ILDs), B) ITDs only and C) ILDs only. A blind equalization-cancellation (EC) model was applied to simulate all measured conditions. SRM decreased significantly in conditions A) and B) when the reference ITD was increased: In condition A) from 8.8 dB SNR on average at 0 ms reference ITD to 4.6 dB at 7 ms, in condition B) from 5.5 dB to 1.1 dB. In condition C) no significant effect was found. These results were accurately predicted by the applied EC-model. The outcomes show that interaural processing latency differences should be considered in asymmetric treatment of hearing loss.
The increase of the Internet of Things (IoT) calls for secure solutions for industrial applications. The security of IoT can be potentially improved by blockchain. However, blockchain technology suffers scalability issues which hinders integration with IoT. Solutions to blockchain’s scalability issues, such as minimizing the computational complexity of consensus algorithms or blockchain storage requirements, have received attention. However, to realize the full potential of blockchain in IoT, the inefficiencies of its inter-peer communication must also be addressed. For example, blockchain uses a flooding technique to share blocks, resulting in duplicates and inefficient bandwidth usage. Moreover, blockchain peers use a random neighbor selection (RNS) technique to decide on other peers with whom to exchange blockchain data. As a result, the peer-to-peer (P2P) topology formation limits the effective achievable throughput. This paper provides a survey on the state-of-the-art network structures and communication mechanisms used in blockchain and establishes the need for network-based optimization. Additionally, it discusses the blockchain architecture and its layers categorizes existing literature into the layers and provides a survey on the state-of-the-art optimization frameworks, analyzing their effectiveness and ability to scale. Finally, this paper presents recommendations for future work.
The significant market growth of stationary electrical energy storage systems both for private and commercial applications has raised the question of battery lifetime under practical operation conditions. Here, we present a study of two 8 kWh lithium-ion battery (LIB) systems, each equipped with 14 lithium iron phosphate/graphite (LFP) single cells in different cell configurations. One system was based on a standard configuration with cells connected in series, including a cell-balancing system and a 48 V inverter. The other system featured a novel configuration of two stacks with a parallel connection of seven cells each, no cell-balancing system, and a 4 V inverter. The two systems were operated as part of a microgrid both in continuous cycling mode between 30% and 100% state of charge, and in solar-storage mode with day–night cycling. The aging characteristics in terms of capacity loss and internal resistance change in the cells were determined by disassembling the systems for regular checkups and characterizing the individual cells under well-defined laboratory conditions. As a main result, the two systems showed cell-averaged capacity losses of 18.6% and 21.4% for the serial and parallel configurations, respectively, after 2.5 years of operation with 810 (serial operation) and 881 (parallel operation) cumulated equivalent full cycles. This is significantly higher than the aging of a reference single cell cycled under laboratory conditions at 20 °C, which showed a capacity loss of only 10% after 1000 continuous full cycles.
To achieve its climate goals, the German industry has to undergo a transformation toward renewable energies. To analyze this transformation in energy system models, the industry’s electricity demands have to be provided in a high temporal and sectoral resolution, which, to date, is not the case due to a lack of open-source data. In this paper, a methodology for the generation of synthetic electricity load profiles is described; it was applied to 11 industry types. The modeling was based on the normalized daily load profiles for eight electrical end-use applications. The profiles were then further refined by using the mechanical processes of different branches. Finally, a fluctuation was applied to the profiles as a stochastic attribute. A quantitative RMSE comparison between real and synthetic load profiles showed that the developed method is especially accurate for the representation of loads from three-shift industrial plants. A procedure of how to apply the synthetic load profiles to a regional distribution of the industry sector completes the methodology.
The lifetime of a battery is affected by various aging processes happening at the electrode scale and causing capacity and power fade over time. Two of the most critical mechanisms are the deposition of metallic lithium (plating) and the loss of lithium inventory to the solid electrolyte interphase (SEI). These side reactions compete with reversible lithium intercalation at the graphite anode. Here we present a comprehensive physicochemical pseudo-3D aging model for a lithium-ion battery cell, which includes electrochemical reactions for SEI formation on graphite anode, lithium plating, and SEI formation on plated lithium. The thermodynamics of the aging reactions are modeled depending on temperature and ion concentration, and the reactions kinetics are described with an Arrhenius-type rate law. The model includes also the positive feedback of plating on SEI growth, with the presence of plated lithium leading to a higher SEI formation rate compared to the values obtained in its absence at the same operating conditions. The model is thus able to describe cell aging over a wide range of temperatures and C-rates. In particular, it allows to quantify capacity loss due to cycling (here in % per year) as function of operating conditions. This allows the visualization of aging colormaps as function of both temperature and C-rate and the identification of critical operation conditions, a fundamental step for a comprehensive understanding of batteries performance and behavior. For example, the model predicts that at the harshest conditions (< –5 °C, > 3 C), aging is reduced compared to most critical conditions (around 0–5 °C) because the cell cannot be fully charged.
Commercial simulators can only reproduce electrocardiograms (ECG) of the normal and diseased heart rhythm in a simplified waveform and with a low number of channels. With the presented project, the variety of digitally archived ECGs, recorded during electrophysiological examinations, should be made usable as original analogue signals for research and teaching purposes by the development of a special printed circuit board for the mini-computer “Raspberry-Pi “.
Heat generation that is coupled with electricity usage, like combined heat and power generators or heat pumps, can provide operational flexibility to the electricity sector. In order to make use of this in an optimized way, the flexibility that can be provided by such plants needs to be properly quantified. This paper proposes a method for quantifying the flexibility provided through a cluster of such heat generators. It takes into account minimum operational time and minimum down-time of heat generating units. Flexibility is defined here as the time period over which plant operation can be either delayed or forced into operation, thus providing upward or downward regulation to the power system on demand. Results for one case study show that a cluster of several smaller heat generation units does not provide much more delayed operation flexibility than one large unit with the same power, while it more than doubles the forced operation flexibility. Considering minimum operational time and minimum down-time of the units considerably limits the available forced and delayed operation flexibility, especially in the case of one large unit.
Occluders made of the shape memory alloy Nitinol are commonly used to close Atrial Septal Defects (ASD). Until now, standard parameters are missing defining the mechanical properties of these implants. In this study,we developed a special measuring setup for the determination of the mechanical properties of customly available occluders (i.e. Occlutech Figulla®Flex II 29ASD12 and AGA AMPLATZER™9-ASD-012
Industrial companies can use blockchain to assist them in resolving their trust and security issues. In this research, we provide a fully distributed blockchain-based architecture for industrial IoT, relying on trust management and reputation to enhance nodes’ trustworthiness. The purpose of this contribution is to introduce our system architecture to show how to secure network access for users with dynamic authorization management. All decisions in the system are made by trustful nodes’ consensus and are fully distributed. The remarkable feature of this system architecture is that the influence of the nodes’ power is lowered depending on their Proof of Work (PoW) and Proof of Stake (PoS), and the nodes’ significance and authority is determined by their behavior in the network.
This impact is based on game theory and an incentive mechanism for reputation between nodes. This system design can be used on legacy machines, which means that security and distributed systems
can be put in place at a low cost on industrial systems. While there are no numerical results yet, this work, based on the open questions regarding the majority problem and the proposed solutions based on a game-theoretic mechanism and a trust management system, points to what and how industrial IoT and existing blockchain frameworks that are focusing only on the power of PoW and PoS can be secured more effectively.
The use of biochar is an important tool to improve soil fertility, reduce the negative environmental impacts of agriculture, and build up terrestrial carbon sinks. However, crop yield increases by biochar amendment were not shown consistently for fertile soils under temperate climate. Recent studies show that biochar is more likely to increase crop yields when applied in combination with nutrients to prepare biochar-based fertilizers. Here, we focused on the root-zone amendment of biochar combined with mineral fertilizers in a greenhouse trial with white cabbage (Brassica oleracea convar. Capitata var. Alba) cultivated in a nutrient-rich silt loam soil originating from the temperate climate zone (Bavaria, Germany). Biochar was applied at a low dosage (1.3 t ha−1). The biochar was placed either as a concentrated hotspot below the seedling or it was mixed into the soil in the root zone representing a mixture of biochar and soil in the planting basin. The nitrogen fertilizer (ammonium nitrate or urea) was either applied on the soil surface or loaded onto the biochar representing a nitrogen-enhanced biochar. On average, a 12% yield increase in dry cabbage heads was achieved with biochar plus fertilizer compared to the fertilized control without biochar. Most consistent positive yield responses were observed with a hotspot root-zone application of nitrogen-enhanced biochar, showing a maximum 21% dry cabbage-head yield increase. Belowground biomass and root-architecture suggested a decrease in the fine root content in these treatments compared to treatments without biochar and with soil-mixed biochar. We conclude that the hotspot amendment of a nitrogen-enhanced biochar in the root zone can optimize the growth of white cabbage by providing a nutrient depot in close proximity to the plant, enabling efficient nutrient supply. The amendment of low doses in the root zone of annual crops could become an economically interesting application option for biochar in the temperate climate zone.
Introduction The use of scaffolds in tissue engineering is becoming increasingly important as solutions need to be found for the problem of preserving human tissue, such as bone or cartilage. In this work, scaffolds were printed from the biomaterial known as polycaprolactone (PCL) on a 3D Bioplotter. Both the external and internal geometry were varied to investigate their influence on mechanical stability and biocompatibility. Materials and Methods: An Envisiontec 3D Bioplotter was used to fabricate the scaffolds. First, square scaffolds were printed with variations in the strand width and strand spacing. Then, the filling structure was varied: either lines, waves, and honeycombs were used. This was followed by variation in the outer shape, produced as either a square, hexagon, octagon, or circle. Finally, the internal and external geometry was varied. To improve interaction with the cells, the printed PCL scaffolds were coated with type-I collagen. MG-63 cells were then cultured on the scaffolds and various tests were performed to investigate the biocompatibility of the scaffolds. Results: With increasing strand thickness and strand spacing, the compressive strengths decreased from 86.18 + 2.34 MPa (200 µm) to 46.38 + 0.52 MPa (600 µm). The circle was the outer shape with the highest compressive strength of 76.07 + 1.49 MPa, compared to the octagon, which had the lowest value of 52.96 ± 0.98 MPa. Varying the external shape (toward roundness) geometry, as well as the filling configuration, resulted in the highest values of compressive strength for the round specimens with honeycomb filling, which had a value of 91.4 + 1.4 MPa. In the biocompatibility tests, the round specimens with honeycomb filling also showed the highest cell count per mm2, with 1591 ± 239 live cells/mm2 after 10 days and the highest value in cell proliferation, but with minimal cytotoxic effects (9.19 ± 2.47% after 3 days).
Lithium-ion batteries exhibit a dynamic voltage behaviour depending nonlinearly on current and state of charge. The modelling of lithium-ion batteries is therefore complicated and model parametrisation is often time demanding. Grey-box models combine physical and data-driven modelling to benefit from their respective advantages. Neural ordinary differential equations (NODEs) offer new possibilities for grey-box modelling. Differential equations given by physical laws and NODEs can be combined in a single modelling framework. Here we demonstrate the use of NODEs for grey-box modelling of lithium-ion batteries. A simple equivalent circuit model serves as a basis and represents the physical part of the model. The voltage drop over the resistor–capacitor circuit, including its dependency on current and state of charge, is implemented as a NODE. After training, the grey-box model shows good agreement with experimental full-cycle data and pulse tests on a lithium iron phosphate cell. We test the model against two dynamic load profiles: one consisting of half cycles and one dynamic load profile representing a home-storage system. The dynamic response of the battery is well captured by the model.
Lithium-ion batteries exhibit a well-known trade-off between energy and power, which is problematic for electric vehicles which require both high energy during discharge (high driving range) and high power during charge (fast-charge capability). We use two commercial lithium-ion cells (high-energy [HE] and high-power) to parameterize and validate physicochemical pseudo-two-dimensional models. In a systematic virtual design study, we vary electrode thicknesses, cell temperature, and the type of charging protocol. We are able to show that low anode potentials during charge, inducing lithium plating and cell aging, can be effectively avoided either by using high temperatures or by using a constant-current/constant-potential/constant-voltage charge protocol which includes a constant anode potential phase. We introduce and quantify a specific charging power as the ratio of discharged energy (at slow discharge) and required charging time (at a fast charge). This value is shown to exhibit a distinct optimum with respect to electrode thickness. At 35°C, the optimum was achieved using an HE electrode design, yielding 23.8 Wh/(min L) volumetric charging power at 15.2 min charging time (10% to 80% state of charge) and 517 Wh/L discharge energy density. By analyzing the various overpotential contributions, we were able to show that electrolyte transport losses are dominantly responsible for the insufficient charge and discharge performance of cells with very thick electrodes.
Jürgen Zierep passed away on July 29, 2021, at the age of 92. To him, science and education was not only a profession, but an affair of the heart. His impressive contributions in fluid mechanics comprise about 200 scientific publications in the fields of gas dynamics, similarity laws, flow instabilities, flows with energy transfer, and non-Newtonian fluids. In addition, he wrote eleven textbooks with great dedication. Those books by the “scientist who loves to teach” are nowadays available in different languages and regularly appear in new editions.
Electrochemical pressure impedance spectroscopy (EPIS) has recently been developed as a potential diagnosis tool for polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of the cell voltage with respect to an excitation of the gas-phase pressure. We present here a combined modeling and experimental study of EPIS. A pseudo-twodimensional PEMFC model was parameterized to a 100 cm2 laboratory cell installed in its test bench, and used to reproduce steady-state cell polarization and electrochemical impedance spectra (EIS). Pressure impedance spectra were obtained both in experiment and simulation by applying a harmonic pressure excitation at the cathode outlet. The model shows good agreement with experimental data for current densities ⩽ 0.4 A cm−2. Here it allows a further simulative analysis of observed EPIS features, including the magnitude and shape of spectra. Key findings include a strong influence of the humidifier gas volume on EPIS and a substantial increase in oxygen partial pressure oscillations towards the channel outlet at the resonance frequency. At current densities ⩾ 0.8 A cm−2 the experimental EIS and EPIS data cannot be fully reproduced. This deviation might be associated with the formation and transport of liquid water, which is not included in the model.
Significant progress in the development and commercialization of electrically conductive adhesives has been made. This makes shingling a very attractive approach for solar cell interconnection. In this study, we investigate the shading tolerance of two types of solar modules based on shingle interconnection: first, the already commercialized string approach, and second, the matrix technology where solar cells are intrinsically interconnected in parallel and in series. An experimentally validated LTspice model predicts major advantages for the power output of the matrix layout under partial shading. Diagonal as well as random shading of a 1.6-m2 solar module is examined. Power gains of up to 73.8 % for diagonal shading and up to 96.5 % for random shading are found for the matrix technology compared to the standard string approach. The key factor is an increased current extraction due to lateral current flows. Especially under minor shading, the matrix technology benefits from an increased fill factor as well. Under diagonal shading, we find the probability of parts of the matrix module being bypassed to be reduced by 40 % in comparison to the string module. In consequence, the overall risk of hotspot occurrence in matrix modules is decreased significantly.
A versatile liquid metal (LM) printing process enabling the fabrication of various fully printed devices such as intra- and interconnect wires, resistors, diodes, transistors, and basic circuit elements such as inverters which are process compatible with other digital printing and thin film structuring methods for integration is presented. For this, a glass capillary-based direct-write method for printing LMs such as eutectic gallium alloys, exploring the potential for fully printed LM-enabled devices is demonstrated. Examples for successful device fabrication include resistors, p–n diodes, and field effect transistors. The device functionality and easiness of one integrated fabrication flow shows that the potential of LM printing is far exceeding the use of interconnecting conventional electronic devices in printed electronics.
Objective: To quantify the effect of inhaled 5% carbon-dioxide/95% oxygen on EEG recordings from patients in non-convulsive status epilepticus (NCSE).
Methods: Five children of mixed aetiology in NCSE were given high flow of inhaled carbogen (5% carbon dioxide/95% oxygen) using a face mask for maximum 120s. EEG was recorded concurrently in all patients. The effects of inhaled carbogen on patient EEG recordings were investigated using band-power, functional connectivity and graph theory measures. Carbogen effect was quantified by measuring effect size (Cohen's d) between "before", "during" and "after" carbogen delivery states.
Results: Carbogen's apparent effect on EEG band-power and network metrics across all patients for "before-during" and "before-after" inhalation comparisons was inconsistent across the five patients.
Conclusion: The changes in different measures suggest a potentially non-homogeneous effect of carbogen on the patients' EEG. Different aetiology and duration of the inhalation may underlie these non-homogeneous effects. Tuning the carbogen parameters (such as ratio between CO2 and O2, duration of inhalation) on a personalised basis may improve seizure suppression in future.
Purpose: Participation and accessibility issues faced by gamers with multi-sensory disabilities are themes yet to be fully understood by accessible technology researchers. In this work, we examine the personal experiences and perceptions of individuals with deafblindness who play games despite their disability, as well as the reasons that lead some of them to stop playing games.
Materials and methods: We conducted 60 semi-structured interviews with individuals living with deafblindness in five European countries: United Kingdom, Germany, Netherlands, Greece and Sweden.
Results: Participants stated that reasons for playing games included them being a fun and entertaining hobby, for socialization and meeting others, or for occupying the mind. Reasons for stop playing games included essentially accessibility issues, followed by high cognitive demand, changes in gaming experience due their disability, financial reasons, or because the accessible version of a specific game was not considered as fun as the original one.
Conclusions: We identified that a considerable number of individuals with deafblindness enjoy playing casual mobile games such as Wordfeud and Sudoku as a pastime activity. Despite challenging accessibility issues, games provide meaningful social interactions to players with deafblindness. Finally, we introduce a set of user-driven recommendations for making digital games more accessible to players with a diverse combination of sensory abilities.
IMPLICATIONS FOR REHABILITATION
- Digital games were considered a fun and entertaining hobby by participants with deafblindness. Furthermore, participants play games for socialization and meeting others, or for occupying the mind.
- Digital games provide meaningful social interactions and past time to persons with deafblindness.
- On top of accessibility implications, our findings draw attention to the importance of the social element of gaming for persons with deafblindness.
- Based on interviews, we introduce a set of user-driven recommendations for making digital games more accessible to players with a diverse combination of sensory abilities.
Emerging applications in soft robotics, wearables, smart consumer products or IoT-devices benefit from soft materials, flexible substrates in conjunction with electronic functionality. Due to high production costs and conformity restrictions, rigid silicon technologies do not meet application requirements in these new domains. However, whenever signal processing becomes too comprehensive, silicon technology must be used for the high-performance computing unit. At the same time, designing everything in flexible or printed electronics using conventional digital logic is not feasible yet due to the limitations of printed technologies in terms of performance, power and integration density. We propose to rather use the strengths of neuromorphic computing architectures consisting in their homogeneous topologies, few building blocks and analog signal processing to be mapped to an inkjet-printed hardware architecture. It has remained a challenge to demonstrate non-linear elements besides weighted aggregation. We demonstrate in this work printed hardware building blocks such as inverter-based comprehensive weight representation and resistive crossbars as well as printed transistor-based activation functions. In addition, we present a learning algorithm developed to train the proposed printed NCS architecture based on specific requirements and constraints of the technology.
The compliant nature of distal limb muscle-tendon units is traditionally considered suboptimal in explosive movements when positive joint work is required. However, during accelerative running, ankle joint net mechanical work is positive. Therefore, this study aims to investigate how plantar flexor muscle-tendon behavior is modulated during fast accelerations. Eleven female sprinters performed maximum sprint accelerations from starting blocks, while gastrocnemius muscle fascicle lengths were estimated using ultrasonography. We combined motion analysis and ground reaction force measurements to assess lower limb joint kinematics and kinetics, and to estimate gastrocnemius muscle-tendon unit length during the first two acceleration steps. Outcome variables were resampled to the stance phase and averaged across three to five trials. Relevant scalars were extracted and analyzed using one-sample and two-sample t-tests, and vector trajectories were compared using statistical parametric mapping. We found that an uncoupling of muscle fascicle behavior from muscle-tendon unit behavior is effectively used to produce net positive mechanical work at the joint during maximum sprint acceleration. Muscle fascicles shortened throughout the first and second steps, while shortening occurred earlier during the first step, where negative joint work was lower compared with the second step. Elastic strain energy may be stored during dorsiflexion after touchdown since fascicles did not lengthen at the same time to dissipate energy. Thus, net positive work generation is accommodated by the reuse of elastic strain energy along with positive gastrocnemius fascicle work. Our results show a mechanism of how muscles with high in-series compliance can contribute to net positive joint work.
This work aimed to determine the influence of two hydrogels (alginate, alginate-di-aldehyde (ADA)/gelatin) on the mechanical strength of microporous ceramics, which have been loaded with these hydrogels. For this purpose, the compressive strength was determined using a Zwick Z005 universal testing machine. In addition, the degradation behavior according to ISO EN 10993-14 in TRIS buffer pH 5.0 and pH 7.4 over 60 days was determined, and its effects on the compressive strength were investigated. The loading was carried out by means of a flow-chamber. The weight of the samples (manufacturer: Robert Mathys Foundation (RMS) and Curasan) in TRIS solutions pH 5 and pH 7 increased within 4 h (mean 48 ± 32 mg) and then remained constant over the experimental period of 60 days. The determination surface roughness showed a decrease in the value for the ceramics incubated in TRIS compared to the untreated ceramics. In addition, an increase in protein concentration in solution was determined for ADA gelatin-loaded ceramics. The macroporous Curasan ceramic exhibited a maximum failure load of 29 ± 9.0 N, whereas the value for the microporous RMS ceramic was 931 ± 223 N. Filling the RMS ceramic with ADA gelatin increased the maximum failure load to 1114 ± 300 N. The Curasan ceramics were too fragile for loading. The maximum failure load decreased for the RMS ceramics to 686.55 ± 170 N by incubation in TRIS pH 7.4 and 651 ± 287 N at pH 5.0.
Introduction: The use of scaffolds in tissue engineering is becoming increasingly important as solutions need to be found to preserve human tissues such as bone or cartilage. Various factors, including cells, biomaterials, cell and tissue culture conditions, play a crucial role in tissue engineering. The in vivo environment of the cells exerts complex stimuli on the cells, thereby directly influencing cell behavior, including proliferation and differentiation. Therefore, to create suitable replacement or regeneration procedures for human tissues, the conditions of the cells’ natural environment should be well mimicked. Therefore, current research is trying to develop 3-dimensional scaffolds (scaffolds) that can elicit appropriate cellular responses and thus help the body regenerate or replace tissues. In this work, scaffolds were printed from the biomaterial polycaprolactone (PCL) on a 3D bioplotter. Biocompatibility testing was used to determine whether the printed scaffolds were suitable for use in tissue engineering.
Material and Methods: An Envisiontec 3D bioplotter was used to fabricate the scaffolds. For better cell-scaffold interaction, the printed polycaprolactone scaffolds were coated with type-I collagen. Three different cell types were then cultured on the scaffolds and various tests were used to investigate the biocompatibility of the scaffolds.
Results: Reproducible scaffolds could be printed from polycaprolactone. In addition, a coating process with collagen was developed, which significantly improved the cell-scaffold interaction. Biocompatibility tests showed that the PCL-collagen scaffolds are suitable for use with cells. The cells adhered to the surface of the scaffolds and as a result extensive cell growth was observed on the scaffolds. The inner part of the scaffolds, however, remained largely uninhabited. In the cytotoxicity studies, it was found that toxicity below 20% was present in some experimental runs. The determination of the compressive strength by means of the universal testing machine Z005 by ZWICK according to DIN EN ISO 604 of the scaffolds resulted in a value of 68.49 ± 0.47 MPa.
Surface acoustic waves are propagated toward the edge of an anisotropic elastic medium (a silicon crystal), which supports leaky waves with a high degree of localization at the tip of the edge. At an angle of incidence corresponding to phase matching with this leaky wedge wave, a sharp peak in the reflection coefficient of the surface wave was found. This anomalous reflection is associated with efficient excitation of the leaky wedge wave. In laser ultrasound experiments, surface acoustic wave pulses were excited and their reflection from the edge of the sample and their partial conversion into leaky wedge wave pulses was observed by optical probe-beam deflection. The reflection scenario and the pulse shapes of the surface and wedge-localized guided waves, including the evolution of the acoustic pulse traveling along the edge, have been confirmed in detail by numerical simulations.